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Dayang Chem (Hangzhou) Co.,Ltd.

img heightAppearance:detailed see specifications Storage:Store in dry, dark and ventilated place. Package:according to the clients requirement Application:Used in Synthesis, Pharmaceuticals and other fields Transportation:by air or by sea Port:Shan

Ethyl methacrylate Manufacturer/High quality/Best price/In stock

Cas:97-63-2

Min.Order:1 Metric Ton

FOB Price: $7.0

Type:Lab/Research institutions

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Appearance colorless liquid colorless liquid Purity ≥99.5%

high purity Ethyl methacrylate 97-63-2

Cas:97-63-2

Min.Order:1 Kilogram

FOB Price: $1.9 / 2.5

Type:Trading Company

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Ethyl Methacrylate supplier in China

Cas:97-63-2

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Hefei TNJ chemical industry co.,ltd

1,ISO Certificate 2,Factory price 3,Free sample and Fast delivery Appearance:Colorless transparent liquid Storage:All products should be stored at a dry and ventilated location away from fire and other dangerous goods, and should avoid direct sunl

Ethyl methacrylate,EMA,CAS 97-63-2

Cas:97-63-2

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off white powder Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

Ethyl methacrylate

Cas:97-63-2

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Ethyl methacrylate

Cas:97-63-2

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Ethyl methacrylate

Cas:97-63-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

Product Name: Ethyl methacrylate Synonyms: Ethyl methacryla;2-Methyl-2-propenoic acid ethyl ester;2-methyl-2-propenoicacid,ethylester;2-methyl-2-propenoicaciethylester;2-Methylacrylic acid, ethyl ester;2-methyl-prop-2-enoicacidethylest

EMA 97-63-2 Ethyl methacrylate

Cas:97-63-2

Min.Order:1 Metric Ton

FOB Price: $8900.0

Type:Lab/Research institutions

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Henan Sinotech Import&Export Corporation

CAS Number 97-63-2 Product Name Ethyl Methacrylate Synonyms 2-methyl-2-propenoicacid,ethylester; 2-methyl-2-propenoicaciethylest

Ethyl methacrylate

Cas:97-63-2

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:97-63-2

Cas:97-63-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Ethyl methacrylate

Cas:97-63-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2-Propenoic acid,2-methyl-, ethyl ester

Cas:97-63-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Ethyl Methacrylate

Cas:97-63-2

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:colorless liquid Storage:sealed in a cool, dark place Package:in 180kgs net new galvanized steel drum; or as per your request. Application:Thermoplastic acrylic resin, two-component

Ethyl methacrylate(EMA)

Cas:97-63-2

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Ethyl Methacrylate

Cas:97-63-2

Min.Order:0

Negotiable

Type:Other

inquiry

JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

Ethyl Methacrylate

Cas:97-63-2

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

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Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Ethyl methacrylate

Cas:97-63-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 97-63-2 with competitive price

Cas:97-63-2

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

2-Propenoic acid,2-methyl-, ethyl ester

Cas:97-63-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

Ethyl Methacrylate

Cas:97-63-2

Min.Order:0

Negotiable

Type:Other

inquiry

Luyunjia Chemistry Xiamen Limited

Xiamen Luyunjia Trading Co.,Ltd Package:1kg/bag; 2914kg/drum, or as customer's request. Application:Xiamen Luyunjia Trading Co.,Ltd Transportation:DHL, EMS, FedEx, TNT, AIR, SEA Port:Beijing,Shanghai,Guangzhou ,China main port

Ethyl Methacrylate

Cas:97-63-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemsigma International Co.,Ltd.

bulk production

Ethyl methacrylate

Cas:97-63-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

HWRK Chem

in storeAppearance:Colorless transparent liquid Package:500ml Application:Organic Chemicals

Ethyl Methacrylate

Cas:97-63-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

Ethyl methacrylate Basic information Product Name: Ethyl methacrylate Synonyms: 2-Methyl-2-propenoic acid ethyl ester;2-methyl-2-propenoicacid,ethylester;2-methyl-2-propenoicaciethylester;2-Methylacrylic

Ethyl methacrylate

Cas:97-63-2

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Changzhou Extraordinary Pharmatech co.,LTD

Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and

Ethyl methacrylate

Cas:97-63-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Changzhou Pesan Chemical Co.,Ltd

Strong R&D strength and team We have a R&D team with around 30 R&D personnel.All of our employees have chemical backgrounds and have worked in the chemical industry for many years.Our laboratory can synthesize target products with wei

Ethyl Methacrylate UV curing monomers CAS NO.97-63-2

Cas:97-63-2

Min.Order:1 Kilogram

FOB Price: $1.0 / 9999.0

Type:Other

inquiry

Suzhou HeChuang Chemical Co.,Ltd.

