CAS No.75-85-4,tert-Amyl alcohol Suppliers

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Amadis Chemical offer CAS#75-85-4;CAT#A838528

Cas:75-85-4

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

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QINGDAO ON-BILLION INDUSTRAIL CO.,LTD

CASNO.75-85-4 EINECSNO.200-908-9 FORMULAC5H12O MOLWT.88.15 TOXICITYOralratLD50:1000mg/kg SYNONYMS t-AmylAlcohol;2-… Appearance:Colorless transparent liquid Storage:Flammables area Package:200L drum Application:synthetic material of perfume a

2-Methyl-2-butanol

Cas:75-85-4

Min.Order:100 Kilogram

Negotiable

Type:Trading Company

inquiry

Synthetic route

: 115-19-5
2-methyl-but-3-yn-2-ol

A: 75-85-4
tert-Amyl alcohol

B: 115-18-4
2-methyl-3-buten-2-ol

Conditions

Conditions	Yield
With hydrogen; copper-palladium; silica gel In ethanol at 25℃; under 760 Torr; Kinetics;	A n/a B 98%
With hydrogen; palladium dichloride In N,N-dimethyl-formamide under 18751.5 Torr; for 0.3h; Product distribution; Ambient temperature; various time;	A 2% B 91%
With hydrogen; nickel dihydroxide; Ni(C17H35COO)2 In toluene at 40℃; Product distribution; Kinetics; other catalyst. Object of study: selectivity;	A 41.6% B 85.5%

: 115-19-5
2-methyl-but-3-yn-2-ol

: 75-85-4
tert-Amyl alcohol

Conditions

Conditions	Yield
With sodium tetrahydroborate; hydrogen; nickel dichloride In isopropyl alcohol at 60℃; under 760.051 Torr; for 7h;	90%
With hydrogen; palladium membrane at 29.9℃; Kinetics; electrochemical reduction;
With alkali durch elektrolytische Reduktion an Platinkathoden;

: 6689-16-3
2-methyl-2-trimethylsiloxybutane

: 75-85-4
tert-Amyl alcohol

Conditions

Conditions	Yield
With nano magnetic sulfated zirconia (Fe3O4 at ZrO2/SO42-) In neat (no solvent) at 20℃; for 0.416667h; Green chemistry;	80%

: 97-94-9
triethyl borane

: 67-64-1
acetone

: 75-85-4
tert-Amyl alcohol

Conditions

Conditions	Yield
With tetra-(n-butyl)ammonium iodide In tetrahydrofuran; N,N-dimethyl-formamide for 7h; Ambient temperature; electrolysis with Pt/Cu electrodes;	76%

: 78-78-4
methylbutane

A: 563-80-4
3-methyl-butan-2-one

B: 75-85-4
tert-Amyl alcohol

C: 96-17-3, 57456-98-1
2-Methylbutyraldehyde

D: 598-75-4
3-methyl-2-butanol

Conditions

Conditions	Yield
With [2,2]bipyridinyl; Ba; trifluoroacetic acid In dichloromethane at 20℃; for 0.0333333h;	A 11% B 70% C 4.5% D n/a
With [2,2]bipyridinyl; Ba; trifluoroacetic acid In dichloromethane at 20℃; for 0.0333333h; Product distribution;	A 11% B 70% C 4.5% D n/a

...Expand

: 563-46-2
2-Methyl-1-butene

: 64-19-7
acetic acid

A: 75-85-4
tert-Amyl alcohol

B: 661-53-0
2-fluoro-2-methylbutane

C: 625-16-1
tert-amyl acetate

Conditions

Conditions	Yield
With hydrogenchloride; water at 25℃; Kinetics;	A 70% B 25% C n/a

...Expand

: 54269-84-0
1,1-dimethyl-1-(2-propenyloxy)-propane

: 75-85-4
tert-Amyl alcohol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride; titanium tetrachloride In tetrahydrofuran for 8h; Ambient temperature;	49%

: 78-78-4
methylbutane

A: 75-85-4
tert-Amyl alcohol

B: 64-19-7
acetic acid

C: 67-64-1
acetone

Conditions

Conditions	Yield
With N-hydroxyphthalimide; air; cobalt(II) acetate In benzonitrile at 100℃; under 7600 Torr; for 8h; Oxidation;	A 21% B 15% C 32%

