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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

PHLOROBENZOPHENONE

Cas:3555-86-0

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for the fine chemicals, ph

Phlorobenzophenone

Cas:3555-86-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Methanone,phenyl(2,4,6-trihydroxyphenyl)-

Cas:3555-86-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

PHLOROBENZOPHENONE CAS:3555-86-0 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic interm

PHLOROBENZOPHENONE CAS:3555-86-0

Cas:3555-86-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Methanone,phenyl(2,4,6-trihydroxyphenyl)-

Cas:3555-86-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Methanone,phenyl(2,4,6-trihydroxyphenyl)-

Cas:3555-86-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Methanone,phenyl(2,4,6-trihydroxyphenyl)-

Cas:3555-86-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Methanone,phenyl(2,4,6-trihydroxyphenyl)-

Cas:3555-86-0

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Phlorobenzophenone

Cas:3555-86-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

Methanone,phenyl(2,4,6-trihydroxyphenyl)-

Cas:3555-86-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Methanone,phenyl(2,4,6-trihydroxyphenyl)-

Cas:3555-86-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemsigma International Co.,Ltd.

bulk productionChemsigma International Co.,Ltd. is a chemical manufacturer, specialize in custom synthesis and organic chemical manufacturing for overseas customers, in the field of API, pharmaceutical intermediates, chemical intermediates, fine chem

2,4,6-Trihydroxybenzophenone

Cas:3555-86-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

PHLOROBENZOPHENONE

Cas:3555-86-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

3555-86-0

Cas:3555-86-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

PHLOROBENZOPHENONE

Cas:3555-86-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Henan Wising Chem Co., Ltd

Henan Wising Chem specialize in sourcing the chemicals in China. We are associated with many trusted manufacturers each having different area of expertise required for meeting the needs of our local as well as overseas buyers . We have access to cu

PHLOROBENZOPHENONE

Cas:3555-86-0

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Nanjing Raymon Biotech Co., Ltd.

Methanone,phenyl(2,4,6-trihydroxyphenyl)- Storage:keep in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/pharma intermediate Transportation:By Sea,by Air,By courier like DHL or Fedx. Port:Shanghai/S

Methanone,phenyl(2,4,6-trihydroxyphenyl)-

Cas:3555-86-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Finetech Industry Limited

High Quality Best Price Storage:Store in dry, dark and ventilated place Application:Chemical Synthesis Intermediate

FT-0715806

Cas:3555-86-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hebei Ruishun Trade Co.,Ltd

Supply top quality products with a reasonable price Application:api

3555-86-0

Cas:3555-86-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

CHEMOS GmbH

phlorobenzophenone

Methanone,phenyl(2,4,6-trihydroxyphenyl)-

Cas:3555-86-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

2,4,6-trimethoxybenzophenone
3770-80-7

2,4,6-trimethoxybenzophenone

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

Conditions
ConditionsYield
With boron tribromide In dichloromethane at -78 - 20℃; for 74h; Inert atmosphere; Schlenk technique;100%
With boron tribromide In dichloromethane at -78 - 20℃; for 20h;99%
With boron tribromide In dichloromethane at -78 - 20℃;99%
3,5-dihydroxyphenol
108-73-6

3,5-dihydroxyphenol

benzoyl chloride
98-88-4

benzoyl chloride

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

Conditions
ConditionsYield
With aluminum (III) chloride In nitrobenzene at 65℃; for 3h; Inert atmosphere;72%
With aluminum (III) chloride In nitrobenzene at 65℃; Friedel-Crafts Acylation;65.8%
Stage #1: 3,5-dihydroxyphenol With aluminum (III) chloride In carbon disulfide; nitrobenzene at 55℃; for 0.5h; Friedel-Crafts Acylation;
Stage #2: benzoyl chloride In carbon disulfide; nitrobenzene for 0.5h; Friedel-Crafts Acylation; Heating;
54%
2,4,6-trimethoxybenzophenone
3770-80-7

2,4,6-trimethoxybenzophenone

A

cotoin
479-21-0

cotoin

B

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

Conditions
ConditionsYield
Stage #1: 2,4,6-trimethoxybenzophenone With boron tribromide In dichloromethane at -78 - 20℃; for 48h; Inert atmosphere;
Stage #2: With water In dichloromethane at 0 - 20℃; for 1.3h;
A 4%
B 52%
3,5-dihydroxyphenol
108-73-6

