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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

2-tert-Amylphenol

Cas:3279-27-4

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

2-tert-AMylphenol

Cas:3279-27-4

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2-(1,1-dimethylpropyl)phenol

Cas:3279-27-4

Min.Order:1

Negotiable

Type:Other

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-tert-Amylphenol

Cas:3279-27-4

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 3279-27-4 with competitive price

Cas:3279-27-4

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Phenol,2-(1,1-dimethylpropyl)-

Cas:3279-27-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Phenol,2-(1,1-dimethylpropyl)-

Cas:3279-27-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

2-(2-methylbutan-2-yl)phenol

Cas:3279-27-4

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

2-(2-methylbutan-2-yl)phenol

Cas:3279-27-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

2-(2-methylbutan-2-yl)phenol

Cas:3279-27-4

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

2-(2-methylbutan-2-yl)phenol

Cas:3279-27-4

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Hebei Mojin Biotechnology Co.,Ltd

1, High quality with competitive price:2, Fast and safe delivery3.Excellent pre-sales and after-sales service4. Well-trained and professional technologist and sales with rich experience in the field for 5-10 yearsAppearance:see detailed specification

Phenol,2-(1,1-dimethylpropyl)-

Cas:3279-27-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Phenol,2-(1,1-dimethylpropyl)-

Cas:3279-27-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

Phenol,2-(1,1-dimethylpropyl)-

Cas:3279-27-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemsigma International Co.,Ltd.

bulk productiongoods in stockswe have the best competitive price in the marketmeantime,we are committed to service to our every customer Chemsigma International Co.,Ltd. is a chemical manufacturer, specialize in custom synthesis and organic chemical

2-(1,1-DIMETHYLPROPYL)PHENOL

Cas:3279-27-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

2-tert-AMylphenol

Cas:3279-27-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Langyou International Trading Co., Ltd

2-(2-methylbutan-2-yl)phenol Application:2-(2-methylbutan-2-yl)phenol

2-(2-methylbutan-2-yl)phenol

Cas:3279-27-4

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

2-(1,1-DIMETHYLPROPYL)PHENOL

Cas:3279-27-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers2. Produce products of different specifications and sizes according to your requirements.3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures sta

2-(1,1-DIMETHYLPROPYL)PHENOL

Cas:3279-27-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Longxianng Runhui Trading Co.,Ltd

2-(2-methylbutan-2-yl)phenolAppearance:ask Storage:keep in dry and cool condition Package:foil aluminium bag/vacuum packing Application:intermediates Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small amount. By air(airport to

2-(2-methylbutan-2-yl)phenol

Cas:3279-27-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

2-(1,1-DIMETHYLPROPYL)PHENOL

Cas:3279-27-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hubei Jusheng Technology Co., Ltd.,

1,Best Quality: Our products have exported to Germany, Spain, UK, USA, Australia, Middle East, and so on other countries, and we have got very good feedback from our customers.so you can trust us.

2-(2-methylbutan-2-yl)phenol

Cas:3279-27-4

Min.Order:10 Gram

FOB Price: $1.0 / 2.0

Type:Trading Company

inquiry

Hebei mingxing biotech co.,ltd

Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers. Prompt reaction, good quality and best service make us reliable and outstanding in this industry.Appearance:yellow to white solid or po

Phenol,2-(1,1-dimethylpropyl)-

Cas:3279-27-4

Min.Order:0

Negotiable

Type:Other

inquiry

Taizhou volsen chemical Co., Ltd

We are a trading company aiming at providing high-quality services to customers. Established for many years, with good reputation in the industry Storage:Sealed and preserved Application:Fine chemical intermediates, used as the main raw material for

2-(2-methylbutan-2-yl)phenol

Cas:3279-27-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Minshang Biotechnology Co., Ltd

2-(2-methylbutan-2-yl)phenol Application:intermediates

3279-27-4

Cas:3279-27-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Jiangxi shengwei chemical technology co. LTD

Jiangxi Shengwei Chemical Technology Co., Ltd.supplies scientific research products as below:1.High-purity organic chemical reagents;2.Analytical reagents; 3.Biochemical reagents;4.Chemical raw materials;5.Experimental instruments;6.Experimental cons

2-tert-Amylphenol

Cas:3279-27-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Fenjun Chemical Co Ltd.

