CAS No.624-92-0,Dimethyl disulfide Suppliers

Jinan Finer Chemical Co., Ltd

Product description: Product name Dimethyl disulfide CAS number 624-92-0 Assay ≥99.5% Appearance Colorless transparent liquid Capacity 5000mt/year Application Solvent, pestic

Dimethyl disulfide

Cas:624-92-0

Min.Order:1 Kilogram

FOB Price: $12.0

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Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

Methyl disulfide 624-92-0

Cas:624-92-0

Min.Order:0

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Type:Trading Company

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Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

Amadis Chemical offer CAS#624-92-0;CAT#A833808

Cas:624-92-0

Min.Order:10 Milligram

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QINGDAO ON-BILLION INDUSTRAIL CO.,LTD

ProductName:DMDS Synonyms:(CH3S)2;(Methyldisulfanyl)methane;(Methyldithio)methane;2,3-dithiobutane;ai3-25305;dimethyldisulfane;Disulfide,dimethyl;disulfide,dimetAppearance:clear, colorless liquid Storage:Flammables area Package:200kg drums or

Dimethyl disulfide

Cas:624-92-0

Min.Order:200 Kilogram

Negotiable

Type:Trading Company

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Pure Chemistry Scientific Inc.

Methyl disulfide Application:823914

Methyl disulfide

Cas:624-92-0

Min.Order:1 Gram

FOB Price: $500.0

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Synthetic route

: 124-63-0
methanesulfonyl chloride

: 624-92-0
Dimethyldisulphide

Conditions

Conditions	Yield
With trimethylsilyl iodide In 1,2-dichloro-ethane for 16h; Heating;	100%
With sulfuric acid; sulfur dioxide; potassium iodide In water at 80℃; for 1h;	92.9%
With tungsten(VI) chloride; sodium iodide In acetonitrile for 12h; Ambient temperature;	90%

: 28925-45-3
S-methyl O-benzyl dithiocarbonate

A: 624-92-0
Dimethyldisulphide

B: 100-44-7
benzyl chloride

Conditions

Conditions	Yield
With copper(l) chloride; copper dichloride In acetonitrile for 96h; Ambient temperature;	A 100% B 60%

: 9-methylsulfinyl-10-(methylthio)anthracene

A: 624-92-0
Dimethyldisulphide

B: 84-65-1
9,10-phenanthrenequinone

Conditions

Conditions	Yield
Stage #1: 9-methylsulfinyl-10-(methylthio)anthracene With air; sulfuric acid In dichloromethane at 20℃; for 0.0833333h; Rearrangement; Stage #2: With water; sodium hydrogencarbonate Hydrolysis;	A n/a B 100%

: 74-93-1
methylthiol

: 624-92-0
Dimethyldisulphide

Conditions

Conditions	Yield
Stage #1: methylthiol With sodium hydroxide at 51℃; Stage #2: With oxygen at 55℃; under 4500.45 Torr; Temperature; Pressure; Reagent/catalyst;	97.6%
With Cu,Na-X zeolite; oxygen at 189.9℃; Product distribution; Mechanism; other catalysts; other temp.;
With air at 170 - 270℃;

: 33696-21-8
N,N-dimethylmethane sulfenamide

: 74-88-4
methyl iodide

A: 624-92-0
Dimethyldisulphide

B: 75-58-1
tertamethylammonium iodide

Conditions

Conditions	Yield
In chloroform Product distribution; Ambient temperature; var. amino thioethers, var. electrophiles;	A 96% B 96%

...Expand

: 629-45-8
dibutyl disulfide

: 1680-29-1
S-methyl decanethioate

A: 624-92-0
Dimethyldisulphide

B: S-butyl decanethioate

Conditions

Conditions	Yield
[RhCl(PPh3)] In 1,2-dichloro-benzene at 150℃; for 1.5h;	A n/a B 95%

...Expand

: 67-56-1
methanol

: 74-93-1
methylthiol

A: 75-15-0
carbon disulfide

B: 624-92-0
Dimethyldisulphide

C: 3658-80-8
dimethyltrisulfane

Conditions

Conditions	Yield
Stage #1: methanol; methylthiol With hydrogen sulfide; aluminum oxide with 14percent by weight of potassium tungstate at 400℃; Stage #2: With sulfur; N-cyclohexyl-cyclohexanamine	A n/a B 94.9% C n/a

