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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Perillaldehyde Manufacturer/High quality/Best price/In stock

Cas:2111-75-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality Food Grade Perillaldehyde HACCP Manufacturer

Cas:2111-75-3

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Perillaldehyde

Cas:2111-75-3

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Leader Biochemical Group

About Product Technical Details (-)-PERILLALDEHYDE Chemical Properties Melting point <25 °C Boiling point 104-105 °C10

China Largest factory Manufacturer Supply L-perillaldehyde CAS 2111-75-3

Cas:2111-75-3

Min.Order:1 Kilogram

FOB Price: $1.0 / 3.0

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

(-)-PERILLALDEHYDE

Cas:2111-75-3

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

C10H14O (-)-PERILLALDEHYDE 2111-75-3

Cas:2111-75-3

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 2111-75-3 with competitive price

Cas:2111-75-3

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

1-Cyclohexene-1-carboxaldehyde,4-(1-methylethenyl)- 2111-75-3

Cas:2111-75-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

(-)-PERILLALDEHYDE CAS:2111-75-3 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic interme

(-)-PERILLALDEHYDE CAS:2111-75-3

Cas:2111-75-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

1-Cyclohexene-1-carboxaldehyde,4-(1-methylethenyl)-

Cas:2111-75-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

1-Cyclohexene-1-carboxaldehyde,4-(1-methylethenyl)-

Cas:2111-75-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

JINING XINHE CHEMICAL CO., LTD

Advantage 1: The product passed the professional production process and quality inspection, the purity is 99% +. 2: Highly qualified engineers to provide technical documents and service. 3: We could provide sample for your test. 4: High qualit

perillaldehyde2111-75-3

Cas:2111-75-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1-Cyclohexene-1-carboxaldehyde,4-(1-methylethenyl)-

Cas:2111-75-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

(-)-PERILLALDEHYDE

Cas:2111-75-3

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Perillaldehyde Manufacturer/High quality/Best price/In stock

Cas:2111-75-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

(-)-PERILLALDEHYDE

Cas:2111-75-3

Min.Order:1 Milligram

Negotiable

Type:Trading Company

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Hebei yanxi chemical co.,LTD.

CHENGDU YANXI is a comprehensive manufacturer and an international distribution of products throughout the world. Specialized in Scrap metal, Chemical raw materials, Paper products and color industry. We aim to become leading position in global dis

offer the price of spices of india/the price of spices of india

Cas:2111-75-3

Min.Order:1 Kilogram

FOB Price: $3.0 / 6.0

Type:Trading Company

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

L-perillaldehyde

Cas:2111-75-3

Min.Order:0

Negotiable

Type:Other

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GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier

Perillaldehyde

Cas:2111-75-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

1-Cyclohexene-1-carboxaldehyde,4-(1-methylethenyl)-

Cas:2111-75-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

PERILLALDEHYDE(SG)

Cas:2111-75-3

Min.Order:0

Negotiable

Type:Manufacturers

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Hubei Taiho Chemical Co.,LTD

TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp

L(-)-Perillaldehyde

Cas:2111-75-3

Min.Order:0

Negotiable

Type:Manufacturers

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Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

(-)-PERILLALDEHYDE

Cas:2111-75-3

Min.Order:0

Negotiable

Type:Manufacturers

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

1-Cyclohexene-1-carboxaldehyde,4-(1-methylethenyl)-

Cas:2111-75-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

(-)-PERILLALDEHYDE

Cas:2111-75-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

Perillaldehyde

Cas:2111-75-3

Min.Order:0

Negotiable

Type:Other

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Guangdong Juda Chemical Industrial Co.,Limited

Appearance:solid or liquid Storage:sealed in cool and dry place Package:As customer's requested Application:Pharma Intermediate Transportation:by courier/air/sea Port:Any port in China