HC Chemical is a technical enterprise,mainly engaged in R & D, production and sales of (meth)acrylate ester monomers. HC Chemical has more than ten years of experience in R&D, industrialization and engineering of (meth)acrylate

Ethyl methacrylate

Cas:97-63-2

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Xiamen BaiFuchem Co.,Ltd

BaiFuChem is a Professional chemical raw material supplier in China, our main products include Biochemical , Pharma Intermediate and Organic chemical etc. BaiFuChem have wealth of products,experience , expertise and state-of-the-art

Best price Ethyl Methacrylate

Cas:97-63-2

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Cerametek Materials(ShenZhen)Co., Ltd.

sub/micron to mesh powders (near/spheres, whiskers, flake, fiber, porous) and grain/ball, thin/ thick metal / alloys pieces / parts, thin and thick (particle) film materials /target, and custom-made crystals, substrates/parts. In the industries and a

Ethyl methacrylate

Cas:97-63-2

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Share Chemical Co., Ltd

At Share Chemical Company, we scrupulously abide by our policy of “Excellent Quality at a Reasonable Price”. We strive to satisfy all of our customers by providing the finest quality products supported by the finest in customer servi

Ethyl Methacrylate, 98+%, stab. with 100ppM 4-Methoxyp

Cas:97-63-2

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Synthetic route

ethyl 2-((tert-butyl(1-(diethoxyphosphoryl)-2,2-dimethylpropyl)amino)oxy)-2-methylpropanoate
1034132-98-3

ethyl 2-((tert-butyl(1-(diethoxyphosphoryl)-2,2-dimethylpropyl)amino)oxy)-2-methylpropanoate

A

Diethyl phosphonate
762-04-9, 123-22-8

Diethyl phosphonate

B

diethyl (1-(tert-butyl((ethoxycarbonyl)oxy)amino)-2,2-dimethylpropyl)phosphonate
1393670-70-6

diethyl (1-(tert-butyl((ethoxycarbonyl)oxy)amino)-2,2-dimethylpropyl)phosphonate

C

methyl methacrylate
97-63-2

methyl methacrylate

Conditions
ConditionsYield
With thiophenol at 70℃; under 7.50075E-06 Torr;A 85%
B 15%
C n/a
2-methyl-2-propenoic acid 2-hydroxyethyl ester
868-77-9

2-methyl-2-propenoic acid 2-hydroxyethyl ester

A

2,3-dioxycarbonylpropyl (ethyl methacrylate) carbonate

2,3-dioxycarbonylpropyl (ethyl methacrylate) carbonate

B

methyl methacrylate
97-63-2

methyl methacrylate

Conditions
ConditionsYield
With pyridine In dichloromethane; waterA n/a
B 84%
ethanol
64-17-5

ethanol

1,2-propanediene
463-49-0

1,2-propanediene

carbon monoxide
201230-82-2

carbon monoxide

methyl methacrylate
97-63-2

methyl methacrylate

Conditions
ConditionsYield
dodecacarbonyl-triangulo-triruthenium at 100℃; under 11400 Torr; for 3h;71%
β-acetoxy-isobutyric acid ethyl ester
88226-62-4

β-acetoxy-isobutyric acid ethyl ester

methyl methacrylate
97-63-2

methyl methacrylate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In benzene at 80℃; for 5h;60%
2-methylpropenal
78-85-3

2-methylpropenal

ethanol
64-17-5

ethanol

methyl methacrylate
97-63-2

methyl methacrylate

Conditions
ConditionsYield
phosphorus-molybdenum catalyst at 310℃;50%
With oxygen at 80℃; under 22502.3 Torr; for 1h; Catalytic behavior;
ethanol
64-17-5

ethanol

chloroform
67-66-3

chloroform

acetone
67-64-1

acetone

A

ethyl 2-chloro-2-methylpropanoate
62554-44-3

ethyl 2-chloro-2-methylpropanoate

B

methyl methacrylate
97-63-2

methyl methacrylate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In benzonitrile; acetonitrile at 50℃; for 42h;A 25%
B 46%
ethyl 2-bromoisobutyrate
600-00-0

