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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde Manufacturer/High quality/Best price/In stock

Cas:472-66-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2,6,6-Trimethyl-1-Cyclohexene-1-Acetaldehyde supplier in China

Cas:472-66-2

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm

2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde Manufacturer/High quality/Best price/In stock CAS NO.472-66-2

Cas:472-66-2

Min.Order:1 Metric Ton

FOB Price: $1.0 / 3.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE Basic information Product Name: 2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE Synonyms: (2,6,6-Trimethyl-1-cyclohexen-1-

2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE

Cas:472-66-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

2,6,6-trimethyl-1-Cyclohexene-1-acetaldehyde CAS 472-66-2

Cas:472-66-2

Min.Order:1 Kilogram

FOB Price: $3.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 472-66-2 with best quality

Cas:472-66-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde 472-66-2

Cas:472-66-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

Product Name: 2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE CAS: 472-66-2 MF: C11H18O MW: 166.26 EINECS: 207-454-0 Mol File: 472-66-2.mol 2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE Structure 2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETAL

2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE

Cas:472-66-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE CAS:472-66-2 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in hig

2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE CAS:472-66-2

Cas:472-66-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde

Cas:472-66-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Shanxi Ankesi Biotechnology Co., Ltd

Our Advantage 1. Rich experience We specialize in this filed for many years, our APIs exported to all over the world and and we established long friendly relations of cooperation with our clients. 2. Great quality,purity and favorable Good qual

2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE CAS 472-66-2 AKS

Cas:472-66-2

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Business Custom Synthesis: Trading(Raw Mater

2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde

Cas:472-66-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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JINING XINHE CHEMICAL CO., LTD

Advantage 1: The product passed the professional production process and quality inspection, the purity is 99% +. 2: Highly qualified engineers to provide technical documents and service. 3: We could provide sample for your test. 4: High qualit

β- Cyclic high citral472-66-2

Cas:472-66-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 2,6,6-Trimethyl-1-Cyclohexene-1-Acetaldehyde

Cas:472-66-2

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde Manufacturer/High quality/Best price/In stock CAS NO.472-66-2

Cas:472-66-2

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

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Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

High Purity 2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde

Cas:472-66-2

Min.Order:0

Negotiable

Type:Trading Company

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EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde Manufacturer/High quality/Best price/In stock CAS NO.472-66-2

Cas:472-66-2

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde

Cas:472-66-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde

Cas:472-66-2

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

beta-Homocyclocitral

Cas:472-66-2

Min.Order:0

Negotiable

Type:Manufacturers

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Golden Pharma Co., Limited

GOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation

2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde

Cas:472-66-2

Min.Order:1 Kilogram

Negotiable

Type:Other

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Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

Hebei Mojin Biotechnology Co.,Ltd

1, High quality with competitive price:2, Fast and safe delivery3.Excellent pre-sales and after-sales service4. Well-trained and professional technologist and sales with rich experience in the field for 5-10 yearsAppearance:see detailed specification

1-Cyclohexene-1-acetaldehyde,2,6,6-trimethyl-

Cas:472-66-2

Min.Order:0

Negotiable

Type:Trading Company

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GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

beta-Homocyclocitral

Cas:472-66-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

2,6,6-trimethyl-1-cyclohexene-1-acetaldehyde

Cas:472-66-2

Min.Order:0

Negotiable

Type:Other

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Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

1-Cyclohexene-1-acetaldehyde,2,6,6-trimethyl-

Cas:472-66-2

Min.Order:0

Negotiable

Type:Manufacturers

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM is one of China's leading providers of integrated fine chemical services including offering, research and development, Custom manufacturing business, as well as other Value-added customer services, for diversified range products of chemicals

