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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

1,3,5-Benzenetrimethanol Manufacturer/High quality/Best price/In stock

Cas:4464-18-0

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Large Stock 99.0% 1,3,5-BENZENETRIMETHANOL 4464-18-0 Producer

Cas:4464-18-0

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

1,3,5-Benzenetrimethanol

Cas:4464-18-0

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1, High quality with competitive price: 1) Standard:BP/USP/EP/Enterprise standard 2) All Purity≥99% 3) We are manufacturer and can provide high quality products with factory price. 2, Fast and safe delivery 1) Parcel can be sent

1,3,5-BENZENETRIMETHANOL

Cas:4464-18-0

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 4464-18-0 with competitive price

Cas:4464-18-0

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the

1,3,5-Benzenetrimethanol/ LIDE PHARMA- Factory supply / Best price

Cas:4464-18-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

1,3,5-Benzenetrimethanol

Cas:4464-18-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

1,3,5-BENZENETRIMETHANOL

Cas:4464-18-0

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 1,3,5-BENZENETRIMETHANOL

Cas:4464-18-0

Min.Order:0 Metric Ton

Negotiable

Type:Other

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1,3,5-Benzenetrimethanol

Cas:4464-18-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

1,3,5-BENZENETRIMETHANOL;Benzene-1,3,5-triyltriMethanol; 1,3,5-Tris(hydroxymethyl)benzene CAS No.: 4464-18-0 Molecular formula: C9H12O3 Molecular weight: 168.19 Homotribenzyl alcohol Melting point 76.0 to 80.0 °C Tris-benzyl alc

1,3,5-BENZENETRIMETHANOL

Cas:4464-18-0

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

1)quick response within 12 hours; 2)quality guarantee: all products are strictly tested by our qc, confirmed by qa and approved by third party lab in china, usa, canada, germany, uk, italy, france etc. 3) oem/odm available; 4) rea

1,3,5-BENZENETRIMETHANOLCAS NO.: 4464-18-0

Cas:4464-18-0

Min.Order:1 Gram

FOB Price: $2.0

Type:Lab/Research institutions

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

1,3,5-Benzenetrimethanol

Cas:4464-18-0

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

1,3,5-tris(Hydroxymethyl)benzene

Cas:4464-18-0

Min.Order:0

Negotiable

Type:Manufacturers

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SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

SAGECHEM/1,3,5-Benzenetrimethanol

Cas:4464-18-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

1,3,5-Benzenetrimethanol

Cas:4464-18-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Greenutra Resource Inc

1,3,5-BENZENETRIMETHANOLAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air

1,3,5-BENZENETRIMETHANOL

Cas:4464-18-0

Min.Order:0

Negotiable

Type:Trading Company

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GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

[3,5-bis-(Hydroxymethyl)phenyl]methanol

Cas:4464-18-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

1,3,5-BENZENETRIMETHANOL

Cas:4464-18-0

Min.Order:0

Negotiable

Type:Other

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Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

1,3,5-BenzenetriMethanol

Cas:4464-18-0

Min.Order:0

Negotiable

Type:Manufacturers

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Shanghai Finebiotech Co.,Ltd.

Shanghai Finebiotech Co.,Ltd.was established in 2020, which providing professional chemical services. As a customer-oriented company, we have distinguished ourself from others in providing worldwide customers with cost-effective and efficient service

1,3,5-Benzenetrimethanol

Cas:4464-18-0

Min.Order:0

Negotiable

Type:Trading Company

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Antimex Chemical Limied

1,3,5-BenzenetrimethanolAppearance:detailed see specifications Storage:Keep away of light, cool place Package:25kg/drum;200kg/drum Application:It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals

1,3,5-Benzenetrimethanol

Cas:4464-18-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou Ocean Chemical Co., Ltd.

★.Best quality according to requirement ★.Competitive price in China market ★.Mature Technical support ★.Professional logistic support

1,3,5-BENZENETRIMETHANOL

Cas:4464-18-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Guangdong Juda Chemical Industrial Co.,Limited

Appearance:solid or liquid Storage:sealed in cool and dry place Package:As customer's requested Application:Pharma Intermediate Transportation:by courier/air/sea Port:Any port in China

1,3,5-BENZENETRIMETHANOL CAS No.4464-18-0

Cas:4464-18-0

Min.Order:0

Negotiable

Type:Trading Company

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HANGZHOU TIANYE CHEMICALS CO., LTD.

