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Binbo Biological Co., Ltd

1.high purity 2.consistent quality 3.competitive price 4.fast shipping Binbo Biological Products Co. Ltd., is a professional high-tech enterprise which engaged in Biological products and raw materials. Binbo is engaged in R&D with perfect eq

Natural Ethyl Ferulate

Cas:4046-02-0

Min.Order:1 Kilogram

FOB Price: $0.1 / 0.2

Type:Lab/Research institutions

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Leader Biochemical Group

PRODUCT DETAILS

China Biggest Factory manufacturer supply Ethyl Ferulate

Cas:4046-02-0

Min.Order:1 Kilogram

FOB Price: $1.0 / 2.0

Type:Lab/Research institutions

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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Ethyl 4'-hydroxy-3'-methoxycinnamate Manufacturer/High quality/Best price/In stock

Cas:4046-02-0

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Ferulic Acid Ethylester supplier in China

Cas:4046-02-0

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Wuhan Fortuna Chemical Co.,Ltd

Ethyl 4-hydroxy-3-methoxycinnamate CAS 4046-02-0 Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Food/Feed additives, Fine chem

Ethyl 4-hydroxy-3-methoxycinnamate CAS 4046-02-0

Cas:4046-02-0

Min.Order:1 Kilogram

FOB Price: $10.0

Type:Trading Company

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Ferulic Acid Ethylester

Cas:4046-02-0

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Content Natural Extract Ethyl ferulate HACCP manufacturer

Cas:4046-02-0

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Ferulic acid ethyl ester

Cas:4046-02-0

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hubei DiBo chemical co., LTD

Name:Ethyl 4'-hydroxy-3'-methoxycinnamate The alias:RARECHEM AL BI 0735 CAS NO:4046-02-0 EINECS NO:223-745-5 Molecular formula:C12H14O4 Molecular weight:222.2372 Product Quality 12 years of chemical raw materials Mature operation

Ethyl 4'-hydroxy-3'-methoxycinnamate/CAS:4046-02-0/with best price

Cas:4046-02-0

Min.Order:25 Kilogram

FOB Price: $1.0 / 2.0

Type:Other

inquiry

Henan Tianfu Chemical Co., Ltd.

6299-39-4 4-NITRO-1H-1,2,3-BENZOTRIAZOLE Now we would like to update our product list for you, kindly check the below information: 1. Catalyst series ( such as Noble Metal Catalyst, Phosphorous ligand, etc ) 2. Pharmaceutical

4046-02-0

Cas:4046-02-0

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. High quality and competitive price: 1) Standard: BP/USP/EP/ enterprise standard 2) All purity ≥99% 3) We are manufacturers and can provide high quality products at factory prices. 2. Fast and safe delivery 1) The package c

Ethyl 4-hydroxy-3-methoxycinnamate CAS:4046-02-0

Cas:4046-02-0

Min.Order:1 Kilogram

FOB Price: $5.0 / 10.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

New production CAS 4046-02-0 with best quality

Cas:4046-02-0

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: High quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Cosmetic Grade Ethyl 4'-hydroxy-3'-methoxycinnamate CAS 4046-02-0 With Fast Delivery

Cas:4046-02-0

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Chemical Name: Ethyl ferulate CAS No.:4046-02-0 Molecular Formula:C12H14O4 Molecular weight: 222.24 Appearance: White Powder Storage:Store in cool and dry place, away from sun light. Package: 25 KG/Woven Bag Or Fiber Drum Application:Pharmaceu

Ethyl ferulate

Cas:4046-02-0

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Hangzhou Sartort Biopharma Co., Ltd

Appearance:White or light yellow crystalline powder Storage:R.T Package:25kg/drum Application:Cosmetic raw materials Transportation:Express/Sea/Air Port:Any port in China

Factory Supply Ethyl ferulate Powder cas 4046-02-0

Cas:4046-02-0

Min.Order:1 Kilogram

FOB Price: $130.0 / 180.0

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Ethyl 4'-hydroxy-3'-methoxycinnamate 4046-02-0

