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Xi'an Yuri Solar Co. Ltd

Xi'an Polymer Light Technology Corp.(Referred as Xi'an p-OLED) is engaged in research, development and production of printing electronic materials. We have six categories of more than 200 products. Over 1000 universities and research institut

2,9-dimethyl-4,7-diphenyl-1,10-Phenanthroline

Cas:4733-39-5

Min.Order:1 Gram

Negotiable

Type:Trading Company

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Bathocuproine

Cas:4733-39-5

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Bathocuproin with high purity

Cas:4733-39-5

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Hangzhou Think Chemical Co. Ltd

Bathocuproin CAS No.:4733-39-5 Name: Bathocuproin Synonyms: 2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline Molecular Structure

High purity Bathocuproin CAS No.:4733-39-5

Cas:4733-39-5

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Other

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

Bathocuproin

Cas:4733-39-5

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Bathocuproin

Cas:4733-39-5

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

CAS 4733-39-5 Bathocuproine

Cas:4733-39-5

Min.Order:1 Kilogram

FOB Price: $15.0 / 50.0

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

Bathocuproin 4733-39-5

Cas:4733-39-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 4733-39-5 with best quality

Cas:4733-39-5

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Henan Sinotech Import&Export Corporation

Name: 2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline CAS:4733-39-5 MF: C26H20N2 Appearance: white powder Storage:Store in cool and dry place, away from sun light. Package: 25kgs/drum Application:OLED hole blocking materials Transportation:By sea or

2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline

Cas:4733-39-5

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Appearance:yellow powder Storage:R T Package:25kg/Barrel Application:Organic electronic materials that can be used as OLED electron transport layer and hole barrier layer. Transportation:Express/Sea/Air Port:Any port in China

Factory Price Ready Stock Bathocuproine

Cas:4733-39-5

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Bathocuproine 4733-39-5

Cas:4733-39-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

Bathocuproine Basic information Classification Applications Product Name: Bathocuproine Synonyms: Bathocuproine subliMed grade, 99.99% trace Metals basis;Bathocuproin SynonyMs 2,9-DiMethyl-4,7-diphenyl-1,10-phenanthroline;2,9-dimethyl-4,7-diphe

Bathocuproine

Cas:4733-39-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

Bathocuproine CAS:4733-39-5 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediate

Bathocuproine CAS:4733-39-5

Cas:4733-39-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Bathocuproine

Cas:4733-39-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Bathocuproin

Cas:4733-39-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Bathocuproine

Cas:4733-39-5

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Bathocuproine

Cas:4733-39-5

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

BATHOCUPROINE

Cas:4733-39-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Bathocuproin

Cas:4733-39-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline

Cas:4733-39-5

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Shaanxi Cuicheng Biomedical Technology Co., Ltd.

Why Choose Us: 1. Factory direct sales, so we can provide the competitive price and high quality product base on 8 years of production and R&D experience. 2. It is available in stock for quick shipment.Products could be packaged according to cu

Bathocuproine

Cas:4733-39-5

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

Bathocuproin

Cas:4733-39-5

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Bathocuproin

Cas:4733-39-5

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

Bathocuproine

Cas:4733-39-5

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

TaiChem Taizhou Limited

Established in May 2015, TaiChem Ltd. is initially invested by a British research and development company and started by PhDs back from aboard. The company is registered in China Medical City (CMC), Taizhou, Jiangsu Province, and the production site

Bathocuproine

Cas:4733-39-5

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED

2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline/BathocuproineCAS NO.: 4733-39-5

Cas:4733-39-5

Min.Order:1 Gram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

BCP

Cas:4733-39-5

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Henan Kanbei Chemical Co.,LTD

High quality, competitive price, fast delivery and first-class service we possesses have won the trust and praise of customers. Standard: BP/USP/EP The purity is equal or greater than 99%. As a supplier, we can provide high-quality products. Cle

