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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

Perfluorodecalin 306-94-5

Cas:306-94-5

Min.Order:1 Metric Ton

FOB Price: $500.0

Type:Lab/Research institutions

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Perfluorodecalin

Cas:306-94-5

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Perflunafene

Cas:306-94-5

Min.Order:1

Negotiable

Type:Other

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Octadecafluorodecahydronaphthalene

Cas:306-94-5

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

Perfluorodecalin

Cas:306-94-5

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Competitve Price in stock CAS 306-94-5 with high-quality service

Cas:306-94-5

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Perfluorodecalin/F-DC/perflunafene 306-94-5

Cas:306-94-5

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages ♦ High purity, all above 98.5%, no impurities after dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available ♦ W

PerfluorodecalinCAS306-94-5

Cas:306-94-5

Min.Order:1 Kilogram

FOB Price: $22.0 / 45.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Naphthalene,1,1,2,2,3,3,4,4,4a,5,5,6,6,7,7,8,8,8a-octadecafluorodecahydro- 306-94-5

Cas:306-94-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

Perfluorodecalin CAS:306-94-5 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermedia

Perfluorodecalin CAS:306-94-5

Cas:306-94-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Naphthalene,1,1,2,2,3,3,4,4,4a,5,5,6,6,7,7,8,8,8a-octadecafluorodecahydro-

Cas:306-94-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Naphthalene,1,1,2,2,3,3,4,4,4a,5,5,6,6,7,7,8,8,8a-octadecafluorodecahydro-

Cas:306-94-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Fluorodecalin

Cas:306-94-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Perfluorodecalin

Cas:306-94-5

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Our Services 1. New Molecules R&D 2. Own test center HPLC NMR GC LC-MS 3. API and Intermediates from China reputed manufacturers 4. Documents support COA MOA MSDS DMF open part Our advantages 1. Government awarded company. Top 100 enter

PERFLUORODECALIN

Cas:306-94-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

Perfluorodecalin

Cas:306-94-5

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Fonlynn Health Technology Co., Ltd.

Packing: According to customer requirements Delivery time: In stock or depands Port of shipment: Ningbo/Shanghai/Qingdao OEM/ODM:Welcome Sample:We can offer our existing samples at once Transportation:Express/Sea/Air Port:Ningbo/Shanghai/Qingd

Perfluorodecalin

Cas:306-94-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Naphthalene,1,1,2,2,3,3,4,4,4a,5,5,6,6,7,7,8,8,8a-octadecafluorodecahydro-

Cas:306-94-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High Quality Perfluorodecalin

Cas:306-94-5

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

Perfluorodecalin 306-94-5

Cas:306-94-5

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:colourless liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum, or as per your request. Application:Used as Pharmaceutical Intermediat

Naphthalene,1,1,2,2,3,3,4,4,4a,5,5,6,6,7,7,8,8,8a-octadecafluorodecahydro-

Cas:306-94-5

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Perfluorodecalin

Cas:306-94-5

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Top Purity Perfluorodecalin

Cas:306-94-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Henan Kanbei Chemical Co.,LTD

High quality, competitive price, fast delivery and first-class service we possesses have won the trust and praise of customers. Standard: BP/USP/EP The purity is equal or greater than 99%. As a supplier, we can provide high-quality products. Cle

high purity Perfluorodecalin

Cas:306-94-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Perfluorodecalin 306-94-5

Cas:306-94-5

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

Perfluorodecalin

Cas:306-94-5

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Perfluorodecalin 306-94-5

Cas:306-94-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Perfluorodecalin 306-94-5

Cas:306-94-5

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Perfluorodecalin

Cas:306-94-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Synthetic route

naphthalene
91-20-3

naphthalene

octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

Conditions
ConditionsYield
With silver(II) fluoride at 225 - 330℃;
With nickel(II) fluoride; cobalt (III) fluoride; fluorine 1.) 450 deg C, 2.) 450-500 deg C; Multistep reaction;
With silver(II) fluoride at 225 - 330℃;
tetralin
119-64-2

tetralin

octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

Conditions
ConditionsYield
With silver plated copper; fluorine at 350 - 380℃;
decalin
91-17-8

decalin

octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

Conditions
ConditionsYield
With silver(II) fluoride at 225 - 330℃;
With silver(II) fluoride at 225 - 330℃;
1-Chloronaphthalene
90-13-1

