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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

1,1,1,3,3,3-hexafluoro-2-iodo-2-(trifluoromethyl)propane

Cas:4459-18-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1,1,1,3,3,3-hexafluoro-2-iodo-2-(trifluoromethyl)propane

Cas:4459-18-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

PERFLUORO-TERT-BUTYL IODIDE

Cas:4459-18-1

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Iodoperfluoro-tert-butane

Cas:4459-18-1

Min.Order:0

Negotiable

Type:Manufacturers

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Henan Allgreen Chemical Co.,Ltd

high qualityAppearance:white crystalline powder Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

4-(Diethylcarbamoyl)benzeneboronic acid 98%

Cas:4459-18-1

Min.Order:0

Negotiable

Type:Manufacturers

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Iodoperfluoro-tert-butane

Cas:4459-18-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

Iodoperfluoro-tert-butane 4459-18-1

Cas:4459-18-1

Min.Order:0

Negotiable

Type:Trading Company

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Shenzhen Foris Technology Co. LTD

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

Iodoperfluoro-tert-butane 4459-18-1

Cas:4459-18-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

Amadis Chemical offer CAS#4459-18-1;CAT#A826633

Cas:4459-18-1

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

Changzhou Extraordinary Pharmatech co.,LTD

Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and fa

Perfluoro-tert-butyl iodide

Cas:4459-18-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Finetech Industry Limited

FINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the Iodoperfluoro-tert-butane, CAS:4459-18-1 with the most competitive price and the best

Iodoperfluoro-tert-butane

Cas:4459-18-1

Min.Order:0

Negotiable

Type:Trading Company

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Pure Chemistry Scientific Inc.

Iodoperfluoro-tert-butane Application:2025666

Iodoperfluoro-tert-butane

Cas:4459-18-1

Min.Order:1 Gram

FOB Price: $500.0

Type:Trading Company

inquiry

PERRIGO CHEMICAL COMPANY

1,1,1,3,3,3-hexafluoro-2-iodo-2-(trifluoromethyl)propane CASNo.:4459-18-1 Storage:as prescribe by the manufaurer Package:pack as requested

1,1,1,3,3,3-hexafluoro-2-iodo-2-(trifluoromethyl)propane

Cas:4459-18-1

Min.Order:100 Kilogram

Negotiable

Type:Trading Company

inquiry

Wuhan Chemwish Technology Co., Ltd

High quality Products with prompt delivery Package:based on customer requirement Application:organic intermediates Transportation:By are or by sea Port:any port of China

Iodoperfluoro-tert-butane

Cas:4459-18-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

2-bromo-1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane
754-43-8

2-bromo-1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane

A

1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane
382-24-1

1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane

B

perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

Conditions
ConditionsYield
With sodium iodide In acetonitrile for 5h; Heating;A 75.7%
B 5.3%
2-chlorocarbonyloxy-1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane
27746-96-9

2-chlorocarbonyloxy-1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane

perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

Conditions
ConditionsYield
With potassium iodide at 150 - 180℃; for 3h;30.8%
iodotrifluoromethane
2314-97-8

iodotrifluoromethane

3,3-bis(trifluoromethyl)diazirine
3024-50-8

3,3-bis(trifluoromethyl)diazirine

perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

Conditions
ConditionsYield
at 150 - 155℃; for 10h;9.8%
perfluoroisobutylene
382-21-8

perfluoroisobutylene

perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

Conditions
ConditionsYield
With potassium fluoride; iodine; nitrobenzene
1,1,1,3,3,3-hexafluoro-2-nitroso-2-trifluoromethyl-propane
354-93-8

1,1,1,3,3,3-hexafluoro-2-nitroso-2-trifluoromethyl-propane

perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

Conditions
ConditionsYield
With iodine
perfluoropropylene
116-15-4

perfluoropropylene

iodotrifluoromethane
2314-97-8

iodotrifluoromethane

A

1,1,1,2,2,3,3-heptafluoro-3-iodo-propane
754-34-7

1,1,1,2,2,3,3-heptafluoro-3-iodo-propane

B

perfluoroisobutylene
382-21-8

perfluoroisobutylene

C

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

D

2-trifluoromethyl-perfluoropropyl iodide
1542-18-3

2-trifluoromethyl-perfluoropropyl iodide

E

perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

F

1,1,1,2-Tetrafluoro-2-iodo-butane

1,1,1,2-Tetrafluoro-2-iodo-butane

Conditions
ConditionsYield
at 360℃; Product distribution; nickel reactor; other temperatures, influence of reactor material;
perfluoropropylene
116-15-4

