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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

(Trimethylsilyl)methyllithium Manufacturer/High quality/Best price/In stock

Cas:1822-00-0

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

[(Trimethylsilyl)-methyl]-lithium

Cas:1822-00-0

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top CAS 1822-00-0 with fast shipping

Cas:1822-00-0

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

(TRIMETHYLSILYL)METHYLLITHIUM CAS:1822-00-0

Cas:1822-00-0

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Lithium,[(trimethylsilyl)methyl]- 1822-00-0

Cas:1822-00-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Factory Supply High Quality CAS 1822-00-0 (TRIMETHYLSILYL)METHYLLITHIUM

Cas:1822-00-0

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

(TRIMETHYLSILYL)METHYLLITHIUM CAS:1822-00-0 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality orga

(TRIMETHYLSILYL)METHYLLITHIUM CAS:1822-00-0

Cas:1822-00-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Lithium,[(trimethylsilyl)methyl]-

Cas:1822-00-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Lithium,[(trimethylsilyl)methyl]-

Cas:1822-00-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

(TRIMETHYLSILYL)METHYLLITHIUM

Cas:1822-00-0

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

(TRIMETHYLSILYL)METHYLLITHIUM

Cas:1822-00-0

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

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Saiwante (shanghai) New Material Technology Co., Ltd.

Melting Point:112-117 °C (decomp) Boiling Point:35-36 °C Flash Point:-49 °C PSA:0.00000 Density:0.65 g/mL at 25 °C LogP:1.83140 Storage Temp.:2-8°C Solubility.:Sol ethereal solvents; reacts with protic solvents.

1822-00-0 (Trimethylsilyl)methyllithium Fast Delivery

Cas:1822-00-0

Min.Order:1 Gram

FOB Price: $6.0

Type:Trading Company

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Lithium,[(trimethylsilyl)methyl]-

Cas:1822-00-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

(Trimethylsilyl)methyllithium Manufacturer

Cas:1822-00-0

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

Buy 1822-00-0 C4H11LiSi (TRIMETHYLSILYL)METHYLLITHIUM

Cas:1822-00-0

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality Appearance:Clear light yellow liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Initiates polymerization and copolymerizatio

TRIMETHYLSILYL)METHYLLITHIUM

Cas:1822-00-0

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providing h

Factory Supply (TRIMETHYLSILYL)METHYLLITHIUM

Cas:1822-00-0

Min.Order:0

Negotiable

Type:Other

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

1822-00-0 (TRIMETHYLSILYL)METHYLLITHIUM

Cas:1822-00-0

Min.Order:1 Kilogram

FOB Price: $1000.0

Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

(TRIMETHYLSILYL)METHYLLITHIUM Basic information Product Name: (TRIMETHYLSILYL)METHYLLITHIUM Synonyms: (TRIMETHYLSILYLMETHYL)LITHIUM , 1.0M SOL UTION IN PENTANE;Lithium, (trimethylsilyl)methyl-;Lithio(trimethylsilyl)methane;Lithiomethyltrimethy

(TRIMETHYLSILYL)METHYLLITHIUM

Cas:1822-00-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

(TRIMETHYLSILYL)METHYLLITHIUM

Cas:1822-00-0

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

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Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Buy 1822-00-0 C4H11LiSi (TRIMETHYLSILYL)METHYLLITHIUM

Cas:1822-00-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Buy 1822-00-0 C4H11LiSi (TRIMETHYLSILYL)METHYLLITHIUM

Cas:1822-00-0

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

(TRIMETHYLSILYL)METHYLLITHIUM

Cas:1822-00-0

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

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Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

Trimethylsilyl Methyl Lithium cas no. 1822-00-0 98%

Cas:1822-00-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou Dingyan Chem Co., Ltd

Hangzhou Dingyan Chem is a leading manufacturer and supplier of chemicals in China.We develop,produce and distribute high quality pharmaceuticals, intermediates, special chemicals and other fine chemicals. We could give you: 1.Best qualit