BCP;Bathocuproin ;2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline.99%

Cas:4733-39-5

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

2,9-dimethyl 4,7-dichloro-1,10-phenanthroline

2,9-dimethyl 4,7-dichloro-1,10-phenanthroline

phenylboronic acid
98-80-6

phenylboronic acid

Bathocuproine
4733-39-5

Bathocuproine

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water for 24h; Suzuki-Miyaura Coupling; Reflux; Inert atmosphere;98%
2-methyl-8-nitro-4-phenyl-quinoline
70205-01-5

2-methyl-8-nitro-4-phenyl-quinoline

Bathocuproine
4733-39-5

Bathocuproine

Conditions
ConditionsYield
Hydrogenation.Erhitzen des erhaltenen Amins mit 1-Phenyl-but-2-en-1-on, sirupoese H3PO4 und H3AsO4;
1-phenylbut-2-en-1-one
495-41-0

1-phenylbut-2-en-1-one

Bathocuproine
4733-39-5

Bathocuproine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: arsenic acid; zinc-chloride; aqueous hydrochloric acid
2: Hydrogenation.Erhitzen des erhaltenen Amins mit 1-Phenyl-but-2-en-1-on, sirupoese H3PO4 und H3AsO4
View Scheme
2-nitro-aniline
88-74-4

2-nitro-aniline

Bathocuproine
4733-39-5

Bathocuproine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: arsenic acid; zinc-chloride; aqueous hydrochloric acid
2: Hydrogenation.Erhitzen des erhaltenen Amins mit 1-Phenyl-but-2-en-1-on, sirupoese H3PO4 und H3AsO4
View Scheme
1,2-diamino-benzene
95-54-5

1,2-diamino-benzene

Bathocuproine
4733-39-5

Bathocuproine

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: 0.25 h / Reflux
1.2: 2 h / Reflux
2.1: diphenylether / 0.67 h / 240 - 260 °C
3.1: trichlorophosphate / 3.5 h / 90 °C / Inert atmosphere
4.1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / water; tetrahydrofuran / 24 h / Reflux; Inert atmosphere
View Scheme
5,5'-((1,2-phenylenebis(azanediyl))bis(ethan-1-yl-1-ylidene))bis(2,2-dimethyl-1,3-dioxane-4,6-dione)
1311162-31-8

5,5'-((1,2-phenylenebis(azanediyl))bis(ethan-1-yl-1-ylidene))bis(2,2-dimethyl-1,3-dioxane-4,6-dione)

Bathocuproine
4733-39-5

Bathocuproine

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: diphenylether / 0.67 h / 240 - 260 °C
2: trichlorophosphate / 3.5 h / 90 °C / Inert atmosphere
3: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / water; tetrahydrofuran / 24 h / Reflux; Inert atmosphere
View Scheme
C37H25MnN6O4

