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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

2-Methylene-1,3-propanediol Manufacturer/High quality/Best price/In stock

Cas:3513-81-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2-Methylene-1,3-Propanediol supplier in China

Cas:3513-81-3

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Wuhan Fortuna Chemical Co.,Ltd

Factory supply 2-Methylene-1,3-propanediol CAS 3513-81-3 with fast delivery Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Foo

Factory supply 2-Methylene-1,3-propanediol CAS 3513-81-3 with fast delivery

Cas:3513-81-3

Min.Order:10 Kilogram

FOB Price: $10.0

Type:Trading Company

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2-Methylene-1,3-Propanediol

Cas:3513-81-3

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Methylene-1,3-propanediol

Cas:3513-81-3

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 3513-81-3 with best quality

Cas:3513-81-3

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Chemical Name: 2-Methylene-1,3-propanediol CAS NO: 3513-81-3 Molecular Formula: C4H8O2 Molecular Weight: 88.11 Appearance: Liquid Purity: 98%-102% Appearance: colorless liquid Storage:Preserve in well-closed, light-resistant and airtight c

2-Methylene-1,3-propanediol

Cas:3513-81-3

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

1,3-Propanediol,2-methylene- 3513-81-3

Cas:3513-81-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:3513-81-3

Cas:3513-81-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

1,3-Propanediol,2-methylene-

Cas:3513-81-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

2-Methylene-1,3-propanediol

Cas:3513-81-3

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

2-Methylene-1,3-Propanediol

Cas:3513-81-3

Min.Order:0

Negotiable

Type:Manufacturers

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

2-Methylenepropane-1,3-diol

Cas:3513-81-3

Min.Order:1 Gram

FOB Price: $35.0

Type:Trading Company

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2-Methylene-1,3-propanediol

Cas:3513-81-3

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

2-METHYLENE-1,3-PROPANEDIOL

Cas:3513-81-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2-Methylene-1,3-propanediol

Cas:3513-81-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

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SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

2-methylidenepropane-1,3-diol

Cas:3513-81-3

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

2-Methylene-1,3-propanediol

Cas:3513-81-3

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

2-Methylene-1,3-propanediol

Cas:3513-81-3

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

Product Name: 2-Methylene-1,3-propanediol Synonyms: 2-METHYLENE-1,3-PROPANEDIOL;3-HYDROXY-2-HYDROXYMETHYL-1-PROPENE;2-methylene-3-propanediol;2-methyle

3513-81-3 C4H8O2 2-Methylene-1,3-propanediol high quality with lower price

Cas:3513-81-3

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

2-Methylene-1,3-propanediol

Cas:3513-81-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

2-Methylene-1,3-propanediol

Cas:3513-81-3

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

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Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

2-Methylene-1,3-propanediol

Cas:3513-81-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

3513-81-3 CAS NO.3513-81-3

Cas:3513-81-3

Min.Order:1 Metric Ton

FOB Price: $7.0 / 8.0

Type:Trading Company

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Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

2-Methylene-1,3-propanediol

Cas:3513-81-3

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

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Shanghai Finebiotech Co.,Ltd.

Shanghai Finebiotech Co.,Ltd.was established in 2020, which providing professional chemical services. As a customer-oriented company, we have distinguished ourself from others in providing worldwide customers with cost-effective and efficient service

2-methylidenepropane-1,3-diol

Cas:3513-81-3

Min.Order:0

Negotiable

Type:Trading Company

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

2-Methylene-1,3-propanediol

Cas:3513-81-3

Min.Order:0

Negotiable

Type:Other

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Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

2-Methylenepropane-1,3-diol

Cas:3513-81-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,Pharmaceutical intermediates Transportation:air,sea,courier

2-Methylene-1,3-propanediol

Cas:3513-81-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec 2-Methylene-1,3-propanediol 25g

Cas:3513-81-3

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

1,3-diacetoxy-2-methylenepropane
3775-29-9

1,3-diacetoxy-2-methylenepropane

2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

Conditions
ConditionsYield
With pyridine; dmap In dichloromethane at 0 - 20℃; for 0.5h;98%
With potassium hydroxide In methanol at 60℃; under 750.075 Torr; Reagent/catalyst; Inert atmosphere;97.5%
With hydrogenchloride In ethanol Heating;65%
With methanol; potassium carbonate at 20℃;
2-methylene-1,3-propane-[bis-(tert-butyl)carbonate]
620161-75-3

2-methylene-1,3-propane-[bis-(tert-butyl)carbonate]