...Expand

: 1927-66-8
2-(1,1-dimethyl-propoxy)-tetrahydropyran

: 75-85-4
tert-Amyl alcohol

Conditions

Conditions	Yield
With acid-washed bentonite In acetone at 40 - 50℃;	10%

: 558-30-5
2-methyl-1,2-epoxypropane

: 2999-74-8
dimethylmagnesium

: 75-85-4
tert-Amyl alcohol

Conditions

Conditions	Yield
With diethyl ether

: 1758-32-3, 1758-33-4, 3266-23-7, 6189-41-9, 21490-63-1, 63864-69-7, 103110-88-9
2,3-epoxybutane

: 75-16-1
methylmagnesium bromide

: 75-85-4
tert-Amyl alcohol

: 5076-19-7
trimethyloxirane

: 75-85-4
tert-Amyl alcohol

Conditions

Conditions	Yield
With lithium aluminium tetrahydride

: 67-56-1
methanol

: 594-38-7
2-iodo-2-methylbutane

A: 75-85-4
tert-Amyl alcohol

B: 74-88-4
methyl iodide

Conditions

Conditions	Yield
at 100℃;

...Expand

: 513-35-9
2-methyl-but-2-ene

: 75-85-4
tert-Amyl alcohol

Conditions

Conditions	Yield
With sulfuric acid at 50℃;
With sulfuric acid at 120℃; under 7355.08 - 11032.6 Torr;
With ammonium sulfate; sulfuric acid at 0℃;

: 60-29-7
diethyl ether

: 28276-08-6
1,1-dimethylpropylmagnesium chloride

: 15719-64-9, 15719-76-3, 97762-63-5
methylammonium carbonate

: 75-85-4
tert-Amyl alcohol

Conditions

Conditions	Yield
ausser Dimethyl-aethyl-essigsaeure;

...Expand

: 594-36-5
2-methyl-2-butylchloride

: 75-85-4
tert-Amyl alcohol

Conditions

Conditions	Yield
With glyceride alkali salt; water Hydrolysis;
With sodium hydroxide Hydrolysis.in Gegenwart von fettsauren Alkalisalzen;

: 115-18-4
2-methyl-3-buten-2-ol

: 75-85-4
tert-Amyl alcohol

Conditions

Conditions	Yield
With alkali durch elektrolytische Reduktion an Platinkathoden;
With hydrogen; palladium at 20℃; under 760 Torr; Rate constant; effect of solvent (methanol, cyclohexane) on hydrogenation;
With hydrogen; palladium at 20℃; under 735.5 Torr; Rate constant; effects of solvent on hydrogenation of title compound;

: 762-64-1
1-diazo-2,2-dimethylpropane

: 75-85-4
tert-Amyl alcohol

Conditions

Conditions	Yield
With sulfuric acid

: 78-78-4
methylbutane

: 75-85-4
tert-Amyl alcohol

Conditions

Conditions	Yield
With hydrogen bromide at 165℃;
With 3,3-dimethyldioxirane In acetone Rate constant; Ambient temperature;

: 507-36-8
2-bromo-2-methylbutane

: 623-11-0
1-methyl-4-nitrosobenzene

A: 75-85-4
tert-Amyl alcohol

B: 513-35-9
2-methyl-but-2-ene

Conditions

Conditions	Yield
at 35℃; Hydrolysis;
at 45℃; Hydrolysis;

...Expand

: 507-36-8
2-bromo-2-methylbutane

A: 75-85-4
tert-Amyl alcohol

B: 513-35-9
2-methyl-but-2-ene

Conditions

Conditions	Yield
Hydrolysis;

: 594-38-7
2-iodo-2-methylbutane

: 75-85-4
tert-Amyl alcohol

Conditions

Conditions	Yield
With potassium hydroxide

: 19781-24-9
3,3-dimethyl-2-pentanol

A: 75-85-4
tert-Amyl alcohol

B: 20669-04-9
3,3-dimethyl-2-pentanone

Conditions

Conditions	Yield
With chromium(VI) oxide; acetic acid

: 66793-92-8
isopropyl-tert-pentyl-carbinol

A: 75-85-4
tert-Amyl alcohol

B: 34575-34-3
2,4,4-trimethyl-hexan-3-one

Conditions

Conditions	Yield
With chromium(VI) oxide; acetic acid

: 4111-08-4
2-hydroxy-2-methyl-butyronitrile

: 75-16-1
methylmagnesium bromide

: 75-85-4
tert-Amyl alcohol

: 4111-08-4
2-hydroxy-2-methyl-butyronitrile

: methyl magnesium (1+); bromide

A: 75-85-4
tert-Amyl alcohol

B: 109916-61-2, 133645-41-7, 560-24-7
3-hydroxy-3-methyl-pentan-2-one

C: 78-93-3
butanone

...Expand

: 24675-20-5
2-methyl-butan-2-ol; zirconium (IV)-compound

A: 75-85-4
tert-Amyl alcohol

B: 591-95-7
penta-1,2-diene

Conditions

Conditions	Yield
at 250 - 320℃; under 175 - 760 Torr; Pyrolysis;

