Products

Refine

Country

Business Type

Certificate

Display

Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

1,1,1,3,3,3-Hexafluoroisopropyl acrylate

Cas:2160-89-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

1,1,1,3,3,3-Hexafluoroisopropyl acrylate

Cas:2160-89-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

1,1,1,3,3,3-Hexafluoroisopropyl acrylate

Cas:2160-89-6

Min.Order:1 Kilogram

FOB Price: $100.0 / 150.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 2160-89-6 with best quality

Cas:2160-89-6

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Henan Sinotech Import&Export Corporation

Molecular Formula C6H4F6O2 Molecular Weight 222.08 CAS Registry Number 2160-89-6 EINECS 218-479-1 Appearance: C

1,1,1,3,3,3-Hexafluoroisopropyl acrylate

Cas:2160-89-6

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

1,1,1,3,3,3-Hexafluoroisopropyl acrylate

Cas:2160-89-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

1,1,1,3,3,3-Hexafluoroisopropyl acrylate CAS:2160-89-6 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high

1,1,1,3,3,3-Hexafluoroisopropyl acrylate CAS:2160-89-6

Cas:2160-89-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

1,1,1,3,3,3-Hexafluoroisopropyl acrylate

Cas:2160-89-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

1,1,1,3,3,3-Hexafluoroisopropyl acrylate

Cas:2160-89-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Lonwin Chemical Group Limited

Lonwin Industry group limited as a professional manufactor & exporter of chemical materials ,we totally haver more than 270 stuffs, we have been on this line for more than 9 years. Our chemical materials are exported to lot of countries and regio

2 2 2-Trifluoro-1-(Trifluoromethyl) Ethyl Acrylate CAS 2160-89-6 2-Propenoic acid

Cas:2160-89-6

Min.Order:100 Kilogram

Negotiable

Type:Other

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 1,1,1,3,3,3-Hexafluoroisopropyl acrylate

Cas:2160-89-6

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1,1,1,3,3,3-Hexafluoroisopropyl acrylate

Cas:2160-89-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

1,1,1,3,3,3-Hexafluoroisopropyl acrylate

Cas:2160-89-6

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

superior quality moderate price & quick delivery Appearance:clear colorless liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used to m

2-Propenoic acid,2,2,2-trifluoro-1-(trifluoromethyl)ethyl ester

Cas:2160-89-6

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

Tianfu Chemical, built in 2009, is a professional supplier for API materials in China. With 10 years development, we have bulit our own factory and lab to produce a certain of products. And we have established stable business relationship

TIANFU CHEM 2160-89-6 1,1,1,3,3,3-Hexafluoroisopropyl acrylate

Cas:2160-89-6

Min.Order:1 Kilogram

FOB Price: $200.0

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

1,1,1,3,3,3-Hexafluoroisopropyl acrylate

Cas:2160-89-6

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

1,1,1,3,3,3-Hexafluoroisopropyl acrylate

Cas:2160-89-6

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Hangzhou Fandachem Co.,Ltd

Hangzhou Fanda Chemical Co.,Ltd (FandaChem) , a China-based chemical company, specialize in exporting 1,1,1,3,3,3-Hexafluoroisopropyl acrylate CAS:2160-89-6 , Please contact us by email freely. We are leading exporter in China. If you

Henan Kanbei Chemical Co.,LTD

High quality, competitive price, fast delivery and first-class service we possesses have won the trust and praise of customers. Standard: BP/USP/EP The purity is equal or greater than 99%. As a supplier, we can provide high-quality products. Cle

hot sale 1,1,1,3,3,3-Hexafluoroisopropyl acrylate

Cas:2160-89-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

1,1,1,3,3,3-Hexafluoroisopropyl acrylate

Cas:2160-89-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

1,1,1,3,3,3-Hexafluoroisopropyl acrylate

Cas:2160-89-6

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

1,1,1,3,3,3-Hexafluoroisopropyl acrylate

Cas:2160-89-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

1,1,1,3,3,3-Hexafluoroisopropyl acrylate

Cas:2160-89-6

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

2-Propenoic acid,2,2,2-trifluoro-1-(trifluoromethyl)ethyl ester

Cas:2160-89-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

1,1,1,3,3,3-Hexafluoroisopropyl acrylate

Cas:2160-89-6

Min.Order:0

Negotiable

Type:Other

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec 1,1,1,3,3,3-Hexafluoroisopropyl Acrylate 25g