Cas:4046-02-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present,

Ethyl 4'-hydroxy-3'-methoxycinnamate

Cas:4046-02-0

Min.Order:1 Kilogram

FOB Price: $150.0

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

Ethyl 4'-hydroxy-3'-methoxycinnamate CAS:4046-02-0 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in hi

Ethyl 4'-hydroxy-3'-methoxycinnamate CAS:4046-02-0

Cas:4046-02-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Ethyl 4'-hydroxy-3'-methoxycinnamate

Cas:4046-02-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of h

ethyl 4-hydroxy-3-methoxycinnamate CAS 4046-02-0

Cas:4046-02-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Mojin Biotechnology Co.,Ltd

Hebei Mojin Biotechnology Co., Ltd,Our business covers more than 30 countries, most of the big customers come from Europe, America and other countries in the world, we can guarantee the quality and price. In recent decades, with the efforts of all em

Ethyl Ferulic Acid CAS No. 4046-02-0

Cas:4046-02-0

Min.Order:1 Gram

FOB Price: $95.0 / 100.0

Type:Trading Company

inquiry

Guangdong Juda Chemical Industrial Co.,Limited

1) For products exported we can offer COA Certificate and official PI. 2) We are manufacturer with own lab and factory, can provide high quality products with factory price. 3) Products can be sent out in 24 hours after payment. Tracking number avai

Ferulic acid ethyl ester CAS 4046-02-0 ethyl ferulate

Cas:4046-02-0

Min.Order:100 Kilogram

Negotiable

Type:Trading Company

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Ethyl 4'-hydroxy-3'-methoxycinnamate

Cas:4046-02-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Ethyl 4-Hydroxy-3-Methoxycinnamate

Cas:4046-02-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Shanxi Ankesi Biotechnology Co., Ltd

Our Advantage 1. Rich experience We specialize in this filed for many years, our APIs exported to all over the world and and we established long friendly relations of cooperation with our clients. 2. Great quality,purity and favorable Good qual

4046-02-0 Warehouse minimum pickup price Ethyl 4'-hydroxy-3'-methoxycinnamate CAS 4046-02-0 AKS

Cas:4046-02-0

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Triumph International Development Limilted

Lorcaserin(856681-05-5)is an orally administered agent and a selective 5-HT2C receptor agonist for the treatment of obesity. It had been approved for marketing in US by FDA on 27 June in 2012. In clinical studies, lorcaserin h

ethyl 4-hydroxy-3-methoxycinnamate

Cas:4046-02-0

Min.Order:100 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Chengdu Biopurify Phytochemicals Ltd.

Chengdu Biopurify Phytochemicals Ltd. is a leading company in the research, development, manufacture and marketing of High Quality Phytochemicals and Extracts(especially Active Ingredients from Traditional Chinese Medicine,Traditional Chinese Medic

Ferulic acid ethyl ester

Cas:4046-02-0

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Miheng Trading Co., Ltd.

Ethyl 4-hydroxy-3-methoxycinnamate CAS 4046-02-0 Our advantage 1.Top quality: Using high quality material and establishing a strict quality control system,assigning specific persons in charge of each part of production,from raw material purch

Ethyl 4-hydroxy-3-methoxycinnamate CAS 4046-02-0

Cas:4046-02-0

Min.Order:1 Kilogram

FOB Price: $10.0 / 50.0

Type:Trading Company

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

ETHYL FERULATE CAS 4046-02-0

Cas:4046-02-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

Ethyl 4'-hydroxy-3'-methoxycinnamate

Cas:4046-02-0

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

(E)-3-(4-hydroxy-3-methoxyphenyl)acrylic acid
1135-24-6

(E)-3-(4-hydroxy-3-methoxyphenyl)acrylic acid

ethanol
64-17-5

ethanol

ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

Conditions
ConditionsYield
With acetyl chloride at 20℃;100%
With sulfuric acid at 88℃; under 1034.32 Torr; for 0.05h; Microwave irradiation;94%
With sulfuric acid for 4h; Reflux;94%
hydrogen ethyl malonate
1071-46-1