2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

Conditions
ConditionsYield
With dmap In tetrahydrofuran Heating;98%
2-(bromomethyl)-2-(hydroxymethyl)propane-1,3-diol
19184-65-7

2-(bromomethyl)-2-(hydroxymethyl)propane-1,3-diol

A

3,3-bis(hydroxymethyl)oxetane
2754-18-9

3,3-bis(hydroxymethyl)oxetane

B

2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

Conditions
ConditionsYield
With baseA 70%
B 17%
With potassium hydroxide
pentaerythrityl mononitrate
1607-00-7

pentaerythrityl mononitrate

A

3,3-bis(hydroxymethyl)oxetane
2754-18-9

3,3-bis(hydroxymethyl)oxetane

B

2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

Conditions
ConditionsYield
With potassium hydroxide In ethanol for 2h; Heating;A 69%
B 8.5%
2-chloromethyl-3-chloroprop-1-ene
1871-57-4

2-chloromethyl-3-chloroprop-1-ene

2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

Conditions
ConditionsYield
With water; calcium carbonate for 120h; Heating;65%
With calcium carbonate
With potassium hydroxide In water for 40h; Heating;
With potassium carbonate In water
2,2-di-hydroxymethylnorborn-5-ene
6707-12-6

2,2-di-hydroxymethylnorborn-5-ene

2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

Conditions
ConditionsYield
With silicon oil at 235 - 237℃; for 4h;54%
2-(bromomethyl)-2-(hydroxymethyl)propane-1,3-diol
19184-65-7

2-(bromomethyl)-2-(hydroxymethyl)propane-1,3-diol

2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

Conditions
ConditionsYield
With water; silver(l) oxide
With barium dihydroxide; water
2-hydroxymethyl-propenal
40364-84-9

2-hydroxymethyl-propenal

2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

Conditions
ConditionsYield
With sodium tetrahydroborate In tetrahydrofuran; methanol at 0℃; for 3h; Yield given;
With sodium tetrahydroborate In tetrahydrofuran; methanol Yield given;
2,2-Dimethyl-propionic acid 2-(2,2-dimethyl-propionyloxymethyl)-allyl ester
113859-64-6

2,2-Dimethyl-propionic acid 2-(2,2-dimethyl-propionyloxymethyl)-allyl ester

2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

Conditions
ConditionsYield
With sodium methylate In methanol for 20h; Ambient temperature; Yield given;
2-isopropoxy-4-methylene-[1,2]oxaborolane

2-isopropoxy-4-methylene-[1,2]oxaborolane

2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

Conditions
ConditionsYield
With sodium hydroxide; dihydrogen peroxide In water at 20℃; for 2h; Oxidation;
2-(bromomethyl)-2-(hydroxymethyl)propane-1,3-diol
19184-65-7

2-(bromomethyl)-2-(hydroxymethyl)propane-1,3-diol

water
7732-18-5

water

barium oxide

barium oxide

2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

2-(bromomethyl)-2-(hydroxymethyl)propane-1,3-diol
19184-65-7

2-(bromomethyl)-2-(hydroxymethyl)propane-1,3-diol

water
7732-18-5

water

silver oxide

silver oxide

2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

2-(bromomethyl)-2-(hydroxymethyl)propane-1,3-diol
19184-65-7

2-(bromomethyl)-2-(hydroxymethyl)propane-1,3-diol

ethanolic KOH-solution

ethanolic KOH-solution

A

3,3-bis(hydroxymethyl)oxetane
2754-18-9

3,3-bis(hydroxymethyl)oxetane

B

2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

Methyltriphenylphosphonium bromide
1779-49-3

Methyltriphenylphosphonium bromide

2,2,-dimethyl-1,3-dioxan-5-one
74181-34-3

2,2,-dimethyl-1,3-dioxan-5-one

2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

Conditions
ConditionsYield
Stage #1: Methyltriphenylphosphonium bromide; 2,2,-dimethyl-1,3-dioxan-5-one With potassium tert-butylate Inert atmosphere;
Stage #2: With toluene-4-sulfonic acid In acetone Inert atmosphere;
2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

benzyl bromide
100-39-0

benzyl bromide

2-methylenepropane-1,3-bisbenzyl ether
27441-79-8

2-methylenepropane-1,3-bisbenzyl ether

Conditions
ConditionsYield
With tetra-(n-butyl)ammonium iodide; sodium hydride In N,N-dimethyl-formamide at 40℃;100%
With sodium hydride In N,N-dimethyl-formamide at 0℃;
2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