(TRIMETHYLSILYL)METHYLLITHIUM

Cas:1822-00-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

(Trimethylsilyl)methyl lithium

Cas:1822-00-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

(TRIMETHYLSILYL)METHYLLITHIUM

Cas:1822-00-0

Min.Order:0

Negotiable

Type:Other

inquiry

JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

(Trimethylsilyl)Methyllithium

Cas:1822-00-0

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec (Trimethylsilyl)methyllithium 500ml

Cas:1822-00-0

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

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Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

(TriMethylsilyl)MethyllithiuM solution in Hexane

Cas:1822-00-0

Min.Order:0

Negotiable

Type:Manufacturers

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Synthetic route

lithium
7439-93-2

lithium

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

Conditions
ConditionsYield
In pentane95%
In pentane95%
In pentane at 40℃; for 16h; Argon gasification;80%
iodo(trimethylsilyl)methane
4206-67-1

iodo(trimethylsilyl)methane

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

Conditions
ConditionsYield
With tert.-butyl lithium In diethyl ether -78 deg C, 0.5-1h, warmed to 23 deg C in 0.5-1h;90 % Spectr.
(trimethylsilyl)(tributylstannyl)methane
77425-85-5

(trimethylsilyl)(tributylstannyl)methane

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran at 0℃; for 0.5h;
Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

Conditions
ConditionsYield
With lithium In pentane for 10h; Heating;700 mg
With lithium In n-heptane at 55 - 60℃; for 5h;
With lithium In hexane for 0.5 - 1.5h; Heating / reflux;
Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

pentane
109-66-0

pentane

lithium

lithium

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

C8H12*Rh(1+)*2(CH3)3SiCH2(1-)*Li(1+)=(C8H12)Rh(CH2Si(CH3)3)2Li

C8H12*Rh(1+)*2(CH3)3SiCH2(1-)*Li(1+)=(C8H12)Rh(CH2Si(CH3)3)2Li

neopentyl lithium
7412-67-1

neopentyl lithium

A

C8H12*Rh(1+)*2(CH3)3CCH2(1-)*Li(1+)=(C8H12)Rh(CH2C(CH3)3)2Li

C8H12*Rh(1+)*2(CH3)3CCH2(1-)*Li(1+)=(C8H12)Rh(CH2C(CH3)3)2Li

B

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

Conditions
ConditionsYield
In not given under N2 or Ar, at room temp. in either PhMe-d8 or THF-d8; not isolated; monitored by NMR;
trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

(-)-methyl (3S)-3,5-bis{[tert-butyl(dimethyl)silyl]oxy}-2,2-dimethylpentanoate
218614-13-2

(-)-methyl (3S)-3,5-bis{[tert-butyl(dimethyl)silyl]oxy}-2,2-dimethylpentanoate

(4S)-4,6-bis{[tert-butyl(dimethyl)silyl]oxy}-3,3-dimethylhexan-2-one
218614-14-3

(4S)-4,6-bis{[tert-butyl(dimethyl)silyl]oxy}-3,3-dimethylhexan-2-one

Conditions
ConditionsYield
In pentane at 0℃; for 3.5h;100%
Stage #1: trimethylsilylmethyllithium; (-)-methyl (3S)-3,5-bis{[tert-butyl(dimethyl)silyl]oxy}-2,2-dimethylpentanoate In pentane at 0℃; for 4h;
Stage #2: With methanol at 20℃; for 1h; Further stages.;
97%
With methanol 1.) pentane, 0 deg C, 4 h; 2.) r.t., 1 h; Yield given. Multistep reaction;
With methanol Substitution;
trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

(-)-methyl (3S)-3,5-bis{[tert-butyl(dimethyl)silyl]oxy}-2,2-dimethylpentanoate
218614-13-2

(-)-methyl (3S)-3,5-bis{[tert-butyl(dimethyl)silyl]oxy}-2,2-dimethylpentanoate

4,6-bis-(tert-butyl-dimethyl-silanyloxy)-3,3-dimethyl-1-trimethylsilanyl-hexan-2-one

4,6-bis-(tert-butyl-dimethyl-silanyloxy)-3,3-dimethyl-1-trimethylsilanyl-hexan-2-one