1-Chloronaphthalene

octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

Conditions
ConditionsYield
With silver(II) fluoride at 225 - 330℃;
With silver(II) fluoride at 225 - 330℃;
octafluoronaphthalene
313-72-4

octafluoronaphthalene

octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

Conditions
ConditionsYield
With antimony pentafluoride at 300℃;
(2,3,7,8,12,13,17,18-octakis(ethylsulfanyl)-5,10,15,20-tetraazaporphyrinato)manganese(II)

(2,3,7,8,12,13,17,18-octakis(ethylsulfanyl)-5,10,15,20-tetraazaporphyrinato)manganese(II)

octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

fluoro(2,3,7,8,12,13,17,18-octakis(ethylsulfanyl)-5,10,15,20-tetraazaporphyrinato)manganese(III)

fluoro(2,3,7,8,12,13,17,18-octakis(ethylsulfanyl)-5,10,15,20-tetraazaporphyrinato)manganese(III)

Conditions
ConditionsYield
In tetrahydrofuran byproducts: C10F14, C10F13; react. of Mn complex with large excess of perfluorodecalin (molar ratio1:19) in THF at 20°C; detd. by GC and GC/MS;95%
octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

C24H23N3NiO2

C24H23N3NiO2

A

octafluoronaphthalene
313-72-4

octafluoronaphthalene

B

C24H22FN3NiO2

C24H22FN3NiO2

Conditions
ConditionsYield
In tetrahydrofuran-d8 at 20℃; for 72h;A n/a
B 94%
octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoro-8-imino-3,4,5,6,7,8-hexahydro-2H-naphthalene-1,4a-diamine
60470-36-2

2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoro-8-imino-3,4,5,6,7,8-hexahydro-2H-naphthalene-1,4a-diamine

Conditions
ConditionsYield
With ammonia; mercury Irradiation;92%
octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

(hydrotris(3,5-dimethylpyrazolyl)borate)2U(CH2Ph)

(hydrotris(3,5-dimethylpyrazolyl)borate)2U(CH2Ph)

(hydrotris(3,5-dimethylpyrazolyl)borate)2UF

(hydrotris(3,5-dimethylpyrazolyl)borate)2UF

Conditions
ConditionsYield
In tetrahydrofuran for 1h; Inert atmosphere;68%
octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

sodium thiophenolate
930-69-8

sodium thiophenolate

octakis(phenylthio)naphthalene
86831-17-6

octakis(phenylthio)naphthalene

Conditions
ConditionsYield
With 1,3-dimethyl-2-imidazolidinone at 50 - 60℃; for 240h;65%
octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

octafluoronaphthalene
313-72-4

octafluoronaphthalene

Conditions
ConditionsYield
With benzophenone; sodium In tetrahydrofuran for 1.5h; -70 deg C to rt;62%
With benzophenone; sodium In tetrahydrofuran for 1.5h; other substrates, other reducing agents, other temperature;62%
With cobaltocene; lithium trifluoromethanesulfonate In diethyl ether for 12h; Ambient temperature;53%
1,2-dimethoxyethanebis(pentadeuterocyclopentadienyl)ytterbium(II)

1,2-dimethoxyethanebis(pentadeuterocyclopentadienyl)ytterbium(II)

octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

tri(bis(cyclopentadienyl)(μ-fluoro)ytterbium(III))

tri(bis(cyclopentadienyl)(μ-fluoro)ytterbium(III))

Conditions
ConditionsYield
In 1,2-dimethoxyethane under Ar or N2; addn. of perfluorodecalin to soln. of YbCp2(DME) in DME, stirring for 48 h at room temp.; filtration of ppt., washing with DME, drying for 3 h under vac.; elem. anal.;49%
octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

A

octafluoronaphthalene
313-72-4

octafluoronaphthalene

B

perfluorotetralin
2342-07-6

perfluorotetralin

Conditions
ConditionsYield
With sodium oxalate at 465℃; Product distribution; Further Variations:; various carrier gases, preheat time and addition time of substrate; Aromatisation;A 42%
B 10%
With sodium oxalate at 425℃;
octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

[Yb(2,6-Et2C6H3 formamidinate)2(thf)2]

[Yb(2,6-Et2C6H3 formamidinate)2(thf)2]

[{Yb(2,6-Et2C6H3 formamidinate)2(μ2-F)}2]

[{Yb(2,6-Et2C6H3 formamidinate)2(μ2-F)}2]

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 24h; Schlenk technique; Inert atmosphere;40%
octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

[Yb(o-PhPhformamidinate)2(thf)2]·2THF

[Yb(o-PhPhformamidinate)2(thf)2]·2THF

[{Yb(o-PhPh formamidinate)2(μ2-F)}2]

[{Yb(o-PhPh formamidinate)2(μ2-F)}2]