...Expand

: 53475-19-7
2,3-dimethyl-3-methylsulfanyl-3H-indole

A: 91-55-4
2,3-dimethylindole

B: 624-92-0
Dimethyldisulphide

Conditions

Conditions	Yield
With mercaptoacetic acid In dichloromethane for 0.5h; Heating;	A 93% B n/a
With mercaptoacetic acid In dichloromethane for 0.5h; Mechanism; Heating;

: 69177-66-8
bis(2-methoxyethyl) disulfide

: 1680-29-1
S-methyl decanethioate

A: 1020261-42-0
S-(2-methoxy)ethyl decanethioate

B: 624-92-0
Dimethyldisulphide

Conditions

Conditions	Yield
[RhCl(PPh3)] In 1,2-dichloro-benzene at 150℃; for 1.5h;	A 93% B n/a

...Expand

: 1680-29-1
S-methyl decanethioate

: 67385-10-8
di-tert-butyl(disulfanediylbis(ethane-2,1-diyl))dicarbamate

A: 1020261-43-1
S-[2-(t-butoxycarbonyl)amino]ethyl decanethioate

B: 624-92-0
Dimethyldisulphide

Conditions

Conditions	Yield
[RhCl(PPh3)] In 1,2-dichloro-benzene at 150℃; for 1.5h;	A 92% B n/a

...Expand

: 12107-04-9
dicarbonyl(cyclopentadienyl)iron(II) chloride

: 10543-35-8
lithium methylsulfinyl carbanion

A: 38117-54-3
cyclopentadienyl iron(II) dicarbonyl dimer

B: 74-93-1
methylthiol

C: 624-92-0
Dimethyldisulphide

D: 6628-18-8
1,2-bis(methylthio)ethane

E: lithium chloride

Conditions

Conditions	Yield
In tetrahydrofuran mixing reactants in THF at -78°C, slow warming to room temp.; evapn. in vac., extn. with pentane, ether and finally acetone or CH2Cl2, concn., chromy. on Al2O3, purifn. by crystn., distn. or sublimation;	A 55% B n/a C 21% D 8% E 92%

...Expand

: 2-nitrobenzenediazonium o-benzenedisulfonamide

: 5188-07-8
sodium thiomethoxide

A: 624-92-0
Dimethyldisulphide

B: 3058-47-7
methyl 2-nitrophenyl sulfide

C: sodium o-benzenedisulfonimide

Conditions

Conditions	Yield
In methanol at -15℃; methylthiodeazoniation; dimerization;	A n/a B 91% C n/a

...Expand

: 2,4-dinitrobenzenediazonium o-benzenedisulfonimide

: 5188-07-8
sodium thiomethoxide

A: 624-92-0
Dimethyldisulphide

B: 2363-23-7
methyl 2,4-dinitriophenyl sulfide

C: sodium o-benzenedisulfonimide

Conditions

Conditions	Yield
In methanol at -15℃; methylthiodediazoniation; dimerization;	A n/a B 89% C n/a

...Expand

: 1271-19-8
bis(cyclopentadienyl)titanium dichloride

: 10543-35-8
lithium methylsulfinyl carbanion

A: Cp2Ti(SMe)2

B: 74-93-1
methylthiol

C: 624-92-0
Dimethyldisulphide

D: titanium(IV) oxide

E: lithium chloride

Conditions

Conditions	Yield
In tetrahydrofuran mixing reactants in THF at -78°C, slow warming to room temp.; evapn. in vac., extn. with pentane, ether and finally acetone or CH2Cl2, concn., chromy. on Al2O3, purifn. by crystn., distn. or sublimation;	A 31% B n/a C 9% D 43% E 89%

...Expand

: 2-methoxybenzenediazonium o-benzenedisulfonamide

: 5188-07-8
sodium thiomethoxide

A: 624-92-0
Dimethyldisulphide

B: 2388-73-0
1-methoxy-2-(methylsulfanyl)benzene

C: sodium o-benzenedisulfonimide

Conditions

Conditions	Yield
In methanol at 0 - 5℃; Dimerization; methylthiodediazoniation;	A n/a B 88% C n/a