Conditions
ConditionsYield
Stage #1: trimethylsilylmethyllithium; (-)-methyl (3S)-3,5-bis{[tert-butyl(dimethyl)silyl]oxy}-2,2-dimethylpentanoate In pentane at 0℃; for 3.25h;
Stage #2: With methanol In pentane at 0 - 20℃; for 5h;
100%
4,6,6-trimethyl-5,6,7,7a-tetrahydro-1,3-benzodioxol-5-one

4,6,6-trimethyl-5,6,7,7a-tetrahydro-1,3-benzodioxol-5-one

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

4,6,6-trimethyl-5,6,7,7a-tetrahydro-5-trimethylsilylmethyl-1,3-benzodioxol-5-ol

4,6,6-trimethyl-5,6,7,7a-tetrahydro-5-trimethylsilylmethyl-1,3-benzodioxol-5-ol

Conditions
ConditionsYield
Stage #1: 4,6,6-trimethyl-5,6,7,7a-tetrahydro-1,3-benzodioxol-5-one; trimethylsilylmethyllithium In tetrahydrofuran; pentane at -20 - 20℃; for 0.666667h; Argon gasification;
Stage #2: With water In tetrahydrofuran; pentane
100%
4,6,6-trimethyl-5,6,7,7a-tetrahydro-1,3-benzodioxol-5-one

4,6,6-trimethyl-5,6,7,7a-tetrahydro-1,3-benzodioxol-5-one

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

Chloromethyltrimethylsilane
2344-80-1

Chloromethyltrimethylsilane

lithium hydride
7580-67-8

lithium hydride

4,6,6-trimethyl-5,6,7,7a-tetrahydro-5-trimethylsilylmethyl-1,3-benzodioxol-5-ol

4,6,6-trimethyl-5,6,7,7a-tetrahydro-5-trimethylsilylmethyl-1,3-benzodioxol-5-ol

Conditions
ConditionsYield
In tetrahydrofuran; water; pentane100%
Ti(N(C(CD3)2CH3)C6H3(CH3)2)(OC6H3(CH(CH3)2)2)I2
181037-28-5

Ti(N(C(CD3)2CH3)C6H3(CH3)2)(OC6H3(CH(CH3)2)2)I2

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

Ti(N(C(CD3)2CH3)C6H3(CH3)2)(OC6H3(CH(CH3)2)2)(CH2Si(CH3)3)I

Ti(N(C(CD3)2CH3)C6H3(CH3)2)(OC6H3(CH(CH3)2)2)(CH2Si(CH3)3)I

Conditions
ConditionsYield
In hexane stirring (-35°C, 20 min); filtering, pptn. on concg.;100%
N-benzylidene-1,1,1-trimethylsilanamine
17599-61-0

N-benzylidene-1,1,1-trimethylsilanamine

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

1-phenyl-2-(trimethylsilyl)ethanamine
71354-69-3

1-phenyl-2-(trimethylsilyl)ethanamine

Conditions
ConditionsYield
Stage #1: N-benzylidene-1,1,1-trimethylsilanamine; trimethylsilylmethyllithium In tetrahydrofuran; pentane at 0℃; for 2.16667h; Inert atmosphere;
Stage #2: With hydrogenchloride; water In tetrahydrofuran; pentane
100%
trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

[(trimethylsilyl)methyl]sodium
53127-81-4

[(trimethylsilyl)methyl]sodium

Conditions
ConditionsYield
With sodium t-butanolate In pentane at -35 - 20℃; for 2h;100%
With sodium t-butanolate In hexane; pentane at 20℃; Inert atmosphere;86.4%
With sodium t-butanolate In hexane; pentane at 0 - 20℃; Schlenk technique;82%
C44H45ClN4Ni

C44H45ClN4Ni

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

C48H56N4NiSi

C48H56N4NiSi

Conditions
ConditionsYield
In pentane; benzene at 20℃; for 0.5h; Cooling;100%
2,5-dimethoxybicyclo[4.2.0]octa-1,3,5-trien-7-one
75833-45-3

