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Luyunjia Chemistry Xiamen Limited

Specifications CAS No.: 14363-16-7 Other Names: Nickel acetylacetonate hydrate MF: C10 H14 O4 Ni . 2 H2 O EINECS No.: 14363-16-7 Place of Origin: Fujian, China (Mainland) Type: Syntheses Material Intermediates Purity: 99% Brand Name:

3264-82-2 Nickel(II) acetylacetonate

Cas:3264-82-2

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Appearance Bright green powder Conforms Assay 99% co

High purity Various Specifications Nickel(II) acetylacetonate CAS:3264-82-2

Cas:3264-82-2

Min.Order:1 Gram

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality bis-(2,4-pentanedionato) nickel supplier in China

Cas:3264-82-2

Min.Order:1 Kilogram

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Bis(pentane-2,4-dionato-O,O')nickel

Cas:3264-82-2

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Large Stock 99.0% Nickel(II) acetylacetonate 3264-82-2 Producer

Cas:3264-82-2

Min.Order:1 Gram

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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Nickel acetylacetonate

Cas:3264-82-2

Min.Order:1 Kilogram

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Henan Tianfu Chemical Co., Ltd.

Now we would like to update our product list for you, kindly check the below information: 1. Catalyst series ( such as Noble Metal Catalyst, Phosphorous ligand, etc ) 2. Pharmaceutical Intermediate ( such as diabtes series, Anti

3264-82-2

Cas:3264-82-2

Min.Order:1 Kilogram

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Professional Factory CAS 3264-82-2 with high-quality service

Cas:3264-82-2

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd

Bis(2,4-pentanediono)nickel

Cas:3264-82-2

Min.Order:1 Kilogram

FOB Price: $95.0 / 100.0

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Nickel acetylacetonate 3264-82-2

Cas:3264-82-2

Min.Order:1 Kilogram

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Shanghai Minstar Chemical Co., Ltd

Nickel(II) acetylacetonate Basic information Physical Properties Uses Preparation Product Name: Nickel(II) acetylacetonate Synonyms: NICKEL PENTANEDIONATE;NICKEL(II) 2,4-PENTANEDIONATE;NICKEL II 2,4-PENTANEDIONATE TRIMERIC COMPOUND;NICKEL(II) A

Nickel(II) acetylacetonate

Cas:3264-82-2

Min.Order:1 Kilogram

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Leader Biochemical Group

About Product Details Items Specifications Test Results Appearance White to white crystalline powde

China Biggest factory Supply High Quality Nickel Acetylacetonate CAS 3264-82-2

Cas:3264-82-2

Min.Order:1 Kilogram

FOB Price: $1.0 / 2.0

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Qingdao Beluga Import and Export Co., LTD

Nickel(II) acetylacetonate CAS:3264-82-2 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic

Nickel(II) acetylacetonate CAS:3264-82-2

Cas:3264-82-2

Min.Order:1 Gram

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Nickel acetylacetonate

Cas:3264-82-2

Min.Order:1 Kilogram

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:3264-82-2

Cas:3264-82-2

Min.Order:0

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Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

NICKEL ACETYLACETONATE

Cas:3264-82-2

Min.Order:1 Gram

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Nickel Acetylacetonate

Cas:3264-82-2

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality bis-(2,4-pentanedionato) nickel

Cas:3264-82-2

Min.Order:10 Gram

FOB Price: $100.0

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Bis(2,4-pentanediono)nickel

Cas:3264-82-2

Min.Order:1 Kilogram

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Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

Nickel(II)acetylacetonate

Cas:3264-82-2

Min.Order:1 Milligram

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

Bis(2,4-pentanediono)nickel

Cas:3264-82-2

Min.Order:1 Kilogram

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Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Nickel acetylacetonate

Cas:3264-82-2

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SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

SAGECHEM/Nickel acetylacetonate/SAGECHEM/Manufacturer in China

Cas:3264-82-2

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Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

Nickel acetylacetonate

Cas:3264-82-2

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Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

Bis(2,4-pentanediono)nickel cas no. 3264-82-2 98%

Cas:3264-82-2

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Greenutra Resource Inc

Nickel(II) acetylacetonateAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air

Nickel(II) acetylacetonate

Cas:3264-82-2

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GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Bis(2,4-Pentanedionato)Nickel(II) Hydrate

Cas:3264-82-2

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Nickel(II) acetylacetonate

Cas:3264-82-2

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Wuxi TAA Chemical Industry Co.,LTD.