...Expand

: 4-nitrobenzenediazonium o-benzenedisulfonimide

: 5188-07-8
sodium thiomethoxide

A: 624-92-0
Dimethyldisulphide

B: 701-57-5
1-methylthio-4-nitro-benzene

C: sodium o-benzenedisulfonimide

Conditions

Conditions	Yield
In methanol at -15℃; methylthiodeazoniation; dimerization;	A n/a B 88% C n/a

...Expand

: 1618-26-4
2,4-dithiapentane

: 65566-22-5
3<(t-Butyl) dimethyl silyloxy>-1-bromobutan

: 139929-52-5
((Z)-5-Bromo-pent-1-enyl)-trimethyl-silane

A: 624-92-0
Dimethyldisulphide

B: 79538-96-8
(Z)-9-(tert-Butyl-dimethyl-silanyloxy)-6,6-bis-methylsulfanyl-1-trimethylsilanyl-dec-1-ene

Conditions

Conditions	Yield
With n-butyllithium In tetrahydrofuran	A n/a B 87%

...Expand

: 558-37-2
tert-butylethylene

: 13882-12-7
S-methyl methanethiosulfinate

: 407-25-0
trifluoroacetic anhydride

A: 2949-92-0
methanethiosulfonic acid S-methyl ester

B: 624-92-0
Dimethyldisulphide

C: 73682-79-8
methyl 3,3-dimethyl-1-trifluoroacetoxy-2-butyl sulfide

Conditions

Conditions	Yield
In tetrachloromethane 1) -20 deg C, 2) up to rt;	A 12% B 17% C 87%

...Expand

: 4-methoxybenzenediazonium o-benzenedisulfonimide

: 5188-07-8
sodium thiomethoxide

A: 624-92-0
Dimethyldisulphide

B: 1879-16-9
1-methoxy-4-methylsulfanyl-benzene

C: sodium o-benzenedisulfonimide

Conditions

Conditions	Yield
In methanol at 0 - 5℃; methylthiodediazoniation; dimerization;	A n/a B 87% C n/a

...Expand

: 4-toluenediazonium o-benzenedisulfonimide

: 5188-07-8
sodium thiomethoxide

A: 624-92-0
Dimethyldisulphide

B: 623-13-2
4-methylphenyl methylsulfide

C: sodium o-benzenedisulfonimide

Conditions

Conditions	Yield
In methanol at 0 - 5℃; Dimerization; methylthiodediazoniation;	A n/a B 86% C n/a

...Expand

: C6H4S2O4N(1-)*N2C6H5CH2(1+)

: 5188-07-8
sodium thiomethoxide

A: 624-92-0
Dimethyldisulphide

B: 14092-00-3
methyl o-tolyl sulfide

C: sodium o-benzenedisulfonimide

Conditions

Conditions	Yield
In methanol at 0 - 5℃; Dimerization; methylthiodediazoniation;	A n/a B 86% C n/a

...Expand

: 4-(chloro)benzenediazonium benzo[d][1,3,2]dithiazol-2-ide-1,1,3,3-tetraoxide

: 5188-07-8
sodium thiomethoxide

A: 624-92-0
Dimethyldisulphide

B: 123-09-1
4-chlorophenyl methyl sulfide

C: sodium o-benzenedisulfonimide

Conditions

Conditions	Yield
In methanol at 0 - 5℃; methylthiodediazoniation; dimerization;	A n/a B 86% C n/a

...Expand

: 4-hydroxybenzenediazonium o-benzenedisulfonimide

: 5188-07-8
sodium thiomethoxide

A: 624-92-0
Dimethyldisulphide

B: 1073-72-9
4-hydroxythioanisole

C: sodium o-benzenedisulfonimide

Conditions

Conditions	Yield
In methanol at 20 - 25℃; methylthiodediazoniation; dimerization;	A n/a B 86% C n/a

...Expand

: 3-methoxybenzenediazonium o-benzenedisulfonimide

: 5188-07-8
sodium thiomethoxide

A: 624-92-0
Dimethyldisulphide

B: 2388-74-1
1-methoxy-3-methylsulfanyl-benzene

C: sodium o-benzenedisulfonimide

Conditions

Conditions	Yield
In methanol at 0 - 5℃; Dimerization; methylthiodediazoniation;	A n/a B 85% C n/a