Cas:2160-89-6

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

1,1,1,3,3,3-Hexafluoroisopropyl Acrylate (stabilized with MEHQ)

Cas:2160-89-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages? High purity, all above 98.5%, no impurities after dissolution? We will test each batch to ensure quality? OEM and private brand services designed for free? Various cap colors available? We can also provide MT1 peptide powder2.

1,1,1,3,3,3-Hexafluoroisopropyl acrylate

Cas:2160-89-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

1,1,1,3,3,3-Hexafluoroisopropyl acrylate, stabilized with MEHQ

Cas:2160-89-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Application:Chemical intermediate

1,1,1,3,3,3-Hexafluoropropan-2-yl acrylate

Cas:2160-89-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

1,1,1,3',3',3'-hexafluoro-propanol
920-66-1

1,1,1,3',3',3'-hexafluoro-propanol

acryloyl chloride
814-68-6

acryloyl chloride

1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

Conditions
ConditionsYield
With scandium tris(trifluoromethanesulfonate) at 20℃; for 20.0833h;
1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

(E)-(pent-3-en-1-yn-1-yl)cyclohexane

(E)-(pent-3-en-1-yn-1-yl)cyclohexane

1,1,1,3,3,3-hexafluoropropan-2-yl (S,E)-3-cyclohexyl-2-(prop-1-en-1-yl) cyclobut-2-ene-1-carboxylate

1,1,1,3,3,3-hexafluoropropan-2-yl (S,E)-3-cyclohexyl-2-(prop-1-en-1-yl) cyclobut-2-ene-1-carboxylate

Conditions
ConditionsYield
With C27H34Br2CoNOP; sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate; zinc In toluene at 23℃; for 15h; Inert atmosphere; Glovebox; Sealed tube; enantioselective reaction;99%
1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

(E)-(pent-3-en-1-yn-1-yl)cyclohexane

(E)-(pent-3-en-1-yn-1-yl)cyclohexane

1,1,1,3,3,3-hexafluoropropan-2-yl (E)-3-cyclohexyl-2-(prop-1-en-1-yl) cyclobut-2-ene-1-carboxylate

1,1,1,3,3,3-hexafluoropropan-2-yl (E)-3-cyclohexyl-2-(prop-1-en-1-yl) cyclobut-2-ene-1-carboxylate

Conditions
ConditionsYield
With C21H18Br2CoNOP; sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate; zinc In toluene at 23℃; Inert atmosphere; Glovebox; Sealed tube; regioselective reaction;99%
1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

C12H16OS

C12H16OS

C18H20F6O3S

C18H20F6O3S

Conditions
ConditionsYield
With 3,6‐di‐tert‐butyl‐9‐mesityl‐10‐phenylacridin‐10‐ium tetrafluoroborate; sodium 2,2,2-trifluoroacetate In methanol; dichloromethane at 30℃; Irradiation;98%
iodobenzene
591-50-4

iodobenzene

1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

(E)-3-Phenyl-acrylic acid 2,2,2-trifluoro-1-trifluoromethyl-ethyl ester

(E)-3-Phenyl-acrylic acid 2,2,2-trifluoro-1-trifluoromethyl-ethyl ester

Conditions
ConditionsYield
With PdAS-V; triethylamine In toluene at 100℃; for 5h; Heck reaction;95%
With triethylamine; poly{bis[(N-iPr-acrylamide)5-co-((4-vinylphenyl)PPh2)]PdCl2} In toluene at 100℃; for 5h; Heck reaction;95%
1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