1.A strong technical force and advanced processing equipments. The quality of the products has been strictly inspected and all kinds of index have reached or exceeded domestic and international standards.2. Now we have established long-term stable re

Nicke(II)acetylacetonate CAS 3264-82-2

Cas:3264-82-2

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Type:Other

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Lonwin Chemical Group Limited

Shanghai Lonwin Chemical company is a subsidiary of Lonwin Industry Group Limited, was established in 2011 and is headquartered in Shanghai, adjacent to China National Convention and Exhibition Center and Hongqiao transportation hub.Lonwinchem is

Hot Sale bis-(2,4-pentanedionato) nickel 3264-82-2

Cas:3264-82-2

Min.Order:100 Kilogram

FOB Price: $100.0 / 150.0

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Synthetic route

N,N-diisopropylcarbamato nickel(II)

N,N-diisopropylcarbamato nickel(II)

acetylacetone
123-54-6

acetylacetone

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

Conditions
ConditionsYield
In n-heptane N2; addn. of the starting Ni-compound to a solution of acetylacetone; immediate reaction;; filtration;;63%
sodium (Z)-4-oxopent-2-en-2-olate
1118-67-8

sodium (Z)-4-oxopent-2-en-2-olate

nickel dichloride

nickel dichloride

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

Conditions
ConditionsYield
In solid solid-state synthesis from NiCl2 (14.7 mmol) and NaCH3COCHCOCH3 (27.0 mmol) by mechanical activation (vibrating quartz vessel for 2 h at 5 Hz); transferring product into dry box under inert atmosphere;; vac. sublimation (0.1 torr) at 150-200°C bath temp.;;24%
2(C6H5SiO2)6(6-)*6Ni(2+)*Na(1+)*Cl(1-)=((C6H5SiO2)6)2Ni6*NaCl

2(C6H5SiO2)6(6-)*6Ni(2+)*Na(1+)*Cl(1-)=((C6H5SiO2)6)2Ni6*NaCl

acetylacetone
123-54-6

acetylacetone

A

polynickelphenylsiloxane

polynickelphenylsiloxane

B

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

Conditions
ConditionsYield
In diethyl ether byproducts: (PhSi(OH)O)6; acetylacetone was added to Ni compd. in Et2O; stirred at room temp. for 50 min; filtered; washed (Et2O); filtrate concd.; C6H6 added; filtered; dried inair; mother liquor evapd.; dried (vac.); elem. anal.;A 8.8%
B n/a
nickel(II) isopropoxide

nickel(II) isopropoxide

acetylacetone enol
26567-75-9

acetylacetone enol

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

Conditions
ConditionsYield
byproducts: i-PrOH; Ni:enole=1:2;
nickel methanolate
7245-23-0, 128424-88-4

nickel methanolate

acetylacetone enol
26567-75-9

acetylacetone enol

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

Conditions
ConditionsYield
byproducts: MeOH; Ni:enole=1:2;
acetylacetone
123-54-6

acetylacetone

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

Conditions
ConditionsYield
With sodium acetate In ethanol dissolving Ni-acetate in ethanol; addn. of stoich. amt. of acetylacetone in a soln. of sodium acetate; keeping the system in a boiling-water bath;; pptn., filtering, washing and drying;;
C10H16N2NiO2

C10H16N2NiO2

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

Conditions
ConditionsYield
With acetyl acetone In acetylacetone quantitative reaction already in the cold;>99
Ni(C7H12NO)2