...Expand

: 4-Bromobenzenediazonium o-benzenedisulfonimide

: 5188-07-8
sodium thiomethoxide

A: 624-92-0
Dimethyldisulphide

B: 104-95-0
(4-bromophenyl)thioanisole

C: sodium o-benzenedisulfonimide

Conditions

Conditions	Yield
In methanol at 0 - 5℃; methylthiodeazoniation; dimerization;	A n/a B 85% C n/a

...Expand

: N-Boc-glutathione disulfide tetramethyl ester

: 2432-51-1
ethylthioacetic acid methyl ester

A: 1020261-44-2
N-[N-[N-{(1,1-dimethylethoxy)carbonyl}-L-γ-glutamyl]-3-(butyloylsulfuryl)-L-alanine] dimethyl ester

B: 624-92-0
Dimethyldisulphide

Conditions

Conditions	Yield
[RhCl(PPh3)] In 1,2-dichloro-benzene at 150℃; for 1.5h;	A 85% B n/a

...Expand

: 74-88-4
methyl iodide

A: 75-18-3
dimethylsulfide

B: 624-92-0
Dimethyldisulphide

Conditions

Conditions	Yield
With potassium hydroxide; sulfur; hydrazine hydrate In water at 50 - 70℃; for 0.5h;	A 6.1% B 84.3%
With sodium hydroxide; sulfur; hydrazine hydrate In water at 50 - 70℃; for 0.5h;	A 10% B 82%
With sodium hydroxide; hydrazine hydrate In water at 50 - 70℃; for 0.5h;	A 14.0 % Chromat. B 62.0 % Chromat.
With potassium hydroxide; hydrazine hydrate In water at 50 - 70℃; for 0.5h;	A 6.1 % Chromat. B 84.3 % Chromat.

: 624-92-0
Dimethyldisulphide

: 676-85-7
methylsulphinyl chloride

Conditions

Conditions	Yield
With sulfuryl dichloride; acetic acid at -20 - 20℃; for 2.5h;	100%
With sulfuryl dichloride; acetic acid at -20 - 35℃; for 6.3h;	97%
With sulfuryl dichloride; acetic acid at -20 - 35℃; for 6h;	97%

: 1003-91-4
N-methyl-2,4,5-tribromoimidazole

: 624-92-0
Dimethyldisulphide

: 145083-26-7
4,5-Dibromo-1-methyl-2-(methylthio)imidazole

Conditions

Conditions	Yield
With n-butyllithium In tetrahydrofuran; hexane 1.) -78 deg C, 30 min, 2.) r.t., 12 h;	100%
With n-butyllithium 1) THF, -78 deg C, 5 min; Yield given. Multistep reaction;

: 624-92-0
Dimethyldisulphide

: 67341-86-0
Ph2CCHHgBr

: 15096-10-3
methyl 2,2-diphenylethenyl sulfide

Conditions

Conditions	Yield
In benzene at 35 - 45℃; for 8h; Irradiation;	100%

: 624-92-0
Dimethyldisulphide

: 86051-74-3
1,2-dimethyl-5-trimethylstannylimidazole

: 86051-77-6
1,2-dimethyl-5-methylthioimidazole

Conditions

Conditions	Yield
With n-butyllithium In tetrahydrofuran; hexane 1.) -100 deg C, 1 h, 2.) room temperature, 1.5 h;	100%

: 624-92-0
Dimethyldisulphide

: 81356-73-2
4-bromo-1-ethoxymethyl-5-methylthio-2-phenylthioimidazole

: 81356-72-1
1-ethoxymethyl-4,5-bis(methylthio)-2-phenylthioimidazole

Conditions

Conditions	Yield
With n-butyllithium In diethyl ether; hexane 1.) -70 deg C, 1 h, 2.) room temperature;	100%
With n-butyllithium In diethyl ether at -70℃;	100%