3,5-dihydroxyphenol

1,4-dibenzoyloxybenzene
14210-97-0

1,4-dibenzoyloxybenzene

A

2,5-dihydroxybenzophenone
2050-37-5

2,5-dihydroxybenzophenone

B

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In benzene for 0.5h; cross Fries reaction; microwave irradiation;A 50%
B 40%
3,5-dihydroxyphenol
108-73-6

3,5-dihydroxyphenol

benzoic acid phenyl ester
93-99-2

benzoic acid phenyl ester

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In benzene for 3h; crossover Friess rearrangement; Heating;25%
2-(α-phenylimino-benzyl)-phloroglucinol

2-(α-phenylimino-benzyl)-phloroglucinol

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

Conditions
ConditionsYield
With hydrogenchloride
3,5-dihydroxyphenol
108-73-6

3,5-dihydroxyphenol

benzonitrile
100-47-0

benzonitrile

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

Conditions
ConditionsYield
With hydrogenchloride; diethyl ether; zinc(II) chloride Erhitzen des Reaktionsprodukts mit Wasser;
With diethyl ether
With hydrogenchloride; diethyl ether; zinc(II) chloride Man verwandelt das ausgeschiedene Ketimidhydrochlorid in das Sulfat und kocht dieses mit der 20-fachen Menge Wasser; Ausbeute 65prozent der Theorie;
7-Phenyl-3,5,7-trioxoheptansaeuremethylester
15148-46-6

7-Phenyl-3,5,7-trioxoheptansaeuremethylester

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

Conditions
ConditionsYield
With sodium hydroxide at -5℃;
4-hydroxy-6-(2-oxo-2-phenylethyl)-2H-pyran-2-one
20851-38-1

4-hydroxy-6-(2-oxo-2-phenylethyl)-2H-pyran-2-one

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

Conditions
ConditionsYield
With lithium hydride
2,4,6-trihydroxy-benzophenone-imine; hydrochloride

2,4,6-trihydroxy-benzophenone-imine; hydrochloride

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

Conditions
ConditionsYield
With water for 1.5h; Heating;
1,2,3-trimethoxybenzene
621-23-8

1,2,3-trimethoxybenzene

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 96 percent / AlCl3 / CH2Cl2 / 12 h / 0 - 20 °C
2: 92 percent / boron tribromide / CH2Cl2 / -78 - 20 °C
View Scheme
Multi-step reaction with 2 steps
1: 7.5 g / AlCl3 / diethyl ether / 15 h / Ambient temperature
2: 5.1 g / HI / acetic anhydride / 4 h / 115 - 120 °C
View Scheme
Multi-step reaction with 2 steps
1.1: aluminum (III) chloride / dichloromethane / 1 h / 0 °C / Inert atmosphere
1.2: 48 h / 20 °C / Inert atmosphere
2.1: boron tribromide / dichloromethane / 48 h / -78 - 20 °C / Inert atmosphere
2.2: 1.3 h / 0 - 20 °C
View Scheme
benzoyl chloride
98-88-4

benzoyl chloride

(η-2,5-Ph2C4H2N)(Ph3P)2ReH2

(η-2,5-Ph2C4H2N)(Ph3P)2ReH2

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 96 percent / AlCl3 / CH2Cl2 / 12 h / 0 - 20 °C
2: 92 percent / boron tribromide / CH2Cl2 / -78 - 20 °C
View Scheme
3,5-dihydroxyphenol
108-73-6

3,5-dihydroxyphenol

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: ZnCl2; HCl / diethyl ether
2: H2O / 1.5 h / Heating
View Scheme
Multi-step reaction with 2 steps
1: AlCl3; diethyl ether
2: ethanolic HCl
View Scheme
benzoyl chloride
98-88-4

benzoyl chloride

O5-benzoyl-O1,O2-isopropyliden-β-D-arabinofuranose

O5-benzoyl-O1,O2-isopropyliden-β-D-arabinofuranose

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 7.5 g / AlCl3 / diethyl ether / 15 h / Ambient temperature
2: 5.1 g / HI / acetic anhydride / 4 h / 115 - 120 °C
View Scheme
N-phenyl-benzimidoyl chloride
4903-36-0

N-phenyl-benzimidoyl chloride

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: AlCl3; diethyl ether
2: ethanolic HCl
View Scheme
1-phenylhexane-1,3,5-trione
1469-95-0