"HANGZHOU TIANYE CHEMICALS Co.LTD , Located in Eastern Science and Innovation Park Hangzhou .We are a high-tech enterprise specialized in technical research and development, production, development and trade of chemical products. We supply Multiple s

1,3,5-Benzenetrimethanol

Cas:4464-18-0

Min.Order:0

Negotiable

Type:Trading Company

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BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:crystalline powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as pri

1,3,5-Benzenetrimethanol

Cas:4464-18-0

Min.Order:0

Negotiable

Type:Trading Company

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Hangzhou Fandachem Co.,Ltd

1,3,5-Benzenetrimethanol cas 4464-18-0Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

1,3,5-Benzenetrimethanol cas 4464-18-0

Cas:4464-18-0

Min.Order:0

Negotiable

Type:Other

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Hangzhou Sartort Biopharma Co., Ltd

Best quality with low price Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai

1,3,5-Benzenetrimethanol

Cas:4464-18-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemlyte Solutions

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

1,3,5-BENZENETRIMETHANOL

Cas:4464-18-0

Min.Order:0

Negotiable

Type:Other

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

1,3,5-tris(Hydroxymethyl)benzene 4464-18-0

Cas:4464-18-0

Min.Order:0

Negotiable

Type:Trading Company

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Synthetic route

1,3,5-tris-(methoxycarbonyl)benzene
2672-58-4

1,3,5-tris-(methoxycarbonyl)benzene

1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran for 1.5h; Ambient temperature;100%
With lithium aluminium tetrahydride In tetrahydrofuran100%
In tetrahydrofuran; methanol100%
trimethyl 1,3,5-benzenetricarboxylate

trimethyl 1,3,5-benzenetricarboxylate

1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

Conditions
ConditionsYield
With dimethylsulfide borane complex In tetrahydrofuran for 3h; Heating;100%
benzene-1,3,5-tricarboxylic acid
554-95-0

benzene-1,3,5-tricarboxylic acid

1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

Conditions
ConditionsYield
Stage #1: benzene-1,3,5-tricarboxylic acid With methanol; sulfuric acid Inert atmosphere; Schlenk technique;
Stage #2: With lithium aluminium tetrahydride In tetrahydrofuran Inert atmosphere; Schlenk technique;
98%
With lithium aluminium tetrahydride In tetrahydrofuran at 20℃;91%
With lithium aluminium tetrahydride In tetrahydrofuran
trimethyl 1,3,5-benzenetricarboxylate

trimethyl 1,3,5-benzenetricarboxylate

1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

Conditions
ConditionsYield
Stage #1: trimethyl 1,3,5-benzenetricarboxylate With lithium aluminium tetrahydride In tetrahydrofuran at 0℃; Inert atmosphere;
Stage #2: for 24h; Reflux;
95%
triethyl benzene-1,3,5-tricarboxylate
4105-92-4

triethyl benzene-1,3,5-tricarboxylate

1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran Reflux;94%
With lithium aluminium tetrahydride In tetrahydrofuran at 0 - 50℃; for 8h; Inert atmosphere;73%
With lithium borohydride In tetrahydrofuran60%
1,3,5-tris-(methoxycarbonyl)benzene
2672-58-4

1,3,5-tris-(methoxycarbonyl)benzene

A

1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

B

3,5-bis(hydroxylmethyl)benzoic acid methyl ester
193953-02-5

3,5-bis(hydroxylmethyl)benzoic acid methyl ester

C

dimethyl 5-hydroxymethylbenzene-1,3-dicarboxylate
109862-53-5

dimethyl 5-hydroxymethylbenzene-1,3-dicarboxylate

Conditions
ConditionsYield
With lithium borohydride In tetrahydrofuran for 0.5h; Inert atmosphere; Reflux;A n/a
B n/a
C 60%
1,3,5-tris(aminomethyl)benzene
77372-56-6

