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Cesium formate Manufacturer Factory CAS 3495-36-1 Cesium formate Manufacturer High quality Best price In stock factory CAS 3495-36-1 Cesium formate COA TDS price MSDS highly quality and immedaite delivery Cesium formate Chemical Propert
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Min.Order:5 Kiloliter
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Type:Manufacturers
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Min.Order:1 Kilogram
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Type:Lab/Research institutions
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Cas:3495-36-1
Min.Order:0 Metric Ton
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Type:Lab/Research institutions
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Min.Order:0
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Type:Lab/Research institutions
inquiryZibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
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Cas:3495-36-1
Min.Order:100 Gram
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inquiryProduct name: Cesium Formate CAS No.:3495-36-1 Molecule Formula:CHCsO2 Molecule Weight:177.92 Purity: 99.0% Package: 25kg/drum Description:White crystalline powder Manufacture Standards:Enterprise Standard TESTING
Cas:3495-36-1
Min.Order:1 Kilogram
Negotiable
Type:Trading Company
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Cas:3495-36-1
Min.Order:1 Metric Ton
FOB Price: $1.0
Type:Lab/Research institutions
inquiryProduct Name: Cesium formate Synonyms: CESIUM FORMATE, MONOHYDRATE;CESIUM FORMATE;FORMIC ACID CESIUM SALT;Cesiumformatehydrate,99.9%(metalsbasis);CESIUM FORMATE 1-HYDRATE;CESIUM FORMATE SOLUTION HIGH DENSITY;CAESIUMFUMARATE;caesium formate CAS
Cas:3495-36-1
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryfactory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B
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Min.Order:1 Kilogram
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Cas:3495-36-1
Min.Order:1 Gram
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Type:Lab/Research institutions
inquiry1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer
Cas:3495-36-1
Min.Order:1 Metric Ton
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inquiryCesium formate is a chemical substance with CAS NO. 3495-36-1 and the chemical formula HCOOCs. It is easy to deliquesce and decompose at high temperature and can be used as a drilling fluid for oil exploration. Appearance:white powder Storage:cool
Cas:3495-36-1
Min.Order:1 Kilogram
FOB Price: $1.0 / 15.0
Type:Trading Company
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methanol
carbon dioxide
carbon monoxide
caesium carbonate
A
Dimethyl oxalate
B
cesium bicarbonate
C
cesium formate
Conditions | Yield |
---|---|
Stage #1: carbon dioxide; carbon monoxide; caesium carbonate With silica gel; pyrographite at 325℃; under 15001.5 - 33753.4 Torr; Stage #2: methanol at 200℃; under 30003 Torr; for 2h; Reagent/catalyst; Temperature; Pressure; | A 95% B n/a C 0.8% |
Conditions | Yield |
---|---|
With cesium hydroxide In water | 80% |
methanol
carbon dioxide
caesium carbonate
A
Dimethyl oxalate
B
cesium formate
Conditions | Yield |
---|---|
Stage #1: carbon dioxide; caesium carbonate With hydrogen at 325℃; under 750.075 Torr; Stage #2: methanol at 150℃; under 26252.6 Torr; | A 58% B 10% |
carbon dioxide
caesium carbonate
A
cesium bicarbonate
B