methyl chloroformate
79-22-1

methyl chloroformate

2-{[(methoxycarbonyl)oxy]methyl}allyl methyl carbonate
130667-36-6

2-{[(methoxycarbonyl)oxy]methyl}allyl methyl carbonate

Conditions
ConditionsYield
With pyridine In dichloromethane at 0 - 20℃;100%
With pyridine; dmap In dichloromethane at 20℃; for 24h;98%
2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

tert-butylchlorodiphenylsilane
58479-61-1

tert-butylchlorodiphenylsilane

2-<(tert-butyldiphenylsilyloxy)methyl>prop-2-en-1-ol
177606-51-8

2-<(tert-butyldiphenylsilyloxy)methyl>prop-2-en-1-ol

Conditions
ConditionsYield
Stage #1: 2-(Hydroxymethyl)allyl alcohol With sodium hydride In tetrahydrofuran; mineral oil at 0℃; for 1h; Inert atmosphere;
Stage #2: tert-butylchlorodiphenylsilane In tetrahydrofuran; mineral oil at 0 - 20℃; Inert atmosphere;
Stage #3: With water In tetrahydrofuran; mineral oil at 0℃; Inert atmosphere;
100%
Stage #1: 2-(Hydroxymethyl)allyl alcohol With sodium hydride In tetrahydrofuran; mineral oil at 0℃; for 1h; Inert atmosphere;
Stage #2: tert-butylchlorodiphenylsilane In tetrahydrofuran; mineral oil at 20℃;
99%
Stage #1: 2-(Hydroxymethyl)allyl alcohol With sodium hydride In tetrahydrofuran at 20℃; for 1.16667h;
Stage #2: tert-butylchlorodiphenylsilane In tetrahydrofuran at 20℃; for 16h;
98%
2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

2-methylene-1,3-propane-[bis-(tert-butyl)carbonate]
620161-75-3

2-methylene-1,3-propane-[bis-(tert-butyl)carbonate]

Conditions
ConditionsYield
With sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate In dichloromethane; water at 15 - 30℃; for 7 - 8h;100%
tetra(n-butyl)ammonium hydrogensulfate In dichloromethane; water at 15 - 30℃; for 10.5 - 13h;100%
With dmap Heating;89%
vinyl acetate
108-05-4

vinyl acetate

2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

1,3-diacetoxy-2-methylenepropane
3775-29-9

1,3-diacetoxy-2-methylenepropane

Conditions
ConditionsYield
With Candida antarctica lipase B In dichloromethane at 20℃; for 24h; Enzymatic reaction;100%
2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

acetic anhydride
108-24-7

acetic anhydride

1,3-diacetoxy-2-methylenepropane
3775-29-9

1,3-diacetoxy-2-methylenepropane

Conditions
ConditionsYield
With pyridine; dmap In dichloromethane at 0℃; for 0.5h;98%
With pyridine; dmap In dichloromethane at 20℃; for 24h;95%
With pyridine
3,4,5,6-Tetrahydrophthalic anhydride
2426-02-0

3,4,5,6-Tetrahydrophthalic anhydride

2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

3a-hydroxymethyl-1-oxo-hexahydro-2-oxa-cyclopenta<1,4>cyclobuta<1,2>benzene-4a-carboxylic acid

3a-hydroxymethyl-1-oxo-hexahydro-2-oxa-cyclopenta<1,4>cyclobuta<1,2>benzene-4a-carboxylic acid

Conditions
ConditionsYield
In acetonitrile for 4h; Irradiation;97%
2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

2-methyl-1.3-propanediol
2163-42-0

2-methyl-1.3-propanediol

Conditions
ConditionsYield
With hydrogen at 60℃; under 15001.5 Torr;97%
2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

(2-hydroxymethyl-oxiranyl)-methanol
340184-54-5

(2-hydroxymethyl-oxiranyl)-methanol

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 20℃; for 4h;96%
2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

benzaldehyde
100-52-7

benzaldehyde

(+/-)-3-methylene-1,5-diphenylpentanediol
71370-00-8

(+/-)-3-methylene-1,5-diphenylpentanediol

Conditions
ConditionsYield
With tin(ll) chloride In various solvent(s) at 50℃; for 15h;95%
2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