4-prop-1-en-2-ylcyclohexene-1-carbaldehyde CAS No.2111-75-3

Cas:2111-75-3

Min.Order:0

Negotiable

Type:Trading Company

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Hangzhou Fandachem Co.,Ltd

Perillaldehyde cas 2111-75-3Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

Perillaldehyde cas 2111-75-3

Cas:2111-75-3

Min.Order:0

Negotiable

Type:Other

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Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

(-)-PERILLALDEHYDE

Cas:2111-75-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Best quality with low price Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai

L-perillaldehyde

Cas:2111-75-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Synthetic route

perillol
536-59-4

perillol

perillaldehyde
2111-75-3

perillaldehyde

Conditions
ConditionsYield
With oxygen In 1,3,5-trimethyl-benzene at 60℃; under 760.051 Torr; for 4h; Solvent; Reagent/catalyst;100%
With Iron(III) nitrate nonahydrate; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; oxygen; sodium chloride In 1,2-dichloro-ethane at 20℃; for 9h;90%
With tert.-butylhydroperoxide; oxygen In decane; toluene at 80℃; under 750.075 Torr; Schlenk technique;90%
2-nitro-benzaldehyde
552-89-6

2-nitro-benzaldehyde

perillaldehyde
2111-75-3

perillaldehyde

Conditions
ConditionsYield
With hydrogenchloride; aluminum isopropoxide In ethyl acetate; benzene84%
l-perillic acid
7694-45-3

l-perillic acid

perillaldehyde
2111-75-3

perillaldehyde

Conditions
ConditionsYield
With Bis(N-methylpiperazinyl) aluminum hydride In tetrahydrofuran for 9h; Heating;78%
perillol
536-59-4

perillol

A

dihydroperilla alcohol
5502-72-7

dihydroperilla alcohol

B

perillaldehyde
2111-75-3

perillaldehyde

Conditions
ConditionsYield
With 6C16H36N(1+)*2Zn(2+)*4Na(1+)*[Bi2Zn2(ZnW9O34)2](14-); urea hydrogen peroxide adduct In acetonitrile at 70℃; for 2h; Ene Reaction;A 40%
B 60%
(+/-)-(1S,5R)-6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde
564-94-3, 18486-69-6, 23727-16-4, 57526-63-3

(+/-)-(1S,5R)-6,6-dimethylbicyclo[3.1.1]hept-2-ene-2-carbaldehyde

perillaldehyde
2111-75-3

perillaldehyde

Conditions
ConditionsYield
at 380 - 400℃; beim Leiten durch ein Eisen-Rohr;
1-Chlor-4-isopropenylcyclohexen
39850-85-6

1-Chlor-4-isopropenylcyclohexen

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

perillaldehyde
2111-75-3

perillaldehyde

Conditions
ConditionsYield
(i) Li, Et2O, (ii) /BRN= 605365/; Multistep reaction;
dihydrocuminyl alcohol

dihydrocuminyl alcohol

perillaldehyde
2111-75-3

perillaldehyde

Conditions
ConditionsYield
With chromic acid levorotatory form;
levorotatory perilla alcohol

levorotatory perilla alcohol

perillaldehyde
2111-75-3

perillaldehyde

Conditions
ConditionsYield
With chromic acid levorotatory perillaldehyde;
(methyl)(4-chlorocyclohex-3-en-1-yl)ketone
41747-24-4

(methyl)(4-chlorocyclohex-3-en-1-yl)ketone

perillaldehyde
2111-75-3

perillaldehyde

Conditions
ConditionsYield
Multi-step reaction with 2 steps
2: (i) Li, Et2O, (ii) /BRN= 605365/
View Scheme
limonene.
138-86-3

limonene.