ethyl 2-bromoisobutyrate

dimanganese decacarbonyl
10170-69-1

dimanganese decacarbonyl

A

diethyl 2,2,3,3-tetramethylsuccinate
33367-54-3

diethyl 2,2,3,3-tetramethylsuccinate

B

diethyl 2,2,3,5,5-pentamethylhexa-1,6-dioate

diethyl 2,2,3,5,5-pentamethylhexa-1,6-dioate

C

diethyl 2,2-dimethyl-4-methylenepenta-1,5-dioate
106471-98-1

diethyl 2,2-dimethyl-4-methylenepenta-1,5-dioate

D

methyl methacrylate
97-63-2

methyl methacrylate

E

Ethyl isobutyrate
97-62-1

Ethyl isobutyrate

Conditions
ConditionsYield
In tetrahydrofuran Irradiation (UV/VIS); (N2 or Ar); 250-W sun lamp, 3 h; colorless solution is filtered, (1)H-NMR;A 45%
B 13%
C 5%
D 12%
E 17%
In chloroform-d1 Irradiation (UV/VIS); (N2 or Ar); 250-W sun lamp, 3 h; colorless solution is filtered, (1)H-NMR;A 36%
B 9%
C 4%
D 5%
E 13%
ethyl 2-bromoisobutyrate
600-00-0

ethyl 2-bromoisobutyrate

A

diethyl 2,2,3,3-tetramethylsuccinate
33367-54-3

diethyl 2,2,3,3-tetramethylsuccinate

B

diethyl 2,2-dimethyl-4-methylenepenta-1,5-dioate
106471-98-1

diethyl 2,2-dimethyl-4-methylenepenta-1,5-dioate

C

methyl methacrylate
97-63-2

methyl methacrylate

D

Ethyl isobutyrate
97-62-1

Ethyl isobutyrate

Conditions
ConditionsYield
With {bis(triphenylphosphine)nitrogen}{manganese(carbonyl)5} In tetrahydrofuran for 5h;A 36%
B 3%
C 6%
D 35%
ethyl 2-bromoisobutyrate
600-00-0

ethyl 2-bromoisobutyrate

bis(triphenylphosphineiminium) pentacarbonylmanganate(1-)
52542-59-3, 192520-17-5

bis(triphenylphosphineiminium) pentacarbonylmanganate(1-)

A

diethyl 2,2,3,3-tetramethylsuccinate
33367-54-3

diethyl 2,2,3,3-tetramethylsuccinate

B

diethyl 2,2-dimethyl-4-methylenepenta-1,5-dioate
106471-98-1

diethyl 2,2-dimethyl-4-methylenepenta-1,5-dioate

C

methyl methacrylate
97-63-2

methyl methacrylate

D

Ethyl isobutyrate
97-62-1

Ethyl isobutyrate

Conditions
ConditionsYield
In tetrahydrofuran (N2 or Ar); solution is allowed to stand for 5 h; determination by NMR and MS fragmentation;A 36%
B 3%
C 6%
D 35%
ethyl 2-bromoisobutyrate
600-00-0

ethyl 2-bromoisobutyrate

sodium pentacarbonyl manganate
13859-41-1

sodium pentacarbonyl manganate

A

diethyl 2,2,3,3-tetramethylsuccinate
33367-54-3

diethyl 2,2,3,3-tetramethylsuccinate

B

diethyl 2,2-dimethyl-4-methylenepenta-1,5-dioate
106471-98-1

diethyl 2,2-dimethyl-4-methylenepenta-1,5-dioate

C

methyl methacrylate
97-63-2

methyl methacrylate

D

Ethyl isobutyrate
97-62-1

Ethyl isobutyrate

Conditions
ConditionsYield
In tetrahydrofuran (N2 or Ar); solution is allowed to stand for 5 h; determination by NMR and MS fragmentation;A 14%
B 1%
C 16%
D 36%
ethyl 2-bromoisobutyrate
600-00-0

ethyl 2-bromoisobutyrate

methyl methacrylate
97-63-2

methyl methacrylate

Conditions
ConditionsYield
With quinoline
With N,N-diethylaniline
formaldehyd
50-00-0

formaldehyd

monoethyl methylmalonate
2985-33-3

monoethyl methylmalonate

methyl methacrylate
97-63-2

methyl methacrylate

Conditions
ConditionsYield
With water; diethylamine
ethyl 2-ethoxy-2-methylpropanoate
151598-88-8

ethyl 2-ethoxy-2-methylpropanoate

methyl methacrylate
97-63-2

methyl methacrylate

ethanol
64-17-5

ethanol

poly(methacrylic acid)
79-41-4

poly(methacrylic acid)

methyl methacrylate
97-63-2

methyl methacrylate

Conditions
ConditionsYield
With sulfuric acid; benzene
With acidic cation exchange resin Amberlyst 70 at 50 - 145℃; Flow reactor; Green chemistry;
ethanol
64-17-5

ethanol

2-ethoxy-2-methyl-propanoic acid
15001-71-5

2-ethoxy-2-methyl-propanoic acid

A

ethyl 2-ethoxy-2-methylpropanoate
151598-88-8

ethyl 2-ethoxy-2-methylpropanoate

B

methyl methacrylate
97-63-2

methyl methacrylate

Conditions
ConditionsYield
With sulfuric acid; tannic acid
ethyl 2-chloro-2-methylpropanoate
62554-44-3

ethyl 2-chloro-2-methylpropanoate

methyl methacrylate
97-63-2

methyl methacrylate

Conditions
ConditionsYield
With quinoline; hydroquinone
With iron(III) chloride
With zinc
α-acetoxy-isobutyric acid ethyl ester
6283-75-6