1-phenylhexane-1,3,5-trione

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: (i) NaNH2, liq. NH3, Et2O, (ii) /BRN= 1900390/
2: diethyl ether
3: aq. NaOH / -5 °C
View Scheme
7-Phenyl-3,5,7-trioxo-heptansaeure
4809-02-3

7-Phenyl-3,5,7-trioxo-heptansaeure

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: diethyl ether
2: aq. NaOH / -5 °C
View Scheme
acide 2,4,6-trihydroxybenzoique
83-30-7

acide 2,4,6-trihydroxybenzoique

benzene
71-43-2

benzene

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

Conditions
ConditionsYield
With zinc(II) chloride; trichlorophosphate at 70℃; for 2.5h; Friedel-Crafts reaction;
Stage #1: acide 2,4,6-trihydroxybenzoique; benzene With zinc(II) chloride; trichlorophosphate at 70℃; for 2.5h;
Stage #2: With water at 4℃; for 24h; Cooling with ice;
benzoyl chloride
98-88-4

benzoyl chloride

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: aluminum (III) chloride / dichloromethane / 1 h / 0 °C / Inert atmosphere
1.2: 48 h / 20 °C / Inert atmosphere
2.1: boron tribromide / dichloromethane / 48 h / -78 - 20 °C / Inert atmosphere
2.2: 1.3 h / 0 - 20 °C
View Scheme
Multi-step reaction with 2 steps
1.1: aluminum (III) chloride / dichloromethane / 1 h / 0 °C
1.2: 12 h / 0 - 20 °C
2.1: boron tribromide / dichloromethane / 20 h / -78 - 20 °C
View Scheme
Multi-step reaction with 2 steps
1.1: aluminum (III) chloride / dichloromethane / 1 h / 0 °C / Inert atmosphere; Schlenk technique
1.2: 16 h / 0 - 20 °C / Inert atmosphere; Schlenk technique
2.1: boron tribromide / dichloromethane / 74 h / -78 - 20 °C / Inert atmosphere; Schlenk technique
View Scheme
Multi-step reaction with 2 steps
1.1: aluminum (III) chloride / dichloromethane / 1 h / 0 °C
1.2: 0 - 20 °C
2.1: boron tribromide / dichloromethane / -78 - 20 °C
View Scheme
<2-14C>malonyl-CoA

<2-14C>malonyl-CoA

S-benzoyl coenzyme A
6756-74-7

S-benzoyl coenzyme A

A

4-hydroxy-6-(2-oxo-2-phenylethyl)-2H-pyran-2-one
20851-38-1

4-hydroxy-6-(2-oxo-2-phenylethyl)-2H-pyran-2-one

B

4-hydroxy-6-phenyl-2H-pyran-2-one
5526-38-5

4-hydroxy-6-phenyl-2H-pyran-2-one

C

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

Conditions
ConditionsYield
With acridone synthase from Citrus Microcarpa pH=6.5 - 8.5; Enzymatic reaction;
S-benzoyl coenzyme A
6756-74-7

S-benzoyl coenzyme A

S-(hydrogen malonyl)coenzyme A
524-14-1

S-(hydrogen malonyl)coenzyme A

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

Conditions
ConditionsYield
With recombinant type III polyketide synthase from Aquilaria sinensis In aq. phosphate buffer at 37℃; for 12h; pH=7.0; Enzymatic reaction;
UDP-glucose
133-89-1

UDP-glucose

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

phlorobenzophenone 3-C-β-D-glucoside

phlorobenzophenone 3-C-β-D-glucoside

Conditions
ConditionsYield
With C-glycosyltransferase from Mangifera indica In methanol at 40℃; for 12h; pH=6.6; Enzymatic reaction;100%
With Mangifera indica C-glycosyltransferase for 12h; Enzymatic reaction; stereospecific reaction;4.5 mg
3,7-dimethyl-2,6-octadienal
141-27-5

3,7-dimethyl-2,6-octadienal

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

6-benzoyl-5-hydroxy-2,8-dimethyl-2,8-bis(4-methylpent-3-enyl)-2H,8H-benzo(1,2-b:3',4'-b')dipyran

6-benzoyl-5-hydroxy-2,8-dimethyl-2,8-bis(4-methylpent-3-enyl)-2H,8H-benzo(1,2-b:3',4'-b')dipyran

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In methanol at 20℃; for 36h;95%
3,3-dimethyl acrylaldehyde
107-86-8

3,3-dimethyl acrylaldehyde

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

6-benzoyl-5-hydroxy-2,2,8,8-tetramethyl-2H,8H-benzo(1,2-b:3',4'-b')dipyran
88662-01-5