perillaldehyde
2111-75-3

perillaldehyde

Conditions
ConditionsYield
With sodium hydrogencarbonate; sodium sulfite In dichloromethane; 3-chloro-benzenecarboperoxoic acid
formaldehyd
50-00-0

formaldehyd

trans-Crotonaldehyde
123-73-9

trans-Crotonaldehyde

isoprene
78-79-5

isoprene

A

3-methyl-1-vinylcyclohex-3-enecarbaldehyde
40398-14-9

3-methyl-1-vinylcyclohex-3-enecarbaldehyde

B

perillaldehyde
2111-75-3

perillaldehyde

C

4-methyl-1-vinylcyclohex-3-enecarbaldehyde
40398-47-8

4-methyl-1-vinylcyclohex-3-enecarbaldehyde

Conditions
ConditionsYield
With pyrrolidine; propionic acid In water at 100℃; for 16h; Autoclave;
perillaldehyde
2111-75-3

perillaldehyde

perillol
536-59-4

perillol

Conditions
ConditionsYield
With lithium pyrrolidinoborohydride at 25℃;97%
Stage #1: perillaldehyde With [Ru(2-(ethylthio)-N-[(pyridin-2-yl)methyl]ethan-1-amine)(triphenylphosphine)Cl2]; potassium tert-butylate In isopropyl alcohol under 22502.3 Torr; Autoclave; Inert atmosphere;
Stage #2: With hydrogen In isopropyl alcohol at 80℃; under 22502.3 Torr; for 1h;
96%
With bis(triphenylphosphine)copper(I) nitrate; hydrogen; 1,4-di(diphenylphosphino)-butane; sodium hydroxide In ethanol at 50℃; under 37503.8 Torr; for 16h; Autoclave; Inert atmosphere; chemoselective reaction;92%
perillaldehyde
2111-75-3

perillaldehyde

cyclopenta-1,3-diene
542-92-7

cyclopenta-1,3-diene

6-(4-Isopropenyl-1-cyclohexenyl)fulvene

6-(4-Isopropenyl-1-cyclohexenyl)fulvene

Conditions
ConditionsYield
With pyrrolidine97%
perillaldehyde
2111-75-3

perillaldehyde

allylmagnesium bromide
1730-25-2

allylmagnesium bromide

1-(1-hydroxy-3-butenyl)-4-(1-methylethenyl)-cyclohexene
95374-99-5

1-(1-hydroxy-3-butenyl)-4-(1-methylethenyl)-cyclohexene

Conditions
ConditionsYield
In diethyl ether93%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

perillaldehyde
2111-75-3

perillaldehyde

diallyldibutyltin
15336-98-8

diallyldibutyltin

[1-(4-Isopropenyl-cyclohex-1-enyl)-but-3-enyloxy]-trimethyl-silane

[1-(4-Isopropenyl-cyclohex-1-enyl)-but-3-enyloxy]-trimethyl-silane

Conditions
ConditionsYield
In acetonitrile for 6h; Ambient temperature;92%
perillaldehyde
2111-75-3

perillaldehyde

ethyl 2-diphenylphosphono-3-(trimethylsilyl)propionate
663155-32-6

ethyl 2-diphenylphosphono-3-(trimethylsilyl)propionate

ethyl 3-(4-isopropenylcyclohex-1-en-1-yl)-2-(trimethylsilylmethyl)prop-2-enoate

ethyl 3-(4-isopropenylcyclohex-1-en-1-yl)-2-(trimethylsilylmethyl)prop-2-enoate

Conditions
ConditionsYield
Stage #1: ethyl 2-diphenylphosphono-3-(trimethylsilyl)propionate With sodium hydride In tetrahydrofuran at 0℃; for 0.5h;
Stage #2: perillaldehyde In tetrahydrofuran at -60 - 20℃; for 14.5h; Ando-Horner-Wadsworth-Emmons reaction; -;
91%
1-methoxy-2-methyl-1-trimethylsiloxy-1-propene
31469-15-5

1-methoxy-2-methyl-1-trimethylsiloxy-1-propene

perillaldehyde
2111-75-3

perillaldehyde

3-hydroxy-3-(4-isopropenyl-cyclohex-1-enyl)-2,2-dimethyl-propionic acid methyl ester