Ni(C7H12NO)2

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

Conditions
ConditionsYield
With acetyl acetone In acetylacetone quantitative reaction already in the cold;>99
Ni(C11H12NO)2

Ni(C11H12NO)2

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

Conditions
ConditionsYield
With acetyl acetone In acetylacetone quantitative reaction already in the cold;<99
C18H16N2NiO2

C18H16N2NiO2

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

Conditions
ConditionsYield
With acetyl acetone In acetylacetone quantitative reaction already in the cold;>99
Ni(C16H14NO)2

Ni(C16H14NO)2

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

Conditions
ConditionsYield
With acetyl acetone In acetylacetone quantitative reaction already in the cold;>99
Ni(C10H10NO)2

Ni(C10H10NO)2

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

Conditions
ConditionsYield
With acetyl acetone In acetylacetone quantitative reaction already in the cold;>99
Ni(C16H14NO)2

Ni(C16H14NO)2

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

Conditions
ConditionsYield
With acetyl acetone In acetylacetone quantitative reaction already in the cold;>99
Ni(C16H14NO)2

Ni(C16H14NO)2

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

Conditions
ConditionsYield
With acetyl acetone In acetylacetone quantitative reaction already in the cold;>99
Ni(C16H14NO)2

Ni(C16H14NO)2

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

Conditions
ConditionsYield
With acetyl acetone In acetylacetone quantitative reaction already in the cold;>99
Ni(C15H12NO)2

Ni(C15H12NO)2

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

Conditions
ConditionsYield
With acetyl acetone In acetylacetone quantitative reaction already in the cold;>99
CONi(OCC8H13)O2C5H7

CONi(OCC8H13)O2C5H7

A

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

B

tetracarbonyl nickel
13463-39-3, 71564-36-8

tetracarbonyl nickel

Conditions
ConditionsYield
With carbon monoxide byproducts: C8H13COCOC8H13; react. with CO at 20 °C;;
{Ni(acetylacetonate)2(4-benzoylpyridine)2}

{Ni(acetylacetonate)2(4-benzoylpyridine)2}

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

Conditions
ConditionsYield
In neat (no solvent) Kinetics; byproducts: 4-benzoylpyridine; thermal decompn. at 273°C;;
trans-[Ni(acetylacetonato)2(PMe2Ph)2]
1236196-28-3

trans-[Ni(acetylacetonato)2(PMe2Ph)2]

A

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

B

Dimethyl(phenyl)phosphine
672-66-2

Dimethyl(phenyl)phosphine

Conditions
ConditionsYield
In not given decomposition of nickel compd.; other compds. were detected;
bis(2,4-pentanedionate)nickel(II) dihydrate

bis(2,4-pentanedionate)nickel(II) dihydrate

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

Conditions
ConditionsYield
In neat (no solvent) heating nickel compd. in vac. at 90°C for 12 h;
nickel(II) nitrate hexahydrate

nickel(II) nitrate hexahydrate

acetylacetone
123-54-6

acetylacetone

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

Conditions
ConditionsYield
With NaOH In neat (no solvent) Ni(NO3)2*6H2O, NaOH, acetylacetone (1:2:4 molar ratio) ground (15 min, room temp.); dried (vac., 100°C, 10 h);
nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

tetracarbonyl nickel
13463-39-3, 71564-36-8

tetracarbonyl nickel

Conditions
ConditionsYield
With diisobutylaluminium hydride In tetrahydrofuran; toluene to a soln. of Ni-complex in THF at room temp. under CO a soln. of ligand in toluene was added dropwise; ppt. was distd. continuously into the internal graduate vessel, excess of Ni(CO)4 was warmed both circulating fluids up to 60°C, N2 was let to pass through the vessel for 3-4 h;99%
With n-butyllithium In tetrahydrofuran; toluene to a soln. of Ni-complex in THF at room temp. under CO a soln. of ligand in toluene was added dropwise; ppt. was distd. continuously into the internal graduate vessel, excess of Ni(CO)4 was warmed both circulating fluids up to 60°C, N2 was let to pass through the vessel for 3-4 h;99%
With n-propylmagnesium bromide In tetrahydrofuran; toluene to a soln. of Ni-complex in THF at room temp. under CO a soln. of ligand in toluene was added dropwise; ppt. was distd. continuously into the internal graduate vessel, excess of Ni(CO)4 was warmed both circulating fluids up to 60°C, N2 was let to pass through the vessel for 3-4 h;97%
2-bromo-5,10,15,20-tetraphenylporphyrin