N-(o-bromobenzyl)-6-pent-4-enylpiperidin-2-one
606123-24-4

N-(o-bromobenzyl)-6-pent-4-enylpiperidin-2-one

1,1,1,3,3,3-hexafluoroisopropyl (E)-6-[1-(2-bromobenzyl)-6-oxopiperidin-2-yl]hex-2-enoate
606123-37-9

1,1,1,3,3,3-hexafluoroisopropyl (E)-6-[1-(2-bromobenzyl)-6-oxopiperidin-2-yl]hex-2-enoate

Conditions
ConditionsYield
Grubbs catalyst first generation In dichloromethane at 20℃; for 12h;92%
1,4-Oxathiane
15980-15-1

1,4-Oxathiane

1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

C10H12F6O3S

C10H12F6O3S

Conditions
ConditionsYield
With 3,6‐di‐tert‐butyl‐9‐mesityl‐10‐phenylacridin‐10‐ium tetrafluoroborate; sodium 2,2,2-trifluoroacetate In methanol; dichloromethane at 30℃; Irradiation;91%
1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

benzaldehyde
100-52-7

benzaldehyde

1,1,1,3,3,3-hexafluoropropan-2-yl (R)-3-hydroxy-2-methylene-3-phenylpropanoate
253197-70-5

1,1,1,3,3,3-hexafluoropropan-2-yl (R)-3-hydroxy-2-methylene-3-phenylpropanoate

Conditions
ConditionsYield
With 4-(3-ethyl-4-oxa-1-azatricyclo[4,4,0,0(3,8)]dec-5-yl)quinolin-6-ol In tetrahydrofuran; N,N-dimethyl-formamide at -55℃; for 24h; Morita-Baylis-Hillman Alkylation; enantioselective reaction;90%
Stage #1: benzaldehyde With 4-[(5S)-3-ethyl-4-oxa-1-azatricyclo[4.4.0.03,8]decan-5-yl]quinolin-6-yl (2,2,2-trichloroacetyl)carbamate In N,N-dimethyl-formamide at 20℃; for 0.166667h; Morita-Baylis-Hillman reaction; Molecular sieve;
Stage #2: 1,1,1,3,3,3-hexafluoroisopropyl acrylate In N,N-dimethyl-formamide at -55℃; for 3h; Morita-Baylis-Hillman reaction; optical yield given as %ee; enantioselective reaction;
83%
With 4-(3-ethyl-4-oxa-1-azatricyclo[4,4,0,0(3,8)]dec-5-yl)quinolin-6-ol In N,N-dimethyl-formamide at -55℃; for 48h; Baylis-Hillman reaction;75%
With (3R,8R,9S)-10,11-dihydro-3,9-epoxy-6'-hydroxy-cinchonane In N,N-dimethyl-formamide at -55℃; for 48h; Baylis-Hillman reaction;75%
tetrahydrothiopyran-4-ol
29683-23-6

tetrahydrothiopyran-4-ol

1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

C11H14F6O3S

C11H14F6O3S

Conditions
ConditionsYield
With 3,6‐di‐tert‐butyl‐9‐mesityl‐10‐phenylacridin‐10‐ium tetrafluoroborate; sodium 2,2,2-trifluoroacetate In methanol; dichloromethane at 30℃; Irradiation;90%
1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

tert-Butyl-((8R,9S,13S,14S)-3-methoxy-13-methyl-7,8,9,11,12,13,14,15-octahydro-6H-cyclopenta[a]phenanthren-17-yloxy)-dimethyl-silane
96157-01-6

tert-Butyl-((8R,9S,13S,14S)-3-methoxy-13-methyl-7,8,9,11,12,13,14,15-octahydro-6H-cyclopenta[a]phenanthren-17-yloxy)-dimethyl-silane