2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde

Cas:472-66-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

2-((E)-2-Methoxy-vinyl)-1,3,3-trimethyl-cyclohexene
86558-54-5, 86558-55-6

2-((E)-2-Methoxy-vinyl)-1,3,3-trimethyl-cyclohexene

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

Conditions
ConditionsYield
With perchloric acid In tetrahydrofuran for 0.5h; Ambient temperature;94%
2,2,6-trimethylcyclohexan-1-one
2408-37-9

2,2,6-trimethylcyclohexan-1-one

Bromoacetaldehyde diethyl acetal
2032-35-1

Bromoacetaldehyde diethyl acetal

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

Conditions
ConditionsYield
Stage #1: Bromoacetaldehyde diethyl acetal With iodine; magnesium In tetrahydrofuran at 30 - 35℃; for 3.25h; Inert atmosphere;
Stage #2: 2,2,6-trimethylcyclohexan-1-one In tetrahydrofuran at 10 - 15℃; for 3h;
93.7%
2-bromomethyl-1,3-dioxolane
4360-63-8

2-bromomethyl-1,3-dioxolane

2,2,6-trimethylcyclohexan-1-one
2408-37-9

2,2,6-trimethylcyclohexan-1-one

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

Conditions
ConditionsYield
Stage #1: 2-bromomethyl-1,3-dioxolane With iodine; magnesium In 2-methyltetrahydrofuran at 30 - 40℃; for 3.25h; Inert atmosphere;
Stage #2: 2,2,6-trimethylcyclohexan-1-one In 2-methyltetrahydrofuran at 10 - 15℃; for 3h;
93.1%
1-bromo-2,2-dimethoxyethane
7252-83-7

1-bromo-2,2-dimethoxyethane

2,2,6-trimethylcyclohexan-1-one
2408-37-9

2,2,6-trimethylcyclohexan-1-one

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

Conditions
ConditionsYield
Stage #1: 1-bromo-2,2-dimethoxyethane With iodine; magnesium In tetrahydrofuran at 30 - 35℃; for 3.25h; Inert atmosphere;
Stage #2: 2,2,6-trimethylcyclohexan-1-one In tetrahydrofuran at 10 - 15℃; for 3h; Temperature; Solvent;
92.8%
chloroacetaldehyde dimethyl acetal
97-97-2

chloroacetaldehyde dimethyl acetal

2,2,6-trimethylcyclohexan-1-one
2408-37-9

2,2,6-trimethylcyclohexan-1-one

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

Conditions
ConditionsYield
Stage #1: chloroacetaldehyde dimethyl acetal With iodine; magnesium In ethylene dibromide at 30 - 45℃; for 3.41667h; Inert atmosphere;
Stage #2: 2,2,6-trimethylcyclohexan-1-one In ethylene dibromide at 10 - 15℃; for 3h;
90.7%
1-((E)-2-Methoxy-vinyl)-6,6-dimethyl-cyclohexene

1-((E)-2-Methoxy-vinyl)-6,6-dimethyl-cyclohexene

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

Conditions
ConditionsYield
With perchloric acid In diethyl ether for 5h;78.9%
α--2,6,6,-trimethyl-1-cyclohexenemethanol
128463-60-5

α--2,6,6,-trimethyl-1-cyclohexenemethanol

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

Conditions
ConditionsYield
With formic acid for 0.166667h; Ambient temperature;75%
1-ethoxyethynyl-2,2,6-trimethyl-cyclohexanol
408511-80-8

1-ethoxyethynyl-2,2,6-trimethyl-cyclohexanol

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

Conditions
ConditionsYield
With quinoline; Petroleum ether bei partieller Hydrierung an bleihaltigem Palladium, anschl. mit wss. H2SO4;
2-acetoxyvinylidene-1,1,3-trimethyl-cyclohexane
87570-49-8, 100678-90-8

2-acetoxyvinylidene-1,1,3-trimethyl-cyclohexane

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

Conditions
ConditionsYield
With hydrogenchloride; water
1-ethynyl-2,2,6-trimethyl-1-cyclohexanol
41613-59-6