: 624-92-0
Dimethyldisulphide

: 41879-78-1
naphtho<1,8-bc:4,5-b'c'>dithiophene

: 2,5-bis(methylthio)naphtho[1,8-bc:4,5-b'c']dithiophene

Conditions

Conditions	Yield
Stage #1: naphtho<1,8-bc:4,5-b'c'>dithiophene With n-butyllithium; N,N,N,N,-tetramethylethylenediamine In tetrahydrofuran; hexane at -30℃; for 1.5h; Stage #2: Dimethyldisulphide In tetrahydrofuran; hexane at -30℃; for 1.5h;	100%
With n-butyllithium; N,N,N,N,-tetramethylethylenediamine 1.) THF, -30 deg C, 1.5 h, 2.) THF, -30 deg C, 1.5 h; Yield given. Multistep reaction;

: 624-92-0
Dimethyldisulphide

2,3-methano-2,4-didehydroadamantane: 2,3-methano-2,4-didehydroadamantane

Conditions

Conditions	Yield
In benzene-d6	100%

A

B: 100-44-7
benzyl chloride

Conditions

Conditions	Yield
With copper(l) chloride; copper dichloride In acetonitrile for 96h; Ambient temperature;	A 100% B 60%

: 624-92-0
Dimethyldisulphide

: 57680-64-5
8-Phenyl-tetrahydro-8λ5-[1,3,2]oxazaphospholo[2,3-b][1,3,2]oxazaphosphole

: 6a-Methylsulfanyl-6a-phenyl-tetrahydro-1,6-dioxa-3a-aza-6aλ5-phospha-pentalene

Conditions

Conditions	Yield
In benzene for 2h; Irradiation; var. time;	100%
In benzene at 20℃; Irradiation; relative rate constants, inhibition by α-methyl styrene;

: 36049-90-8
2-lithio-1,3-dithiane

: 624-92-0
Dimethyldisulphide

: 14758-37-3
2-(methylthio)-1,3-dithiane

Conditions

Conditions	Yield
In tetrahydrofuran at -78 - 20℃;	100%

: 624-92-0
Dimethyldisulphide

: 824-79-3
sodium 4-methylbenzenesulfinate

: 4973-66-4
methyl thiotosylate

Conditions

Conditions	Yield
With iodine In dichloromethane at 20℃; for 1h;	100%
With iodine at 30℃; for 2h;	90%
With copper(l) iodide; 1,10-Phenanthroline; ammonium tetrafluoroborate In N,N-dimethyl acetamide; water at 30℃; for 36h;	79%

: 624-92-0
Dimethyldisulphide

: 560095-49-0
(1-phenyl-2-propen-1-yl)pentamethyl phosphoric triamide

: 560095-81-0
(3-methylsulfanyl-1-phenyl-1-propen-1-yl)pentamethyl phosphoric triamide

Conditions

Conditions	Yield
Stage #1: (1-phenyl-2-propen-1-yl)pentamethyl phosphoric triamide With n-butyllithium In tetrahydrofuran; hexane at -50℃; for 0.166667h; Stage #2: Dimethyldisulphide In tetrahydrofuran; hexane at -50 - 20℃;	100%

: 624-92-0
Dimethyldisulphide

: 108-20-3
di-isopropyl ether

: sodium hydrogensulfite

: 101-79-1
4-amino-4'-chlorodiphenyl ether

: 4-chloro-4'-thiomethyldiphenylether

Conditions

Conditions	Yield
With hydrogenchloride; sodium nitrite In water	100%

...Expand

: 624-92-0
Dimethyldisulphide

: 1,1'-bis[N-[(2S)-2-(methoxymethyl)tetrahydro-1H-1-pyrrolyl]-N-(E)-[phenylmethylideneamino]]ferrocene

: [1,1'-bis[N-[(2S)-2-(methoxymethyl)tetrahydro-1H-1-pyrrolyl]-N-[(E)phenylmethylideneamino]]]-[(Sp)-2-methylsulfanyl]ferrocene

Conditions

Conditions	Yield
With n-butyllithium In tetrahydrofuran; hexane Fe-complex in THF was cooled to -78°C, nBuLi in hexane was added,stirred for 9 h at -78°C under Ar, ligand was added dropwise, wa rmed to room temp. overnight, cooled to 0°C, quenched with aq. NH4Cl; washed with brine, dried over MgSO4, concd. under reduced pressure, column chromy. on silica gel with pentane-Et2O; elem. anal.;	100%