cesium oxalate
C
cesium formate
Conditions | Yield |
---|---|
In neat (no solvent) High Pressure; 2 h at 380°C; cooling, dissolution in water, addn. of HClO4; HPLC; | A 39.2% B 0% C 0% |
carbon dioxide
carbon monoxide
caesium carbonate
A
cesium bicarbonate
B
cesium oxalate
C
cesium formate
Conditions | Yield |
---|---|
In neat (no solvent) High Pressure; 2 h at 380°C; cooling, dissolution in water, addn. of HClO4; HPLC; | A 0.1% B 22.4% C 2.1% |
carbon monoxide
caesium carbonate
A
cesium bicarbonate
B
cesium oxalate
C
cesium formate
Conditions | Yield |
---|---|
In neat (no solvent) High Pressure; 2 h at 380°C; cooling, dissolution in water, addn. of HClO4; HPLC; | A 0% B 4.4% C 6.9% |
Conditions | Yield |
---|---|
at 141 - 164℃; Product distribution; Thermodynamic data; ΔH of the decomposition; |
Conditions | Yield |
---|---|
In neat (no solvent) purified Cs2CO3 was neutralized with formic acid forming CsHCO2;; | |
In neat (no solvent) Na-containing Cs2CO3 was treated with formic acid forming CsHCO2;; recrystn. from formic acid, remaining acid was removed with Cs2CO3, recrystn. from alcoholic soln. with addn. of ether;; | |
In neat (no solvent) Na-containing Cs2CO3 was treated with formic acid forming CsHCO2;; recrystn. from formic acid, remaining acid was removed with Cs2CO3, recrystn. from alcoholic soln. with addn. of ether;; |
cesium formate
Conditions | Yield |
---|---|
With carbon dioxide reaction proceeds only in presence of traces of H2O; moist CO2 reacts at -75°C, well dried CO2 at +42°C; | |
With CO2 reaction proceeds only in presence of traces of H2O; moist CO2 reacts at -75°C, well dried CO2 at +42°C; |
Conditions | Yield |
---|---|
With water In neat (no solvent) CsH was treated with CO2 at ambient temp. in presence of traces of water forming CsHCO2; in absence of moisture reaction occured only with heating to 54 °C;; | |
With H2O In neat (no solvent) CsH was treated with CO2 at ambient temp. in presence of traces of water forming CsHCO2; in absence of moisture reaction occured only with heating to 54 °C;; |
Conditions | Yield |
---|---|
In solid Irradiation (UV/VIS); Solid state photolysis is investigated by exposing the complex to 250 W Hg-lamp.; detected by Moessbauer spectroscopy; | A n/a B n/a C 0% |
In sulfuric acid Irradiation (UV/VIS); Alkali hexa(formato)ferrate(III) is subjected to photolysis by irradiating it with radiations from a mercury lamp, 1,10-phenanthroline is added, photochemical reduction is studied at 25°C.; |
cesium formate
Conditions | Yield |
---|---|
In not given water was removed from hydrated formiate before examination it thermal decomposition; detd. by XRD and IR; |
cesium formate
Conditions | Yield |
---|---|
byproducts: caesium oxalate; exothermally decompn. at 38-55°C; |
methanol
cesium bicarbonate
A
caesium methyl carbonate
B
cesium formate
Conditions | Yield |
---|---|
With tris(triphenylphosphine)ruthenium(II) chloride; hydrogen at 110℃; under 15201 Torr; for 16h; Catalytic behavior; Inert atmosphere; |
cesium bicarbonate
cesium formate
Conditions | Yield |
---|---|
With {RuCl2(m-triphenylphosphine trisulfonate)2}2; hydrogen; tris-(m-sulfonatophenyl)phosphine In water at 80℃; under 75007.5 Torr; for 20h; Concentration; Autoclave; | |
With carbonyl chlorohydride{bis[2-(bis-tert-butylphosphino)ethyl]amine}ruthenium(II); hydrogen In 2-methyltetrahydrofuran; water at 80℃; under 37503.8 Torr; for 1.05h; | 98 %Spectr. |
carbon dioxide
benzene
C
cesium acetate
D
cesium benzoate
E