1-ethynyl-2,2,6-trimethyl-1-cyclohexanol

ethanethiol
75-08-1

ethanethiol

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

Conditions
ConditionsYield
In tetrachloromethane (i) AIBN, (irradiation), (ii) CF3CO2H; Multistep reaction;
1-ethynyl-2,2,6-trimethyl-1-cyclohexanol
41613-59-6

1-ethynyl-2,2,6-trimethyl-1-cyclohexanol

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

Conditions
ConditionsYield
With vanadium tri-n-propoxide; benzoic acid; triphenylhydroxysilane In various solvent(s) at 140 - 150℃;81 % Turnov.
1-ethynyl-2,2,6-trimethyl-1-cyclohexanol
41613-59-6

1-ethynyl-2,2,6-trimethyl-1-cyclohexanol

A

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

B

α-(2,6,6-Trimethyl-1-cyclohexenyl)acetaldehyd
100513-69-7

α-(2,6,6-Trimethyl-1-cyclohexenyl)acetaldehyd

Conditions
ConditionsYield
tetrabutoxytitanium; p-Toluic acid; copper(l) chloride In 1,2-dichloro-benzene at 130℃; for 4h; Title compound not separated from byproducts;
(E)-3-(2,6,6-trimethylcyclohex-1-enyl)acrylic acid
14393-45-4

(E)-3-(2,6,6-trimethylcyclohex-1-enyl)acrylic acid

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

Conditions
ConditionsYield
With hydrogenchloride; diphenyl phosphoryl azide; triethylamine 1) dioxan, RT, 1 h, 2.) reflux, 15 min; Yield given. Multistep reaction;
2,2,6-trimethylcyclohexan-1-one
2408-37-9

2,2,6-trimethylcyclohexan-1-one

lithium acetylide-ethylenediamine complex
1216963-74-4

lithium acetylide-ethylenediamine complex

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

Conditions
ConditionsYield
(i), (ii) Ph3SiOH, (iii) (Ph3SiO)3VO; Multistep reaction;
1-acetoxy-2-<2,6,6-trimethyl-cyclohex-1-enyl>-ethene

1-acetoxy-2-<2,6,6-trimethyl-cyclohex-1-enyl>-ethene

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

Conditions
ConditionsYield
With methanol; water; sodium hydrogencarbonate
1-ethoxy-2-<2,6,6-trimethyl-cyclohex-1-enyl>-ethene

1-ethoxy-2-<2,6,6-trimethyl-cyclohex-1-enyl>-ethene

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

Conditions
ConditionsYield
With ethanol; water; toluene-4-sulfonic acid
(E)-β-ionone
79-77-6

(E)-β-ionone

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 92 percent / NaOH, Br2 / H2O; dioxane / 4 h / Ambient temperature
2: 1.) Et3N, diphenyl phosphoryl azide, 2.) 0.5 N aq. HCl / 1) dioxan, RT, 1 h, 2.) reflux, 15 min
View Scheme
2,6,6-trimethylcyclohex-1-enecarbaldehyde
432-25-7

2,6,6-trimethylcyclohex-1-enecarbaldehyde

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: s-BuLi / 1.) THF, hexane, from -70 deg C to -25 deg C, 2.) -25 deg C, 0.5 h
2: 75 percent / 90percent aq. formic acid / 0.17 h / Ambient temperature
View Scheme
Multi-step reaction with 2 steps
1: 61 percent / tetrahydrofuran / 1 h / Ambient temperature
2: 94 percent / 60percent perchloric acid / tetrahydrofuran / 0.5 h / Ambient temperature
View Scheme
acetic acid-(1-ethynyl-2,2,6-trimethyl-cyclohexyl ester)
87570-48-7

acetic acid-(1-ethynyl-2,2,6-trimethyl-cyclohexyl ester)