C37H25MnN6O4

A

carbon monoxide
201230-82-2

carbon monoxide

B

Bathocuproine
4733-39-5

Bathocuproine

C

4-(1H-1,2,3,4-tetrazol-5-yl)benzaldehyde
74815-22-8

4-(1H-1,2,3,4-tetrazol-5-yl)benzaldehyde

Conditions
ConditionsYield
In dichloromethane UV-irradiation;
C36H25MnN6O3

C36H25MnN6O3

A

5-Phenyl-1H-tetrazole
18039-42-4

5-Phenyl-1H-tetrazole

B

carbon monoxide
201230-82-2

carbon monoxide

C

Bathocuproine
4733-39-5

Bathocuproine

Conditions
ConditionsYield
In dichloromethane UV-irradiation;
C35H24MnN7O3

C35H24MnN7O3

A

3-(1H-tetrazol-5-yl)pyridine
3250-74-6

3-(1H-tetrazol-5-yl)pyridine

B

carbon monoxide
201230-82-2

carbon monoxide

C

Bathocuproine
4733-39-5

Bathocuproine

Conditions
ConditionsYield
In dichloromethane UV-irradiation;
C35H24MnN7O3

C35H24MnN7O3

A

5-(4-pyridyl)tetrazole
14389-12-9

5-(4-pyridyl)tetrazole

B

carbon monoxide
201230-82-2

carbon monoxide

C

Bathocuproine
4733-39-5

Bathocuproine

Conditions
ConditionsYield
In dichloromethane UV-irradiation;
C37H24MnN7O3

C37H24MnN7O3

A

5-(4-cyanophenyl)tetrazole
14389-10-7

5-(4-cyanophenyl)tetrazole

B

carbon monoxide
201230-82-2

carbon monoxide

C

Bathocuproine
4733-39-5

Bathocuproine

Conditions
ConditionsYield
In dichloromethane UV-irradiation;
tetrakis(actonitrile)copper(I) hexafluorophosphate
64443-05-6

tetrakis(actonitrile)copper(I) hexafluorophosphate

Bathocuproine
4733-39-5

Bathocuproine

bis[2-(diphenylphosphino)phenyl] ether
166330-10-5

bis[2-(diphenylphosphino)phenyl] ether

2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline bis[(2-diphenyl-phosphino)phenyl]ether copper(I) hexafluorophosphate
1421057-27-3

2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline bis[(2-diphenyl-phosphino)phenyl]ether copper(I) hexafluorophosphate

Conditions
ConditionsYield
Stage #1: tetrakis(actonitrile)copper(I) hexafluorophosphate; bis[2-(diphenylphosphino)phenyl] ether In dichloromethane at 20℃; for 2h; Inert atmosphere;
Stage #2: Bathocuproine In dichloromethane for 1h; Inert atmosphere;
99%
Stage #1: tetrakis(actonitrile)copper(I) hexafluorophosphate; bis[2-(diphenylphosphino)phenyl] ether In dichloromethane at 20℃; for 2h; Inert atmosphere;
Stage #2: Bathocuproine In dichloromethane for 1h;
91%
Stage #1: tetrakis(actonitrile)copper(I) hexafluorophosphate; bis[2-(diphenylphosphino)phenyl] ether In dichloromethane Schlenk technique; Reflux;
Stage #2: Bathocuproine In dichloromethane at 20℃; Schlenk technique; Reflux;
85%
Stage #1: tetrakis(actonitrile)copper(I) hexafluorophosphate; bis[2-(diphenylphosphino)phenyl] ether In dichloromethane at 20℃; for 2h;
Stage #2: Bathocuproine In dichloromethane at 20℃; for 1h;
43.8%
Stage #1: tetrakis(actonitrile)copper(I) hexafluorophosphate; bis[2-(diphenylphosphino)phenyl] ether In dichloromethane at 20℃;
Stage #2: Bathocuproine In dichloromethane at 20℃;
tetrakis(actonitrile)copper(I) hexafluorophosphate
64443-05-6

tetrakis(actonitrile)copper(I) hexafluorophosphate

Bathocuproine
4733-39-5

Bathocuproine

nixantphos

nixantphos

[Cu(bathocuproine)(4,6-bis(diphenylphosphino)-10H-phenoxazine)]PF6
1421057-56-8

[Cu(bathocuproine)(4,6-bis(diphenylphosphino)-10H-phenoxazine)]PF6

Conditions
ConditionsYield
Stage #1: tetrakis(actonitrile)copper(I) hexafluorophosphate; nixantphos In dichloromethane Schlenk technique; Reflux;
Stage #2: Bathocuproine In dichloromethane at 20℃; Schlenk technique; Reflux;
99%
Stage #1: tetrakis(actonitrile)copper(I) hexafluorophosphate; nixantphos In dichloromethane at 20℃;
Stage #2: Bathocuproine In dichloromethane at 20℃;
Bathocuproine
4733-39-5

Bathocuproine

palladium diacetate
3375-31-3

palladium diacetate

(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)palladium(II) acetate
152506-88-2