A

(4bS,6aS,6bR,7R,8aS,9aS,9bR)-6b-(tert-Butyl-dimethyl-silanyloxy)-2-methoxy-6a-methyl-5,6,6a,6b,7,8,8a,9,9a,9b,10,11-dodecahydro-4bH-cyclobuta[3,4]cyclopenta[1,2-a]phenanthrene-7-carboxylic acid 2,2,2-trifluoro-1-trifluoromethyl-ethyl ester

(4bS,6aS,6bR,7R,8aS,9aS,9bR)-6b-(tert-Butyl-dimethyl-silanyloxy)-2-methoxy-6a-methyl-5,6,6a,6b,7,8,8a,9,9a,9b,10,11-dodecahydro-4bH-cyclobuta[3,4]cyclopenta[1,2-a]phenanthrene-7-carboxylic acid 2,2,2-trifluoro-1-trifluoromethyl-ethyl ester

B

(4bS,6aS,6bR,7S,8aS,9aS,9bR)-6b-(tert-Butyl-dimethyl-silanyloxy)-2-methoxy-6a-methyl-5,6,6a,6b,7,8,8a,9,9a,9b,10,11-dodecahydro-4bH-cyclobuta[3,4]cyclopenta[1,2-a]phenanthrene-7-carboxylic acid 2,2,2-trifluoro-1-trifluoromethyl-ethyl ester

(4bS,6aS,6bR,7S,8aS,9aS,9bR)-6b-(tert-Butyl-dimethyl-silanyloxy)-2-methoxy-6a-methyl-5,6,6a,6b,7,8,8a,9,9a,9b,10,11-dodecahydro-4bH-cyclobuta[3,4]cyclopenta[1,2-a]phenanthrene-7-carboxylic acid 2,2,2-trifluoro-1-trifluoromethyl-ethyl ester

Conditions
ConditionsYield
With ethylaluminum dichloride In dichloromethane at -60℃; for 0.166667h; Temperature; Inert atmosphere; Overall yield = 86 %; diastereoselective reaction;A n/a
B 89%
With ethylaluminum dichloride In dichloromethane at -78℃; for 4h; Title compound not separated from byproducts;
1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

tert-Butyl-((8R,9S,13S,14S)-3-methoxy-13-methyl-7,8,9,11,12,13,14,15-octahydro-6H-cyclopenta[a]phenanthren-17-yloxy)-dimethyl-silane
96157-01-6

tert-Butyl-((8R,9S,13S,14S)-3-methoxy-13-methyl-7,8,9,11,12,13,14,15-octahydro-6H-cyclopenta[a]phenanthren-17-yloxy)-dimethyl-silane

(4bS,6aS,6bR,7S,8aS,9aS,9bR)-6b-(tert-Butyl-dimethyl-silanyloxy)-2-methoxy-6a-methyl-5,6,6a,6b,7,8,8a,9,9a,9b,10,11-dodecahydro-4bH-cyclobuta[3,4]cyclopenta[1,2-a]phenanthrene-7-carboxylic acid 2,2,2-trifluoro-1-trifluoromethyl-ethyl ester

(4bS,6aS,6bR,7S,8aS,9aS,9bR)-6b-(tert-Butyl-dimethyl-silanyloxy)-2-methoxy-6a-methyl-5,6,6a,6b,7,8,8a,9,9a,9b,10,11-dodecahydro-4bH-cyclobuta[3,4]cyclopenta[1,2-a]phenanthrene-7-carboxylic acid 2,2,2-trifluoro-1-trifluoromethyl-ethyl ester