1,3,5-tris(aminomethyl)benzene

1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

Conditions
ConditionsYield
With water; sodium hydroxide In methanol at 240℃; for 2h; Inert atmosphere; Autoclave;43%
propargyl alcohol
107-19-7

propargyl alcohol

A

1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

B

[2,4-bis(hydroxymethyl)-phenyl]methanol
25147-76-6

[2,4-bis(hydroxymethyl)-phenyl]methanol

Conditions
ConditionsYield
[tricarbonyl(triphenylphosphine)nickel] In benzene at 80℃; for 14h; Product distribution; other catalysts, solvents, times, temperatures;
With dicarbonylcyclopentadienylcobalt; supercritical CO2 at 90℃; under 135011 Torr; for 24h; Irradiation;
di-tert-butylphosphanylethylcyclopentadienylcobalt(I) In ethanol at 25℃; for 8h; Title compound not separated from byproducts;
With BF4(1-)*C18H27ClRu(1+); N-benzyl-N,N,N-triethylammonium chloride; 2,2-dimethyl-5,5-di(prop-2-ynyl)-1,3-dioxane-4,6-dione In dichloromethane at 20℃;
With molybdenum hexacarbonyl In toluene at 20℃; for 2h; Inert atmosphere; Irradiation; stereoselective reaction;
propargyl alcohol
107-19-7

propargyl alcohol

A

1,3,5,7,Tetrakis(hydroxymethyl)-cycloocta(1,3,5,7)-tetraen
52776-08-6

1,3,5,7,Tetrakis(hydroxymethyl)-cycloocta(1,3,5,7)-tetraen

B

1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

C

1,3,6,8-Tetrakis(hydroxymethyl)-cycloocta(1,3,5,7)-tetraen
110254-62-1

1,3,6,8-Tetrakis(hydroxymethyl)-cycloocta(1,3,5,7)-tetraen

Conditions
ConditionsYield
silica gel; nickel at 110℃; for 2h; Product distribution; other Ni-catalysts;
silica gel; nickel at 110℃; for 2h; Yield given;
benzene-1,3,5-trialdehyde
3163-76-6

benzene-1,3,5-trialdehyde

1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

Conditions
ConditionsYield
With sodium tetrahydroborate
propargyl alcohol
107-19-7

propargyl alcohol

benzene
71-43-2

benzene

triphenyl phosphine nickel carbonyl

triphenyl phosphine nickel carbonyl

A

1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

B

[2,4-bis(hydroxymethyl)-phenyl]methanol
25147-76-6

[2,4-bis(hydroxymethyl)-phenyl]methanol

Conditions
ConditionsYield
Verlauf der Reaktion bei Anwendung anderer Loesungsmittel oder ohne Loesungsmittel;
ω.ω'.ω''-tribromo-mesitylene

ω.ω'.ω''-tribromo-mesitylene

1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

Conditions
ConditionsYield
With lead(II) carbonate; water
propargyl alcohol
107-19-7

propargyl alcohol

dicarbonyl-bis-triphenyl phosphine nickel

dicarbonyl-bis-triphenyl phosphine nickel

A

1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

B

[2,4-bis(hydroxymethyl)-phenyl]methanol
25147-76-6

[2,4-bis(hydroxymethyl)-phenyl]methanol

Conditions
ConditionsYield
With benzene
propargyl alcohol
107-19-7

propargyl alcohol

1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

Conditions
ConditionsYield
mesoporous graphitic C3N4 In xylene at 120℃; for 24h;
C39H45N3O15

C39H45N3O15

A

1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

B

1-(4,5-dimethoxy-2-nitrosophenyl)ethan-1-one

1-(4,5-dimethoxy-2-nitrosophenyl)ethan-1-one

Conditions
ConditionsYield
In chloroform at 20℃; Product distribution; Further Variations:; Solvents; UV irradiation;
C183H165N3O33

C183H165N3O33

A

C58H51NO10

C58H51NO10

B

1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

Conditions
ConditionsYield
In chloroform Product distribution; Further Variations:; Solvents; UV irradiation;
C60H60N6O27

C60H60N6O27

A

1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

B

(4,5-Dimethoxy-2-nitro-phenyl)-(4,5-dimethoxy-2-nitroso-phenyl)-methanone
30007-81-9

(4,5-Dimethoxy-2-nitro-phenyl)-(4,5-dimethoxy-2-nitroso-phenyl)-methanone

Conditions
ConditionsYield
In chloroform Product distribution; Further Variations:; Solvents; UV irradiation;
1,3,5-benzene tris(carbonyl chloride)
4422-95-1

1,3,5-benzene tris(carbonyl chloride)