3-hydroxy-3-(4-isopropenyl-cyclohex-1-enyl)-2,2-dimethyl-propionic acid methyl ester

Conditions
ConditionsYield
With pyridine N-oxide; lithium chloride In N,N-dimethyl-formamide at 20℃; for 10h;91%
With 1-methyl-1H-imidazole; lithium chloride In N,N-dimethyl-formamide at 20℃; for 10h;90%
perillaldehyde
2111-75-3

perillaldehyde

aniline
62-53-3

aniline

N-((4-(prop-1-en-2-yl)cyclohex-1-enyl)methyl)aniline

N-((4-(prop-1-en-2-yl)cyclohex-1-enyl)methyl)aniline

Conditions
ConditionsYield
With Dimethylphenylsilane In acetonitrile at 20℃; for 2h; Inert atmosphere; Green chemistry;91%
Stage #1: perillaldehyde; aniline In methanol at 20℃; for 12h;
Stage #2: With sodium tetrahydroborate In methanol at 20℃; for 2h; Cooling with ice;
89%
Stage #1: perillaldehyde; aniline In methanol for 24h;
Stage #2: With sodium tetrahydroborate In methanol at 0 - 20℃;
perillaldehyde
2111-75-3

perillaldehyde

ethyl sodiodiethylphosphonoacetate
22822-85-1

ethyl sodiodiethylphosphonoacetate

(E)-3-(4-Isopropenyl-cyclohex-1-enyl)-acrylic acid ethyl ester
516472-73-4

(E)-3-(4-Isopropenyl-cyclohex-1-enyl)-acrylic acid ethyl ester

Conditions
ConditionsYield
In tetrahydrofuran Ambient temperature;89.5%
perillaldehyde
2111-75-3

perillaldehyde

N-butylamine
109-73-9

N-butylamine

p-perilla-7-n-butylamine

p-perilla-7-n-butylamine

Conditions
ConditionsYield
Stage #1: perillaldehyde; N-butylamine In methanol at 20℃; for 12h;
Stage #2: With methanol; sodium tetrahydroborate at 20℃; for 2h; Temperature; Reagent/catalyst; Cooling with ice;
88%
Stage #1: perillaldehyde; N-butylamine In methanol for 24h;
Stage #2: With sodium tetrahydroborate In methanol at 0 - 20℃;
perillaldehyde
2111-75-3

perillaldehyde

[4-(1-methylethenyl)-1-cyclohexen-1-yl]methylamine
52209-34-4

[4-(1-methylethenyl)-1-cyclohexen-1-yl]methylamine

Conditions
ConditionsYield
With N,N'-bis(salicylidene)-1,2-phenylene-diaminocobalt(II); ammonia; hydrogen In water at 120℃; for 24h; Autoclave;87%
perillaldehyde
2111-75-3

perillaldehyde

4-isopropenylcyclohexene-1-carbonitrile
60188-94-5, 156555-45-2

4-isopropenylcyclohexene-1-carbonitrile

Conditions
ConditionsYield
With ammonia; oxygen In tert-Amyl alcohol at 40℃; under 750.075 Torr; for 24h; Green chemistry;85%
4-phenylbut-1-en-3-yne
13633-26-6

4-phenylbut-1-en-3-yne

perillaldehyde
2111-75-3

perillaldehyde

(1S,2R)-2-(phenylethynyl)-1-((S)-4-(prop-1-en-2-yl)cyclohex-1-en-1-yl)propane-1,3-diol

(1S,2R)-2-(phenylethynyl)-1-((S)-4-(prop-1-en-2-yl)cyclohex-1-en-1-yl)propane-1,3-diol