Conditions
ConditionsYield
With ethylaluminum dichloride In dichloromethane at -40℃; for 0.166667h; Temperature; Inert atmosphere; diastereoselective reaction;89%
Multi-step reaction with 2 steps
1: ethylaluminum dichloride / dichloromethane / 0.17 h / -60 °C / Inert atmosphere
2: ethylaluminum dichloride / dichloromethane / 0.17 h / 20 °C / Inert atmosphere
View Scheme
Multi-step reaction with 2 steps
1: ethylaluminum dichloride / dichloromethane / 0.17 h / -78 °C / Inert atmosphere
2: ethylaluminum dichloride / dichloromethane / 0.17 h / 20 °C / Inert atmosphere
View Scheme
1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

3,3-diethyl-5,5-dimethylmorpholin-2-one
264279-67-6

3,3-diethyl-5,5-dimethylmorpholin-2-one

C16H21F6NO4

C16H21F6NO4

Conditions
ConditionsYield
With silver(I) acetate; palladium diacetate at 60℃;89%
1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

1-(((dimethyl(oxo)- λ6-sulfanylidene)methyl)sulfonyl)-4-methylbenzene

1-(((dimethyl(oxo)- λ6-sulfanylidene)methyl)sulfonyl)-4-methylbenzene

1,1,1,3,3,3-hexafluoropropan-2-yl 2-(6-methyl-3-oxo-2,3-dihydro-1H-inden-1-yl)acetate

1,1,1,3,3,3-hexafluoropropan-2-yl 2-(6-methyl-3-oxo-2,3-dihydro-1H-inden-1-yl)acetate

Conditions
ConditionsYield
With silver hexafluoroantimonate; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; 1,1,1,3',3',3'-hexafluoro-propanol; sodium acetate at 100℃; for 24h; Glovebox;88%
1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

(2R,3S)-3-triethylsiloxy-2-methyl-3-phenylpropanal

(2R,3S)-3-triethylsiloxy-2-methyl-3-phenylpropanal

1,1,1,3,3,3-hexafluoropropan-2-yl (3R,4S,5R)-3-hydroxy-5-triethylsiloxy-4-methyl-2-methylene-5-phenylpentanoate

1,1,1,3,3,3-hexafluoropropan-2-yl (3R,4S,5R)-3-hydroxy-5-triethylsiloxy-4-methyl-2-methylene-5-phenylpentanoate

Conditions
ConditionsYield
With 4-(3-ethyl-4-oxa-1-azatricyclo[4,4,0,0(3,8)]dec-5-yl)quinolin-6-ol In tetrahydrofuran; N,N-dimethyl-formamide at -55℃; for 72h; Morita-Baylis-Hillman Alkylation;87%
1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

4-nitrobenzaldehdye
555-16-8

4-nitrobenzaldehdye

1,1,1,3,3,3-hexafluoropropan-2-yl (R)-3-hydroxy-2-methylene-3-(4-nitrophenyl)-propanoate

1,1,1,3,3,3-hexafluoropropan-2-yl (R)-3-hydroxy-2-methylene-3-(4-nitrophenyl)-propanoate

Conditions
ConditionsYield
With C33H27F6FeN2PS; sodium hydroxide In tetrahydrofuran at 25℃; for 48h; Catalytic behavior; Reagent/catalyst; Morita-Baylis-Hillman Alkylation; enantioselective reaction;85%
Stage #1: 4-nitrobenzaldehdye With 4-[(5S)-3-ethyl-4-oxa-1-azatricyclo[4.4.0.03,8]decan-5-yl]quinolin-6-yl (2,2,2-trichloroacetyl)carbamate In N,N-dimethyl-formamide at 20℃; for 0.166667h; Morita-Baylis-Hillman reaction; Molecular sieve;
Stage #2: 1,1,1,3,3,3-hexafluoroisopropyl acrylate In N,N-dimethyl-formamide at -55℃; for 2h; Morita-Baylis-Hillman reaction; optical yield given as %ee; enantioselective reaction;
63%
1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

tert-Butyl-((8R,9S,13S,14S)-3-methoxy-13-methyl-7,8,9,11,12,13,14,15-octahydro-6H-cyclopenta[a]phenanthren-17-yloxy)-dimethyl-silane
96157-01-6

tert-Butyl-((8R,9S,13S,14S)-3-methoxy-13-methyl-7,8,9,11,12,13,14,15-octahydro-6H-cyclopenta[a]phenanthren-17-yloxy)-dimethyl-silane