α-acetoxy-isobutyric acid ethyl ester

methyl methacrylate
97-63-2

methyl methacrylate

Conditions
ConditionsYield
at 475℃;
ethyl 2-aminoisobutyrate hydrochloride
17288-15-2

ethyl 2-aminoisobutyrate hydrochloride

methyl methacrylate
97-63-2

methyl methacrylate

Conditions
ConditionsYield
With hydrogenchloride; sodium nitrite at 20℃;
poly(methacrylic acid)
79-41-4

poly(methacrylic acid)

propyl bromide
106-94-5

propyl bromide

triethyl phosphite
122-52-1

triethyl phosphite

A

β-diethoxyphosphoryl-isobutyric acid propyl ester
109313-50-0

β-diethoxyphosphoryl-isobutyric acid propyl ester

B

methyl methacrylate
97-63-2

methyl methacrylate

C

phosphonic acid diethyl ester
762-04-9

phosphonic acid diethyl ester

Conditions
ConditionsYield
und Erwaermen des Reaktionsgemisches;
sodium acetate
127-09-3

sodium acetate

hydroquinone
123-31-9

hydroquinone

3-hydroxy-2-methyl-propionic acid ethyl ester
89534-52-1

3-hydroxy-2-methyl-propionic acid ethyl ester

methyl methacrylate
97-63-2

methyl methacrylate

ethyl sulfate
540-82-9

ethyl sulfate

2-amino-2-cyanopropane
19355-69-2

2-amino-2-cyanopropane

methyl methacrylate
97-63-2

methyl methacrylate

Conditions
ConditionsYield
Einw. von NaNO2-Loesung auf das Reaktionsprodukt;
ethanol
64-17-5

ethanol

methacrylonitrile
126-98-7

methacrylonitrile

methyl methacrylate
97-63-2

methyl methacrylate

Conditions
ConditionsYield
With sulfuric acid
ethyl 2-hydroxy-2,2-dimethylethanoate
80-55-7

ethyl 2-hydroxy-2,2-dimethylethanoate

methyl methacrylate
97-63-2

methyl methacrylate

Conditions
ConditionsYield
With phosphorus trichloride
ethyl 2-hydroxy-2,2-dimethylethanoate
80-55-7

ethyl 2-hydroxy-2,2-dimethylethanoate

A

ethyl 2-chloro-2-methylpropanoate
62554-44-3

ethyl 2-chloro-2-methylpropanoate

B

methyl methacrylate
97-63-2

methyl methacrylate

Conditions
ConditionsYield
With thionyl chloride anschliessenden Erwaermen mit wenig Pyridin;
With 1-chloro-1-(dimethylamino)-2-methyl-1-propene In dichloromethane at 20℃; for 2h; Inert atmosphere;A 75 %Spectr.
B 25 %Spectr.
Brommethyl-methylmalonsaeure-ethyl-thioethylester
62442-83-5

Brommethyl-methylmalonsaeure-ethyl-thioethylester

A

C9H15(2)HO3S

C9H15(2)HO3S

B

methyl methacrylate
97-63-2

methyl methacrylate

C

C8H15(2)HO2S

C8H15(2)HO2S

D

C9H15(2)HO3S

C9H15(2)HO3S

Conditions
ConditionsYield
With ethyl [2]alcohol; vitamin B12s for 14h; Mechanism; Ambient temperature; other reactant;
1-ethoxycarbonyl-1-methylethyl phenyl sulfoxide
127074-24-2

1-ethoxycarbonyl-1-methylethyl phenyl sulfoxide

methyl methacrylate
97-63-2

methyl methacrylate

Conditions
ConditionsYield
In 1,4-dioxane at 90℃; Kinetics; Thermodynamic data; Ea, ΔS(excit.);
2-Methyl-2-(toluene-4-sulfinyl)-propionic acid ethyl ester

2-Methyl-2-(toluene-4-sulfinyl)-propionic acid ethyl ester

methyl methacrylate
97-63-2

methyl methacrylate

Conditions
ConditionsYield
In 1,4-dioxane at 70℃; Rate constant;
2-(3-Chloro-benzenesulfinyl)-2-methyl-propionic acid ethyl ester