: 544-97-8
dimethyl zinc(II)

: 79-03-8
propionyl chloride

: 75-85-4
tert-Amyl alcohol

: 28276-08-6
1,1-dimethylpropylmagnesium chloride

: 15719-64-9, 15719-76-3, 97762-63-5
methylammonium carbonate

: 75-85-4
tert-Amyl alcohol

: 28276-08-6
1,1-dimethylpropylmagnesium chloride

: 75-85-4
tert-Amyl alcohol

Conditions

Conditions	Yield
With oxygen Zersetzung des Reaktionsproduktes mit Wasser;

: 75-85-4
tert-Amyl alcohol

: 594-36-5
2-methyl-2-butylchloride

Conditions

Conditions	Yield
With bismuth(III) chloride In tetrachloromethane at 25℃; for 0.0833333h;	100%
With hydrogenchloride In water at 20℃; for 0.05h;	98%
With chloro-trimethyl-silane; dimethyl sulfoxide for 0.166667h;	88%

: 75-85-4
tert-Amyl alcohol

: 32115-55-2
N,N-Dimethylcarbamidsaeure-trimethylsilylester

: 6689-16-3
2-methyl-2-trimethylsiloxybutane

Conditions

Conditions	Yield
at 100℃; for 15h;	100%
at 69.9℃; Mechanism; Rate constant; Kinetics; var. time and temp.;

: 75-85-4
tert-Amyl alcohol

: 79-04-9
chloroacetyl chloride

: 5439-30-5
2-methylbut-2-yl chloroacetate

Conditions

Conditions	Yield
With pyridine In diethyl ether at 0℃;	100%

: 75-85-4
tert-Amyl alcohol

: 52177-63-6
4-methylthiophenyl chloroformate

: tert-amyl p-methylthiophenyl carbonate

Conditions

Conditions	Yield
With pyridine In dichloromethane	100%

: 75-85-4
tert-Amyl alcohol

: Fe{Nb(OCH(CH3)2)6}3

: Fe{Nb(OCH(CH3)2)2(OC(CH3)2C2H5)4}3

Conditions

Conditions	Yield
In tert-Amyl alcohol byproducts: isopropanol; anhydrous conditions; refluxing (48 h, distn. off of i-PrOH); solvent removal (vac.); elem. anal.;	99.5%

: 75-85-4
tert-Amyl alcohol

: 71-43-2
benzene

: 2049-95-8
tery-amylbenzene

Conditions

Conditions	Yield
With aluminum (III) chloride; iron(III) chloride at 0 - 5℃; for 6h; Large scale;	99.4%
With AlCl2
With iron(III) chloride
With aluminium trichloride

: 75-85-4
tert-Amyl alcohol

: K{hexaisopropoxytantalate}

: bis(tri-t-amyloxy-tri-isopropoxy-tantalate)iron(II)

Conditions

Conditions	Yield
under N2; elem. anal.;	99.3%

: 75-85-4
tert-Amyl alcohol

: 108-24-7
acetic anhydride

: 625-16-1
tert-amyl acetate

Conditions

Conditions	Yield
With erbium(III) chloride at 50℃; for 3.5h;	99%
cerium triflate In acetonitrile at 20℃; for 24h;	98%
With Methylenediphosphonic acid at 20℃; for 3.5h; neat (no solvent);	97%

: 75-85-4
tert-Amyl alcohol

: 1-(2-bromo-6-fluorophenyl)-1-methylsiletane

: 8-fluoro-1-methyl-1-(tert-pentyloxy)-1,2,3,4-tetrahydrobenzo[b]siline

Conditions

Conditions	Yield
With bis(tri-t-butylphosphine)palladium(0); N,N-diethyl-1,1,1-trimethylsilanamine at 80℃; for 24h; Inert atmosphere; Schlenk technique;	99%

: 75-85-4
tert-Amyl alcohol

: 94370-87-3
tert-amyl hypobromite

Conditions

Conditions	Yield
With bromine; mercury(II) oxide In pentane for 1h; Product distribution; Ambient temperature; other tertiary and secondary alcohols;	98.5%