2-bromo-5,10,15,20-tetraphenylporphyrin

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

(2-bromo-5,10,15,20-tetraphenylporphyrinato)nickel(II)
52588-61-1

(2-bromo-5,10,15,20-tetraphenylporphyrinato)nickel(II)

Conditions
ConditionsYield
In 1,2-dichloro-ethane porphyrin dissolved with warming, Ni compd. added, reacted for 45 min; solvent removed (vac.), crystd. (CH2Cl2/pentane), washed (pentane);99%
oxomolybdenum(VI) methoxide
126769-40-2

oxomolybdenum(VI) methoxide

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

A

oxomolybdenum(VI) acetylacetonate methoxide

oxomolybdenum(VI) acetylacetonate methoxide

B

dinickel(II) dioxomolybdenum(VI) bis(acetylacetonate)(metoxide)10

dinickel(II) dioxomolybdenum(VI) bis(acetylacetonate)(metoxide)10

Conditions
ConditionsYield
In not given XRD;A n/a
B 99%
(3,5-F2C6H3)3((MeO)2C10H5)C20H10N4

(3,5-F2C6H3)3((MeO)2C10H5)C20H10N4

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

[5-(4,7-dimethoxynaphth-1-yl)-10,15,20-tris(3,5-difluorophenyl)porphyrinato]nickel(II)
1350372-44-9

[5-(4,7-dimethoxynaphth-1-yl)-10,15,20-tris(3,5-difluorophenyl)porphyrinato]nickel(II)

Conditions
ConditionsYield
In toluene reaction of nickel compd. with porphyrin deriv. in toluene at 100°C for 5 h;99%
diethylaluminium chloride
96-10-6

diethylaluminium chloride

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

A

Ni(acetylacetonate)2(triphenylphosphine)
31200-71-2

Ni(acetylacetonate)2(triphenylphosphine)

B

[((C6H5)3P)3NiCl]2

[((C6H5)3P)3NiCl]2

Conditions
ConditionsYield
With triphenylphosphine In diethyl ether byproducts: C2H6, C2H4, H2; Ar-atmosphere; addn. of Et2AlCl to suspn. of 6 equiv. Ni-complex and 6 equiv. PPh3 (-40°C), stirring (4 h, room temp., pptn.); filtration, washing (ether), drying (vac.); elem. anal.; gas chromy. ofbyproducts;A 30.9%
B 98%
nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

N,N'-bis-(2-methyl-2-mercaptoprop-1-yl)-1,3-diamino-2,2-dimethylpropane
134777-42-7

N,N'-bis-(2-methyl-2-mercaptoprop-1-yl)-1,3-diamino-2,2-dimethylpropane

N,N'-bis-(2-methyl-2-mercaptoprop-1-yl)-1,3-diamino-2,2-dimethylpropanenickel(II)
870694-90-9, 308323-03-7

N,N'-bis-(2-methyl-2-mercaptoprop-1-yl)-1,3-diamino-2,2-dimethylpropanenickel(II)

Conditions
ConditionsYield
In dichloromethane soln. of Ni-complex in CH2Cl2 was added to soln. of ligand in CH2Cl2; concd., ether was added, filtered, washed with ether, dried in air;98%
(H2(C6F5)3(C5H2N)2C5HNO)2

(H2(C6F5)3(C5H2N)2C5HNO)2

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

(C6F5)6C30H10N6O2Ni2
500116-51-8

(C6F5)6C30H10N6O2Ni2

Conditions
ConditionsYield
In toluene refluxing toluene-soln.;95%
C12H6(NC6H2(CH3)C6H4C2H4C6H4)2