perfluoropropylene

iodotrifluoromethane
2314-97-8

iodotrifluoromethane

A

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

B

2-trifluoromethyl-perfluoropropyl iodide
1542-18-3

2-trifluoromethyl-perfluoropropyl iodide

C

perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

D

1,1,1,2-Tetrafluoro-2-iodo-butane

1,1,1,2-Tetrafluoro-2-iodo-butane

Conditions
ConditionsYield
at 360℃; Yield given. Further byproducts given. Yields of byproduct given;
2-bromo-1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane
754-43-8

2-bromo-1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane

A

iodotrifluoromethane
2314-97-8

iodotrifluoromethane

B

perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

Conditions
ConditionsYield
With iodine Product distribution; Irradiation; multiple-photon IR laser excitation; different laser frequency and energy fluence;
With iodine Irradiation; Yield given. Yields of byproduct given;
benzenediazonium hexafluorophosphate
369-58-4

benzenediazonium hexafluorophosphate

C8F18I(1-)*C6H18N3S(1+)

C8F18I(1-)*C6H18N3S(1+)

A

2-phenylazo-2-trifluoromethylperfluoropropane
38771-38-9

2-phenylazo-2-trifluoromethylperfluoropropane

B

perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

C

C6H18N3S(1+)*F6P(1-)

C6H18N3S(1+)*F6P(1-)

Conditions
ConditionsYield
In tetrahydrofuran at 25℃;
C8F18I(1-)*C6H18N3S(1+)

C8F18I(1-)*C6H18N3S(1+)

methyl trifluoromethanesulfonate
333-27-7

methyl trifluoromethanesulfonate

A

perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

B

1,1,1,3,3,3-hexafluoro-2-methyl-2-trifluoromethyl-propane
36553-69-2

1,1,1,3,3,3-hexafluoro-2-methyl-2-trifluoromethyl-propane

C

C6H18N3S(1+)*CF3O3S(1-)

C6H18N3S(1+)*CF3O3S(1-)

Conditions
ConditionsYield
In dichloromethane at 25℃;
1,1,1,2,3,5,5,5-Octafluoro-2,3,4,4-tetrakis-trifluoromethyl-pentane
122432-75-1

1,1,1,2,3,5,5,5-Octafluoro-2,3,4,4-tetrakis-trifluoromethyl-pentane

A

Perfluoro-2-iodo-3-methylbutane
7626-45-1

Perfluoro-2-iodo-3-methylbutane

B

perfluoroisopropyl iodide
677-69-0

perfluoroisopropyl iodide

C

perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

D

1,1,1,2,4,4,4-Heptafluoro-2-iodo-3,3-bis-trifluoromethyl-butane

1,1,1,2,4,4,4-Heptafluoro-2-iodo-3,3-bis-trifluoromethyl-butane

Conditions
ConditionsYield
With iodine at 161℃; for 48h;
With iodine at 201℃; for 48h;
With iodine at 201℃; for 48h; Rate constant; Thermodynamic data; other temp., activation energy;
perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

triethylchlorogermane
994-28-5

triethylchlorogermane

triethylfluorogermane
358-41-8

triethylfluorogermane

Conditions
ConditionsYield
With hexaethylphosphoric triamide In dichloromethane byproducts: P(NEt2)3ClI; a soln. of ClGeEt3 and t-C4F9I in CH2Cl2 is cooled to -40 to -50°C with stirring in Ar, then a soln. of P(NEt2)3 in CH2Cl2 is added, stirred for 1-1.5 h, warmed to room temp. within 2-3 h; extd. (pentane), the extract is washed, dried, distd.;87%
Cp*Rh(ethylene)2
32613-78-8

Cp*Rh(ethylene)2

perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

trimethylphosphane
594-09-2

trimethylphosphane

[(η5-pentamethylcyclopentadienyl)RhI(CH2CH2C(CF3)3)(trimethylphosphine)]
1349737-26-3

[(η5-pentamethylcyclopentadienyl)RhI(CH2CH2C(CF3)3)(trimethylphosphine)]