: 43112-38-5
3-(trimethylsilyl)-2-oxazolidinone

: 75-85-4
tert-Amyl alcohol

: 6689-16-3
2-methyl-2-trimethylsiloxybutane

Conditions

Conditions	Yield
chloro-trimethyl-silane at 0℃; for 0.0333333h;	98%

: 75-85-4
tert-Amyl alcohol

: nickel tantalum isopropoxide

: Ni(2+)*2Ta(5+)*8OC(CH2CH3)(CH3)2(1-)*4OCH(CH3)2(1-) = Ni[Ta(OC(CH2CH3)(CH3)2)4(OCH(CH3)2)2]2

Conditions

Conditions	Yield
In benzene byproducts: isopropanol; moisture excluded; excess alcohol added to soln. of nickel tantalum isopropoxide; refluxed over a fractionating column; isopropanol liberated was continuously fractionated out with benzene between 72-80°C; excess of solvent removed under reduced pressure and compd. dried; elem. anal.;	98%

: 5765-44-6
5-methylisoxazole

: 75-85-4
tert-Amyl alcohol

: 4878-36-8
3,5-diamino-6-chloro-pyrazine-2-carboxylic acid

: 1431937-50-6
1-(2-methyl-2-butyl-carbamoyl)prop-1-en-2-yl 3,5-diamino-6-chloropyrazine-2-carboxylate

Conditions

Conditions	Yield
Stage #1: 5-methylisoxazole; tert-Amyl alcohol With trifluorormethanesulfonic acid In N,N-dimethyl-formamide for 1h; Cooling with ice; Stage #2: 3,5-diamino-6-chloro-pyrazine-2-carboxylic acid With triethylamine In N,N-dimethyl-formamide at 20℃; for 2h; Cooling with ice;	98%
Stage #1: 5-methylisoxazole; tert-Amyl alcohol With trifluorormethanesulfonic acid Cooling with ice; Stage #2: 3,5-diamino-6-chloro-pyrazine-2-carboxylic acid With triethylamine In N,N-dimethyl-formamide at 25℃; for 2h; Cooling with ice;	98%

...Expand

: 75-85-4
tert-Amyl alcohol

: {iron(II)((μ-isopropoxy)3Nb(isopropoxy)3)2}

: bis(tri-t-amyloxy-tri-isopropoxy-niobate)iron(II)

Conditions

Conditions	Yield
In benzene byproducts: isopropanol; Excess of 2,2'-dimethylpentanol is added to a benzene soln. of the starting complex, the mixt. is refluxed for 5 h (N2).; The liberated isopropanol is removed azeotropically (72-80°C) till no isopropanol is detected in the destillate, the volatiles are stripped off in vacuo, the resulting complex is recrystallized from n-hexane (-10 to -15°C), elem. anal.;	97.5%

: 75-85-4
tert-Amyl alcohol

: tert-butyltin tris(dimethylamide)

: C19H42O3Sn

Conditions

Conditions	Yield
With oxygen In isopropyl alcohol at 20℃; under 51.7162 - 103.432 Torr; Schlenk technique; Cooling with ice;	97.3%
Glovebox; Inert atmosphere; Sealed tube;	97.3%
With 2,2',2''-triaminotriethylamine In pentane for 2h; Schlenk technique; Cooling with ice; Glovebox;	435 g

: 75-85-4
tert-Amyl alcohol

: 6343-16-4, 24425-58-9, 38447-89-1, 51252-31-4
bicyclo<2.2.1>hept-5,6-ene-2α,3β-dicarbonitrile

: (1S,2R,3R,4R)-Bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid bis-[(1,1-dimethyl-propyl)-amide]

Conditions

Conditions	Yield
With sulfuric acid In acetic acid for 12h; Ritter reaction;	97%

: 75-85-4
tert-Amyl alcohol

: 463934-08-9
methanesulfonic acid 3-(naphthalen-2-oxy)-1-propyl ester

A: 894085-83-7
2-[3-(2-methyl-2-butoxy)propoxy]naphthalene

B: 398-53-8
2-(3-fluoro-n-propoxy)naphthalene

Conditions

Conditions	Yield
With rubidium fluoride; polystyrene-supported 1-n-hexyl-3-methylimidazolium BF4 at 90℃; for 1.5h;	A 2 % Spectr. B 97%
With cesium fluoride at 80℃; for 2.5 - 6h; Product distribution / selectivity;	A 4% B 93%
With cesium fluoride at 80℃; for 6h;	A 5 % Spectr. B 93%

...Expand

: 1-(3-p-toluenesulfonyloxypropyl)-4-nitroimidazole

: 75-85-4
tert-Amyl alcohol

A: C11H19N3O3

B: 1-(3-fluoropropyl)-4-nitro-1H-imidazole

Conditions

Conditions	Yield
With cesium fluoride; polystyrene-supported 1-n-hexyl-3-methylimidazolium BF4 at 80℃; for 1h;	A n/a B 97%