6-benzoyl-5-hydroxy-2,2,8,8-tetramethyl-2H,8H-benzo(1,2-b:3',4'-b')dipyran

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In methanol at 20℃; for 36h;94%
2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

2-benzylidene-indan-1,3-dione
5381-33-9

2-benzylidene-indan-1,3-dione

2-((3-benzoyl-2,4,6-trihydroxy-5-((3-hydroxy-1-oxo-1H-inden-2-yl)(phenyl)methyl)phenyl)(phenyl)methyl)-3-hydroxy-1H-inden-1-one

2-((3-benzoyl-2,4,6-trihydroxy-5-((3-hydroxy-1-oxo-1H-inden-2-yl)(phenyl)methyl)phenyl)(phenyl)methyl)-3-hydroxy-1H-inden-1-one

Conditions
ConditionsYield
Stage #1: 2-benzoylphloroglucinol With sodium hydride In tetrahydrofuran for 0.166667h; Inert atmosphere;
Stage #2: 2-benzylidene-indan-1,3-dione In tetrahydrofuran for 1h;
92%
With sodium hydride In tetrahydrofuran at 20℃; Michael Addition;643 mg
2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

3-benzoyl-2,4,6-trihydroxy-benzaldehyde

3-benzoyl-2,4,6-trihydroxy-benzaldehyde

Conditions
ConditionsYield
With trichlorophosphate In ethyl acetate at 20℃; Inert atmosphere;91%
With trichlorophosphate In ethyl acetate79%
2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

2-(2-methylpropylidene)-1H-indene-1,3(2H)-dione
22123-54-2

2-(2-methylpropylidene)-1H-indene-1,3(2H)-dione

2-(1-(3-benzoyl-2,4,6-trihydroxy-5-(1-(3-hydroxy-1-oxo-1H-inden-2-yl)-2-methylpropyl)phenyl)-2-methylpropyl)-3-hydroxy-1H-inden-1-one

2-(1-(3-benzoyl-2,4,6-trihydroxy-5-(1-(3-hydroxy-1-oxo-1H-inden-2-yl)-2-methylpropyl)phenyl)-2-methylpropyl)-3-hydroxy-1H-inden-1-one

Conditions
ConditionsYield
Stage #1: 2-benzoylphloroglucinol With sodium hydride In tetrahydrofuran for 0.166667h; Inert atmosphere;
Stage #2: 2-(2-methylpropylidene)-1H-indene-1,3(2H)-dione In tetrahydrofuran for 1h;
77%
With sodium hydride In tetrahydrofuran at 20℃; Michael Addition;486 mg
2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

acetic acid
64-19-7

acetic acid

2-acetyl-4-benzoylphloroglucinol
31188-65-5

2-acetyl-4-benzoylphloroglucinol

Conditions
ConditionsYield
With boron trifluoride76%
trans-geranyl bromide
6138-90-5

trans-geranyl bromide

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

(E)-(3-(3,7-dimethylocta-2,6-dienyl)-2,4,6-trihydroxyphenyl)(phenyl)methanone
70219-87-3

(E)-(3-(3,7-dimethylocta-2,6-dienyl)-2,4,6-trihydroxyphenyl)(phenyl)methanone

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran at 20℃; for 24h;63%
2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

prenyl bromide
870-63-3

prenyl bromide

phenyl[2,4,6-trihydroxy-3-(3-methyl-2-butenyl)phenyl]methanone
93796-20-4

phenyl[2,4,6-trihydroxy-3-(3-methyl-2-butenyl)phenyl]methanone

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran at 20℃; for 24h;63%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran at 20℃; for 24h;62%
bromethyl methyl ether
13057-17-5

bromethyl methyl ether

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

(2-hydroxy-4,6-bis(methoxymethoxy)phenyl)(phenyl)methanone

(2-hydroxy-4,6-bis(methoxymethoxy)phenyl)(phenyl)methanone

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 0 - 20℃; for 12h; Inert atmosphere;60%
2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

tert-butyldimethylsilyl chloride
18162-48-6

tert-butyldimethylsilyl chloride

1-(2,4-bis((tert-butyldimethylsilyl)oxy)-6-hydroxyphenyl)-2-phen-1-one

1-(2,4-bis((tert-butyldimethylsilyl)oxy)-6-hydroxyphenyl)-2-phen-1-one

Conditions
ConditionsYield
Stage #1: 2-benzoylphloroglucinol With 1H-imidazole In acetone for 0.0833333h;
Stage #2: tert-butyldimethylsilyl chloride In acetone at 20℃; for 2h; regioselective reaction;
58%
geranyl diphosphate
763-10-0

geranyl diphosphate

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

A

(E)-(3-(3,7-dimethylocta-2,6-dienyl)-2,4,6-trihydroxyphenyl)(phenyl)methanone
70219-87-3