2-(3-Chloro-benzenesulfinyl)-2-methyl-propionic acid ethyl ester

methyl methacrylate
97-63-2

methyl methacrylate

Conditions
ConditionsYield
In 1,4-dioxane at 70℃; Rate constant;
2-(4-Chloro-benzenesulfinyl)-2-methyl-propionic acid ethyl ester

2-(4-Chloro-benzenesulfinyl)-2-methyl-propionic acid ethyl ester

methyl methacrylate
97-63-2

methyl methacrylate

Conditions
ConditionsYield
In 1,4-dioxane at 70℃; Rate constant;
2-(4-Methoxy-benzenesulfinyl)-2-methyl-propionic acid ethyl ester

2-(4-Methoxy-benzenesulfinyl)-2-methyl-propionic acid ethyl ester

methyl methacrylate
97-63-2

methyl methacrylate

Conditions
ConditionsYield
In 1,4-dioxane at 70℃; Rate constant;
methyl methacrylate
97-63-2

methyl methacrylate

8-fluoro-5,11-dihydro-11-(4-piperidyldene)<1>benzoxepino<4,3-b>pyridine
153249-96-8

8-fluoro-5,11-dihydro-11-(4-piperidyldene)<1>benzoxepino<4,3-b>pyridine

3-[4-(8-Fluoro-11H-10-oxa-4-aza-dibenzo[a,d]cyclohepten-5-ylidene)-piperidin-1-yl]-2-methyl-propionic acid ethyl ester

3-[4-(8-Fluoro-11H-10-oxa-4-aza-dibenzo[a,d]cyclohepten-5-ylidene)-piperidin-1-yl]-2-methyl-propionic acid ethyl ester

Conditions
ConditionsYield
In ethanol Heating;100%
N-((1S)-1-phenylethyl)hydroxylamine
53933-47-4

N-((1S)-1-phenylethyl)hydroxylamine

methyl methacrylate
97-63-2

methyl methacrylate

C14H21NO3
912650-22-7

C14H21NO3

Conditions
ConditionsYield
In tetrahydrofuran100%
methyl methacrylate
97-63-2

methyl methacrylate

ethyl 2-chloro-2-(hydroxyimino)acetate
14337-43-0

ethyl 2-chloro-2-(hydroxyimino)acetate

5-Methyl-4,5-dihydro-isoxazole-3,5-dicarboxylic acid diethyl ester
141562-82-5

5-Methyl-4,5-dihydro-isoxazole-3,5-dicarboxylic acid diethyl ester

Conditions
ConditionsYield
With triethylamine In diethyl ether Ambient temperature;99%
α,α-dichloromethyl p-tolyl sulfoxide
37067-52-0

α,α-dichloromethyl p-tolyl sulfoxide

methyl methacrylate
97-63-2

methyl methacrylate

2-chloro-1-methyl-2-(toluene-4-sulfinyl)cyclopropanecarboxylic acid ethyl ester

2-chloro-1-methyl-2-(toluene-4-sulfinyl)cyclopropanecarboxylic acid ethyl ester

Conditions
ConditionsYield
With sodium hexamethyldisilazane In tetrahydrofuran at -78 - 0℃; for 2h;99%
α,α-dichloromethyl p-tolyl sulfoxide
37067-52-0

α,α-dichloromethyl p-tolyl sulfoxide

methyl methacrylate
97-63-2

methyl methacrylate

C14H17ClO3S

C14H17ClO3S

Conditions
ConditionsYield
With sodium hexamethyldisilazane In tetrahydrofuran at -78 - 20℃;99%
With sodium hexamethyldisilazane In tetrahydrofuran at -78 - 20℃; for 3h; Inert atmosphere;90%
With lithium diisopropyl amide In tetrahydrofuran diastereoselective reaction;
With sodium hexamethyldisilazane In tetrahydrofuran Inert atmosphere;
(-)-(R)-dichloromethyl p-tolyl sulfoxide
123849-08-1

(-)-(R)-dichloromethyl p-tolyl sulfoxide

methyl methacrylate
97-63-2

methyl methacrylate

(1R,2S)-ethyl 2-chloro-1-methyl-2-((R)-p-tolylsulfinyl)cyclopropanecarboxylate
1356563-72-8

(1R,2S)-ethyl 2-chloro-1-methyl-2-((R)-p-tolylsulfinyl)cyclopropanecarboxylate

Conditions
ConditionsYield
With lithium diisopropyl amide In tetrahydrofuran at -85 - 20℃; Inert atmosphere; optical yield given as %ee;99%
With lithium diisopropyl amide In tetrahydrofuran at -85 - 0℃; diastereoselective reaction;99%
With (2R,5S)-menthone; sodium hexamethyldisilazane In tetrahydrofuran Inert atmosphere;
n-perfluorohexyl iodide
355-43-1

n-perfluorohexyl iodide

methyl methacrylate
97-63-2

methyl methacrylate

Ethyl 2-methyl-4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononanoate
140834-68-0