2-(2-methylbutan-2-yl)phenol Application:2-(2-methylbutan-2-yl)phenol

2-(2-methylbutan-2-yl)phenol

Cas:3279-27-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

NovaChemistry

high purity Application:Drug intermediates Materials intermediates and active molecules

2-(2-methylbutan-2-yl)phenol

Cas:3279-27-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

SCHENECT

more information,pls contact with us!

Phenol,2-(1,1-dimethylpropyl)-

Cas:3279-27-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

2-methyl-but-2-ene
513-35-9

2-methyl-but-2-ene

phenol
108-95-2

phenol

tert-amylphenol
3279-27-4

tert-amylphenol

Conditions
ConditionsYield
With trichlorophosphate
With aluminium(III) phenoxide
2-methyl-2-butylchloride
594-36-5

2-methyl-2-butylchloride

phenol
108-95-2

phenol

tert-amylphenol
3279-27-4

tert-amylphenol

Conditions
ConditionsYield
With aluminium trichloride at 20 - 100℃;
2-Methyl-1-butene
563-46-2

2-Methyl-1-butene

phenol
108-95-2

phenol

tert-amylphenol
3279-27-4

tert-amylphenol

Conditions
ConditionsYield
With diphenyl hydrogen phosphate
4-t-amylphenol
80-46-6

4-t-amylphenol

tert-amylphenol
3279-27-4

tert-amylphenol

Conditions
ConditionsYield
In neat (no solvent) at 99.9 - 209.9℃; Equilibrium constant; effect of temperature;
2-methyl-but-2-ene
513-35-9

2-methyl-but-2-ene

phenol
108-95-2

phenol

A

tert-amylphenol
3279-27-4

tert-amylphenol

B

4-tert-pentyl-phenol, 2.4-di-tert-pentyl-phenol

4-tert-pentyl-phenol, 2.4-di-tert-pentyl-phenol

Conditions
ConditionsYield
With sulfuric acid at 50℃;
tert-Amyl alcohol
75-85-4

tert-Amyl alcohol

phenol
108-95-2

phenol

A

tert-amylphenol
3279-27-4

tert-amylphenol

B

4-t-amylphenol
80-46-6

4-t-amylphenol

Conditions
ConditionsYield
With sulfated zirconia at 140℃; for 1h;
tert-amylphenol
3279-27-4

tert-amylphenol

tert-Amyl-o-Bromophenol

tert-Amyl-o-Bromophenol

Conditions
ConditionsYield
With N-Bromosuccinimide; diisopropylamine In dichloromethane at 40℃; for 20h; Inert atmosphere;92%
With N-Bromosuccinimide; diisopropylamine In dichloromethane for 16h; Inert atmosphere; Reflux;81%
With N-Bromosuccinimide; diisopropylamine In dichloromethane Reflux;
tert-amylphenol
3279-27-4

tert-amylphenol

methyl iodide
74-88-4

methyl iodide

2-methoxy-4-tert-pentylbenzene

2-methoxy-4-tert-pentylbenzene

Conditions
ConditionsYield
Stage #1: tert-amylphenol With sodium hydride In N,N-dimethyl-formamide; mineral oil at 20℃; for 0.666667h; Schlenk technique; Sealed tube;
Stage #2: methyl iodide In N,N-dimethyl-formamide; mineral oil for 3h; Schlenk technique; Sealed tube;
70%
tert-amylphenol
3279-27-4

tert-amylphenol

2-bromoethanol
540-51-2

2-bromoethanol

C13H20O2

C13H20O2

Conditions
ConditionsYield
Stage #1: tert-amylphenol With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 0.25h;
Stage #2: 2-bromoethanol With tetra-(n-butyl)ammonium iodide In N,N-dimethyl-formamide at 110℃; for 96h;
52%
tert-amylphenol
3279-27-4