hydrogen ethyl malonate

vanillin
121-33-5

vanillin

ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

Conditions
ConditionsYield
Stage #1: hydrogen ethyl malonate; vanillin With piperidine; pyridine at 100℃; for 24h; Knoevenagel Condensation;
Stage #2: With hydrogenchloride In water at -10 - 0℃; for 24h;
98%
With piperidine In pyridine at 100℃; for 8h; Knoevenagel Condensation;97%
With piperidine; pyridine; aniline
With pyridine Knoevenagel Condensation; Reflux;
ethyl (E)-3-(4-acetoxy-3-methoxyphenyl)-prop-2-enoate
6635-27-4

ethyl (E)-3-(4-acetoxy-3-methoxyphenyl)-prop-2-enoate

ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

Conditions
ConditionsYield
With ammonium acetate In methanol at 20℃; for 3.5h;98%
With silica-supported phosphomolybdic acid In methanol at 20℃; for 2h;96%
3-(4-hydroxy-3-methoxyphenyl)acrylic acid
1135-24-6

3-(4-hydroxy-3-methoxyphenyl)acrylic acid

ethanol
64-17-5

ethanol

ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

Conditions
ConditionsYield
With sulfuric acid for 12h;96%
With sulfuric acid Reflux;92%
With acetyl chloride at 0 - 20℃; Inert atmosphere;86%
With sulfuric acid Fischer-Speier Esterification; Sealed tube; Heating; Microwave irradiation;
vanillin
121-33-5

vanillin

ethyl (triphenylphosphoranylidene)acetate
1099-45-2

ethyl (triphenylphosphoranylidene)acetate

ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

Conditions
ConditionsYield
In toluene for 4h; Wittig Olefination; Reflux;95%
In chloroform Reflux;85%
In chloroform for 5h; Wittig Olefination; Inert atmosphere; Reflux;85%
2-methoxy-4-propenylphenol
97-54-1

2-methoxy-4-propenylphenol

ethyl acrylate
140-88-5

ethyl acrylate

ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

Conditions
ConditionsYield
With Hoveyda-Grubbs catalyst first generation In 1,2-dichloro-ethane at 70℃; Cross Metathesis; Schlenk technique; Inert atmosphere; Glovebox;95%
ethyl (E)-3-(3-methoxy-4-(methoxymethoxy)phenyl)acrylate

ethyl (E)-3-(3-methoxy-4-(methoxymethoxy)phenyl)acrylate

ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

Conditions
ConditionsYield
bismuth(lll) trifluoromethanesulfonate In tetrahydrofuran; water at 20℃; for 0.166667h;92%
ethanol
64-17-5

ethanol

trans-4-hydroxy-3-methoxycinnamic acid chloride
138769-50-3, 108608-04-4

trans-4-hydroxy-3-methoxycinnamic acid chloride

ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

Conditions
ConditionsYield
With pyridine; potassium carbonate In dichloromethane; chloroform; toluene at 70℃; for 6h; Temperature; Reagent/catalyst;87.8%
With pyridine; potassium carbonate; triethylamine In dichloromethane; chloroform; toluene at 70℃; for 6h; Solvent; Reagent/catalyst; Concentration; Temperature; Time;87.8%
(carbethoxymethyl)triphenylphosphonium bromide
1530-45-6