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 24h; Schlenk technique; Inert atmosphere;38%
octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

hexadecafluoro-bicyclo<4.4.0>dec-1(6)-ene
54939-04-7

hexadecafluoro-bicyclo<4.4.0>dec-1(6)-ene

Conditions
ConditionsYield
With N,N,N',N'-tetramethyl-para-phenylenediamine In hexane; N,N-dimethyl-formamide for 4h; Irradiation;35%
With pyrographite at 450℃; for 2h; Product distribution; further reagent, temperature, substituted perfluorodecalins;
With tetra-(n-butyl)ammonium iodide In tetrahydrofuran Elimination; Irradiation;
octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

sodium cyclohexanethiolate
50729-68-5

sodium cyclohexanethiolate

octakis(cyclohexylsulfanyl)naphthalene
133494-14-1

octakis(cyclohexylsulfanyl)naphthalene

Conditions
ConditionsYield
With 1,3-dimethyl-2-imidazolinone at 60℃; for 336h;34%
Yb(η5-methylcyclopentadienyl)2*(tetrahydrofuran)
76137-73-0

Yb(η5-methylcyclopentadienyl)2*(tetrahydrofuran)

octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

tetra((μ-fluoro)bis(methylcyclopentadienyl)ytterbium(III))
275377-70-3

tetra((μ-fluoro)bis(methylcyclopentadienyl)ytterbium(III))

Conditions
ConditionsYield
In 1,2-dimethoxyethane under Ar or N2; addn. of DME to Yb(MeCp)2(THF) and perfluorodecalin, stirring for 24 h at room temp.; filtration of solid, washing with DME, drying for 3 h under vac.; elem.anal.;25%
Yb(η5-methylcyclopentadienyl)2*(tetrahydrofuran)
76137-73-0

Yb(η5-methylcyclopentadienyl)2*(tetrahydrofuran)

octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

di((μ-fluoro)bis(methylcyclopentadienyl)(tetrahydrofuran)ytterbium(III))
275377-73-6

di((μ-fluoro)bis(methylcyclopentadienyl)(tetrahydrofuran)ytterbium(III))

Conditions
ConditionsYield
In tetrahydrofuran under Ar or N2; stirring Yb(MeCp)2(THF) and perfluorodecalin for 48 h in THF at room temp., warming up to 50°C for 2 h, slow cooling; filtration of ppt., washing with THF; elem. anal.;24%
naphthalene
91-20-3

naphthalene

octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

Conditions
ConditionsYield
With silver(II) fluoride at 225 - 330℃;
With nickel(II) fluoride; cobalt (III) fluoride; fluorine 1.) 450 deg C, 2.) 450-500 deg C; Multistep reaction;
With silver(II) fluoride at 225 - 330℃;
tetralin
119-64-2

tetralin

octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

Conditions
ConditionsYield
With silver plated copper; fluorine at 350 - 380℃;
decalin
91-17-8

decalin

octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

Conditions
ConditionsYield
With silver(II) fluoride at 225 - 330℃;
With silver(II) fluoride at 225 - 330℃;
1-Chloronaphthalene
90-13-1

1-Chloronaphthalene

octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

Conditions
ConditionsYield
With silver(II) fluoride at 225 - 330℃;
With silver(II) fluoride at 225 - 330℃;
octafluoronaphthalene
313-72-4

octafluoronaphthalene

octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

Conditions
ConditionsYield
With antimony pentafluoride at 300℃;
(2,3,7,8,12,13,17,18-octakis(ethylsulfanyl)-5,10,15,20-tetraazaporphyrinato)manganese(II)

(2,3,7,8,12,13,17,18-octakis(ethylsulfanyl)-5,10,15,20-tetraazaporphyrinato)manganese(II)

octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

fluoro(2,3,7,8,12,13,17,18-octakis(ethylsulfanyl)-5,10,15,20-tetraazaporphyrinato)manganese(III)

fluoro(2,3,7,8,12,13,17,18-octakis(ethylsulfanyl)-5,10,15,20-tetraazaporphyrinato)manganese(III)

Conditions
ConditionsYield
In tetrahydrofuran byproducts: C10F14, C10F13; react. of Mn complex with large excess of perfluorodecalin (molar ratio1:19) in THF at 20°C; detd. by GC and GC/MS;95%
octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

C24H23N3NiO2

C24H23N3NiO2

A

octafluoronaphthalene
313-72-4

octafluoronaphthalene

B

C24H22FN3NiO2

C24H22FN3NiO2

Conditions
ConditionsYield
In tetrahydrofuran-d8 at 20℃; for 72h;A n/a
B 94%
octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoro-8-imino-3,4,5,6,7,8-hexahydro-2H-naphthalene-1,4a-diamine
60470-36-2