1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 93 percent / trimethylamine / CHCl3 / Heating
2: LiAlH4 / diethyl ether / 1 h / Heating
View Scheme
propargyl alcohol
107-19-7

propargyl alcohol

A

1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

B

[2,4-bis(hydroxymethyl)-phenyl]methanol
25147-76-6

[2,4-bis(hydroxymethyl)-phenyl]methanol

C

C9H14O3

C9H14O3

Conditions
ConditionsYield
With pentacarbonyl(tetrahydrofuran)molybdenum(0) In dichloromethane at 20℃; for 1h; Inert atmosphere; stereoselective reaction;
1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

benzene-1,3,5-trialdehyde
3163-76-6

benzene-1,3,5-trialdehyde

Conditions
ConditionsYield
With 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione In tert-butyl alcohol for 5h; Reflux;100%
With pyridinium chlorochromate99%
With Dess-Martin periodane In dichloromethane for 15h;98%
glutaric anhydride,
108-55-4

glutaric anhydride,

1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

C24H30O12

C24H30O12

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃; Inert atmosphere;100%
1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

methyl iodide
74-88-4

methyl iodide

1,3,5-tris(methoxymethyl)benzene
84941-01-5

1,3,5-tris(methoxymethyl)benzene

Conditions
ConditionsYield
Stage #1: 1,3,5-tris(hydroxymethyl)benzene With sodium hydride In tetrahydrofuran for 2h; Heating;
Stage #2: methyl iodide In tetrahydrofuran for 1.4h;
99%
2-(2-methacryloyloxyethyloxy)ethyl isocyanate
107023-60-9

2-(2-methacryloyloxyethyloxy)ethyl isocyanate

1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

C36H51N3O15

C36H51N3O15

Conditions
ConditionsYield
With dibutyltin(II) dilaurate In N,N-dimethyl-formamide at 20℃; for 3h;99%
1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

1,3,5-Tris(bromomethyl)benzene
18226-42-1

1,3,5-Tris(bromomethyl)benzene

Conditions
ConditionsYield
With hydrogen bromide In acetic acid at 20℃; for 46h;98%
With hydrogen bromide In water; toluene at 110℃; for 24h;98%
With hydrogen bromide In acetic acid Bromination;97%
1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

ethyl 1-(iodomethyl)-2-oxocyclopentane-1-carboxylate
2900-10-9

ethyl 1-(iodomethyl)-2-oxocyclopentane-1-carboxylate

C36H48O12
1246655-05-9

C36H48O12

Conditions
ConditionsYield
With potassium carbonate at 70℃; for 72h; Grob/Eschenmoser fragmentation reaction; Inert atmosphere;98%
1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

(S)-(N-Boc-pyrrolidin-2-yl)methyl 1-(iodomethyl)-2-oxocyclohexanecarboxylate
1452877-40-5

(S)-(N-Boc-pyrrolidin-2-yl)methyl 1-(iodomethyl)-2-oxocyclohexanecarboxylate

C63H93N3O18
1452877-43-8

C63H93N3O18

Conditions
ConditionsYield
With potassium carbonate at 70℃; for 72h; Grob-Eschenmoser Fragmentation; Inert atmosphere;97%
1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

1,3-bis-(tert-butyl-dimethyl-silanyloxymethyl)-5-prop-1-ynyl-benzene

1,3-bis-(tert-butyl-dimethyl-silanyloxymethyl)-5-prop-1-ynyl-benzene

C78H132O9Si6

C78H132O9Si6

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); benzoic acid In 1,4-dioxane at 100℃;96%
1-Phenylprop-1-yne
673-32-5

1-Phenylprop-1-yne

1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

1,3,5-Tris-((E)-3-phenyl-allyloxymethyl)-benzene

1,3,5-Tris-((E)-3-phenyl-allyloxymethyl)-benzene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); benzoic acid In 1,4-dioxane at 100℃; for 96h;95%
1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

ethyl 1-(iodomethyl)-2-oxocyclohexanecarboxylate
2900-11-0

ethyl 1-(iodomethyl)-2-oxocyclohexanecarboxylate

C39H54O12
1246655-02-6

C39H54O12

Conditions
ConditionsYield
With potassium carbonate at 70℃; for 72h; Grob/Eschenmoser fragmentation reaction; Inert atmosphere;93%
1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