Ethyl 2-methyl-4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononanoate

Conditions
ConditionsYield
With tris-(trimethylsilyl)silane; sodium thiosulfate In dichloromethane; water at 20℃; for 4h; UV-irradiation; Sealed tube;99%
(S)-methyl p-tolyl sulfoxide
5056-07-5

(S)-methyl p-tolyl sulfoxide

methyl methacrylate
97-63-2

methyl methacrylate

(S)-3-methyl-1-(p-tolylsulfinyl)but-3-en-2-one

(S)-3-methyl-1-(p-tolylsulfinyl)but-3-en-2-one

Conditions
ConditionsYield
Stage #1: (S)-methyl p-tolyl sulfoxide With lithium diisopropyl amide In tetrahydrofuran at -70℃; for 0.916667h; Inert atmosphere;
Stage #2: methyl methacrylate In tetrahydrofuran at -70 - -25℃; for 1.5h; Inert atmosphere;
99%
2-(propan-2-yl)adamantan-2-ol
38432-77-8

2-(propan-2-yl)adamantan-2-ol

methyl methacrylate
97-63-2

methyl methacrylate

2-isopropyl-2-adamantyl methacrylate
297156-50-4

2-isopropyl-2-adamantyl methacrylate

Conditions
ConditionsYield
With sodium methylate In tetrahydrofuran at 77℃; for 24h;98%
C-(p-nitrophenyl)-N-phenylnitrone
69173-79-1, 94664-80-9

C-(p-nitrophenyl)-N-phenylnitrone

methyl methacrylate
97-63-2

methyl methacrylate

3-Dimethylcarbamoyl-5-methyl-2-phenyl-isoxazolidine-5-carboxylic acid ethyl ester

3-Dimethylcarbamoyl-5-methyl-2-phenyl-isoxazolidine-5-carboxylic acid ethyl ester

Conditions
ConditionsYield
for 3h;97%
methyl methacrylate
97-63-2

methyl methacrylate

4-(2-perfluorodecyl)ethylbenzylalcohol
356055-78-2

4-(2-perfluorodecyl)ethylbenzylalcohol

4-(2-perfluorodecyl)ethylbenzyl methacrylate
356055-87-3

4-(2-perfluorodecyl)ethylbenzyl methacrylate

Conditions
ConditionsYield
With sodium hydride In benzene for 1h; Heating;97%
methyl methacrylate
97-63-2

methyl methacrylate

polymer, Mn = 10600, PD = 1.12; monomer(s): ethyl methacrylate

polymer, Mn = 10600, PD = 1.12; monomer(s): ethyl methacrylate

Conditions
ConditionsYield
With ethyl 2-methyl-2-methyl tellurium propionate; dimethyl ditelluride at 105℃; for 2h;97%
methyl methacrylate
97-63-2

methyl methacrylate

2-[4-(Benzyloxycarbonyl-methyl-amino)-benzoylamino]-malonic acid diethyl ester
112495-27-9

2-[4-(Benzyloxycarbonyl-methyl-amino)-benzoylamino]-malonic acid diethyl ester

2-[4-(Benzyloxycarbonyl-methyl-amino)-benzoylamino]-2-ethoxycarbonyl-4-methyl-pentanedioic acid diethyl ester
112495-26-8

2-[4-(Benzyloxycarbonyl-methyl-amino)-benzoylamino]-2-ethoxycarbonyl-4-methyl-pentanedioic acid diethyl ester

Conditions
ConditionsYield
With sodium ethanolate In ethanol Ambient temperature;96.4%
2-aminopyridine
504-29-0

2-aminopyridine

methyl methacrylate
97-63-2

methyl methacrylate

N-(2-pyridyl)methylacrylamid, sodium salt
126660-81-9

N-(2-pyridyl)methylacrylamid, sodium salt

Conditions
ConditionsYield
With sodium In diethyl ether 1) 3h, 2) 12h, 20 deg C;96%
3-(trifluoromethyl)pyridine
3796-23-4