2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoro-8-imino-3,4,5,6,7,8-hexahydro-2H-naphthalene-1,4a-diamine

Conditions
ConditionsYield
With ammonia; mercury Irradiation;92%
octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

(hydrotris(3,5-dimethylpyrazolyl)borate)2U(CH2Ph)

(hydrotris(3,5-dimethylpyrazolyl)borate)2U(CH2Ph)

(hydrotris(3,5-dimethylpyrazolyl)borate)2UF

(hydrotris(3,5-dimethylpyrazolyl)borate)2UF

Conditions
ConditionsYield
In tetrahydrofuran for 1h; Inert atmosphere;68%
octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

sodium thiophenolate
930-69-8

sodium thiophenolate

octakis(phenylthio)naphthalene
86831-17-6

octakis(phenylthio)naphthalene

Conditions
ConditionsYield
With 1,3-dimethyl-2-imidazolidinone at 50 - 60℃; for 240h;65%
octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

octafluoronaphthalene
313-72-4

octafluoronaphthalene

Conditions
ConditionsYield
With benzophenone; sodium In tetrahydrofuran for 1.5h; -70 deg C to rt;62%
With benzophenone; sodium In tetrahydrofuran for 1.5h; other substrates, other reducing agents, other temperature;62%
With cobaltocene; lithium trifluoromethanesulfonate In diethyl ether for 12h; Ambient temperature;53%
1,2-dimethoxyethanebis(pentadeuterocyclopentadienyl)ytterbium(II)

1,2-dimethoxyethanebis(pentadeuterocyclopentadienyl)ytterbium(II)

octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

tri(bis(cyclopentadienyl)(μ-fluoro)ytterbium(III))

tri(bis(cyclopentadienyl)(μ-fluoro)ytterbium(III))

Conditions
ConditionsYield
In 1,2-dimethoxyethane under Ar or N2; addn. of perfluorodecalin to soln. of YbCp2(DME) in DME, stirring for 48 h at room temp.; filtration of ppt., washing with DME, drying for 3 h under vac.; elem. anal.;49%
octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

A

octafluoronaphthalene
313-72-4

octafluoronaphthalene

B

perfluorotetralin
2342-07-6

perfluorotetralin

Conditions
ConditionsYield
With sodium oxalate at 465℃; Product distribution; Further Variations:; various carrier gases, preheat time and addition time of substrate; Aromatisation;A 42%
B 10%
With sodium oxalate at 425℃;
octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

[Yb(2,6-Et2C6H3 formamidinate)2(thf)2]

[Yb(2,6-Et2C6H3 formamidinate)2(thf)2]

[{Yb(2,6-Et2C6H3 formamidinate)2(μ2-F)}2]

[{Yb(2,6-Et2C6H3 formamidinate)2(μ2-F)}2]

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 24h; Schlenk technique; Inert atmosphere;40%
octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

[Yb(o-PhPhformamidinate)2(thf)2]·2THF

[Yb(o-PhPhformamidinate)2(thf)2]·2THF

[{Yb(o-PhPh formamidinate)2(μ2-F)}2]

[{Yb(o-PhPh formamidinate)2(μ2-F)}2]

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 24h; Schlenk technique; Inert atmosphere;38%
octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

hexadecafluoro-bicyclo<4.4.0>dec-1(6)-ene
54939-04-7

hexadecafluoro-bicyclo<4.4.0>dec-1(6)-ene

Conditions
ConditionsYield
With N,N,N',N'-tetramethyl-para-phenylenediamine In hexane; N,N-dimethyl-formamide for 4h; Irradiation;35%
With pyrographite at 450℃; for 2h; Product distribution; further reagent, temperature, substituted perfluorodecalins;
With tetra-(n-butyl)ammonium iodide In tetrahydrofuran Elimination; Irradiation;
octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

sodium cyclohexanethiolate
50729-68-5

sodium cyclohexanethiolate

octakis(cyclohexylsulfanyl)naphthalene
133494-14-1

octakis(cyclohexylsulfanyl)naphthalene

Conditions
ConditionsYield
With 1,3-dimethyl-2-imidazolinone at 60℃; for 336h;34%
Yb(η5-methylcyclopentadienyl)2*(tetrahydrofuran)
76137-73-0