: 624-92-0
Dimethyldisulphide

: tricarbonyl((3a,7a-trans)-octahydro-3-(t-butyl)-2-(η(6)-phenyl)benzoxazole)chromium(0)

: tricarbony(l(3a,7a-trans)-octahydro-3-(t-butyl)-2-(η(6)-2'-methylthiophenyl)benzoxazole)chromium(0)

Conditions

Conditions	Yield
With BuLi In tetrahydrofuran N2-atmosphere, absence of light; addn. of slight excess of BuLi (in hexanes) to Cr-complex soln. (in THF) at -78°C, stirring (-78°C, 2.5 h), addn. of excess Me2S2, stirring (-78°C, 3.5 h), warming to room temp. over 45 min; evapn. (reduced pressure), dissoln. in Et2O, filtration (Celite), evapn., recrystn. (hexanes/Et2O); elem. anal.;	100%

: 624-92-0
Dimethyldisulphide

: 852950-12-0
(4-bromo-2,6-dimethylphenoxy)triisopropylsilane

: 852950-13-1
2,6-dimethyl-4-methylsulfanylphenoxytriisopropylsilane

Conditions

Conditions	Yield
With n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; Inert atmosphere;	100%
Stage #1: (4-bromo-2,6-dimethylphenoxy)triisopropylsilane With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Stage #2: Dimethyldisulphide In tetrahydrofuran; hexane at -78 - 20℃; for 1h;	100%

: 3141-27-3
2,5-dibromothiophen

: 624-92-0
Dimethyldisulphide

: 86369-96-2
2-bromo-5-(methylthio)thiophene

Conditions

Conditions	Yield
Stage #1: 2,5-dibromothiophen With n-butyllithium In hexanes; diethyl ether at -78 - -65℃; Stage #2: Dimethyldisulphide In hexanes; diethyl ether at 0 - 20℃;	100%
Stage #1: 2,5-dibromothiophen With n-butyllithium In diethyl ether; hexane at -78℃; for 1h; Inert atmosphere; Stage #2: Dimethyldisulphide In diethyl ether; hexane at 20℃; for 8h; Inert atmosphere;	98%
Stage #1: 2,5-dibromothiophen With n-butyllithium In tetrahydrofuran; hexane at -78 - -30℃; Stage #2: Dimethyldisulphide In tetrahydrofuran; hexane at -78 - 0℃;
With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 12h; Inert atmosphere;

: 624-92-0
Dimethyldisulphide

: 42298-28-2
2-methoxyanthracene

: 1309600-92-7
3-methylthio-2-methoxyanthracene

Conditions

Conditions	Yield
Stage #1: 2-methoxyanthracene With n-butyllithium In tetrahydrofuran; hexane at 0 - 20℃; for 1h; Inert atmosphere; Stage #2: Dimethyldisulphide In tetrahydrofuran; hexane at 0 - 20℃; for 7h; Inert atmosphere;	100%

: 624-92-0
Dimethyldisulphide

: 59115-43-4
2-methoxy-6-phenylnaphthalene

: 1310197-78-4
2-methoxy-3-methylthio-6-phenylnaphthalene

Conditions

Conditions	Yield
Stage #1: 2-methoxy-6-phenylnaphthalene With n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; for 1h; Inert atmosphere; Stage #2: Dimethyldisulphide In tetrahydrofuran; hexane at -78 - 20℃; for 20h; Inert atmosphere;	100%

: 624-92-0
Dimethyldisulphide

: 6-n-decyl-2-methoxynaphthalene

: 1310197-76-2
6-n-decyl-3-methylthio-2-methoxynaphthalene

Conditions

Conditions	Yield
Stage #1: 6-n-decyl-2-methoxynaphthalene With n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; for 1h; Inert atmosphere; Stage #2: Dimethyldisulphide In tetrahydrofuran; hexane at -78 - 20℃; for 20h; Inert atmosphere;	100%
Stage #1: 6-n-decyl-2-methoxynaphthalene With n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; for 1h; Stage #2: Dimethyldisulphide In tetrahydrofuran; hexane at -78 - 20℃; for 18h;	100%

: 97877-74-2
bis(acetonitrile)(5,10,15,20-tetramesitylporphyrinato)ruthenium(II)