1,3,5-tris(azidomethyl)benzene
107864-71-1

1,3,5-tris(azidomethyl)benzene

Conditions
ConditionsYield
Stage #1: 1,3,5-tris(hydroxymethyl)benzene With phosphorus tribromide In diethyl ether at 20℃;
Stage #2: With sodium azide In N,N-dimethyl-formamide at 80℃;
92%
Multi-step reaction with 2 steps
1: phosphorus tribromide / dichloromethane
2: sodium azide / N,N-dimethyl-formamide / 80 °C
View Scheme
Multi-step reaction with 2 steps
1: phosphorus tribromide / diethyl ether / 16 h
2: sodium azide / N,N-dimethyl-formamide / 3 h / 80 °C
View Scheme
1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

ethyl 2-(iodomethyl)-1-oxo-2,3-dihydro-1H-indene-2-carboxylate
1246655-01-5

ethyl 2-(iodomethyl)-1-oxo-2,3-dihydro-1H-indene-2-carboxylate

C48H48O12
1246655-07-1

C48H48O12

Conditions
ConditionsYield
With potassium carbonate at 70℃; for 72h; Grob/Eschenmoser fragmentation reaction; Inert atmosphere;91%
1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

methyl 1-(iodomethyl)-2-oxocycloheptanecarboxylate

methyl 1-(iodomethyl)-2-oxocycloheptanecarboxylate

C39H54O12
1246655-06-0

C39H54O12

Conditions
ConditionsYield
With potassium carbonate at 70℃; for 72h; Grob/Eschenmoser fragmentation reaction; Inert atmosphere;91%
1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

isonicotinoyl chloride hydrochloride
39178-35-3

isonicotinoyl chloride hydrochloride

1,3,5-tris(isonicotinoyloxy-methyl)benzene

1,3,5-tris(isonicotinoyloxy-methyl)benzene

Conditions
ConditionsYield
With pyridine; triethylamine In chloroform at 60℃; for 12h; Reflux;91%
1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

allyl 1-(iodomethyl)-2-oxocyclohexanecarboxylate
1452877-32-5

allyl 1-(iodomethyl)-2-oxocyclohexanecarboxylate

C42H54O12
1452877-34-7

C42H54O12

Conditions
ConditionsYield
With potassium carbonate at 70℃; for 72h; Grob-Eschenmoser Fragmentation; Inert atmosphere;89%
1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

chromium(0) hexacarbonyl
199620-14-9, 13007-92-6

chromium(0) hexacarbonyl

[Cr(η6-C6H3(CH2OH)3-1,3,5)(CO)3]
293758-56-2

[Cr(η6-C6H3(CH2OH)3-1,3,5)(CO)3]

Conditions
ConditionsYield
In tetrahydrofuran; dibutyl ether the mixt. of Cr(CO)6 and the alcohol in dibutyl ether and THF was heated under reflux with stirring at between 180 and 240°C for 20-48 hunder N2; filtered, washed with THF, concd., filtered, dried in vac., dissolved in THF, filtered, concd. in vac. (N2 atm.); elem. anal.;87%
1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

ethyl 5-(tert-butyldimethylsilyloxy)-1-(iodomethyl)-2-oxocyclohexanecarboxylate
1246655-00-4

ethyl 5-(tert-butyldimethylsilyloxy)-1-(iodomethyl)-2-oxocyclohexanecarboxylate

C57H96O15Si3
1246655-04-8

C57H96O15Si3

Conditions
ConditionsYield
With potassium carbonate at 70℃; for 72h; Grob/Eschenmoser fragmentation reaction; Inert atmosphere;87%
1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

[(2-t-butyl-4-methyl-6-(((2-(dimethylamino)cyclohexyl)amino)methyl)phenolate)InCl]2(μ-Cl)(μ-Et)

[(2-t-butyl-4-methyl-6-(((2-(dimethylamino)cyclohexyl)amino)methyl)phenolate)InCl]2(μ-Cl)(μ-Et)

[(2-t-butyl-4-methyl-6-(((2-(dimethylamino)cyclohexyl)amino)methyl)phenolate)InCl]2(μ-Cl)(μ-(3,5-bis(hydroxymethyl)phenyl)methoxide)

[(2-t-butyl-4-methyl-6-(((2-(dimethylamino)cyclohexyl)amino)methyl)phenolate)InCl]2(μ-Cl)(μ-(3,5-bis(hydroxymethyl)phenyl)methoxide)