2,5-dimethoxybicyclo[4.2.0]octa-1,3,5-trien-7-one

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

1-trimethylsilylmethyl-3,6-dimethoxybenzocyclobuten-1-ol

1-trimethylsilylmethyl-3,6-dimethoxybenzocyclobuten-1-ol

Conditions
ConditionsYield
In tetrahydrofuran; pentane at -78℃; for 0.0833333h;99%
trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

2-<<4-bromo-2-<(tert-butyldimethylsilyl)oxy>-5-methoxyphenyl>methyl>-5,5-dimethylcyclohexan-1-one
175883-01-9

2-<<4-bromo-2-<(tert-butyldimethylsilyl)oxy>-5-methoxyphenyl>methyl>-5,5-dimethylcyclohexan-1-one

2-[4-Bromo-2-(tert-butyl-dimethyl-silanyloxy)-5-methoxy-benzyl]-3,3-dimethyl-1-trimethylsilanylmethyl-cyclohexanol

2-[4-Bromo-2-(tert-butyl-dimethyl-silanyloxy)-5-methoxy-benzyl]-3,3-dimethyl-1-trimethylsilanylmethyl-cyclohexanol

Conditions
ConditionsYield
In tetrahydrofuran; pentane at -78℃;99%
trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

1-adamantan-1-yl-2-ethoxy-propenone
749888-12-8

1-adamantan-1-yl-2-ethoxy-propenone

2-adamantan-1-yl-3-ethoxy-1-trimethylsilanyl-but-3-en-2-ol
749888-28-6

2-adamantan-1-yl-3-ethoxy-1-trimethylsilanyl-but-3-en-2-ol

Conditions
ConditionsYield
Stage #1: trimethylsilylmethyllithium With cerium(III) chloride In toluene; pentane at -78℃; for 1h;
Stage #2: 1-adamantan-1-yl-2-ethoxy-propenone In toluene; pentane at -78℃; for 2h;
99%
bis(n-butylcyclopentadienyl)hafnium dichloride

bis(n-butylcyclopentadienyl)hafnium dichloride

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

(n-BuCp)2Hf(CH2SiMe3)2

(n-BuCp)2Hf(CH2SiMe3)2

Conditions
ConditionsYield
In toluene at 0 - 20℃; for 5.01667h;99%
[bis(2,6-diisopropylphenylimino-κN,N'-ethyl)pyridine-κN]CoCl
392292-96-5

[bis(2,6-diisopropylphenylimino-κN,N'-ethyl)pyridine-κN]CoCl

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

2,6-[2,6-(iPr)2C6H3NCMe]2C5H3NCoCH2SiMe3
404876-80-8

2,6-[2,6-(iPr)2C6H3NCMe]2C5H3NCoCH2SiMe3

Conditions
ConditionsYield
In toluene N2, standard Schlenk techniques, mixed, stirred for 10 min room temp.; filtered over celite, evapd. to dryness in vac., elem. anal.;99%
[TaCl3(2,3,5,6-tetraphenylphenoxide)2]
182256-01-5

[TaCl3(2,3,5,6-tetraphenylphenoxide)2]

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

Ta(OC6H(C6H5)4)2(CH2Si(CH3)3)3

Ta(OC6H(C6H5)4)2(CH2Si(CH3)3)3

Conditions
ConditionsYield
In benzene 25°C;99%
[(η(5)-C5H4(CH2)2P(H)(2,4,6-trimethylphenyl)-κP)ZrCl3(tetrahydrothiophene)]
389123-76-6

[(η(5)-C5H4(CH2)2P(H)(2,4,6-trimethylphenyl)-κP)ZrCl3(tetrahydrothiophene)]

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

[(η(5)-C5H4(CH2)2P(H)(2,4,6-trimethylphenyl))Zr(CH2SiMe3)3]
502966-58-7

[(η(5)-C5H4(CH2)2P(H)(2,4,6-trimethylphenyl))Zr(CH2SiMe3)3]

Conditions
ConditionsYield
In not given99%
Sc(C5H4NCCH3(CH2NSi(CH3)3)2)Cl(C4H8O)
526199-98-4

Sc(C5H4NCCH3(CH2NSi(CH3)3)2)Cl(C4H8O)