(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)palladium(II) acetate

Conditions
ConditionsYield
With air In dichloromethane at 20℃;98%
In dichloromethane pptn. from diethyl ether;96%
In dichloromethane at 30℃; for 3h; Inert atmosphere;96%
NiCl2(bathocuproine)
120763-13-5

NiCl2(bathocuproine)

Bathocuproine
4733-39-5

Bathocuproine

C52H40N4Ni(1+)*Cl(1-)

C52H40N4Ni(1+)*Cl(1-)

Conditions
ConditionsYield
With cyclohexa-1,4-diene In acetonitrile Irradiation; Photolysis; Inert atmosphere; Glovebox;98%
[(η5-4,7-Me2C9H5)Mo(CO)2(NCMe)2][BF4]

[(η5-4,7-Me2C9H5)Mo(CO)2(NCMe)2][BF4]

Bathocuproine
4733-39-5

Bathocuproine

[(η5-4,7-Me2C9H5)-Mo(CO)2(2,9-Me2-4,7-Ph2-phen)][BF4]

[(η5-4,7-Me2C9H5)-Mo(CO)2(2,9-Me2-4,7-Ph2-phen)][BF4]

Conditions
ConditionsYield
In dichloromethane at 20℃; Inert atmosphere; Schlenk technique;98%
ammonium hexafluorophosphate

ammonium hexafluorophosphate

rhenium(I) pentacarbonyl chloride
14099-01-5

rhenium(I) pentacarbonyl chloride

2,6-dimethylphenyl isonitrile
119072-54-7, 2769-71-3

2,6-dimethylphenyl isonitrile

Bathocuproine
4733-39-5

Bathocuproine

fac-[Re(CO)3(2,6-dimethylphenylisocyanide)(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)](PF6)
850813-85-3

fac-[Re(CO)3(2,6-dimethylphenylisocyanide)(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)](PF6)

Conditions
ConditionsYield
With AgCF3SO3 In ethanol byproducts: AgCl; addn. of Re(CO)5Cl to Me2Ph2-phen, addn. EtOH, reflux for 2 h; pptn., filtration at room temp., drying (vac.) for 3 h; addn. of AgCF3SO3 and EtOH, reflux for 4 h; cooling, pptn., filtration, addn. Me2C6H3NC/EtOH; reflux for 3 h; concn., addn. aq. NH4PF6; dilution with water, pptn., filtration, drying in vac. oven, elem. anal.;97%
(1,2-dimethoxyethane)dichloronickel(II)
29046-78-4

(1,2-dimethoxyethane)dichloronickel(II)

Bathocuproine
4733-39-5

Bathocuproine

NiCl2(bathocuproine)
120763-13-5

NiCl2(bathocuproine)

Conditions
ConditionsYield
In tetrahydrofuran at 23℃; for 10h; Inert atmosphere; Glovebox;96%
Bathocuproine
4733-39-5

Bathocuproine

palladium diacetate
3375-31-3

palladium diacetate

(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)-palladium(II) acetate

(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)-palladium(II) acetate

Conditions
ConditionsYield
In dichloromethane at 20℃; for 3h;96%
(9,9-dimethyl-9H-xanthene-4,5-diyl)bis(dicyclohexylphosphane)

(9,9-dimethyl-9H-xanthene-4,5-diyl)bis(dicyclohexylphosphane)

tetrakis(actonitrile)copper(I) hexafluorophosphate
64443-05-6

tetrakis(actonitrile)copper(I) hexafluorophosphate

Bathocuproine
4733-39-5

Bathocuproine

[Cu(bathocuproine)((9,9-dimethyl-9H-xanthene-4,5-diyl)bis(dicyclohexylphosphine))]PF6
1421057-52-4

[Cu(bathocuproine)((9,9-dimethyl-9H-xanthene-4,5-diyl)bis(dicyclohexylphosphine))]PF6