(E)-(3-(3,7-dimethylocta-2,6-dienyl)-2,4,6-trihydroxyphenyl)(phenyl)methanone

B

(E)-4-(3,7-dimethylocta-2,6-dienyloxy)-2,6-dihydroxybenzophenone

(E)-4-(3,7-dimethylocta-2,6-dienyloxy)-2,6-dihydroxybenzophenone

Conditions
ConditionsYield
With Aspergillus terreus aromatic prenyltransferase; calcium chloride In dimethyl sulfoxide; glycerol at 37℃; for 2h; pH=7.5; Enzymatic reaction;A 54.72%
B 0.62%
2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

chloromethyl methyl ether
107-30-2

chloromethyl methyl ether

(2-hydroxy-4,6-bis(methoxymethoxy)phenyl)(phenyl)methanone

(2-hydroxy-4,6-bis(methoxymethoxy)phenyl)(phenyl)methanone

Conditions
ConditionsYield
Stage #1: 2-benzoylphloroglucinol With potassium carbonate In acetone at 20℃; for 0.166667h; Inert atmosphere; Schlenk technique;
Stage #2: chloromethyl methyl ether In acetone at 20℃; for 1h; Inert atmosphere; Schlenk technique;
50%
2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

2-chloro-4-nitrophenyl β-D-xylopyranoside

2-chloro-4-nitrophenyl β-D-xylopyranoside

C18H18O8

C18H18O8

Conditions
ConditionsYield
With recombinant Streptomyces venezuelae ISP5230 GT1 Sv0189 glycosyltransferase; UDP In aq. phosphate buffer at 20℃; pH=7.0; Enzymatic reaction;50%
2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

isoprene
78-79-5

isoprene

A

8-Benzoyl-5,7-dihydroxy-2,2-dimethyl-3,4-dihydro-2H-1-benzopyran
63565-07-1

8-Benzoyl-5,7-dihydroxy-2,2-dimethyl-3,4-dihydro-2H-1-benzopyran

B

6-Benzoyl-5,7-dihydroxy-2,2-dimethyl-3,4-dihydro-2H-1-benzopyran
86606-14-6

6-Benzoyl-5,7-dihydroxy-2,2-dimethyl-3,4-dihydro-2H-1-benzopyran

C

6-Benzoyl-5-hydroxy-2,2,8,8-tetramethyl-3,4,9,10-tetrahydro-2H,8H-benzo<1,2-b:3,4-b'>dipyran
83611-02-3

6-Benzoyl-5-hydroxy-2,2,8,8-tetramethyl-3,4,9,10-tetrahydro-2H,8H-benzo<1,2-b:3,4-b'>dipyran

Conditions
ConditionsYield
With phosphoric acid In xylene at 30 - 35℃; for 12h;A 30%
B 48%
C 7%
2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

prenyl bromide
870-63-3

prenyl bromide

A

phenyl(2,4,6-trihydroxy-3,5-bis(3-methylbut-2-en-1-yl)-phenyl)methanone
70219-84-0

phenyl(2,4,6-trihydroxy-3,5-bis(3-methylbut-2-en-1-yl)-phenyl)methanone

B

phenyl[2,4,6-trihydroxy-3-(3-methyl-2-butenyl)phenyl]methanone
93796-20-4

phenyl[2,4,6-trihydroxy-3-(3-methyl-2-butenyl)phenyl]methanone

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran at 45℃; for 24h;A 48%
B 13%
2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

prenyl bromide
870-63-3

prenyl bromide

phenyl(2,4,6-trihydroxy-3,5-bis(3-methylbut-2-en-1-yl)-phenyl)methanone
70219-84-0

phenyl(2,4,6-trihydroxy-3,5-bis(3-methylbut-2-en-1-yl)-phenyl)methanone

Conditions
ConditionsYield
With potassium hydroxide at 0℃; for 2h;45%
With potassium hydroxide In water at 0℃; for 1.33h;34%
With potassium hydroxide In water at 0℃; for 1.33333h; Inert atmosphere;34%
C17H35S(1+)*BF4(1-)