C12H6(NC6H2(CH3)C6H4C2H4C6H4)2

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

trityl tetrakis(pentafluorophenyl)borate

trityl tetrakis(pentafluorophenyl)borate

[((CH3)2C52H34N2)Ni(acetylacetonate)](tetrakis(pentafluorophenyl)borate)
1175097-04-7

[((CH3)2C52H34N2)Ni(acetylacetonate)](tetrakis(pentafluorophenyl)borate)

Conditions
ConditionsYield
In diethyl ether; dichloromethane (N2); addn. of dry CH2Cl2 and dry ether to mixt. of nickel compd., diimine deriv. and trityl salt, stirring at room temp. for 1 h; addn. of pentane, decantation, washing with diethyl ether and pentane, drying in vac. for 2 ds, elem. anal.;93%
(2,4,6-Me3C6H2)3((MeO)2C10H5)C20H10N4

(2,4,6-Me3C6H2)3((MeO)2C10H5)C20H10N4

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

[5-(4,7-dimethoxynaphth-1-yl)-10,15,20-trimesitylporphyrinato]nickel(II)
1350372-43-8

[5-(4,7-dimethoxynaphth-1-yl)-10,15,20-trimesitylporphyrinato]nickel(II)

Conditions
ConditionsYield
In toluene reaction of nickel compd. with porphyrin deriv. in toluene at 100°C for 5 h;93%
ethene
74-85-1

ethene

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

ethene-bis(tricyclohexylphosphane)-nickel(0)
41685-59-0

ethene-bis(tricyclohexylphosphane)-nickel(0)

Conditions
ConditionsYield
With (C2H5)2AlOC2H5 In not given prepn. at room temp.;;91%
With (C2H5)2AlOC2H5 In not given prepn. at room temp.;;91%
With (C2H5)2AlOC2H5 In not given prepn. at room temp.;;63%
With (C2H5)2AlOC2H5 In not given prepn. at room temp.;;63%
triethylaluminum
97-93-8

triethylaluminum

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

o-diphenylphosphinostyrene
17165-18-3

o-diphenylphosphinostyrene

bis{(2-vinylphenyl)diphenylphosphine}nickel(0)
113509-30-1

bis{(2-vinylphenyl)diphenylphosphine}nickel(0)

Conditions
ConditionsYield
With butadiene In toluene Under inert atmosphere, cooling a soln. of anhyd. Ni(acac)2 and the organic ligand to -50°C, condensing dry butadiene into the soln., slow addn. of AlEt3 while holding the temp. at -20°C, stirring overnight (warming to room temp.).; Cooling of resulting yellow soln. to -70°C, addn. of hexane gives a bright yellow ppt. immediately, filtn., washing (hexane, cold ether), drying in vac.;91%
5,10,15-tris(pentafluorophenyl)-20-(o-nitrophenyl)porphyrin

5,10,15-tris(pentafluorophenyl)-20-(o-nitrophenyl)porphyrin

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

5-(nitrophenyl)-10,15,20-tri(pentafluorophenyl)porphyrinato nickel(II)
507489-09-0

5-(nitrophenyl)-10,15,20-tri(pentafluorophenyl)porphyrinato nickel(II)

Conditions
ConditionsYield
In xylene reaction under reflux;91%
(2-mercaptoethyl)diphenylphosphine
3190-79-2

(2-mercaptoethyl)diphenylphosphine

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

trans-bis((2-thiolatoethyl)diphenylphosphine)nickel(II)
90668-33-0

trans-bis((2-thiolatoethyl)diphenylphosphine)nickel(II)

Conditions
ConditionsYield
In toluene (Ar); addn. of (C6H5)2PCH2CH2SH (20 mmol) to a soln. of Ni(CH3COCHCOCH3)2 (10 mmol) in toluene;; pptn.; washing with toluene and diethyl ether; drying in vac.; recrystn. from CH2Cl2/hexane or CH2Cl2/Et2O; elem. anal.;;90%
C20H4N4(CH3)6(C2H5)2C6H3(OCH3)2(C6H4)(C9H3N2)(CH3)2(C2H5)2(C2H5CO2)2