tert-amylphenol

2-hydroxy-3-tert-pentyl-benzaldehyde

2-hydroxy-3-tert-pentyl-benzaldehyde

Conditions
ConditionsYield
With hexamethylenetetramine durch Eintragen in ein zuvor auf 150-165grad erhitztes Gemisch von Glycerin und Borsaeure und anschliessendes Behandeln mit wss.H2SO4 unter Durchleiten von Wasserdampf;
tert-amylphenol
3279-27-4

tert-amylphenol

tert-pentyl-[1,4]benzoquinone-4-oxime

tert-pentyl-[1,4]benzoquinone-4-oxime

Conditions
ConditionsYield
With hydrogenchloride; sodium nitrite
tert-amylphenol
3279-27-4

tert-amylphenol

2,4-dichloro-6-tert-pentyl-phenol
122269-08-3

2,4-dichloro-6-tert-pentyl-phenol

Conditions
ConditionsYield
With tetrachloromethane; chlorine
tert-amylphenol
3279-27-4

tert-amylphenol

3.5-dinitro-2-hydroxy-1-tert-pentyl-benzene
87014-94-6

3.5-dinitro-2-hydroxy-1-tert-pentyl-benzene

Conditions
ConditionsYield
With tetrachloromethane; nitric acid at 40℃;
tert-amylphenol
3279-27-4

tert-amylphenol

4-t-amylphenol
80-46-6

4-t-amylphenol

Conditions
ConditionsYield
In neat (no solvent) at 99.9 - 209.9℃; Equilibrium constant; effect of temperature;
tert-amylphenol
3279-27-4

tert-amylphenol

cis-1-tert.-Pentyl-cyclohexanol-(2)

cis-1-tert.-Pentyl-cyclohexanol-(2)

Conditions
ConditionsYield
With hydrogen; nickel In ethanol at 140 - 200℃; under 98800 - 129200 Torr;
tert-amylphenol
3279-27-4

tert-amylphenol

hexamethylenetetramine
100-97-0

hexamethylenetetramine

metaboric acid
13460-50-9

metaboric acid

glycerol
56-81-5

glycerol

2-hydroxy-3-tert-pentyl-benzaldehyde

2-hydroxy-3-tert-pentyl-benzaldehyde

Conditions
ConditionsYield
at 165℃; anschliessendes Behandeln mit wss. H2SO4 bei 115grad;
tert-amylphenol
3279-27-4

tert-amylphenol

N,N'-bis-(2-hydroxy-3-tert-pentyl-benzyliden)-ethylenediamine

N,N'-bis-(2-hydroxy-3-tert-pentyl-benzyliden)-ethylenediamine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: hexamethylenetetramine / durch Eintragen in ein zuvor auf 150-165grad erhitztes Gemisch von Glycerin und Borsaeure und anschliessendes Behandeln mit wss.H2SO4 unter Durchleiten von Wasserdampf
View Scheme
tert-amylphenol
3279-27-4

tert-amylphenol

2-tert-Pentylcyclohexanon
5441-54-3

2-tert-Pentylcyclohexanon

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: H2 / Raney-Ni / ethanol / 140 - 200 °C / 98800 - 129200 Torr
2: Na2Cr2O7
View Scheme
tert-amylphenol
3279-27-4

tert-amylphenol

N-(2-diethylaminoethyl)-3-t-amylsalicylamide hydrochloride

N-(2-diethylaminoethyl)-3-t-amylsalicylamide hydrochloride

Conditions
ConditionsYield
With sodium
4,4'-methylenebis(cyclohexyl urea)

4,4'-methylenebis(cyclohexyl urea)

tert-amylphenol
3279-27-4

tert-amylphenol

N,N'-(4,4'-methanediyl-dicyclohexyl)-di(carbamic acid (2-tert-amylphenyl) ester)

N,N'-(4,4'-methanediyl-dicyclohexyl)-di(carbamic acid (2-tert-amylphenyl) ester)