3-(trifluoromethyl)pyridine

methyl methacrylate
97-63-2

methyl methacrylate

C12H14F3NO2

C12H14F3NO2

Conditions
ConditionsYield
Stage #1: 3-(trifluoromethyl)pyridine With potassium phosphate; chloro(1,5-cyclooctadiene)rhodium(I) dimer; P,P'-(1,2-ethanediyl)bis{bis[3,5-di(trifluoromethyl)phenyl]phosphane} In toluene for 0.0833333h; Inert atmosphere; Microwave irradiation;
Stage #2: methyl methacrylate In toluene at 120℃; for 24h; Inert atmosphere; Microwave irradiation; Sealed tube; regioselective reaction;
96%
methyl methacrylate
97-63-2

methyl methacrylate

3-methyl-3H-imidazo[4,5-b]pyridine
6688-61-5

3-methyl-3H-imidazo[4,5-b]pyridine

ethyl 2-methyl-2-(3-methyl-3H-imidazo[4,5-b]pyridin-2-yl)propanoate

ethyl 2-methyl-2-(3-methyl-3H-imidazo[4,5-b]pyridin-2-yl)propanoate

Conditions
ConditionsYield
With potassium dihydrogenphosphate; chloro(1,5-cyclooctadiene)rhodium(I) dimer; P,P'-(1,2-ethanediyl)bis{bis[3,5-di(trifluoromethyl)phenyl]phosphane} In toluene at 120℃; for 24h; Inert atmosphere; Glovebox; Microwave irradiation; Sealed tube;96%
2-(4-phenylnaphthalen-1-yl)aniline

2-(4-phenylnaphthalen-1-yl)aniline

methyl methacrylate
97-63-2

methyl methacrylate

ethyl 2-((1-(2-aminophenyl)-4-phenylnaphthalen-2-yl)methyl)acrylate

ethyl 2-((1-(2-aminophenyl)-4-phenylnaphthalen-2-yl)methyl)acrylate

Conditions
ConditionsYield
With disodium hydrogenphosphate; (S)-STRIP; palladium diacetate; silver sulfate In toluene at 60℃; for 48h; Schlenk technique; stereoselective reaction;96%
piperidin-2-one
675-20-7

piperidin-2-one

methyl methacrylate
97-63-2

methyl methacrylate

2-Methyl-3-(2-oxo-piperidin-1-yl)-propionic acid ethyl ester

2-Methyl-3-(2-oxo-piperidin-1-yl)-propionic acid ethyl ester

Conditions
ConditionsYield
With tetraethoxy orthosilicate; cesium fluoride In neat (no solvent) at 25℃; for 0.333333h;95%
trimethyl(4-mercaptomethylphenyl)silane
57337-85-6

trimethyl(4-mercaptomethylphenyl)silane

methyl methacrylate
97-63-2

methyl methacrylate

2-methyl-3-(4-trimethylsilanyl-benzylsulfanyl)-propionic acid ethyl ester
497181-01-8

2-methyl-3-(4-trimethylsilanyl-benzylsulfanyl)-propionic acid ethyl ester

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride In tetrahydrofuran at 20℃; for 0.5h; Michael addition;95%
With tetrabutyl ammonium fluoride In tetrahydrofuran at 20℃; for 0.5h; Michael addition;95%
(S)-2-benzyloxycarbonylamino-4-hydroxyphosphinoyl-butyric acid methyl ester
864682-69-9

(S)-2-benzyloxycarbonylamino-4-hydroxyphosphinoyl-butyric acid methyl ester

methyl methacrylate
97-63-2

methyl methacrylate

ethyl (3S)-3-[((3-(N-benzyloxycarbonyl)amino-3-methoxycarbonyl)propyl(hydroxy)phosphinyl)]-2-methylpropanoate

ethyl (3S)-3-[((3-(N-benzyloxycarbonyl)amino-3-methoxycarbonyl)propyl(hydroxy)phosphinyl)]-2-methylpropanoate

Conditions
ConditionsYield
With N,O-bis-(trimethylsilyl)-acetamide In dichloromethane at 0 - 20℃; Inert atmosphere;95%
methyl methacrylate
97-63-2

methyl methacrylate

N,N-bis(2-butynyl)-(4-methylphenyl)sulfonamide
170751-34-5

N,N-bis(2-butynyl)-(4-methylphenyl)sulfonamide

C21H27NO4S
1277186-28-3

C21H27NO4S

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; (R)-segphos In dichloromethane at 20℃; for 1h; Inert atmosphere;94%
formic acid
64-18-6

formic acid

methyl methacrylate
97-63-2

methyl methacrylate

1-Ethyl 4-hydrogen 2-methylbutanedioate
32980-27-1

1-Ethyl 4-hydrogen 2-methylbutanedioate

Conditions
ConditionsYield
With palladium diacetate; acetic anhydride; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In toluene at 70℃; for 24h; Inert atmosphere; Sealed tube; regioselective reaction;94%
3-pyridinecarboxylic acid ethyl ester
614-18-6