cesium formate
F
cesium o-phthalate
G
caesium isophthalate
Conditions | Yield |
---|---|
With caesium carbonate at 360℃; for 8h; Sealed tube; Overall yield = 19 %Spectr.; |
carbon dioxide
caesium carbonate
A
cesium oxalate
B
cesium formate
Conditions | Yield |
---|---|
With hydrogen at 325℃; under 750.075 Torr; |
Conditions | Yield |
---|---|
In methanol for 10h; | 95% |
cesium formate
tetra-n-butylphosphonium formate
Conditions | Yield |
---|---|
In ethanol | 90% |
cesium formate
Conditions | Yield |
---|---|
In acetonitrile Inert atmosphere; | 85% |
Conditions | Yield |
---|---|
In isopropyl alcohol at 20℃; for 48h; | 77% |
Conditions | Yield |
---|---|
In isopropyl alcohol at 20℃; | 76% |
In isopropyl alcohol for 16h; |
Conditions | Yield |
---|---|
Stage #1: 2-phenylethyl acrylate; cesium formate With carbon dioxide; C38H55F3GeO3P2PdS In 1,4-dioxane at 80℃; under 760.051 Torr; for 6h; Inert atmosphere; Green chemistry; Stage #2: trimethylsilylazide In methanol; diethyl ether at 0℃; for 0.5h; Inert atmosphere; Green chemistry; regioselective reaction; | 75% |
cesium formate
(+)-(1S,3S)-(2,2-dimethyl-6-methylene-3-p-toluenesulfonyloxycyclohexyl)methyl p-toluenesulfonate
(1S,3S)-(+)-2,2-dimethyl-6-methylene-3-tosyloxycyclohexanemethyl formate
Conditions | Yield |
---|---|
With perhydrodibenzo-18-crown-6 In methanol; toluene at 110℃; for 35h; | 66.6% |
cesium formate
3-epi-3-trifluoromethanesulfonyl-altholactone
3-formyloxy-altholactone
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 20℃; for 4h; | 60% |
trimethylsilylazide
PVS
cesium formate
methyl α-(phenylsulfonyl)propionate
Conditions | Yield |
---|---|
Stage #1: PVS; cesium formate With carbon dioxide; C38H55F3GeO3P2PdS In 1,4-dioxane at 80℃; under 760.051 Torr; for 6h; Green chemistry; Stage #2: trimethylsilylazide In methanol; diethyl ether at 0℃; for 0.5h; Green chemistry; regioselective reaction; | 59% |
Conditions | Yield |
---|---|
Stage #1: ethyl crotonate; cesium formate With C22H31F3GeO3P2PdS In N,N-dimethyl-formamide at 80℃; for 6h; Inert atmosphere; Green chemistry; Stage #2: benzyl bromide With potassium carbonate; sodium iodide In N,N-dimethyl-formamide at 20℃; for 12h; Green chemistry; regioselective reaction; | 50% |
benzyl bromide
cesium formate
methyl methacrylate
1-benzyl 3-ethyl 2,2-dimethylmalonate
Conditions | Yield |
---|---|
Stage #1: cesium formate; methyl methacrylate With C22H31F3GeO3P2PdS In N,N-dimethyl-formamide at 80℃; for 6h; Inert atmosphere; Green chemistry; Stage #2: benzyl bromide With potassium carbonate; sodium iodide In N,N-dimethyl-formamide at 20℃; for 12h; Inert atmosphere; Green chemistry; regioselective reaction; | 40% |
(3S,5S,8R,9S,10S,13R,14S,17R)-10,13-dimethyl-17-((R)-6-methylheptan-2-yl)hexadecahydro-1H-cyclopenta[a]phenanthren-3-yl methanesulfonate
cesium formate
A
5α-cholest-3-ene
B
cholest-2-ene
C
3α-cholestanyl formate
Conditions | Yield |
---|---|
With dmap In toluene for 96h; Heating; | A n/a B n/a C 13% |
Conditions | Yield |
---|---|
In neat (no solvent) Kinetics; heating in air up to 600°C under atmospheric pressure and humidity (heating rate 5-10°C/min); thermogravimetric monitoring; |
cesium formate
A
methane
B
carbon dioxide
C
carbon monoxide
D
cesium oxalate
E
caesium carbonate
Conditions | Yield |
---|---|
In solid byproducts: C, CH3OH, HCO2CH3; thermal decomposition of CsHCO2 under N2 at 200-250°C; detd. by XRD and IR; |
cesium formate
tin(II) formate
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