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: zinc oxide; silicon oil / 200 °C / Erhitzen unter vermindertem Druck
2: HCl; water
View Scheme
(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

trimethyl orthoformate
149-73-5

trimethyl orthoformate

Dimethoxy-2',2' ethyl-2 trimethyl-1,3,3 cyclohexene-1
86558-53-4

Dimethoxy-2',2' ethyl-2 trimethyl-1,3,3 cyclohexene-1

Conditions
ConditionsYield
With toluene-4-sulfonic acid In methanol for 24h; Ambient temperature;100%
(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

C11H19NO

C11H19NO

Conditions
ConditionsYield
With hydroxylamine hydrochloride; sodium acetate In methanol; water Reflux;100%
(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

2,2-dideutero-2-(2,6,6-trimethylcyclohex-1-en-1-yl)ethanal
269057-55-8

2,2-dideutero-2-(2,6,6-trimethylcyclohex-1-en-1-yl)ethanal

Conditions
ConditionsYield
With water-d2; sodium hydride In pyridine at 25℃; for 4h; deuteration;99.9%
(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

(2,6,6-trimethylcyclohex-1-enyl)acetonitrile
57576-15-5

(2,6,6-trimethylcyclohex-1-enyl)acetonitrile

Conditions
ConditionsYield
With hydroxylamine hydrochloride; 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane-2,4,6-trioxide; triethylamine In ethyl acetate; N,N-dimethyl-formamide at 100℃;97%
Multi-step reaction with 2 steps
1: hydroxylamine hydrochloride; sodium acetate / methanol; water / Reflux
2: 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane-2,4,6-trioxide / tetrahydrofuran; ethyl acetate / 20 °C / Inert atmosphere
View Scheme
pyrrolidine
123-75-1

pyrrolidine

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

1-<2-(2,6,6-trimethyl-1-cyclohexen-1-yl)ethenyl>pyrrolidine
93178-30-4

1-<2-(2,6,6-trimethyl-1-cyclohexen-1-yl)ethenyl>pyrrolidine

Conditions
ConditionsYield
In toluene at 60℃; for 1h;96%
In toluene at 60℃; for 1h;88%
3-bromo-1-trifluoromethylbenzene
401-78-5

3-bromo-1-trifluoromethylbenzene

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

1-(3-(trifluoromethyl)phenyl)-2-(2,6,6-trimethylcyclohex-1-enyl)ethanol
1441167-69-6

1-(3-(trifluoromethyl)phenyl)-2-(2,6,6-trimethylcyclohex-1-enyl)ethanol

Conditions
ConditionsYield
Stage #1: 3-bromo-1-trifluoromethylbenzene With iodine; magnesium In tetrahydrofuran for 0.0833333h; Reflux;
Stage #2: (2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde In tetrahydrofuran at -78 - 20℃; for 2h;
90%
(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

2,4,4-trimethyl-3-(2'-hydroxymethyl)-2-cyclohexene
472-65-1

2,4,4-trimethyl-3-(2'-hydroxymethyl)-2-cyclohexene

Conditions
ConditionsYield
With sodium tetrahydroborate In methanol at 0 - 20℃; for 1h;85%
With lithium aluminium tetrahydride In diethyl ether Heating;
With lithium aluminium tetrahydride
With lithium aluminium tetrahydride In diethyl ether
With sodium tetrahydroborate In methanol Inert atmosphere;
(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

tert-butyldimethylsilyl chloride
18162-48-6

tert-butyldimethylsilyl chloride

tert-butyl-dimethyl-[2-(2,6,6-trimethyl-cyclohex-1-enyl)-vinyloxy]-silane

tert-butyl-dimethyl-[2-(2,6,6-trimethyl-cyclohex-1-enyl)-vinyloxy]-silane

Conditions
ConditionsYield
With lithium diisopropyl amide In tetrahydrofuran85%
(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

C13H13NOS2

C13H13NOS2

(1R,4S,7R,8S,11S)-11-methyl-8-(2′,6′,6′-trimethylcyclohexenemethyl)-4-phenyl-9-oxa-2,10-dithia-5-azatricyclo[5,2,2,01,5]undecan-6-one