(carbethoxymethyl)triphenylphosphonium bromide

vanillin
121-33-5

vanillin

ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

Conditions
ConditionsYield
With Amberlite IR-400 In N,N-dimethyl-formamide at 95℃; for 10h; Inert atmosphere;80%
vanillin
121-33-5

vanillin

ethyl (triphenylphosphoranylidene)acetate
1099-45-2

ethyl (triphenylphosphoranylidene)acetate

A

ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

cis-3-(4-Hydroxy-3-methoxyphenyl)-2-propensaeure-ethylester
4046-02-0, 28028-62-8, 74257-26-4

cis-3-(4-Hydroxy-3-methoxyphenyl)-2-propensaeure-ethylester

Conditions
ConditionsYield
In dichloromethane at 50℃; under 10000 Torr; for 12h; Product distribution; other solvent, time, pressure, other sibstituent. aldehydes;
In dichloromethane at 50℃; under 10000 Torr; for 12h; Yield given. Yields of byproduct given;
In dichloromethane at 50℃; for 12h; normal pressure; Yield given. Yields of byproduct given;
vanillin
121-33-5

vanillin

iron (II)-chloride

iron (II)-chloride

ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
2: H2SO4
View Scheme
vanillin
121-33-5

vanillin

ethyl (triphenylphosphoranylidene)acetate
1099-45-2

ethyl (triphenylphosphoranylidene)acetate

A

ethyl (2Z)-3-(4-hydroxy-3-methoxyphenyl)prop-2-enoate
74257-26-4

ethyl (2Z)-3-(4-hydroxy-3-methoxyphenyl)prop-2-enoate

B

ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

Conditions
ConditionsYield
In benzene Wittig Olefination; Reflux; Overall yield = 81 %;A n/a
B n/a
In benzene for 1h; Wittig Olefination; Inert atmosphere; Reflux; Overall yield = 96 %; Overall yield = 5.6 g;
In dichloromethane for 18h; Wittig Olefination; Inert atmosphere; Overall yield = 94 %; Overall yield = 4.13 g;A n/a
B n/a
In benzene at 80℃; for 4.5h; Wittig Olefination; Inert atmosphere; Overall yield = 99 %; Overall yield = 11.638 g;A n/a
B n/a
(carbethoxymethyl)triphenylphosphonium bromide
1530-45-6

(carbethoxymethyl)triphenylphosphonium bromide

vanillin
121-33-5

vanillin

A

ethyl (2Z)-3-(4-hydroxy-3-methoxyphenyl)prop-2-enoate
74257-26-4

ethyl (2Z)-3-(4-hydroxy-3-methoxyphenyl)prop-2-enoate

B

ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

Conditions
ConditionsYield
Stage #1: (carbethoxymethyl)triphenylphosphonium bromide With sodium hexamethyldisilazane In tetrahydrofuran at -78℃; for 1h;
Stage #2: vanillin In tetrahydrofuran at -78 - 20℃; for 50h; Overall yield = 85 %; Overall yield = 1.25 g;
A n/a
B n/a
(E)-3-(4-hydroxy-3-methoxyphenyl)acrylic acid
1135-24-6

(E)-3-(4-hydroxy-3-methoxyphenyl)acrylic acid

ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: aluminum (III) chloride; N,N-dimethyl-formamide / dichloromethane; toluene / 6 h / 70 °C
2: potassium carbonate; pyridine / dichloromethane; toluene; chloroform / 6 h / 70 °C
View Scheme
Multi-step reaction with 2 steps
1: N,N-dimethyl-formamide; thionyl chloride / dichloromethane; toluene / 6 h / 70 °C
2: potassium carbonate; triethylamine; pyridine / dichloromethane; toluene; chloroform / 6 h / 70 °C
View Scheme
With boron trifluoride methanol complex for 0.05h; Reflux;
(E)-3-(4-hydroxy-3-methoxyphenyl)acrylic acid
1135-24-6

(E)-3-(4-hydroxy-3-methoxyphenyl)acrylic acid

acetyl chloride
75-36-5

acetyl chloride

ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

Conditions
ConditionsYield
In ethanol at 20℃;
(E)-ethyl 3-(4-(((4,5-dimethoxy-2-nitrobenzyl)sulfonyl)oxy)-3-methoxyphenyl)acrylate

(E)-ethyl 3-(4-(((4,5-dimethoxy-2-nitrobenzyl)sulfonyl)oxy)-3-methoxyphenyl)acrylate