N-phenylbenzohydrazonoyl chloride
15424-14-3

N-phenylbenzohydrazonoyl chloride

(3-hydroxymethyl-2,5-diphenyl-3,4-dihydro-2H-pyrazol-3-yl)methanol

(3-hydroxymethyl-2,5-diphenyl-3,4-dihydro-2H-pyrazol-3-yl)methanol

Conditions
ConditionsYield
With triethylamine In dichloromethane; water at 20℃; for 10h; Reagent/catalyst; Huisgen Cycloaddition;95%
2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

methyl chloroformate
79-22-1

methyl chloroformate

1,3-diacetoxy-2-methylenepropane
3775-29-9

1,3-diacetoxy-2-methylenepropane

Conditions
ConditionsYield
With pyridine; dmap In dichloromethane at 25℃; for 24h;94%
2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

2-(4-methoxyphenyl)-5-methylene-[1,3]dioxane
168321-65-1

2-(4-methoxyphenyl)-5-methylene-[1,3]dioxane

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene for 3h; Heating;93%
2-chloromethyl-3-chloroprop-1-ene
1871-57-4

2-chloromethyl-3-chloroprop-1-ene

2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

(+/-)-3-methylene-1,5-diphenylpentanediol
71370-00-8

(+/-)-3-methylene-1,5-diphenylpentanediol

Conditions
ConditionsYield
With tin(ll) chloride; bis(benzonitrile)palladium(II) dichloride In N,N-dimethyl-formamide for 72h; Ambient temperature;92%
2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

tert-butyldimethylsilyl chloride
18162-48-6

tert-butyldimethylsilyl chloride

2-(tert-butyl-dimethyl-silanyloxymethyl)-prop-2-en-1-ol
116700-73-3

2-(tert-butyl-dimethyl-silanyloxymethyl)-prop-2-en-1-ol

Conditions
ConditionsYield
Stage #1: 2-(Hydroxymethyl)allyl alcohol With sodium hydride In tetrahydrofuran; mineral oil at 20℃; for 0.75h; Inert atmosphere;
Stage #2: tert-butyldimethylsilyl chloride In tetrahydrofuran; mineral oil at 20℃; for 2h; Inert atmosphere;
92%
Stage #1: 2-(Hydroxymethyl)allyl alcohol With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; Inert atmosphere;
Stage #2: tert-butyldimethylsilyl chloride In tetrahydrofuran; mineral oil at 20℃; for 1h; Inert atmosphere;
92%
With sodium hydride In tetrahydrofuran91%
iodobenzene
591-50-4

iodobenzene

2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

2-benzylidene-1,3-propanediol
99186-23-9

2-benzylidene-1,3-propanediol

Conditions
ConditionsYield
With palladium diacetate; tributylphosphine; potassium carbonate In N,N-dimethyl-formamide at 80℃; for 1h;91%
2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

cyclohexanone
108-94-1

cyclohexanone

3-methylene-1,5-dioxa-spiro[5.5]undecane
3290-73-1

3-methylene-1,5-dioxa-spiro[5.5]undecane

Conditions
ConditionsYield
With toluene-4-sulfonic acid In benzene for 4h; Condensation;91%
2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

5-methylene-1,3,2-dioxathiane 2-oxide
548482-49-1

5-methylene-1,3,2-dioxathiane 2-oxide

Conditions
ConditionsYield
With thionyl chloride In tetrachloromethane at 0℃; for 0.75h;91%
With thionyl chloride In tetrachloromethane at 0℃; for 0.75h; Inert atmosphere;90.63%
With thionyl chloride In tetrachloromethane at 0℃; for 0.833333h;86%
With thionyl chloride In tetrachloromethane at 0℃; for 0.75h; Inert atmosphere;9.63%
With thionyl chloride In dichloromethane at 0℃; for 0.75h; Inert atmosphere;
2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

1-(bromomethyl)-4-(1,1-dimethylethyl)benzene
18880-00-7

1-(bromomethyl)-4-(1,1-dimethylethyl)benzene

2-(((4-(tert-butyl)benzyl)oxy)methyl)prop-2-en-1-ol
1360903-27-0

2-(((4-(tert-butyl)benzyl)oxy)methyl)prop-2-en-1-ol

Conditions
ConditionsYield
Stage #1: 2-(Hydroxymethyl)allyl alcohol With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; Inert atmosphere;
Stage #2: 1-(bromomethyl)-4-(1,1-dimethylethyl)benzene With tetra-(n-butyl)ammonium iodide In tetrahydrofuran; mineral oil at 0 - 20℃; Inert atmosphere;
91%
triisopropylsilyl chloride
13154-24-0

triisopropylsilyl chloride

2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

2-methylidene-3-(triisopropylsilyloxy)-propan-1-ol
852235-21-3

2-methylidene-3-(triisopropylsilyloxy)-propan-1-ol

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran90%
Stage #1: 2-(Hydroxymethyl)allyl alcohol With sodium hydride In tetrahydrofuran; mineral oil for 0.0833333h;
Stage #2: triisopropylsilyl chloride In tetrahydrofuran; mineral oil for 3.08333h;
Stage #3: With ammonium chloride In diethyl ether; water
2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