Conditions
ConditionsYield
at 230℃; under 262.526 Torr; Product distribution / selectivity; Industry scale;
tert-amylphenol
3279-27-4

tert-amylphenol

(2-bromo-6-(tert-pentyl)phenoxy)trimethylsilane
1334501-85-7

(2-bromo-6-(tert-pentyl)phenoxy)trimethylsilane

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: N-Bromosuccinimide; diisopropylamine / dichloromethane / 20 h / 40 °C / Inert atmosphere
2: triethylamine / toluene / 12 h / 50 °C / Inert atmosphere
View Scheme
tert-amylphenol
3279-27-4

tert-amylphenol

2-(tert-pentyl)-6-(trimethylsilyl)phenol
1334501-86-8

2-(tert-pentyl)-6-(trimethylsilyl)phenol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: N-Bromosuccinimide; diisopropylamine / dichloromethane / 20 h / 40 °C / Inert atmosphere
2: triethylamine / toluene / 12 h / 50 °C / Inert atmosphere
3: n-butyllithium / hexanes; diethyl ether / 12 h / -78 - 20 °C / Inert atmosphere
View Scheme
tert-amylphenol
3279-27-4

tert-amylphenol

2-(tert-Pentyl)-6-(trimethylsilyl)phenyl trifluoromethanesulfonate
1334501-77-7

2-(tert-Pentyl)-6-(trimethylsilyl)phenyl trifluoromethanesulfonate

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: N-Bromosuccinimide; diisopropylamine / dichloromethane / 20 h / 40 °C / Inert atmosphere
2.1: triethylamine / toluene / 12 h / 50 °C / Inert atmosphere
3.1: n-butyllithium / hexanes; diethyl ether / 12 h / -78 - 20 °C / Inert atmosphere
4.1: n-butyllithium / hexanes; diethyl ether / -78 - 20 °C / Inert atmosphere
4.2: 12 h / -78 - 20 °C / Inert atmosphere
View Scheme
tert-amylphenol
3279-27-4

tert-amylphenol

A

trimethyl(3-(2-methylbut-3-en-2-yl)phenyl)silane
1334501-78-8

trimethyl(3-(2-methylbut-3-en-2-yl)phenyl)silane

B

(8-ethyl-8-methylbicyclo[4.2.0]octa-1,3,5-trien-3-yl)trimethylsilane
1334501-79-9

(8-ethyl-8-methylbicyclo[4.2.0]octa-1,3,5-trien-3-yl)trimethylsilane

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1.1: N-Bromosuccinimide; diisopropylamine / dichloromethane / 20 h / 40 °C / Inert atmosphere
2.1: triethylamine / toluene / 12 h / 50 °C / Inert atmosphere
3.1: n-butyllithium / hexanes; diethyl ether / 12 h / -78 - 20 °C / Inert atmosphere
4.1: n-butyllithium / hexanes; diethyl ether / -78 - 20 °C / Inert atmosphere
4.2: 12 h / -78 - 20 °C / Inert atmosphere
5.1: tris-(dibenzylideneacetone)dipalladium(0); 1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazolium tetrafluoroborate; lithium tert-butoxide / toluene / 4 h / 110 °C / Inert atmosphere
View Scheme
tert-amylphenol
3279-27-4

tert-amylphenol

C23H27BBrOP
1429416-09-0

C23H27BBrOP

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: N-Bromosuccinimide; diisopropylamine / dichloromethane / Reflux
2.1: 1,4-diaza-bicyclo[2.2.2]octane
2.3: 0 °C
View Scheme
Multi-step reaction with 2 steps
1.1: diisopropylamine; N-Bromosuccinimide / dichloromethane / 16 h / Inert atmosphere; Reflux
2.1: 1,4-diaza-bicyclo[2.2.2]octane / dichloromethane / 0.25 h / 20 °C / Inert atmosphere
2.2: 2.67 h / 0 - 20 °C / Inert atmosphere
2.3: 1.17 h / 0 - 20 °C / Inert atmosphere
View Scheme
tert-amylphenol
3279-27-4