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

Sc(C5H4NCCH3(CH2NSi(CH3)3)2)CH2Si(CH3)3(C4H8O)
526200-01-1

Sc(C5H4NCCH3(CH2NSi(CH3)3)2)CH2Si(CH3)3(C4H8O)

Conditions
ConditionsYield
In benzene-d6 the soln. of complex and Li-compound in C6D6 were mixed in NMR tube, 30 min (inert atm.); not sepd., detected by NMR spectra;99%
[η(2),η(1)-Me3SiNC(Ph)N(CH2)3NMe]TiCl2

[η(2),η(1)-Me3SiNC(Ph)N(CH2)3NMe]TiCl2

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

[η(2),η(1)-Me3SiNC(Ph)N(CH2)3NMe]Ti(CH2SiMe3)2

[η(2),η(1)-Me3SiNC(Ph)N(CH2)3NMe]Ti(CH2SiMe3)2

Conditions
ConditionsYield
In pentane all manipulations under purified N2; pentane condensed into vessel containing solid mixt. of Ti and Li compds., frozen in liq. N2, allowed to warm to -15°C, stirred for 2 h; filtered, extd. with pentane, volatiles removed in vac., recrystd., elem. anal.;99%
RhCl[2,6-bis(1-(2,6-diisopropylphenyl)iminoethyl)pyridine]
314733-86-3

RhCl[2,6-bis(1-(2,6-diisopropylphenyl)iminoethyl)pyridine]

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

[Rh(CH2Si(CH3)3)(C5H3N(C(CH3)N(C6H3(CH(CH3)2)2))2)]
756876-44-5

[Rh(CH2Si(CH3)3)(C5H3N(C(CH3)N(C6H3(CH(CH3)2)2))2)]

Conditions
ConditionsYield
In toluene; pentane under inert atm. mixt. Rh complex and Me3SiCH2Li in toluene-pentane was stirred for 24 h; soln. was filtered and dried in vacuo, residue was extd. with hexane, solvent was removed in vacuo;99%
In toluene; pentane under Ar, Schlenk setup, pentane/toluene soln. of ligand added to metalcompd. (2:1), stirred for 1 d; filtered, evapd.;
TaCl3(OC6H(CH3)2(C6H5)2)2
182256-06-0

TaCl3(OC6H(CH3)2(C6H5)2)2

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

Ta(CH2Si(CH3)3)3(OC6H(CH3)2(C6H5)2)2

Ta(CH2Si(CH3)3)3(OC6H(CH3)2(C6H5)2)2

Conditions
ConditionsYield
In benzene 25°C;99%
Ta(2,6-diphenylphenoxide)2Cl3
116642-99-0

Ta(2,6-diphenylphenoxide)2Cl3

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

Ta(CH2Si(CH3)3)3(OC6H3(C6H5)2)2

Ta(CH2Si(CH3)3)3(OC6H3(C6H5)2)2

Conditions
ConditionsYield
In benzene 25°C;99%
(N-[2-P(CHMe2)2-4-methylphenyl]2(1-))Ti=CH(t)Bu(triflate)

(N-[2-P(CHMe2)2-4-methylphenyl]2(1-))Ti=CH(t)Bu(triflate)

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

(N-[2-P(CHMe2)2-4-methylphenyl]2(1-))Ti=CDSiMe3(C6D5)
871558-40-6

(N-[2-P(CHMe2)2-4-methylphenyl]2(1-))Ti=CDSiMe3(C6D5)

Conditions
ConditionsYield
In benzene-d6 byproducts: CH3Bu-t; at 40°C for 24 h;99%
[ZrCl3(κ3-N2P-(tert-butyl)NSiMe2N(CH2CH2P(i-Pr)2)2)]
1001195-98-7

[ZrCl3(κ3-N2P-(tert-butyl)NSiMe2N(CH2CH2P(i-Pr)2)2)]

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

[Zr(CH2SiMe3)3((tert-butyl)NSiMe2N(CH2CH2P(i-Pr)2)2)]

[Zr(CH2SiMe3)3((tert-butyl)NSiMe2N(CH2CH2P(i-Pr)2)2)]