C17H35S(1+)*BF4(1-)

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

A

2,6-dihydroxy-4-prenyloxybenzophenone
70219-83-9

2,6-dihydroxy-4-prenyloxybenzophenone

B

phenyl[2,4,6-trihydroxy-3-(3-methyl-2-butenyl)phenyl]methanone
93796-20-4

phenyl[2,4,6-trihydroxy-3-(3-methyl-2-butenyl)phenyl]methanone

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine In chloroform at 20℃; for 7h;A 10%
B 42%
geranyl bromide
6138-90-5

geranyl bromide

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

phenyl[3-(3,7-dimethyl-2,6-octadienyl)-2,4,6-trihydroxyphenyl]methanone
70219-87-3, 76015-48-0

phenyl[3-(3,7-dimethyl-2,6-octadienyl)-2,4,6-trihydroxyphenyl]methanone

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In tetrahydrofuran at 20℃; for 24h;42%
allyl iodid
556-56-9

allyl iodid

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

(3,5-diallyl-2,4,6-trihydroxyphenyl)(phenyl)methanone
1570098-55-3

(3,5-diallyl-2,4,6-trihydroxyphenyl)(phenyl)methanone

Conditions
ConditionsYield
Stage #1: 2-benzoylphloroglucinol With potassium hydroxide In water at 20℃; Inert atmosphere;
Stage #2: allyl iodid In water at 20 - 60℃; for 0.666667h; Inert atmosphere;
Stage #3: With 1.3-propanedithiol In water at 60℃; for 0.0833333h; Inert atmosphere;
36%
2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

ethyl propanoylacetate
4949-44-4

ethyl propanoylacetate

6-benzoyl-4-ethyl-5,7-dihydroxy-2H-chromen-2-one
1313524-58-1

6-benzoyl-4-ethyl-5,7-dihydroxy-2H-chromen-2-one

Conditions
ConditionsYield
With sulfuric acid; acetic acid at 20℃; for 2h; Pechmann reaction;27%
3,7-dimethyl-2,6-octadienal
141-27-5

3,7-dimethyl-2,6-octadienal

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

A

[5,7-dihydroxy-2-methyl-2-(4-methylpent-3-enyl)-2H-1-benzopyran-6-yl]phenylmethanone
933983-29-0

[5,7-dihydroxy-2-methyl-2-(4-methylpent-3-enyl)-2H-1-benzopyran-6-yl]phenylmethanone

B

[5,7-dihydroxy-2-methyl-2-(4-methylpent-3-enyl)-2H-1-benzopyran-8-yl]phenylmethanone
933997-22-9, 163634-65-9

[5,7-dihydroxy-2-methyl-2-(4-methylpent-3-enyl)-2H-1-benzopyran-8-yl]phenylmethanone

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In methanol at 0℃; for 6h;A 11%
B 26%
dimethylallyl diphosphate
358-72-5

dimethylallyl diphosphate

2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

A

C23H26O4

C23H26O4

B

phenyl[2,4,6-trihydroxy-3-(3-methyl-2-butenyl)phenyl]methanone
93796-20-4

phenyl[2,4,6-trihydroxy-3-(3-methyl-2-butenyl)phenyl]methanone

Conditions
ConditionsYield
With Aspergillus terreus aromatic prenyltransferase; calcium chloride In dimethyl sulfoxide; glycerol at 37℃; for 2h; pH=7.5; Enzymatic reaction;A 5.29%
B 22.06%
2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

allyl bromide
106-95-6

allyl bromide

(3,5-diallyl-2,4,6-trihydroxyphenyl)(phenyl)methanone
1570098-55-3

(3,5-diallyl-2,4,6-trihydroxyphenyl)(phenyl)methanone

Conditions
ConditionsYield
With potassium hydroxide In water at 0 - 20℃; for 1.33333h; Inert atmosphere;22%
2-benzoylphloroglucinol
3555-86-0

2-benzoylphloroglucinol

ethyl 3-oxo-3-phenylpropionate
94-02-0

ethyl 3-oxo-3-phenylpropionate

6-benzoyl-5,7-dihydroxy-4-phenyl-2H-chromen-2-one
213834-81-2

6-benzoyl-5,7-dihydroxy-4-phenyl-2H-chromen-2-one

Conditions
ConditionsYield
With sulfuric acid; acetic acid In nitrobenzene at 20℃; for 2h; Pechmann reaction;15%

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