...Expand

: 75-85-4
tert-Amyl alcohol

: nickel niobium isopropoxide

: Ni(2+)*2Nb(5+)*4OCH(CH3)2(1-)*8OC(CH2CH3)(CH3)2(1-) = Ni[Nb(OCH(CH3)2)2(OC(CH2CH3)(CH3)2)4]2

Conditions

Conditions	Yield
In benzene byproducts: isopropanol; moisture excluded; excess alcohol added to soln. of nickel niobium isopropoxide; refluxed over a fractionating column; isopropanol liberated was continuously fractionated out with benzene between 72-80°C; excess of solvent removed under reduced pressure and compd. dried; elem. anal.;	97%

: 75-85-4
tert-Amyl alcohol

: 2-methylbutan-2-ol (lithium salt)

Conditions

Conditions	Yield
With n-butyllithium In tetrahydrofuran; hexane at 0 - 22℃; for 1h; Inert atmosphere;	97%
With lithium In hexane Inert atmosphere; Schlenk technique; Reflux;	77.8%

: 75-85-4
tert-Amyl alcohol

: 88477-42-3
RbOC(Me)2Et

Conditions

Conditions	Yield
With rubidium In n-heptane Inert atmosphere; Schlenk technique; Reflux;	96.7%
With rubidium In tetrahydrofuran for 48h; Inert atmosphere; Reflux;	92.5%

: 75-85-4
tert-Amyl alcohol

: 507-36-8
2-bromo-2-methylbutane

Conditions

Conditions	Yield
With hydrogen bromide at 50℃; for 0.25h;	96.5%
With hydrogen bromide; lithium bromide at -10℃; for 2h;	91%
With 1,2-dibromo-1,1,2,2-tetrachloroethane; triphenylphosphine In dichloromethane at 20℃; for 0.15h; Appel Halogenation;	85%

: 75-85-4
tert-Amyl alcohol

: 54237-96-6
2-Chloromethyl-1,3-dioxepane

: 1634-04-4
tert-butyl methyl ether

: 107-21-1
ethylene glycol

: 69814-56-8
2-methylene-1,3-dioxepane

Conditions

Conditions	Yield
With potassium hydroxide	96.3%

...Expand

: 75-85-4
tert-Amyl alcohol

: 622-58-2
p-Tolylisocyanate

: 40083-80-5
tert-pentyl p-tolyl carbamate

Conditions

Conditions	Yield
at 120℃; for 0.5h; Mechanism;	96%
at 120℃; for 0.5h;	96%
copper(II) 2-ethylhexanoate In benzene Heating;

: 75-85-4
tert-Amyl alcohol

: 7677-24-9
trimethylsilyl cyanide

: 6689-16-3
2-methyl-2-trimethylsiloxybutane

Conditions

Conditions	Yield
at 25℃; for 0.0833333h;	96%

: 75-85-4
tert-Amyl alcohol

: 939-26-4
2-bromomethylnaphthyl bromide

A: C16H20O

B: 55831-11-3
2-(fluoromethyl)naphthalene

Conditions

Conditions	Yield
With cesium fluoride; polystyrene-supported 1-n-hexyl-3-methylimidazolium BF4 at 80℃; for 0.5h;	A n/a B 96%

...Expand

: 75-85-4
tert-Amyl alcohol

: (dimethylamino)titanatrane

: 137516-03-1
(CH3)2C2H5COTi(OCH2CH2)3N

Conditions

Conditions	Yield
In dichloromethane byproducts: HN(CH3)2; under Ar, stirring at room temp. for 10 min;; layering with pentane, cooling to -25°C, standing overnight, elem. anal.;;	96%

: 75-85-4
tert-Amyl alcohol

: 75-36-5
acetyl chloride

: 625-16-1
tert-amyl acetate

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 24h;	95%
With sodium carbonate; potassium carbonate; N-benzyl-N,N,N-triethylammonium chloride In dichloromethane for 3h; Heating;	80%
With diethyl ether; magnesium

: 75-85-4
tert-Amyl alcohol

: 999-97-3
1,1,1,3,3,3-hexamethyl-disilazane

: 6689-16-3
2-methyl-2-trimethylsiloxybutane

Conditions

Conditions	Yield
With aluminium(III) triflate at 20℃; for 1.11667h;	95%
With copper(II) bis(trifluoromethanesulfonate) In acetonitrile at 20℃; for 2.5h;	93%
With nano magnetic sulfated zirconia (Fe3O4 at ZrO2/SO42-) In neat (no solvent) at 20℃; for 0.5h; Green chemistry;	82%