Conditions
ConditionsYield
In toluene byproducts: LiCl; using Schlenk techniques; addn. soln. of LiCH2SiMe3 (3 equiv.) to soln. of ZrCl3((t-Bu)NSiMe2N(CH2CH2P(i-Pr)2)2) in toluene at -40°C; warming to room temp.; stirring for 3 h; removal of volatile material under vac., extn. with pentane; removal of solvent under vac.;99%
(E)-2-(2-methoxyethenyl)naphthalene

(E)-2-(2-methoxyethenyl)naphthalene

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

2-[(1E)-3-(trimethylsilyl)-1-propen-1-yl]naphthalene
623582-16-1

2-[(1E)-3-(trimethylsilyl)-1-propen-1-yl]naphthalene

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)nickel (0) In toluene; pentane at 60℃; for 2h; Reagent/catalyst; Solvent; Temperature; Inert atmosphere; Sealed tube; stereospecific reaction;99%
trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

1-(2-naphthalenyl)-1-(trimethylsilyloxy)ethylene
52119-18-3

1-(2-naphthalenyl)-1-(trimethylsilyloxy)ethylene

[2-(naphthalene-2-yl)allyl]trimethylsilane

[2-(naphthalene-2-yl)allyl]trimethylsilane

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)nickel (0) In toluene; pentane at 60℃; for 2h; Inert atmosphere; Sealed tube; stereospecific reaction;99%
[scandium(III)(chloride)3(tetrahydrofuran)3]
53317-83-2, 14782-78-6

[scandium(III)(chloride)3(tetrahydrofuran)3]

C11H19BN(1-)*Li(1+)

C11H19BN(1-)*Li(1+)

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

C23H49BNOScSi2

C23H49BNOScSi2

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.25h;99%
2-Methoxynaphthalene
93-04-9

2-Methoxynaphthalene

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

trimethyl(naphthalen-2-ylmethyl)silane
27016-35-9

trimethyl(naphthalen-2-ylmethyl)silane

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)nickel (0) In toluene; pentane at 50℃; for 2h; Reagent/catalyst; Solvent; Temperature; Inert atmosphere; Schlenk technique; Sealed tube;99%
With bis(1,5-cyclooctadiene)nickel (0); sodium t-butanolate; tricyclohexylphosphine In toluene at 80℃; for 12h; Inert atmosphere; Schlenk technique; Glovebox;76%
(6-methoxynaphthalen-2-yl)trimethylsilane
18410-39-4

(6-methoxynaphthalen-2-yl)trimethylsilane

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

trimethyl(6-((trimethylsilyl)methyl)naphthalen-2-yl)silane

trimethyl(6-((trimethylsilyl)methyl)naphthalen-2-yl)silane

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)nickel (0) In toluene; pentane at 50℃; for 2h; Inert atmosphere; Schlenk technique; Sealed tube;99%
2-(4-methoxyphenyl)naphthalene
59115-45-6

2-(4-methoxyphenyl)naphthalene

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

trimethyl(4-(naphthalen-2-yl)benzyl)silane

trimethyl(4-(naphthalen-2-yl)benzyl)silane

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)nickel (0) In toluene; pentane at 80℃; for 2h; Inert atmosphere; Schlenk technique; Sealed tube;99%
4-methoxylbiphenyl
613-37-6

4-methoxylbiphenyl

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

([1,1'-biphenyl]-4-ylmethyl)trimethylsilane
81309-60-6

([1,1'-biphenyl]-4-ylmethyl)trimethylsilane

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)nickel (0) In toluene; pentane at 80℃; for 2h; Inert atmosphere; Schlenk technique; Sealed tube;99%
2-(4-chlorophenyl)naphthalene
28396-55-6

2-(4-chlorophenyl)naphthalene

trimethylsilylmethyllithium
1822-00-0

trimethylsilylmethyllithium

trimethyl(4-(naphthalen-2-yl)benzyl)silane

trimethyl(4-(naphthalen-2-yl)benzyl)silane

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)nickel (0); 1,2-bis-(diphenylphosphino)ethane In toluene; pentane at 80℃; for 2h; Sealed tube; Inert atmosphere;99%
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