A

ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

B

4,5-dimethoxy-2-nitrosobenzaldehyde
119137-07-4

4,5-dimethoxy-2-nitrosobenzaldehyde

Conditions
ConditionsYield
In aq. phosphate buffer; acetonitrile pH=7.4; UV-irradiation;
(Z)-2-(2,4-dihydroxyphenyl)-4-(4-((E)-3-ethoxy-3-oxoprop-1-en-1-yl)-2-methoxyphenoxy)-4-oxobut-2-en-1-yl 2-hydroxybenzoate

(Z)-2-(2,4-dihydroxyphenyl)-4-(4-((E)-3-ethoxy-3-oxoprop-1-en-1-yl)-2-methoxyphenoxy)-4-oxobut-2-en-1-yl 2-hydroxybenzoate

A

7-hydroxy-4-(hydroxylmethyl)-2H-chromen-2-one
151889-83-7

7-hydroxy-4-(hydroxylmethyl)-2H-chromen-2-one

B

ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

Conditions
ConditionsYield
In water; acetonitrile for 1h; UV-irradiation;
vanillin
121-33-5

vanillin

ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: piperidine; p-toluidine / toluene / 3 h / 80 °C
2: sulfuric acid / 75 °C
View Scheme
ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

ethyl 3-(4-hydroxy-3-methoxyphenyl)propanoate
61292-90-8

ethyl 3-(4-hydroxy-3-methoxyphenyl)propanoate

Conditions
ConditionsYield
With palladium 10% on activated carbon; hydrogen In ethanol at 20℃; for 2h;100%
Hydrogenation;
With samarium diiodide; tert-butyl alcohol In hexane at 30℃; Kinetics;
ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

(E)-3-(4-hydroxy-3-methoxyphenyl)acrylic acid
1135-24-6

(E)-3-(4-hydroxy-3-methoxyphenyl)acrylic acid

Conditions
ConditionsYield
With sodium hydroxide In methanol; water for 3h; Reflux;100%
With sodium hydroxide In tetrahydrofuran; water at 20℃; for 8h;98%
With Sporotrichum thermophile type C feruloyl esterase; water Enzyme kinetics;
With recombinant Tan410 In aq. phosphate buffer at 35℃; for 0.75h; pH=7; Enzymatic reaction;
3,4-Dimethylphenol
95-65-8

3,4-Dimethylphenol

ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

4-(4-hydroxy-3-methoxyphenyl)-6,7-dimethyl-3,4-dihydrocoumarin

4-(4-hydroxy-3-methoxyphenyl)-6,7-dimethyl-3,4-dihydrocoumarin

Conditions
ConditionsYield
With trifluoroacetic acid at 20℃; for 24h;100%
ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

β-naphthol
135-19-3

β-naphthol

1,2-dihydro-1-(4-hydroxy-3-methoxyphenyl)-3H-naphtho[2,1-b]pyran-3-one

1,2-dihydro-1-(4-hydroxy-3-methoxyphenyl)-3H-naphtho[2,1-b]pyran-3-one

Conditions
ConditionsYield
With trifluoroacetic acid at 20℃; for 24h;100%
ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

tert-butylchlorodiphenylsilane
58479-61-1

tert-butylchlorodiphenylsilane

(E)-ethyl 3-(4-((tert-butyldiphenylsilyl)oxy)-3-methoxyphenyl)acrylate

(E)-ethyl 3-(4-((tert-butyldiphenylsilyl)oxy)-3-methoxyphenyl)acrylate

Conditions
ConditionsYield
With 1H-imidazole; dmap In dichloromethane at 0 - 20℃; for 2h; Inert atmosphere;100%
ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

chloromethyl methyl ether
107-30-2

chloromethyl methyl ether

ethyl (E)-3-(3-methoxy-4-(methoxymethoxy)phenyl)acrylate

ethyl (E)-3-(3-methoxy-4-(methoxymethoxy)phenyl)acrylate

Conditions
ConditionsYield
Stage #1: ethyl 4-hydroxy-3-methoxycinnamate With potassium carbonate In acetone at 20℃; for 1h;
Stage #2: chloromethyl methyl ether In acetone at 0 - 20℃; for 6h;
98%
ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