(4bS,6aS,6bR,7R,8aS,9aS,9bR)-6b-(tert-Butyl-dimethyl-silanyloxy)-2-methoxy-6a-methyl-5,6,6a,6b,7,8,8a,9,9a,9b,10,11-dodecahydro-4bH-cyclobuta[3,4]cyclopenta[1,2-a]phenanthrene-7-carboxylic acid 2,2,2-trifluoro-1-trifluoromethyl-ethyl ester

(4bS,6aS,6bR,7R,8aS,9aS,9bR)-6b-(tert-Butyl-dimethyl-silanyloxy)-2-methoxy-6a-methyl-5,6,6a,6b,7,8,8a,9,9a,9b,10,11-dodecahydro-4bH-cyclobuta[3,4]cyclopenta[1,2-a]phenanthrene-7-carboxylic acid 2,2,2-trifluoro-1-trifluoromethyl-ethyl ester

Conditions
ConditionsYield
With ethylaluminum dichloride In dichloromethane at -78℃; for 0.166667h; Inert atmosphere; diastereoselective reaction;85%
3-hydroxypropyl benzoate
6946-99-2

3-hydroxypropyl benzoate

1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

2-(5-oxotetrahydrofuran-2-yl)ethyl benzoate

2-(5-oxotetrahydrofuran-2-yl)ethyl benzoate

Conditions
ConditionsYield
With quinuclidin-3-yl benzenesulfonate; 3,3,3',3'-tetrakis(trifluoromethyl)-1,1'(3H,3'H)-spirobi<2,1-benzoxasilole>; C36H16F16IrN4(1+)*F6P(1-) In acetonitrile at 20℃; for 14h; Glovebox; Inert atmosphere; Sealed tube; Irradiation;85%
1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

β-naphthaldehyde
66-99-9

β-naphthaldehyde

1,1,1,3,3,3-hexafluoropropan-2-yl (S)-3-hydroxy-2-methylene-3-(naphthalen-2-yl)-propanoate
1476067-48-7

1,1,1,3,3,3-hexafluoropropan-2-yl (S)-3-hydroxy-2-methylene-3-(naphthalen-2-yl)-propanoate

Conditions
ConditionsYield
With α-isocupreine In N,N-dimethyl-formamide at -55℃; for 48h; Morita-Baylis-Hillman Alkylation; Inert atmosphere; enantioselective reaction;84%
1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

3-nitro-benzaldehyde
99-61-6

3-nitro-benzaldehyde

C13H9F6NO5

C13H9F6NO5

Conditions
ConditionsYield
With C33H27F6FeN2PS; sodium hydroxide In tetrahydrofuran at 25℃; for 48h; Morita-Baylis-Hillman Alkylation; enantioselective reaction;84%
1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

(S)-N-tert-butoxycarbonylvalinal
79069-51-5

(S)-N-tert-butoxycarbonylvalinal

A

tert-butyl (3S,4S)-[5-((1,1,1,3,3,3-hexafluoropropan-2-yloxy)carbonyl)-4-hydroxy-2-methylhex-5-en-3-yl]carbamate
916823-42-2

tert-butyl (3S,4S)-[5-((1,1,1,3,3,3-hexafluoropropan-2-yloxy)carbonyl)-4-hydroxy-2-methylhex-5-en-3-yl]carbamate

B

(2R,6S)-2,6-bis((S)-1-((tert-butoxycarbonyl)amino)-2-methylpropyl)-5-methylidene-1,3-dioxan-4-one