(1R,4S,7R,8S,11S)-11-methyl-8-(2′,6′,6′-trimethylcyclohexenemethyl)-4-phenyl-9-oxa-2,10-dithia-5-azatricyclo[5,2,2,01,5]undecan-6-one

Conditions
ConditionsYield
With titanium tetrachloride In dichloromethane at -40 - 0℃; for 10h; diastereoselective reaction;85%
(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid In chloroform for 17h; Heating;83%
Multi-step reaction with 2 steps
1: 81 percent / m-CPBA (50-60percent), p-TsOH / CHCl3 / 1 h / Ambient temperature
2: 83 percent / silica gel / Heating; Irradiation; microwave irradiation (1.0 kW), 5-10 min
View Scheme
(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

S-benzyl malonic acid half thioester
61668-14-2

S-benzyl malonic acid half thioester

S-benzyl (E)-4-(2,6,6-trimethylcyclohex-1-enyl)but-3-enethioate

S-benzyl (E)-4-(2,6,6-trimethylcyclohex-1-enyl)but-3-enethioate

Conditions
ConditionsYield
With 5-methoxy-1H-benzimidazole; ytterbium(III) triflate In tetrahydrofuran at 25℃; for 16h; Doebner-Knoevenagel condensation;82%
(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

(+/-)-aeginetolide
29951-40-4

(+/-)-aeginetolide

Conditions
ConditionsYield
With toluene-4-sulfonic acid; 3-chloro-benzenecarboperoxoic acid In chloroform for 1h; Ambient temperature;81%
(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

propionaldehyde
123-38-6

propionaldehyde

C14H24O2

C14H24O2

Conditions
ConditionsYield
With water; sodium hydroxide In N,N-dimethyl-formamide at 30℃; Solvent; Temperature; Reagent/catalyst; Concentration; Aldol Condensation;81%
3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

1-(3-fluorophenyl)-2-(2,6,6-trimethylcyclohex-1-enyl)ethanol
1441167-61-8

1-(3-fluorophenyl)-2-(2,6,6-trimethylcyclohex-1-enyl)ethanol

Conditions
ConditionsYield
Stage #1: 3-fluorobromobenzene With iodine; magnesium In tetrahydrofuran for 0.0833333h; Reflux;
Stage #2: (2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde In tetrahydrofuran at -78 - 20℃; for 2h;
75%
(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid In tetrachloromethane at 0 - 30℃; for 3h; Yields of byproduct given;A n/a
B 73%
(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

phenylbis[(trifluoromethyl)sulfonyl]amine

phenylbis[(trifluoromethyl)sulfonyl]amine

(E)-2-(2,6,6-trimethylcyclohexen-1-yl)-ethenyl (trifluoromethyl)sulfonate
303779-99-9

(E)-2-(2,6,6-trimethylcyclohexen-1-yl)-ethenyl (trifluoromethyl)sulfonate

Conditions
ConditionsYield
Stage #1: (2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -78℃; for 2h;
Stage #2: phenylbis[(trifluoromethyl)sulfonyl]amine In tetrahydrofuran; hexane at -78℃; Cooling; stereoselective reaction;
73%
1-bromo-3-chlorobenzene
108-37-2

1-bromo-3-chlorobenzene

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

1-(3-chlorophenyl)-2-(2,6,6-trimethylcyclohex-1-enyl)ethanol
1441167-65-2

1-(3-chlorophenyl)-2-(2,6,6-trimethylcyclohex-1-enyl)ethanol

Conditions
ConditionsYield
Stage #1: 1-bromo-3-chlorobenzene With iodine; magnesium In tetrahydrofuran for 0.0833333h; Reflux;
Stage #2: (2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde In tetrahydrofuran at -78 - 20℃; for 2h;
72%
(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