Conditions
ConditionsYield
Stage #1: 4-phenylbut-1-en-3-yne; perillaldehyde With [(1S,4R)-3-[4-(diphenylphosphino)-2,5-dimethyl-3-thienyl]-4,7,7-trimethylbicyclo[2.2.1]hept-2-en-2-yl]diphenylphosphine; copper(l) chloride; sodium t-butanolate In tetrahydrofuran at 22℃; for 8h; Inert atmosphere; Glovebox;
Stage #2: With sodium perborate tetrahydrate In tetrahydrofuran at 22℃; for 3h; Inert atmosphere; Glovebox;
79%
[2-(acetoxymethyl)prop-2-enyl]trimethylsilane
72047-94-0

[2-(acetoxymethyl)prop-2-enyl]trimethylsilane

perillaldehyde
2111-75-3

perillaldehyde

2-(4-Isopropenyl-cyclohex-1-enyl)-4-methylene-tetrahydro-furan
99583-47-8

2-(4-Isopropenyl-cyclohex-1-enyl)-4-methylene-tetrahydro-furan

Conditions
ConditionsYield
With triphenylphosphine; palladium diacetate In 1,4-dioxane Heating;71%
perillaldehyde
2111-75-3

perillaldehyde

A

perillol
536-59-4

perillol

B

C20H30O2

C20H30O2

Conditions
ConditionsYield
With acetic acid; zinc In water at 20℃; for 0.333333h; Green chemistry;A 6%
B 71%
perillaldehyde
2111-75-3

perillaldehyde

A

C10H13ClO

C10H13ClO

B

C10H12Cl2O

C10H12Cl2O

Conditions
ConditionsYield
Stage #1: perillaldehyde With iron(III) chloride In dichloromethane; water at 20℃;
Stage #2: With sodium hypochlorite In dichloromethane; water at 20℃; for 0.583333h;
A 68%
B 30%
perillaldehyde
2111-75-3

perillaldehyde

A

(4S)-(3-oxoprop-1-en-2-yl)cyclohex-1-enecarbaldehyde

(4S)-(3-oxoprop-1-en-2-yl)cyclohex-1-enecarbaldehyde

B

4-hydroxy-4-(prop-1-en-2-yl)cyclohex-1-enecarbaldehyde

4-hydroxy-4-(prop-1-en-2-yl)cyclohex-1-enecarbaldehyde

Conditions
ConditionsYield
With selenium(IV) oxide In ethanol for 18h; Heating;A 66%
B n/a
perfluorophenyl azide
1423-15-0

perfluorophenyl azide

perillaldehyde
2111-75-3

perillaldehyde

C16H14F5NO

C16H14F5NO

Conditions
ConditionsYield
With Co(3,5-DitBu-Ibu-Phyrin) In chlorobenzene at 80℃; for 24h; Molecular sieve;50%
Dimethyldisulphide
624-92-0

Dimethyldisulphide

perillaldehyde
2111-75-3

perillaldehyde

C11H18OS

C11H18OS

Conditions
ConditionsYield
With [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate In 1,2-dichloro-ethane at 20℃; for 16h; Irradiation; regioselective reaction;48%
perillaldehyde
2111-75-3

perillaldehyde

4-hydroxy-2-deoxy-2-thiocoumarin
70685-46-0

4-hydroxy-2-deoxy-2-thiocoumarin

A

(6aH)-7,8,9,10-tetrahydro-8-(prop-1-en-2-yl)-5-oxa-6-thia-naphthacen-12-one

(6aH)-7,8,9,10-tetrahydro-8-(prop-1-en-2-yl)-5-oxa-6-thia-naphthacen-12-one

B

(6aH)-9,10,11,11a-tetrahydro-10-(prop-1-en-2-yl)-chromeno[4,3-b]chromen-6-thione

(6aH)-9,10,11,11a-tetrahydro-10-(prop-1-en-2-yl)-chromeno[4,3-b]chromen-6-thione

Conditions
ConditionsYield
ytterbium(III) trifluoromethanesulphonate In methanol Knoevenagel reaction;A 44%
B 36%
Allyl acetate
591-87-7