(2R,6S)-2,6-bis((S)-1-((tert-butoxycarbonyl)amino)-2-methylpropyl)-5-methylidene-1,3-dioxan-4-one

Conditions
ConditionsYield
With 4-(3-ethyl-4-oxa-1-azatricyclo[4,4,0,0(3,8)]dec-5-yl)quinolin-6-ol In N,N-dimethyl-formamide at -55℃; for 46h;A 83%
B 3%
thiophene
110-01-0

thiophene

1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

C10H12F6O2S

C10H12F6O2S

Conditions
ConditionsYield
With 3,6‐di‐tert‐butyl‐9‐mesityl‐10‐phenylacridin‐10‐ium tetrafluoroborate; sodium 2,2,2-trifluoroacetate In methanol; dichloromethane at 30℃; Irradiation;83%
sulfure de pentamethylene
1613-51-0

sulfure de pentamethylene

1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

C11H14F6O2S

C11H14F6O2S

Conditions
ConditionsYield
With 3,6‐di‐tert‐butyl‐9‐mesityl‐10‐phenylacridin‐10‐ium tetrafluoroborate; sodium 2,2,2-trifluoroacetate In methanol; dichloromethane at 30℃; Irradiation;83%
Tetrahydrothiopyran-4-one
1072-72-6

Tetrahydrothiopyran-4-one

1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

C11H12F6O3S

C11H12F6O3S

Conditions
ConditionsYield
With 3,6‐di‐tert‐butyl‐9‐mesityl‐10‐phenylacridin‐10‐ium tetrafluoroborate; sodium 2,2,2-trifluoroacetate In methanol; dichloromethane at 30℃; Irradiation;83%
1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

tert-butyl (cyclohept-1-en-1-yloxy)dimethylsilane
68081-19-6

tert-butyl (cyclohept-1-en-1-yloxy)dimethylsilane

(1RS,7SR,9RS)-1-(tert-butyldimethylsiloxy)-9-(1,1,1,3,3,3-hexafluoroisopropoxycarbonyl)bicyclo[5.2.0]nonane

(1RS,7SR,9RS)-1-(tert-butyldimethylsiloxy)-9-(1,1,1,3,3,3-hexafluoroisopropoxycarbonyl)bicyclo[5.2.0]nonane

Conditions
ConditionsYield
With ethylaluminum dichloride In dichloromethane at -78℃; for 4h;82%
1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

β-naphthaldehyde
66-99-9

β-naphthaldehyde

1,1,1,3,3,3-hexafluoropropan-2-yl (R)-3-hydroxy-2-methylene-3-(naphthalen-2-yl)propanoate

1,1,1,3,3,3-hexafluoropropan-2-yl (R)-3-hydroxy-2-methylene-3-(naphthalen-2-yl)propanoate

Conditions
ConditionsYield
With (3R,8R,9S)-10,11-dihydro-3,9-epoxy-6'-hydroxy-cinchonane In N,N-dimethyl-formamide at -55℃; for 58h; Baylis-Hillman reaction;82%
1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

1,1,1,3,3,3-hexafluoro-propan-2-yl 3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)propanoate
1454308-52-1

1,1,1,3,3,3-hexafluoro-propan-2-yl 3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)propanoate

Conditions
ConditionsYield
Stage #1: bis(pinacol)diborane With copper(II) carbonate; triphenylphosphine In water at 20℃; for 0.5h; Inert atmosphere;
Stage #2: 1,1,1,3,3,3-hexafluoroisopropyl acrylate In water at 27℃; for 24h; Inert atmosphere;
82%
Stage #1: bis(pinacol)diborane With copper carbonate hydroxide; triphenylphosphine In water at 20℃; for 0.5h; Inert atmosphere;
Stage #2: 1,1,1,3,3,3-hexafluoroisopropyl acrylate In water at 27℃; for 24h; Inert atmosphere;
82%
Stage #1: bis(pinacol)diborane With copper(II) carbonate; triphenylphosphine In water at 20℃; for 0.5h; Inert atmosphere;
Stage #2: 1,1,1,3,3,3-hexafluoroisopropyl acrylate In water at 27℃; for 24h; Inert atmosphere;
82%
1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