Conditions
ConditionsYield
Stage #1: (9,9-dimethyl-9H-xanthene-4,5-diyl)bis(dicyclohexylphosphane); tetrakis(actonitrile)copper(I) hexafluorophosphate In dichloromethane Schlenk technique; Reflux;
Stage #2: Bathocuproine In dichloromethane at 20℃; Schlenk technique; Reflux;
95%
Bathocuproine
4733-39-5

Bathocuproine

4,7-diphenyl-1,10-phenanthroline-2,9-dicarboxylic acid

4,7-diphenyl-1,10-phenanthroline-2,9-dicarboxylic acid

Conditions
ConditionsYield
Stage #1: Bathocuproine With selenium(IV) oxide In 1,4-dioxane; water for 3h; Reflux;
Stage #2: With nitric acid for 3h; Reflux;
94%
With dihydrogen peroxide at 80℃; for 8h;80%
Multi-step reaction with 2 steps
1: 76 percent / N-chlorosuccinimide, 3-chloroperbenzoic acid / CCl4; CHCl3 / 16 h / Heating
2: 89 percent / aq. formic acid / 24 h / Heating
View Scheme
Multi-step reaction with 2 steps
1: N-chloro-succinimide; dibenzoyl peroxide / chloroform / 6 h / Reflux
2: sulfuric acid / 2 h / Microwave irradiation; Heating
View Scheme
tetrakis(actonitrile)copper(I) hexafluorophosphate
64443-05-6

tetrakis(actonitrile)copper(I) hexafluorophosphate

Bathocuproine
4733-39-5

Bathocuproine

bis(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)copper(I) hexafluorophosphate
47895-81-8

bis(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)copper(I) hexafluorophosphate

Conditions
ConditionsYield
In acetonitrile Ar-atmosphere; addn. of 2 equiv. of phen derivative to Cu-complex soln.,stirring for 10 min; pptn. on Et2O addn., filtration, dissoln. in CH2Cl2, crystn. on layeringwith Et2O; elem. anal.;94%
In methanol for 1h; Inert atmosphere;82%
for 0.333333h; Inert atmosphere;
NiCl2(bathocuproine)
120763-13-5

NiCl2(bathocuproine)

Bathocuproine
4733-39-5

Bathocuproine

Ni(bathocuproine)2
1508299-90-8

Ni(bathocuproine)2

Conditions
ConditionsYield
With 2,6-dimethylpyridine In tetrahydrofuran Irradiation; Inert atmosphere; Glovebox;94%
Bathocuproine
4733-39-5

Bathocuproine

2,9-bis(trichloromethyl)-4,7-diphenyl-1,10-phenanthroline

2,9-bis(trichloromethyl)-4,7-diphenyl-1,10-phenanthroline

Conditions
ConditionsYield
With N-chloro-succinimide; dibenzoyl peroxide In chloroform for 6h; Reflux;93%
With N-chloro-succinimide; dibenzoyl peroxide In chloroform for 24h; Reflux;80%
With N-chloro-succinimide; 3-chloro-benzenecarboperoxoic acid In tetrachloromethane; chloroform for 16h; Heating;76%
With N-chloro-succinimide; dibenzoyl peroxide In tetrachloromethane; chloroform6.1 g (97%)
Bathocuproine
4733-39-5

Bathocuproine

2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline N-oxide

2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline N-oxide

Conditions
ConditionsYield
With water; fluorine; acetonitrile In chloroform at 0℃;93%
tetrakis(actonitrile)copper(I) hexafluorophosphate
64443-05-6

tetrakis(actonitrile)copper(I) hexafluorophosphate

Bathocuproine
4733-39-5

Bathocuproine

4,5-bis(diphenylphosphino)-9,9-dimethylxanthene
161265-03-8

4,5-bis(diphenylphosphino)-9,9-dimethylxanthene

[Cu(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)(4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)](PF6)
1421057-42-2

[Cu(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)(4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)](PF6)