Conditions
ConditionsYield
In toluene byproducts: CH2CH2; High Pressure; (N2, Schlenk technique); heating mixt. of rhodium compd. and phosphine deriv. in toluene at 120°C for 24 h, cooling to room temp., addn. of perfluoroisopropyl iodide, stirring for 40 min; evapn. in vac., extn. (n-pentane), evapn., elem. anal.;80%
With CH3O(2)H In (2)H8-toluene byproducts: (CF3)2CF(2)H; High Pressure; (N2, Schlenk technique); heating toluene-d8 soln. of rhodium compd. and phosphine deriv. at 120°c for 24 h, treatment with tert-perfluorobutyl iodide and methanol-d1;
perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

C12H20I2Ir

C12H20I2Ir

triphenylphosphine
603-35-0

triphenylphosphine

[Ir(η5-Cp*)(CH2CH2-t-C4F9)I(PPh3)]

[Ir(η5-Cp*)(CH2CH2-t-C4F9)I(PPh3)]

Conditions
ConditionsYield
Stage #1: perfluoro-tert-butyl iodide; C12H20I2Ir In pentane at 20℃; for 18h; Inert atmosphere; Schlenk technique;
Stage #2: triphenylphosphine In tetrahydrofuran at 20℃; for 3h; Inert atmosphere; Schlenk technique;
77.6%
perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

C12H20I2Ir

C12H20I2Ir

[Ir(η5-Cp*)(CH2CH2-t-C4F9)(μ-I)]2

[Ir(η5-Cp*)(CH2CH2-t-C4F9)(μ-I)]2

Conditions
ConditionsYield
In pentane at 20℃; for 22h; Inert atmosphere; Schlenk technique;64.2%
perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

C12H20I2Rh

C12H20I2Rh

triphenylphosphine
603-35-0

triphenylphosphine

[Rh(η5-Cp*)(CH2CH2-t-C4F9)I(PPh3)]

[Rh(η5-Cp*)(CH2CH2-t-C4F9)I(PPh3)]

Conditions
ConditionsYield
Stage #1: C12H20I2Rh; triphenylphosphine In toluene at 120℃; for 4h; Inert atmosphere; Schlenk technique;
Stage #2: perfluoro-tert-butyl iodide In toluene at 20℃; for 1.5h; Inert atmosphere; Schlenk technique;
60.3%
[W(η-C5H5)2(η-ethylene)]

[W(η-C5H5)2(η-ethylene)]

perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

W(C5H5)2[CH2CH2C(CF3)3]I
191788-66-6

W(C5H5)2[CH2CH2C(CF3)3]I

Conditions
ConditionsYield
In tetrahydrofuran; benzene under N2; adding soln. of IC(CF3)3 in benzene to THF soln. of WCp2(C2H4), stirring for 15 min; removal of solvent in vacuo, dissolving residue in CH2Cl2, filtration, redn. of solvent vol., addn. of hexane; elem. anal.;60%
Mo(η5-cyclopentadienyl)2(η2-C2H4)

Mo(η5-cyclopentadienyl)2(η2-C2H4)

perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

Mo(C5H5)2[CH2CH2C(CF3)3]I
191788-62-2

Mo(C5H5)2[CH2CH2C(CF3)3]I

Conditions
ConditionsYield
In tetrahydrofuran; benzene under N2; adding soln. of IC(CF3)3 in benzene to THF soln. of MoCp2(C2H4), stirring for 0.5 h; removal of solvent, recrystn. from CH2Cl2/hexane; elem. anal.;54%
Cp*Rh(ethylene)2
32613-78-8

Cp*Rh(ethylene)2

perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

trimethylphosphane
594-09-2

trimethylphosphane

A

[(η5-pentamethylcyclopentadienyl)RhI2(trimethylphosphine)]

[(η5-pentamethylcyclopentadienyl)RhI2(trimethylphosphine)]

B

[(η5-pentamethylcyclopentadienyl)RhI(CH2CH2C(CF3)3)(trimethylphosphine)]
1349737-26-3

[(η5-pentamethylcyclopentadienyl)RhI(CH2CH2C(CF3)3)(trimethylphosphine)]

Conditions
ConditionsYield
In toluene byproducts: CH2CH2; (N2, Schlenk technique); addn. of tert-perfluorobutyl iodide to rhodium compd. in pentane, stirring for 20 h at room temp., evapn., dissolving in toluene, addn. of phosphine deriv., stirring for 3 h; evapn., extn. (n-pentane), evapn., chromy. (silica gel, diethyl ether/n-hexane (1:1)), evapn., elem. anal.;A n/a
B 52%
perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