A

2,4,4-trimethyl-3-(2-oxoethyl)-2-cyclohexen-1-one
186451-82-1

2,4,4-trimethyl-3-(2-oxoethyl)-2-cyclohexen-1-one

B

(3-Hydroxy-2,6,6-trimethyl-cyclohex-1-enyl)-acetaldehyde

(3-Hydroxy-2,6,6-trimethyl-cyclohex-1-enyl)-acetaldehyde

Conditions
ConditionsYield
With pyridine N-oxide; selenium(IV) oxide In 1,4-dioxane at 80℃; for 4h;A 15%
B 64%
N,N-phenylbistrifluoromethane-sulfonimide
37595-74-7

N,N-phenylbistrifluoromethane-sulfonimide

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

(E)-2-(2,6,6-trimethylcyclohexen-1-yl)-ethenyl (trifluoromethyl)sulfonate
303779-99-9

(E)-2-(2,6,6-trimethylcyclohexen-1-yl)-ethenyl (trifluoromethyl)sulfonate

Conditions
ConditionsYield
Stage #1: (2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde With potassium tert-butylate In tetrahydrofuran at 0℃; for 0.25h;
Stage #2: N,N-phenylbistrifluoromethane-sulfonimide In tetrahydrofuran at 20℃; for 0.5h;
58%
Nonafluorobutanesulfonyl fluoride
375-72-4

Nonafluorobutanesulfonyl fluoride

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

(E)-2-(2,6,6-trimethylcyclohexen-1-yl)ethenyl nonafluorobutanesulfonate
475673-41-7

(E)-2-(2,6,6-trimethylcyclohexen-1-yl)ethenyl nonafluorobutanesulfonate

Conditions
ConditionsYield
With potassium tert-butylate In tetrahydrofuran for 1h; Heating;52%
With potassium tert-butylate In tetrahydrofuran for 1h; Heating;52%
(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

4-fluoro-3-trifluoromethylbenzyl bromide

4-fluoro-3-trifluoromethylbenzyl bromide

2-(4-fluoro-3-(trifluoromethyl)phenyl)-1-(2,6,6-trimethylcyclohex-1-enyl)ethanol
1441167-75-4

2-(4-fluoro-3-(trifluoromethyl)phenyl)-1-(2,6,6-trimethylcyclohex-1-enyl)ethanol

Conditions
ConditionsYield
Stage #1: 4-fluoro-3-trifluoromethylbenzyl bromide With magnesium In diethyl ether for 1.25h; Reflux;
Stage #2: (2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde In diethyl ether at -78 - 20℃; for 1h;
42%
4-bromo-2-fluoro-1-(trifluoromethoxy)benzene
105529-58-6

4-bromo-2-fluoro-1-(trifluoromethoxy)benzene

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

1-(3-fluoro-4-(trifluoromethoxy)phenyl)-2-(2,6,6-trimethylcyclohex-1-enyl)ethanol
1441167-79-8

1-(3-fluoro-4-(trifluoromethoxy)phenyl)-2-(2,6,6-trimethylcyclohex-1-enyl)ethanol

Conditions
ConditionsYield
Stage #1: 4-bromo-2-fluoro-1-(trifluoromethoxy)benzene With magnesium In diethyl ether for 0.666667h; Reflux;
Stage #2: (2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde In diethyl ether at -78 - 20℃; for 1h;
42%
(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde
472-66-2

(2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde

1-bromomethyl-3-methyl-benzene
620-13-3

1-bromomethyl-3-methyl-benzene

2-m-tolyl-1-(2,6,6-trimethylcyclohex-1-enyl)ethanol
1441167-71-0

2-m-tolyl-1-(2,6,6-trimethylcyclohex-1-enyl)ethanol

Conditions
ConditionsYield
Stage #1: 1-bromomethyl-3-methyl-benzene With magnesium In diethyl ether for 1.33333h; Reflux;
Stage #2: (2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde In diethyl ether at -78 - 20℃; for 1h;
41%

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