1-(2'-methoxybenzyl)-4-chloroethyl piperidine

1-(2'-methoxybenzyl)-4-chloroethyl piperidine

C27H35NO5

C27H35NO5

Conditions
ConditionsYield
With pyridine; potassium carbonate In dichloromethane; chloroform; toluene at 70℃; for 6h; Temperature; Reagent/catalyst;97.8%
ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

3,5-Dimethylphenol
108-68-9

3,5-Dimethylphenol

4-(4-hydroxy-3-methoxyphenyl)-5,7-dimethyl-3,4-dihydrocoumarin

4-(4-hydroxy-3-methoxyphenyl)-5,7-dimethyl-3,4-dihydrocoumarin

Conditions
ConditionsYield
With trifluoroacetic acid at 20℃; for 24h;97%
ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

ethylene dibromide
106-93-4

ethylene dibromide

ethyl (E)-3-(4-(2-bromoethoxy)-3-methoxyphenyl)acrylate

ethyl (E)-3-(4-(2-bromoethoxy)-3-methoxyphenyl)acrylate

Conditions
ConditionsYield
With pyridine; potassium carbonate In dichloromethane; chloroform; toluene at 70℃; for 6h; Solvent; Reagent/catalyst; Concentration; Temperature; Time;95.3%
With potassium carbonate In acetone at 65℃;68%
Stage #1: ethyl 4-hydroxy-3-methoxycinnamate With potassium carbonate In butanone at 20℃; for 1h;
Stage #2: ethylene dibromide In butanone at 80℃;
Tetraethylene glycol
112-60-7

Tetraethylene glycol

ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

(E)-3-(4-{2-[2-(2-{2-[4-((E)-2-Ethoxycarbonyl-vinyl)-2-methoxy-phenoxy]-ethoxy}-ethoxy)-ethoxy]-ethoxy}-3-methoxy-phenyl)-acrylic acid ethyl ester

(E)-3-(4-{2-[2-(2-{2-[4-((E)-2-Ethoxycarbonyl-vinyl)-2-methoxy-phenoxy]-ethoxy}-ethoxy)-ethoxy]-ethoxy}-3-methoxy-phenyl)-acrylic acid ethyl ester

Conditions
ConditionsYield
With di-isopropyl azodicarboxylate; triphenylphosphine In tetrahydrofuran at 20℃; for 0.0833333h; Mitsunobu reaction;95%
ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

11-azide-1-{(methylsulfonyl)oxy}-3,6,9-trioxaundecane
134179-43-4

11-azide-1-{(methylsulfonyl)oxy}-3,6,9-trioxaundecane

(E)-3-(4-(2-(2-(2-(2-azidoethoxy)ethoxy)ethoxy)ethoxy)-3-methoxyphenyl)acrylic acid ethyl ester
1437306-80-3

(E)-3-(4-(2-(2-(2-(2-azidoethoxy)ethoxy)ethoxy)ethoxy)-3-methoxyphenyl)acrylic acid ethyl ester

Conditions
ConditionsYield
With caesium carbonate In N,N-dimethyl-formamide at 80℃;94%
ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

tert-butyldimethylsilyl chloride
18162-48-6

tert-butyldimethylsilyl chloride

(E)-ethyl 3-(4-((tert-butyldimethylsilyl)oxy)-3-methoxyphenyl)acrylate
1485529-16-5

(E)-ethyl 3-(4-((tert-butyldimethylsilyl)oxy)-3-methoxyphenyl)acrylate

Conditions
ConditionsYield
With 1H-imidazole In N,N-dimethyl-formamide at 20℃; for 2h;90%
With 1H-imidazole In N,N-dimethyl-formamide at 20℃; for 2h; Inert atmosphere;90%
1 ,6-dibromohexane
629-03-8