tert-amylphenol

2-boranatodiphenylphosphanyl-6-tert-pentylphenol
1429416-13-6

2-boranatodiphenylphosphanyl-6-tert-pentylphenol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: N-Bromosuccinimide; diisopropylamine / dichloromethane / Reflux
2.1: 1,4-diaza-bicyclo[2.2.2]octane
2.3: 0 °C
3.1: n-butyllithium / tetrahydrofuran / 0 °C
View Scheme
Multi-step reaction with 3 steps
1.1: diisopropylamine; N-Bromosuccinimide / dichloromethane / 16 h / Inert atmosphere; Reflux
2.1: 1,4-diaza-bicyclo[2.2.2]octane / dichloromethane / 0.25 h / 20 °C / Inert atmosphere
2.2: 2.67 h / 0 - 20 °C / Inert atmosphere
2.3: 1.17 h / 0 - 20 °C / Inert atmosphere
3.1: n-butyllithium / tetrahydrofuran / 2.5 h / 0 °C / Inert atmosphere
View Scheme
tert-amylphenol
3279-27-4

tert-amylphenol

(2R,3R,4aR,9aR)-7-(2-(diphenylphosphino)-6-tert-pentylphenoxy)-2,3-dimethoxy-2,3-dimethyl-5,5,9,9-tetraphenylhexahydro[1,4]dioxino[2,3-e][1,3,2]dioxaphosphepine

(2R,3R,4aR,9aR)-7-(2-(diphenylphosphino)-6-tert-pentylphenoxy)-2,3-dimethoxy-2,3-dimethyl-5,5,9,9-tetraphenylhexahydro[1,4]dioxino[2,3-e][1,3,2]dioxaphosphepine

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: N-Bromosuccinimide; diisopropylamine / dichloromethane / Reflux
2.1: 1,4-diaza-bicyclo[2.2.2]octane
2.3: 0 °C
3.1: n-butyllithium / tetrahydrofuran / 0 °C
4.1: 1,4-diaza-bicyclo[2.2.2]octane / dichloromethane / 0.17 h / 20 °C / Inert atmosphere; Schlenk technique
4.2: 0 - 20 °C / Inert atmosphere; Schlenk technique
4.3: 0 - 20 °C / Inert atmosphere; Schlenk technique
View Scheme
tert-amylphenol
3279-27-4

tert-amylphenol

(3aR,8aR)-6-(2-(diphenylphosphanyl)-6-(tert-pentyl)phenoxy)-2,2-dimethyl-4,4,8,8-tetraphenyltetrahydro[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepine
1429416-17-0

(3aR,8aR)-6-(2-(diphenylphosphanyl)-6-(tert-pentyl)phenoxy)-2,2-dimethyl-4,4,8,8-tetraphenyltetrahydro[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepine

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: diisopropylamine; N-Bromosuccinimide / dichloromethane / 16 h / Inert atmosphere; Reflux
2.1: 1,4-diaza-bicyclo[2.2.2]octane / dichloromethane / 0.25 h / 20 °C / Inert atmosphere
2.2: 2.67 h / 0 - 20 °C / Inert atmosphere
2.3: 1.17 h / 0 - 20 °C / Inert atmosphere
3.1: n-butyllithium / tetrahydrofuran / 2.5 h / 0 °C / Inert atmosphere
4.1: 1,4-diaza-bicyclo[2.2.2]octane / dichloromethane / 0.17 h / 20 °C / Schlenk technique; Inert atmosphere
4.2: 4 h / 0 - 20 °C / Schlenk technique; Inert atmosphere
4.3: 21 h / 0 - 20 °C / Schlenk technique; Inert atmosphere
View Scheme
tert-amylphenol
3279-27-4

tert-amylphenol

A

C18H29BO3

C18H29BO3

B

C18H29BO3

C18H29BO3

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0.67 h / 20 °C / Schlenk technique; Sealed tube
1.2: 3 h / Schlenk technique; Sealed tube
2.1: [(1,5-cyclooctadiene)(OH)iridium(I)]2; 2,2'-bis-[bis-(3,5-dimethyl-phenyl)-phosphanyl]-biphenyl / tert-butyl methyl ether / 20 h / 85 °C / Glovebox; Inert atmosphere; Sealed tube
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