3-pyridinecarboxylic acid ethyl ester

methyl methacrylate
97-63-2

methyl methacrylate

ethyl 6-(1-ethoxy-2-methyl-1-oxopropan-2-yl)nicotinate

ethyl 6-(1-ethoxy-2-methyl-1-oxopropan-2-yl)nicotinate

Conditions
ConditionsYield
Stage #1: 3-pyridinecarboxylic acid ethyl ester With potassium phosphate; chloro(1,5-cyclooctadiene)rhodium(I) dimer; P,P'-(1,2-ethanediyl)bis{bis[3,5-di(trifluoromethyl)phenyl]phosphane} In toluene for 0.0833333h; Inert atmosphere; Microwave irradiation;
Stage #2: methyl methacrylate In toluene at 120℃; for 24h; Inert atmosphere; Microwave irradiation; Sealed tube; regioselective reaction;
94%
diphenyl-phosphinic acid
1707-03-5

diphenyl-phosphinic acid

methyl methacrylate
97-63-2

methyl methacrylate

ethyl 2-((diphenylphosphoryl)oxy)-3-iodo-2-methylpropanoate

ethyl 2-((diphenylphosphoryl)oxy)-3-iodo-2-methylpropanoate

Conditions
ConditionsYield
With N-iodo-succinimide In tetrahydrofuran at 40℃; for 6h; Inert atmosphere; regioselective reaction;94%
methyl phosphite
96-36-6, 868-85-9

methyl phosphite

methyl methacrylate
97-63-2

methyl methacrylate

3-(Dimethoxy-phosphoryl)-2-methyl-propionic acid ethyl ester
126473-10-7

3-(Dimethoxy-phosphoryl)-2-methyl-propionic acid ethyl ester

Conditions
ConditionsYield
With trimethylaluminum In dichloromethane; toluene Ambient temperature;93%
tert-butylmercury chloride
38442-51-2

tert-butylmercury chloride

methyl methacrylate
97-63-2

methyl methacrylate

ethyl 2,4,4-trimethylpentanoate
60302-30-9

ethyl 2,4,4-trimethylpentanoate

Conditions
ConditionsYield
With triethylsilane In dimethyl sulfoxide at 35℃; for 11h; Irradiation; add of (E)-PhCH=CHI: competitive reaction;93%
With triethylsilane; sodium thiosulfate 1.) DMSO, 11 h, 2.) DMSO; Yield given. Multistep reaction;
methyl methacrylate
97-63-2

methyl methacrylate

poly(ethyl methacrylate), atom transfer radical polymerization product, Mn: 40500, PDI: 1.15; monomer(s): ethyl methacrylate

poly(ethyl methacrylate), atom transfer radical polymerization product, Mn: 40500, PDI: 1.15; monomer(s): ethyl methacrylate

Conditions
ConditionsYield
With ethyl 2-bromoisobutyrate; [(1,3,5-iPr3C6H3)Ru(μ-Cl)3RuCl(C2H4)(PCy3)] In toluene at 35℃;93%
4-methyl-benzaldehyde
104-87-0

4-methyl-benzaldehyde

methyl methacrylate
97-63-2

methyl methacrylate

3-hydroxy-2,2-dimethyl-3-p-tolyl-propionic acid ethyl ester
64284-54-4

3-hydroxy-2,2-dimethyl-3-p-tolyl-propionic acid ethyl ester

Conditions
ConditionsYield
With C38H31F3O3P2PdSSn; triethylaluminum In tetrahydrofuran; toluene at 20 - 60℃; for 3h;93%
3-(methylsulfonyl)pyridine
52693-61-5

3-(methylsulfonyl)pyridine

methyl methacrylate
97-63-2

methyl methacrylate

C12H17NO4S

C12H17NO4S

Conditions
ConditionsYield
Stage #1: 3-(methylsulfonyl)pyridine With potassium phosphate; chloro(1,5-cyclooctadiene)rhodium(I) dimer; P,P'-(1,2-ethanediyl)bis{bis[3,5-di(trifluoromethyl)phenyl]phosphane} In toluene for 0.0833333h; Inert atmosphere; Microwave irradiation;
Stage #2: methyl methacrylate In toluene at 120℃; for 24h; Inert atmosphere; Microwave irradiation; Sealed tube; regioselective reaction;
93%
2-methyladamantan-2-ol
702-98-7

2-methyladamantan-2-ol

methyl methacrylate
97-63-2

methyl methacrylate

ethyl 2-methyl-3-(2-methyladamantan-2-yl)propanoate

ethyl 2-methyl-3-(2-methyladamantan-2-yl)propanoate

Conditions
ConditionsYield
With cyclopentadienyl titanium(IV) trichloride; triethylsilyl chloride; zinc In tetrahydrofuran at 60℃; for 12h; Molecular sieve; Sealed tube; Inert atmosphere;93%

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