hexan-1-ol
111-27-3

hexan-1-ol

γ-nonalactone
104-61-0

γ-nonalactone

Conditions
ConditionsYield
With quinuclidin-3-yl benzenesulfonate; 3,3,3',3'-tetrakis(trifluoromethyl)-1,1'(3H,3'H)-spirobi<2,1-benzoxasilole>; C36H16F16IrN4(1+)*F6P(1-) In acetonitrile at 20℃; for 14h; Glovebox; Inert atmosphere; Sealed tube; Irradiation;82%
1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

1-triisopropylsiloxy-1-cyclohexene
80522-46-9

1-triisopropylsiloxy-1-cyclohexene

(1RS,6SR,8RS)-1-(triisopropylsiloxy)-8-(1,1,1,3,3,3-hexafluoroisopropoxycarbonyl)bicyclo[4.2.0]octane

(1RS,6SR,8RS)-1-(triisopropylsiloxy)-8-(1,1,1,3,3,3-hexafluoroisopropoxycarbonyl)bicyclo[4.2.0]octane

Conditions
ConditionsYield
With ethylaluminum dichloride In dichloromethane at -78℃; for 4h;80%
1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

4-chloro-3-nitro-benzaldehyde
16588-34-4

4-chloro-3-nitro-benzaldehyde

C13H8ClF6NO5

C13H8ClF6NO5

Conditions
ConditionsYield
With C33H27F6FeN2PS; sodium hydroxide In tetrahydrofuran at 25℃; for 48h; Morita-Baylis-Hillman Alkylation; enantioselective reaction;80%
4-(phenylthio-methyl)-piperidine-1-carboxylic acid tert-butyl ester
875282-59-0

4-(phenylthio-methyl)-piperidine-1-carboxylic acid tert-butyl ester

1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

C23H29F6NO4S

C23H29F6NO4S

Conditions
ConditionsYield
With 3,6‐di‐tert‐butyl‐9‐mesityl‐10‐phenylacridin‐10‐ium tetrafluoroborate; sodium 2,2,2-trifluoroacetate In methanol; dichloromethane at 30℃; Irradiation;78%
1,1,1,3,3,3-hexafluoroisopropyl acrylate
2160-89-6

1,1,1,3,3,3-hexafluoroisopropyl acrylate

tert-butoxycarbonyl-L-leucinal
58521-45-2

tert-butoxycarbonyl-L-leucinal

A

tert-butyl (3S,4S)-[2-((1,1,1,3,3,3-hexafluoropropan-2-yloxy)carbonyl)-3-hydroxy-6-methylhept-1-en-4-yl]carbamate
916823-40-0

tert-butyl (3S,4S)-[2-((1,1,1,3,3,3-hexafluoropropan-2-yloxy)carbonyl)-3-hydroxy-6-methylhept-1-en-4-yl]carbamate

B

2,6-bis((S)-1-((tert-butoxycarbonyl)amino)-3-methylbutyl)-5-methylidene-1,3-dioxan-4-one

2,6-bis((S)-1-((tert-butoxycarbonyl)amino)-3-methylbutyl)-5-methylidene-1,3-dioxan-4-one

Conditions
ConditionsYield
With 4-(3-ethyl-4-oxa-1-azatricyclo[4,4,0,0(3,8)]dec-5-yl)quinolin-6-ol In N,N-dimethyl-formamide at -55℃; for 46h;A 77%
B 4%

Hot Products

Post buying leads

About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia

Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog

©2008 LookChem.com,License: ICP

NO.:Zhejiang16009103

complaints:service@lookchem.com Desktop View