N-{2-(1,3-dioxoisoindolin-2-yl)acryloyl}-(1R,2S,4S)-bornane-10,2-sultam
1332724-61-4

N-{2-(1,3-dioxoisoindolin-2-yl)acryloyl}-(1R,2S,4S)-bornane-10,2-sultam

N-{(R)-2-(1,3-dioxoisoindolin-2-yl)-3-perfluoro-tert-butylpropanoyl}-(1R,2S,4S)-bornane-10,2-sultam
1430817-55-2

N-{(R)-2-(1,3-dioxoisoindolin-2-yl)-3-perfluoro-tert-butylpropanoyl}-(1R,2S,4S)-bornane-10,2-sultam

Conditions
ConditionsYield
With tris-(trimethylsilyl)silane; sodium thiosulfate In dichloromethane; water at 20℃; UV-irradiation; Sealed tube; stereoselective reaction;51%
perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

(trimethylsilyl)diphenylphosphine
17154-34-6

(trimethylsilyl)diphenylphosphine

Ph2P(t-C4F9)
1202071-52-0

Ph2P(t-C4F9)

Conditions
ConditionsYield
In hexane at -30 - 20℃; Inert atmosphere;30%
In chloroform-d1 at 20℃; for 0.5h; Inert atmosphere;30 %Spectr.
perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

1,1,1-trifluoro-4-iodo-2,2-bis-trifluoromethyl-butane
14115-45-8

1,1,1-trifluoro-4-iodo-2,2-bis-trifluoromethyl-butane

Conditions
ConditionsYield
In diethyl ether
ethene
74-85-1

ethene

perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

1,1,1-trifluoro-4-iodo-2,2-bis-trifluoromethyl-butane
14115-45-8

1,1,1-trifluoro-4-iodo-2,2-bis-trifluoromethyl-butane

Conditions
ConditionsYield
With dicyclohexyl peroxydicarbonate
perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane
382-24-1

1,1,1,3,3,3-hexafluoro-2-trifluoromethyl-propane

Conditions
ConditionsYield
With diiron nonacarbonyl In hexane
1,4-dioxane-2,3-dione
3524-70-7

1,4-dioxane-2,3-dione

perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

3-perfluoro-tert-butyl-3-hydroxy-1,4-dioxan-2-one
129282-33-3

3-perfluoro-tert-butyl-3-hydroxy-1,4-dioxan-2-one

Conditions
ConditionsYield
With magnesium; ethylene dibromide 1.) ether, -25 deg C, 1.5 h, 2.) from -12 deg C to RT; Yield given. Multistep reaction;
perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

tris(dimethylamino)sulfonium1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)-2-propanide
100645-89-4

tris(dimethylamino)sulfonium1,1,1,3,3,3-hexafluoro-2-(trifluoromethyl)-2-propanide

C8F18I(1-)*C6H18N3S(1+)

C8F18I(1-)*C6H18N3S(1+)

Conditions
ConditionsYield
In tetrahydrofuran for 0.5h;720 mg
perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

perfluoroisobutylene
382-21-8

perfluoroisobutylene

Conditions
ConditionsYield
at 426.9 - 626.9℃;
perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

oxalic acid diethyl ester
95-92-1

oxalic acid diethyl ester

ethyl 4,4,4-trifluoro-3,3-bis(trifluoromethyl)-2-oxobutyrate
129301-53-7

ethyl 4,4,4-trifluoro-3,3-bis(trifluoromethyl)-2-oxobutyrate

Conditions
ConditionsYield
With magnesium; ethylene dibromide 1.) ether, -25 deg C, 1.5 h, 2.) from -12 deg C to RT; Yield given. Multistep reaction;
perfluoro-tert-butyl iodide
4459-18-1

perfluoro-tert-butyl iodide

acetone
67-64-1

acetone

4,4,4-trifluoro-2-methyl-3,3-bis(trifluoromethyl)-2-butanol
129282-28-6

4,4,4-trifluoro-2-methyl-3,3-bis(trifluoromethyl)-2-butanol

Conditions
ConditionsYield
With magnesium; ethylene dibromide 1.) ether, -25 deg C, 1.5 h, 2.) from -12 deg C to RT; Yield given. Multistep reaction;

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