C20H4N4(CH3)6(C2H5)2C6H3(OCH3)2(C6H4)(C9H3N2)(CH3)2(C2H5)2(C2H5CO2)2

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

NiC20H2N4(CH3)6(C2H5)2C6H3(OCH3)2(C6H4)(C9H3N2)(CH3)2(C2H5)2(CO2C2H5)2
176651-36-8

NiC20H2N4(CH3)6(C2H5)2C6H3(OCH3)2(C6H4)(C9H3N2)(CH3)2(C2H5)2(CO2C2H5)2

Conditions
ConditionsYield
In o-xylene (N2); in the dark; reflux(4 h), evapn. of the solvent; chromatography (alumina), crystn. (CH2Cl2, cyclohexane); elem. anal.;90%
C20H8N4(C6H5)3(C6H4CH)O

C20H8N4(C6H5)3(C6H4CH)O

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

[Ni(C20H6N4(C6H5)3(C6H4CH)O)]*0.5H2O

[Ni(C20H6N4(C6H5)3(C6H4CH)O)]*0.5H2O

Conditions
ConditionsYield
In toluene mixt. of ketoporphyrin and Ni acetylacetonate in toluene heated under reflux overnight; chromy. (silica gel, CH2Cl2), crystn. from CH2Cl2/MeOH; elem. anal.;90%
C20H10N4-5,10-(3,5-(Me2CHCH2CH2O)2C6H3)2-15,20-[CCC20H10BrN4-10',20'-(C6H3-3,5-(OCH2CH2CHMe2)2)2]2

C20H10N4-5,10-(3,5-(Me2CHCH2CH2O)2C6H3)2-15,20-[CCC20H10BrN4-10',20'-(C6H3-3,5-(OCH2CH2CHMe2)2)2]2

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

NiC20H8N4-5,10-(3,5-(Me2CHCH2CH2O)2C6H3)2-15,20-[CCC20H8N4BrNi-10';20'-(C6H3-3,5-(OCH2CH2CHMe2)2)2]2
721922-85-6

NiC20H8N4-5,10-(3,5-(Me2CHCH2CH2O)2C6H3)2-15,20-[CCC20H8N4BrNi-10';20'-(C6H3-3,5-(OCH2CH2CHMe2)2)2]2

Conditions
ConditionsYield
In toluene87%
ethene
74-85-1

ethene

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

triphenylphosphine
603-35-0

triphenylphosphine

bis(triphenylphosphine)ethylenenickel(0)
23777-40-4

bis(triphenylphosphine)ethylenenickel(0)

Conditions
ConditionsYield
With triethylaluminum In diethyl ether prepn. in ether at 0 °C;;85%
With Al(C2H5)3 In diethyl ether prepn. in ether at 0 °C;;85%
With (C2H5)2AlOC2H5 In not given prepn. at room temp.;;<=95
With (C2H5)2AlOC2H5 In not given prepn. at room temp.;;<=95
ethene
74-85-1

ethene

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

triethylphosphine
554-70-1

triethylphosphine

bis(triethylphosphane)mono(ethene)nickel(0)
41051-87-0

bis(triethylphosphane)mono(ethene)nickel(0)

Conditions
ConditionsYield
With (C2H5)2AlOC2H5 In not given prepn. at room temp.;;85%
With (C2H5)2AlOC2H5 In not given prepn. at room temp.;;85%
With (C2H5)2AlOC2H5 In not given prepn. at room temp.;;70%
With (C2H5)2AlOC2H5 In not given prepn. at room temp.;;70%
ethene
74-85-1

ethene

C30H51O3P
93634-84-5

C30H51O3P

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

π-C2H4Ni(P(OC10H17)3)2
54721-04-9

π-C2H4Ni(P(OC10H17)3)2

Conditions
ConditionsYield
With Al(C2H5)3 In diethyl ether prepn. in ether at -50 °C up to room temp.;;85%
C20H8N4(C6H4CH3)3(C6H3(CH3)CH)O

