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inquiryIsobutylene oxide CAS:558-30-5 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermedi
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A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc
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inquiryMethyl propylene oxide Boiling point 50-51 °C (lit.) Density 0.812 g/mL at 25 °C (lit.) Refractive index n20/D 1.374 (lit.) Flash point 33 °F Storage Conditions
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1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer
Conditions | Yield |
---|---|
With methyltrifluoromethyldioxirane In various solvent(s) for 0.0333333h; other reagent: dimethyldioxirane; | 99% |
With tert.-butylhydroperoxide; molybdenum(V) chloride In 1,2-dimethoxyethane at 120℃; under 3750.38 Torr; for 4h; Reagent/catalyst; Temperature; Solvent; Pressure; Inert atmosphere; | 90% |
With DL-dithiothreitol; 1-phenylethyl hydroperoxide; C18H29Cl3NS3Y; molybdenum stearate In ethylbenzene at 150℃; under 37503.8 Torr; for 3.5h; Inert atmosphere; | 89.6% |
Conditions | Yield |
---|---|
With potassium hydroxide at -15℃; under 500 Torr; for 5h; Epoxidation; Cyclization; | 92% |
With potassium hydroxide | |
With sodium hydroxide; water |
Conditions | Yield |
---|---|
decompn. at 70°C (0.5 h); | A 89% B n/a |
(C4H9)3SnOC(CH3)2CH2Cl
A
2-methyl-1,2-epoxypropane
B
tributyltin chloride
Conditions | Yield |
---|---|
decompn. at 210°C (1 h); | A 85% B n/a |
5-ethyl-2,2-dimethyl-4,6-dioxa-1-aza-bicyclo[3.1.0]hexane
phenylacetylene
A
2-methyl-1,2-epoxypropane
B
3-ethyl-5-phenylisoxazole
Conditions | Yield |
---|---|
In toluene for 0.166667h; Reflux; regioselective reaction; | A n/a B 85% |
phenylacetylene
2,4,4-trimethyloxazoline 2,3-oxide
A
2-methyl-1,2-epoxypropane
B
3-methyl-5-phenylisoxazole
Conditions | Yield |
---|---|
In toluene for 0.166667h; Reflux; regioselective reaction; | A n/a B 85% |
bis(triphenylphosphine)-t-butoxy(methyl)nickel
A
2-methyl-1,2-epoxypropane
B
2-methyl-but-2-ene
C
methane
D
isobutene
Conditions | Yield |
---|---|
In toluene at 50℃; for 12h; Further byproducts given; | A 45% B 16% C 81% D 21% |
In toluene at 50℃; for 12h; Further byproducts given; | A 45 % Chromat. B 16 % Chromat. C 81 % Chromat. D 21 % Chromat. |
exo-2-(1a,9b-dihydro-1H-cyclopropa[l]phenanthren-1-yl)propan-2-ol
A
2-methyl-1,2-epoxypropane
B
phenanthrene
C
1-methylcyclopropanol
D
butanone
Conditions | Yield |
---|---|
With Methylenedioxybenzene In benzene-d6 at 20℃; Product distribution; Photolysis; | A 3% B n/a C 28% D 69% |
bis(triphenylphosphine)dimethylnickel
isopropyl alcohol
A
2-methyl-1,2-epoxypropane
B
acetone
Conditions | Yield |
---|---|
A 2% B 68% |
cis-bis(acetonitrile)chloronitropalladium(II)
isobutene
A
2-methyl-1,2-epoxypropane
Conditions | Yield |
---|---|
With oxygen In chloroform-d1 CDCl3, 25°C, 24 h, air;; not sepd., detected by NMR spectra;; | A 16% B n/a |
Conditions | Yield |
---|---|
With 1,1,1-trichloroethanol at 0℃; | |
With water at 0℃; | |
With ethanol at 0℃; | |
With lithium chloride at 0℃; | |
With formamide at 0℃; |
Conditions | Yield |
---|---|
With potassium hydroxide |
di-tert-butyl peroxide
A
2-methyl-1,2-epoxypropane
B
acetone
C
tert-butyl alcohol
Conditions | Yield |
---|---|
at 17℃; Photolysis; |
di-tert-butyl peroxide
A
2-methyl-1,2-epoxypropane
B
methane
C
acetone
D
tert-butyl alcohol
Conditions | Yield |
---|---|
at 110℃; Produkt5:Aethan; |
di-tert-butyl peroxide
A
2-methyl-1,2-epoxypropane
B
ethane
C
acetone
D
tert-butyl alcohol
Conditions | Yield |
---|---|
at 25 - 79℃; Produkt5-7:Kohlenmonoxid,tert-Butyl-methyl-aether,Methan.Photolysis; |
methylene
acetone
A
2-methyl-1,2-epoxypropane
B
2,2,4,4-tetramethyl-[1,3]dioxolane
C
2-Methoxypropene
D
butanone
ethyl N-methyl-N-nitrosocarbamate
acetone
butan-1-ol
A
2-methyl-1,2-epoxypropane
B
butanone
Conditions | Yield |
---|---|
With potassium carbonate |
Conditions | Yield |
---|---|
With iodine; potassium iodide |