1 ,6-dibromohexane

ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

(E)-ethyl 3-(4-((6-bromohexyl)oxy)-3-methoxyphenyl)acrylate

(E)-ethyl 3-(4-((6-bromohexyl)oxy)-3-methoxyphenyl)acrylate

Conditions
ConditionsYield
With potassium carbonate; sodium iodide In acetone for 8h; Reflux;90%
With potassium carbonate In acetone at 65℃;65%
ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

acetyl chloride
75-36-5

acetyl chloride

ethyl (E)-3-(4-acetoxy-3-methoxyphenyl)-prop-2-enoate
6635-27-4

ethyl (E)-3-(4-acetoxy-3-methoxyphenyl)-prop-2-enoate

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran at 20℃; for 1h; Cooling with ice;90%
ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

methyl iodide
74-88-4

methyl iodide

ethyl (E)-3,4-dimethoxycinnamate
20583-78-2, 24393-65-5

ethyl (E)-3,4-dimethoxycinnamate

Conditions
ConditionsYield
With potassium carbonate In acetone for 24h; Reflux;89%
With potassium carbonate In acetone
trans-geranyl bromide
6138-90-5

trans-geranyl bromide

ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

ethyl 3-(4'-geranyloxy-3'-methoxyphenyl)-2-propenoate

ethyl 3-(4'-geranyloxy-3'-methoxyphenyl)-2-propenoate

Conditions
ConditionsYield
With potassium carbonate In acetone for 2h; Heating;89%
diethyl phenylphosphonate
1754-49-0

diethyl phenylphosphonate

ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

(E)-ethyl 3-(4-((ethoxy(phenyl)phosphoryl)oxy)-3-methoxyphenyl)acrylate

(E)-ethyl 3-(4-((ethoxy(phenyl)phosphoryl)oxy)-3-methoxyphenyl)acrylate

Conditions
ConditionsYield
Stage #1: diethyl phenylphosphonate With pyridine; trifluoromethylsulfonic anhydride In dichloromethane at 20℃; for 0.166667h; Sealed tube;
Stage #2: ethyl 4-hydroxy-3-methoxycinnamate In dichloromethane at 20℃; for 0.5h; Sealed tube;
87%
ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

Conditions
ConditionsYield
With lithium aluminium tetrahydride; benzyl chloride In tetrahydrofuran at 0 - 20℃;85%
With lithium aluminium tetrahydride; benzyl chloride In tetrahydrofuran at 20℃;83%
With diisobutylaluminium hydride In toluene at -78 - 20℃; for 4.5h; Inert atmosphere;83%
ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

A

5-((E)-2-Ethoxycarbonyl-vinyl)-7-methoxy-benzofuran-3-carboxylic acid ethyl ester

5-((E)-2-Ethoxycarbonyl-vinyl)-7-methoxy-benzofuran-3-carboxylic acid ethyl ester

B

(2E,3E)-diethyl 2,3-bis(4-hydroxy-3-methoxybenzylidene)succinate

(2E,3E)-diethyl 2,3-bis(4-hydroxy-3-methoxybenzylidene)succinate

Conditions
ConditionsYield
With potassium hydroxide; potassium hexacyanoferrate(III) In benzene for 0.5h;A 84%
B 9%
triethyl phosphate
78-40-0

triethyl phosphate

ethyl 4-hydroxy-3-methoxycinnamate
4046-02-0

ethyl 4-hydroxy-3-methoxycinnamate

(E)-ethyl 3-(4-((diethoxyphosphoryl)oxy)-3-methoxyphenyl)acrylate

(E)-ethyl 3-(4-((diethoxyphosphoryl)oxy)-3-methoxyphenyl)acrylate

Conditions
ConditionsYield
Stage #1: triethyl phosphate With pyridine; trifluoromethylsulfonic anhydride In dichloromethane at 20℃; for 0.166667h;
Stage #2: ethyl 4-hydroxy-3-methoxycinnamate In dichloromethane at 20℃; for 0.5h;
84%

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