Allyl acetate

perillaldehyde
2111-75-3

perillaldehyde

1-(1-hydroxy-3-butenyl)-4-(1-methylethenyl)-cyclohexene
95374-99-5

1-(1-hydroxy-3-butenyl)-4-(1-methylethenyl)-cyclohexene

Conditions
ConditionsYield
With tetraethylammonium tosylate; zinc(II) chloride; bis-triphenylphosphine-palladium(II) chloride In N,N-dimethyl-formamide electrochemical reduction;42%
perillaldehyde
2111-75-3

perillaldehyde

(S)-5-oxopyrrolidine-2-carbohydrazide
934-06-5

(S)-5-oxopyrrolidine-2-carbohydrazide

5-oxo-N'-((4-(prop-1-en-2-yl)cyclohex-1-en-1 yl)methylene)pyrrolidine-2-carbohydrazide

5-oxo-N'-((4-(prop-1-en-2-yl)cyclohex-1-en-1 yl)methylene)pyrrolidine-2-carbohydrazide

Conditions
ConditionsYield
With hydrazine hydrate In water at 20℃; for 1h;40%
perillaldehyde
2111-75-3

perillaldehyde

O,O-dimethyl bismethylphosphonate
114121-06-1

O,O-dimethyl bismethylphosphonate

A

(Z)-4-isopropenyl-1-(2-(dimethylphosphono)-2-(trimethylsilylvinyl))cyclohexene
1615248-95-7

(Z)-4-isopropenyl-1-(2-(dimethylphosphono)-2-(trimethylsilylvinyl))cyclohexene

B

(E)-4-isopropenyl-1-(2-(dimethylphosphono)-2-(trimethylsilylvinyl))cyclohexene
1615248-94-6

(E)-4-isopropenyl-1-(2-(dimethylphosphono)-2-(trimethylsilylvinyl))cyclohexene

Conditions
ConditionsYield
Stage #1: O,O-dimethyl bismethylphosphonate With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -70℃; for 0.25h; Inert atmosphere;
Stage #2: perillaldehyde In tetrahydrofuran; hexane at -70℃; for 0.25h; Peterson Olefination; Inert atmosphere;
Stage #3: With benzoic acid methyl ester In tetrahydrofuran; hexane at 20℃; for 12h; Reagent/catalyst; Inert atmosphere;
A 24%
B 18%
With benzoic acid methyl ester; lithium diisopropyl amide In tetrahydrofuran at -78 - 20℃; for 12.5h; Peterson Olefination; Inert atmosphere; Overall yield = 53 %;A n/a
B n/a
perillaldehyde
2111-75-3

perillaldehyde

3-methyl-2-buten-1-ol
556-82-1

3-methyl-2-buten-1-ol

3-(3-methylbut-2-en-1-yl)-4-(prop-1-en-2-yl)cyclohex-1-ene-1-carbaldehyde

3-(3-methylbut-2-en-1-yl)-4-(prop-1-en-2-yl)cyclohex-1-ene-1-carbaldehyde

Conditions
ConditionsYield
With triethylamine hydrochloride In 5,5-dimethyl-1,3-cyclohexadiene at 140℃; for 16h; Inert atmosphere; Enzymatic reaction;23%
perillaldehyde
2111-75-3

perillaldehyde

sodium cyanide
143-33-9

sodium cyanide

borontrifluoride acetic acid
753-53-7, 373-61-5

borontrifluoride acetic acid

Acetic acid 2-(4-isopropylidene-cyclohexyl)-ethyl ester

Acetic acid 2-(4-isopropylidene-cyclohexyl)-ethyl ester

Conditions
ConditionsYield
Multistep reaction;
perillaldehyde
2111-75-3

perillaldehyde

p-menth-3-en-7-ol
21425-79-6

p-menth-3-en-7-ol

Conditions
ConditionsYield
(i) Li, liq. NH3, iPrOH, Et2O, (ii) aq. H2SO4; Multistep reaction;

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