4-methoxy-N'-phenylbenzohydrazonoyl chloride
40277-63-2

4-methoxy-N'-phenylbenzohydrazonoyl chloride

[3-hydroxymethyl-5-(4-methoxyphenyl)-2-phenyl-3,4-dihydro-2H-pyrazol-3-yl]methanol

[3-hydroxymethyl-5-(4-methoxyphenyl)-2-phenyl-3,4-dihydro-2H-pyrazol-3-yl]methanol

Conditions
ConditionsYield
With triethylamine In dichloromethane; water at 20℃; for 11h; Reagent/catalyst; Huisgen Cycloaddition;89%
2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

ethyl 2-((N-(2,4,6-trichlorophenyl)sulfamoyl)amino)acetate
1354438-71-3

ethyl 2-((N-(2,4,6-trichlorophenyl)sulfamoyl)amino)acetate

ethyl 2-(4-methylene-1,1-dioxido-6-(2,4,6-trichlorophenyl)-1,2,6-thiadiazinan-2-yl)acetate
1354438-87-1

ethyl 2-(4-methylene-1,1-dioxido-6-(2,4,6-trichlorophenyl)-1,2,6-thiadiazinan-2-yl)acetate

Conditions
ConditionsYield
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at -20 - 20℃; for 5h; Inert atmosphere;89%
4-acetoxy azetidinone
28562-53-0

4-acetoxy azetidinone

2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

4-<(3-hydroxy-2-methylenepropyl)oxy>-2-azetidinone
109975-85-1

4-<(3-hydroxy-2-methylenepropyl)oxy>-2-azetidinone

Conditions
ConditionsYield
With zinc diacetate In benzene for 1h; Heating;86%
2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

Methyl 3-mercaptopropionate
2935-90-2

Methyl 3-mercaptopropionate

methyl 3-((3-hydroxy-2-(hydroxymethyl)propyl)thio)propanoate

methyl 3-((3-hydroxy-2-(hydroxymethyl)propyl)thio)propanoate

Conditions
ConditionsYield
With 2,2-dimethoxy-2-phenylacetophenone In acetonitrile at 20℃; for 0.5h; UV-irradiation;86%
2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

benzoyl chloride
98-88-4

benzoyl chloride

2-(hydroxymethyl)allyl benzoate

2-(hydroxymethyl)allyl benzoate

Conditions
ConditionsYield
With triethylamine In acetonitrile at 0 - 20℃; for 3h;86%
2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

dichlorodiphenoxymethane
4885-03-4

dichlorodiphenoxymethane

3,9-dimethylene-1,5,7,11-tetraoxaspiro [5.5] undecane
55849-58-6

3,9-dimethylene-1,5,7,11-tetraoxaspiro [5.5] undecane

Conditions
ConditionsYield
With pyridine In dichloromethane at 20℃; for 1h;85%
2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

acetic anhydride
108-24-7

acetic anhydride

2-(acetoxymethyl)prop-2-en-1-ol
57859-50-4

2-(acetoxymethyl)prop-2-en-1-ol

Conditions
ConditionsYield
With pyridine; dmap In dichloromethane at 20℃; for 16h;85%
With dmap; triethylamine80%
With dmap; triethylamine In dichloromethane at 0 - 20℃; for 2h; Inert atmosphere;30%
With triethylamine In dichloromethane at 0 - 20℃; for 5h;
With lanthanum(III) nitrate hexahydrate at 20℃;
2-(Hydroxymethyl)allyl alcohol
3513-81-3

2-(Hydroxymethyl)allyl alcohol

bis(trichloromethyl) carbonate
32315-10-9

bis(trichloromethyl) carbonate

2-methylidenetrimethylene carbonate
3775-32-4

2-methylidenetrimethylene carbonate

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃; for 2.5h; Inert atmosphere;85%
With pyridine In tetrahydrofuran at 20℃; for 8h;24 %Spectr.

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