C20H8N4(C6H4CH3)3(C6H3(CH3)CH)O

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

[Ni(C20H6N4(C6H4CH3)3(C6H3(CH3)CH)O)]*H2O

[Ni(C20H6N4(C6H4CH3)3(C6H3(CH3)CH)O)]*H2O

Conditions
ConditionsYield
In toluene mixt. of ketoporphyrin and Ni acetylacetonate in toluene heated under reflux overnight; chromy. (silica gel, CH2Cl2), crystn. from CH2Cl2/MeOH; elem. anal.;85%
{(CH3)3NH}{1.2-C2B9H12}

{(CH3)3NH}{1.2-C2B9H12}

tetramethlyammonium chloride
75-57-0

tetramethlyammonium chloride

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

{(CH3)4N}{Ni(1.2-dicarba-undecahydro-closo-undecaborate)2}
51159-92-3

{(CH3)4N}{Ni(1.2-dicarba-undecahydro-closo-undecaborate)2}

Conditions
ConditionsYield
With NaH; O2 In tetrahydrofuran prepn. of Na2(C2B9H11) soln. by react. of ((CH3)3NH)(C2B9H12) and NaH in boiling THF and evapn. of N(CH3)3 in N2 stream, treating nickel acetylacetonate with this soln. at 35 °C (3 h), oxidn. by introduction of O2, processing with (N(CH3)4)Cl;;84%
With NaH; O2 In tetrahydrofuran prepn. of Na2(C2B9H11) soln. by react. of ((CH3)3NH)(C2B9H12) and NaH in boiling THF and evapn. of N(CH3)3 in N2 stream, treating nickel acetylacetonate with this soln. at 35 °C (3 h), oxidn. by introduction of O2, processing with (N(CH3)4)Cl;;84%
1-hexene
592-41-6

1-hexene

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

tricyclohexylphosphine
2622-14-2

tricyclohexylphosphine

C4H9CHCH2Ni(P(C6H11-cyclo)3)2
76160-45-7

C4H9CHCH2Ni(P(C6H11-cyclo)3)2

Conditions
ConditionsYield
With Al(CH3)3 or (C2H5)2AlOC2H5 or Al(C4H9-i)3 In not given redn. of Ni acetylacetonate with Al org. compound in benzene or toluene soln.;;84%
With Al(CH3)3 or (C2H5)2AlOC2H5 or Al(C4H9-i)3 In not given redn. of Ni acetylacetonate with Al org. compound in benzene or toluene soln.;;84%
trans-rac-N,N'-bis(2-mercapto-2-methylprop-1-yl)-1,2-cyclohexanediamine

trans-rac-N,N'-bis(2-mercapto-2-methylprop-1-yl)-1,2-cyclohexanediamine

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

trans-rac-N,N'-bis(2-mercapto-2-methylprop-1-yl)-1,2-cyclohexanediaminenickel(II)

trans-rac-N,N'-bis(2-mercapto-2-methylprop-1-yl)-1,2-cyclohexanediaminenickel(II)

Conditions
ConditionsYield
In acetonitrile soln. of ligand in MeCN was added to suspn. of Ni-complex in MeCN, stirred overnight; filtered, washed with MeCN, dried in vacuo;84%
[H2(C4H2NCC6H5)3(C4H2NCC6H4C6H4NNC5H4N)]

[H2(C4H2NCC6H5)3(C4H2NCC6H4C6H4NNC5H4N)]

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

[Ni(C4H2NCC6H5)3(C4H2NCC6H4C6H4NNC5H4N)]

[Ni(C4H2NCC6H5)3(C4H2NCC6H4C6H4NNC5H4N)]