Yb(η5-methylcyclopentadienyl)2*(tetrahydrofuran)

octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

tetra((μ-fluoro)bis(methylcyclopentadienyl)ytterbium(III))
275377-70-3

tetra((μ-fluoro)bis(methylcyclopentadienyl)ytterbium(III))

Conditions
ConditionsYield
In 1,2-dimethoxyethane under Ar or N2; addn. of DME to Yb(MeCp)2(THF) and perfluorodecalin, stirring for 24 h at room temp.; filtration of solid, washing with DME, drying for 3 h under vac.; elem.anal.;25%
Yb(η5-methylcyclopentadienyl)2*(tetrahydrofuran)
76137-73-0

Yb(η5-methylcyclopentadienyl)2*(tetrahydrofuran)

octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

di((μ-fluoro)bis(methylcyclopentadienyl)(tetrahydrofuran)ytterbium(III))
275377-73-6

di((μ-fluoro)bis(methylcyclopentadienyl)(tetrahydrofuran)ytterbium(III))

Conditions
ConditionsYield
In tetrahydrofuran under Ar or N2; stirring Yb(MeCp)2(THF) and perfluorodecalin for 48 h in THF at room temp., warming up to 50°C for 2 h, slow cooling; filtration of ppt., washing with THF; elem. anal.;24%
octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

sodium cyclopentanethiolate
56481-26-6

sodium cyclopentanethiolate

oktakis(cyclopentylthio)naphthalene
139223-57-7

oktakis(cyclopentylthio)naphthalene

Conditions
ConditionsYield
With 1,3-dimethyl-2-imidazolinone at 60℃; for 336h;23%
octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

perfluorotetralin
2342-07-6

perfluorotetralin

Conditions
ConditionsYield
iron at 460 - 500℃;
octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

β‐cyclodextrin
7585-39-9

β‐cyclodextrin

C42H70O35*C10F18

C42H70O35*C10F18

Conditions
ConditionsYield
Equilibrium constant;
octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

alpha cyclodextrin
10016-20-3

alpha cyclodextrin

C36H60O30*C10F18

C36H60O30*C10F18

Conditions
ConditionsYield
Equilibrium constant;
octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

A

octafluoronaphthalene
313-72-4

octafluoronaphthalene

B

1,3,4,5,6,7,8-heptafluoronaphthalene
784-00-9

1,3,4,5,6,7,8-heptafluoronaphthalene

Conditions
ConditionsYield
With zirconocene dichloride; magnesium; mercury dichloride In tetrahydrofuran for 2h; Ambient temperature;A 55 % Spectr.
B 35 % Spectr.
octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

2,6-dihydrogenhexafluoronaphthalene
123414-66-4

2,6-dihydrogenhexafluoronaphthalene

Conditions
ConditionsYield
With zirconocene dichloride; magnesium; mercury dichloride In tetrahydrofuran for 14h; Ambient temperature;
octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

perfluorobicyclo<4.4.0>dec-1(2)-en-6-ol
128455-04-9

perfluorobicyclo<4.4.0>dec-1(2)-en-6-ol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: Bu4NI*xH2O / tetrahydrofuran / Irradiation
2: Bu4NI*xH2O / tetrahydrofuran / Irradiation
View Scheme
octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

2,2,3,3,4,4,5,5,6,6,7,7,8,8-tetradecafluoro-3,4,5,6,7,8-hexahydro-2H-naphthalene-1,4a-diol

2,2,3,3,4,4,5,5,6,6,7,7,8,8-tetradecafluoro-3,4,5,6,7,8-hexahydro-2H-naphthalene-1,4a-diol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: Bu4NI*xH2O / tetrahydrofuran / Irradiation
2: Bu4NI*xH2O / tetrahydrofuran / Irradiation
3: Bu4NI*xH2O / tetrahydrofuran / Irradiation
View Scheme
Yb(2,6-di-tert-butylphenolate)2(THF)3
148352-98-1

Yb(2,6-di-tert-butylphenolate)2(THF)3

octadecafluorodecahydronaphthalene (cis+trans)
306-94-5

octadecafluorodecahydronaphthalene (cis+trans)

di(bis(2,6-di-tert-butylphenolato)(μ-fluoro)(tetrahydrofuran)ytterbium(III))
275377-65-6

di(bis(2,6-di-tert-butylphenolato)(μ-fluoro)(tetrahydrofuran)ytterbium(III))

Conditions
ConditionsYield
In tetrahydrofuran under Ar or N2; stirring Yb complex and perfluorodecalin in THF at roomtemp. for 48 h, heating to 50°C, cooling to room temp.; filtration of solid, washing with THF, drying for at least 3 h under vac.; elem. anal.;
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