: 624-92-0
Dimethyldisulphide

: 1357363-89-3
Ru(meso-tetrakis(2,4,6-trimethylphenyl)porphyrin)(MeSSMe)2

Conditions

Conditions	Yield
In benzene at 20℃; for 24h;	100%
In benzene-d6 identified by NMR;

: 624-92-0
Dimethyldisulphide

: 36319-03-6
2,6-dimethoxyanthracene

: 1397972-18-7
2,6-dimethoxy-3,7-bis(methylthio)anthracene

Conditions

Conditions	Yield
Stage #1: 2,6-dimethoxyanthracene With n-butyllithium In tetrahydrofuran; hexane at 0 - 20℃; for 1h; Inert atmosphere; Stage #2: Dimethyldisulphide In tetrahydrofuran; hexane at 0 - 20℃; for 9h; Inert atmosphere;	100%

: 624-92-0
Dimethyldisulphide

: 34246-96-3
1-methoxypyrene

: 1527009-83-1
1-methoxy-2-methylthiopyrene

Conditions

Conditions	Yield
Stage #1: 1-methoxypyrene With n-butyllithium Inert atmosphere; Schlenk technique; Stage #2: Dimethyldisulphide Inert atmosphere; Schlenk technique;	100%

: 624-92-0
Dimethyldisulphide

: 2-(4-(methoxymethoxy)phenyl)-5,5-dimethyl-1,3-dioxane

: 2-(4-(methoxymethoxy)-3-(methylthio)phenyl)-5,5-dimethyl-1,3-dioxane

Conditions

Conditions	Yield
Stage #1: 2-(4-(methoxymethoxy)phenyl)-5,5-dimethyl-1,3-dioxane With n-butyllithium In tetrahydrofuran at -78 - 20℃; for 0.333333h; Stage #2: Dimethyldisulphide In tetrahydrofuran at -78 - 20℃; for 3h;	100%

: 624-92-0
Dimethyldisulphide

: 1,3-dibromo-5-methoxy-2-((4-methoxyphenyl)ethynyl)benzene

: (3-bromo-5-methoxy-2-((4-methoxyphenyl)ethynyl)phenyl)(methyl)sulfane

Conditions

Conditions	Yield
Stage #1: 1,3-dibromo-5-methoxy-2-((4-methoxyphenyl)ethynyl)benzene With n-butyllithium In tetrahydrofuran at -78℃; for 1.5h; Inert atmosphere; Stage #2: Dimethyldisulphide In tetrahydrofuran at -78 - 20℃; for 3h; Inert atmosphere;	100%

: 624-92-0
Dimethyldisulphide

: 78592-82-2
4-(tert-butyldimethylsilyloxy)-1-butyne

: 125657-48-9
tert-Butyl-dimethyl-(4-methylsulfanyl-but-3-ynyloxy)-silane

Conditions

Conditions	Yield
Stage #1: 4-(tert-butyldimethylsilyloxy)-1-butyne With n-butyllithium In tetrahydrofuran; hexane at 0℃; for 1h; Inert atmosphere; Stage #2: Dimethyldisulphide In tetrahydrofuran; hexane at 20℃; for 3h; Inert atmosphere;	100%

: 624-92-0
Dimethyldisulphide

: 153495-48-8
but-3-ynyloxy-triisopropyl-silane

: triisopropyl((4-(methylthio)but-3-yn-1-yl)oxy)silane

Conditions

Conditions	Yield
Stage #1: but-3-ynyloxy-triisopropyl-silane With n-butyllithium In tetrahydrofuran; hexane at 0℃; for 1h; Inert atmosphere; Stage #2: Dimethyldisulphide In tetrahydrofuran; hexane at 20℃; for 3h; Inert atmosphere;	100%

: 474711-11-0
2-bromo-4-fluoro-1-(methoxymethoxy)benzene

: 624-92-0
Dimethyldisulphide

: 4-fluoro-1-(methoxymethoxy)-2-(methylsulfanyl)benzene

Conditions

Conditions	Yield
Stage #1: 2-bromo-4-fluoro-1-(methoxymethoxy)benzene With tert.-butyl lithium In diethyl ether; pentane at -78℃; for 1h; Inert atmosphere; Stage #2: Dimethyldisulphide In diethyl ether; pentane at 20℃; for 1h; Inert atmosphere;	100%