Conditions | Yield |
---|---|
With water Irradiation; addition of t-BuOH, N2O; |
tetrachloromethane
di-tert-butyl peroxide
A
2-methyl-1,2-epoxypropane
B
methylene chloride
C
hexachloroethane
D
tert-butyl alcohol
Conditions | Yield |
---|---|
at 35℃; Product distribution; Mechanism; Irradiation; |
Methoxy-(3,4-epoxycyclohexyl)-methyl-tert.-butyl-peroxid
A
2-methyl-1,2-epoxypropane
B
methyl 7-oxabicyclo[4.1.0]heptane-3-carboxylate
C
Methyl formate
D
cyclohexane-1,2-epoxide
E
acetone
F
tert-butyl alcohol
Conditions | Yield |
---|---|
In solid matrix at -196℃; for 10h; Rate constant; Thermodynamic data; Irradiation; activation energy; |
tert-butylperoxytrimethylsilane
A
2-methyl-1,2-epoxypropane
B
Trimethylsilanol
C
methane
D
Hexamethyldisiloxane
E
acetone
F
tert-butyl alcohol
Conditions | Yield |
---|---|
In hexane at 25℃; Product distribution; Kinetics; Irradiation; |
Methoxy-tert.-butylperoxycyclohexenylmethan
A
2-methyl-1,2-epoxypropane
B
Methyl formate
C
methyl cyclohex-3-ene-1-carboxylate
D
acetone
E
tert-butyl alcohol
F
cyclohexene
Conditions | Yield |
---|---|
In solid matrix at -196℃; for 10h; Rate constant; Thermodynamic data; Mechanism; Irradiation; activation energy, other substrates; |
vinyltri(tert-butylperoxysilane)
A
2-methyl-1,2-epoxypropane
B
methane
C
acetone
D
tert-butyl alcohol
Conditions | Yield |
---|---|
In hexane at 25℃; Product distribution; Kinetics; Heating; |
C4H9O2
2-methyl-1,2-epoxypropane
Conditions | Yield |
---|---|
Rate constant; |
2-tert-butylperoxy-2-methyl-propyl
A
2-methyl-1,2-epoxypropane
B
di-tert-butyl peroxide
Conditions | Yield |
---|---|
With tri-n-butyl-tin hydride In benzene at 24.9℃; Rate constant; Irradiation; |
bis(triphenylphosphine)-t-butoxy(methyl)palladium
A
2-methyl-1,2-epoxypropane
B
2-methyl-but-2-ene
C
methane
D
isobutene
Conditions | Yield |
---|---|
In toluene 1.) -30 deg C, 2.) raising the temperature to 50 deg C; | A 68 % Chromat. B 4 % Chromat. C 94 % Chromat. D 7 % Chromat. |
C41H27(2)H15NiOP2
A
2-methyl-1,2-epoxypropane
B
methane-d3
C
methane
D
isobutene
Conditions | Yield |
---|---|
In (2)H8-toluene at 50℃; Further byproducts given; | A n/a B 93 % Chromat. C 7 % Chromat. D n/a |
3.4-Epoxyhexahydroperbenzoesaeure-tert-butylester
2,2-diphenyl-1-picrylhydrazine
A
2-methyl-1,2-epoxypropane
B
2,2-diphenyl-1-(2,4,6-trinitrophenyl)hydrazyl
C
acetone
D
tert-butyl alcohol
Conditions | Yield |
---|---|
In chlorobenzene at 70℃; Thermodynamic data; Kinetics; Rate constant; E(activ.), ΔS(activ.), oth. solvents, oth. temperature; |
Dimethylaminomethyl-tert-butylperoxid
2,2-diphenyl-1-picrylhydrazine
A
2-methyl-1,2-epoxypropane
B
2,2-diphenyl-1-(2,4,6-trinitrophenyl)hydrazyl
C
acetone
D
tert-butyl alcohol
Conditions | Yield |
---|---|
In chlorobenzene at 70℃; Thermodynamic data; Kinetics; Rate constant; E(activ.), ΔS(activ.), oth. solvents, oth. temperature; |
2-methyl-1,2-epoxypropane
dimethyl amine
1-dimethylamino-2-methyl-propan-2-ol
Conditions | Yield |
---|---|
In water at -5 - 20℃; Schlenk technique; Inert atmosphere; Sealed tube; | 100% |
With water In water at 20 - 50℃; for 120h; Sealed tube; | 91% |
In water at 20℃; for 12h; Cooling with ice; Inert atmosphere; | 89% |
2-methyl-1,2-epoxypropane
dibenzylamine
1-dibenzylamino-2-methyl-propan-2-ol
Conditions | Yield |
---|---|
In ethanol at 50℃; for 72h; | 100% |
With water | |
With lithium bromide In methanol at 20 - 65℃; for 6h; | |
With lithium bromide at 20 - 60℃; for 18h; | |
With lithium bromide at 20 - 60℃; for 18h; |
2-methyl-1,2-epoxypropane
carbon dioxide
4,4-dimethyl-1,3-dioxolan-2-one
Conditions | Yield |
---|---|
With tetrabutylammomium bromide at 60℃; under 7500.75 Torr; for 72h; Time; Autoclave; | 100% |
With 2-(bis(5-(tert-butyl)-2-hydroxybenzyl)amino)-N,N,N-trimethylethan-1-aminium iodide at 120℃; Reagent/catalyst; Inert atmosphere; Schlenk technique; | 99% |
With tetrabutylammomium bromide In neat (no solvent) at 100℃; under 22502.3 Torr; for 8h; | 99% |
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