Conditions
ConditionsYield
In toluene stoich. mixt., for 3 h;84%
ethene
74-85-1

ethene

tris(2-methoxyphenyl) phosphite
36370-75-9

tris(2-methoxyphenyl) phosphite

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

C2H4Ni(P(OC6H4OCH3)3)2
63517-34-0

C2H4Ni(P(OC6H4OCH3)3)2

Conditions
ConditionsYield
With (C2H5)2AlOC2H5 In not given prepn. at room temp.;;83%
With (C2H5)2AlOC2H5 In not given prepn. at room temp.;;83%
triisopropyl phosphite
116-17-6

triisopropyl phosphite

triethylaluminum
97-93-8

triethylaluminum

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

<(i-PrO)3P>3Ni-Et

<(i-PrO)3P>3Ni-Et

Conditions
ConditionsYield
In toluene treatment of 3.89 mM Ni(acac)2 in dry toluene with 15.56 mM P(i-OPr)3 and cooling to -10 - - 15°C; stirring under Ar and addn. of 11.67 mM AlEt3; stirring mixture 10 min at -15°C; addn. of i-PrOH and MeCN;; pptn.; washing with cold dry MeCN and drying in vacuo at 20°C;;83%
ethene
74-85-1

ethene

tris(2-phenylphenyl)phosphite
2752-19-4

tris(2-phenylphenyl)phosphite

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

C2H4Ni(P(OC6H4C6H5)3)2
108537-21-9

C2H4Ni(P(OC6H4C6H5)3)2

Conditions
ConditionsYield
With (C2H5)2AlOC2H5 In not given prepn. at room temp.;;82%
With (C2H5)2AlOC2H5 In not given prepn. at room temp.;;82%
bis(1,2-di(perfluoroethyl)phosphino)ethane
120263-08-3

bis(1,2-di(perfluoroethyl)phosphino)ethane

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

[Ni(bis(1,2-diperfluoroethylphosphino)ethane)2]
616225-28-6

[Ni(bis(1,2-diperfluoroethylphosphino)ethane)2]

Conditions
ConditionsYield
With butadiene; Al(CH2CH(CH3)2)3 In hexane; toluene under N2, Schlenk technique; excess diphosphane added to suspn. of Ni acetylacetonate in hexane/toluene (1/1), mixt. cooled to -78°C, butadiene and Al(i-Bu)3 added, slowly warmed to room temp., stirred for 24 h; volatiles removed, residue triturated with petroleum ether, ppt. filtered off, washed with petroleum ether, dried under vac.; elem. anal.;82%
5-(4-carbomethoxynaphth-1-yl)-10,15,20-tris(2,4,6-trimethylphenyl)porphyrin

5-(4-carbomethoxynaphth-1-yl)-10,15,20-tris(2,4,6-trimethylphenyl)porphyrin

nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

(5-(4-carbomethoxynaphth-1-yl)-10,15,20-tris(2,4,6-trimethylphenyl)porphyrin-2H)Ni
950856-49-2

(5-(4-carbomethoxynaphth-1-yl)-10,15,20-tris(2,4,6-trimethylphenyl)porphyrin-2H)Ni

Conditions
ConditionsYield
In toluene refluxed (110°C, 20 h); 1HNMR, MALDI-TOF MS;82%
nickel(II) acetylacetonate
3264-82-2

nickel(II) acetylacetonate

N,N'-dineopentyl-2-amino-5-alcoholate-1,4-benzoquinonemonoiminium
429693-77-6

N,N'-dineopentyl-2-amino-5-alcoholate-1,4-benzoquinonemonoiminium

Ni(C6H2(O)2(NHCH2C(CH3)3)(NCH2C(CH3)3))2
622784-51-4

Ni(C6H2(O)2(NHCH2C(CH3)3)(NCH2C(CH3)3))2

Conditions
ConditionsYield
In toluene under dry Ar atm. using Schlenk techniques; zwitterion dissolved in anhyd. toluene; acetylacetonate added; mixt. refluxed for 12 h; colled to room temp.; ppt. filtered; washed (cold toluene); elem. anal.;81%

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