Conditions
ConditionsYield
In toluene at 70℃; for 16h; Temperature; Schlenk technique; Glovebox;81%
Succinimide
123-56-8

Succinimide

1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

1,3,5-tris-(N-succinimidomethyl) benzene

1,3,5-tris-(N-succinimidomethyl) benzene

Conditions
ConditionsYield
Stage #1: 1,3,5-tris(hydroxymethyl)benzene With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran at -78℃; for 0.166667h; Mitsunobu reaction;
Stage #2: Succinimide In tetrahydrofuran at 20℃; for 12h;
77%
3-pyridinylacetonitrile
6443-85-2

3-pyridinylacetonitrile

1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

3,3',3''-benzene-1,3,5-trityltris(2-pyridin-3-yl)propanenitrile

3,3',3''-benzene-1,3,5-trityltris(2-pyridin-3-yl)propanenitrile

Conditions
ConditionsYield
With potassium hydroxide; [IrCP*Cl2]2 at 110℃; for 0.166667h; microwave irradiation;72%
3,6-epoxy-1,2,3,6-tetrahydrophthalimide
6253-28-7, 19878-26-3, 42074-03-3

3,6-epoxy-1,2,3,6-tetrahydrophthalimide

1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

1,3,5-tris-(2-methylamino-3α,4,7,7α-tetrahydro-4,7-epoxy-1H-indole-1,3(2H-dione)) benzene

1,3,5-tris-(2-methylamino-3α,4,7,7α-tetrahydro-4,7-epoxy-1H-indole-1,3(2H-dione)) benzene

Conditions
ConditionsYield
Stage #1: 1,3,5-tris(hydroxymethyl)benzene With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran at -78℃; for 0.166667h; Mitsunobu reaction;
Stage #2: 3,6-epoxy-1,2,3,6-tetrahydrophthalimide In tetrahydrofuran at 20℃; for 12h;
70%
1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

allyl bromide
106-95-6

allyl bromide

1,3,5-tris((allyloxy)methyl)benzene
1158483-15-8

1,3,5-tris((allyloxy)methyl)benzene

Conditions
ConditionsYield
Stage #1: 1,3,5-tris(hydroxymethyl)benzene With sodium hydride In tetrahydrofuran; mineral oil for 2h; Reflux;
Stage #2: allyl bromide In tetrahydrofuran at 50℃; for 17h;
69%
1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

tert-butyldimethylsilyl chloride
18162-48-6

tert-butyldimethylsilyl chloride

1,3,5-tris(((tert-butyldimethylsilyl)oxy)methyl)benzene
883893-69-4

1,3,5-tris(((tert-butyldimethylsilyl)oxy)methyl)benzene

Conditions
ConditionsYield
With 1H-imidazole In N,N-dimethyl-formamide at 0 - 20℃;68%
N-tert-butoxycarbonyl-L-leucine
13139-15-6

N-tert-butoxycarbonyl-L-leucine

1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

(S)-2-tert-Butoxycarbonylamino-4-methyl-pentanoic acid 3,5-bis-((S)-2-tert-butoxycarbonylamino-4-methyl-pentanoyloxymethyl)-benzyl ester
142811-52-7

(S)-2-tert-Butoxycarbonylamino-4-methyl-pentanoic acid 3,5-bis-((S)-2-tert-butoxycarbonylamino-4-methyl-pentanoyloxymethyl)-benzyl ester

Conditions
ConditionsYield
With dmap; dicyclohexyl-carbodiimide In tetrahydrofuran at 0 - 4℃; for 34h;67%
2-(2-bromoethoxy)tetrahydropyran
17739-45-6, 59146-56-4

2-(2-bromoethoxy)tetrahydropyran

1,3,5-tris(hydroxymethyl)benzene
4464-18-0

1,3,5-tris(hydroxymethyl)benzene

1,3,5-tris(4'-hydroxy-2'-oxa-1'-butyl)benzene tri(2'-tetrahydropyranyl) ether
152065-57-1

1,3,5-tris(4'-hydroxy-2'-oxa-1'-butyl)benzene tri(2'-tetrahydropyranyl) ether

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran for 144h; Heating;63%
In tetrahydrofuran for 168h; Heating;60%

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