Conditions
ConditionsYield
Stage #1: tetrakis(actonitrile)copper(I) hexafluorophosphate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In dichloromethane Schlenk technique; Reflux;
Stage #2: Bathocuproine In dichloromethane at 20℃; Schlenk technique; Reflux;
93%
Stage #1: tetrakis(actonitrile)copper(I) hexafluorophosphate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In dichloromethane Inert atmosphere; Schlenk technique; Reflux;
Stage #2: Bathocuproine In dichloromethane Inert atmosphere; Schlenk technique; Reflux;
93%
Stage #1: tetrakis(actonitrile)copper(I) hexafluorophosphate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In dichloromethane at 20℃;
Stage #2: Bathocuproine In dichloromethane at 20℃;
Stage #1: tetrakis(actonitrile)copper(I) hexafluorophosphate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In dichloromethane Inert atmosphere; Reflux;
Stage #2: Bathocuproine In dichloromethane for 3h; Inert atmosphere; Reflux;
bis(1,5-cyclooctadiene)nickel (0)
1295-35-8

bis(1,5-cyclooctadiene)nickel (0)

Bathocuproine
4733-39-5

Bathocuproine

Ni(bathocuproine)2
1508299-90-8

Ni(bathocuproine)2

Conditions
ConditionsYield
In tetrahydrofuran at 60℃; for 12h; Inert atmosphere; Glovebox;93%
tetrakis(actonitrile)copper(I) hexafluorophosphate
64443-05-6

tetrakis(actonitrile)copper(I) hexafluorophosphate

2,6-dimethylphenyl isonitrile
119072-54-7, 2769-71-3

2,6-dimethylphenyl isonitrile

Bathocuproine
4733-39-5

Bathocuproine

[Cu(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)(2,6-dimethylphenylisocyanide)2]PF6

[Cu(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)(2,6-dimethylphenylisocyanide)2]PF6

Conditions
ConditionsYield
In dichloromethane for 1h;93%
C34H36CuN4(1+)*F6P(1-)

C34H36CuN4(1+)*F6P(1-)

Bathocuproine
4733-39-5

Bathocuproine

(2,9-dimesityl-1,10-phenanthroline)(bathocuproine)copper(I) hexafluorophosphate

(2,9-dimesityl-1,10-phenanthroline)(bathocuproine)copper(I) hexafluorophosphate

Conditions
ConditionsYield
In dichloromethane at 20℃; for 0.5h;91%
Bathocuproine
4733-39-5

Bathocuproine

4-methyl-N-(2-(7-phenylindolo[1,2-a]quinazolin-9-yl)phenyl)benzenesulfonamide

4-methyl-N-(2-(7-phenylindolo[1,2-a]quinazolin-9-yl)phenyl)benzenesulfonamide

7-phenyl-13-tosyl-13H-quinazolino[1',2':1,5]pyrrolo[2,3-b]carbazole

7-phenyl-13-tosyl-13H-quinazolino[1',2':1,5]pyrrolo[2,3-b]carbazole

Conditions
ConditionsYield
With sodium acetate; palladium diacetate In 1,3,5-trimethyl-benzene at 100℃; for 6h;91%
tetrakis(actonitrile)copper(I) hexafluorophosphate
64443-05-6

tetrakis(actonitrile)copper(I) hexafluorophosphate

2,2′-bis(diphenylphosphino)-1,1′-binaphthalene.

2,2′-bis(diphenylphosphino)-1,1′-binaphthalene.

Bathocuproine
4733-39-5

Bathocuproine

[Cu(bathocuproine)(binap)]PF6

[Cu(bathocuproine)(binap)]PF6

Conditions
ConditionsYield
Stage #1: tetrakis(actonitrile)copper(I) hexafluorophosphate; 2,2′-bis(diphenylphosphino)-1,1′-binaphthalene. In dichloromethane Schlenk technique; Reflux;
Stage #2: Bathocuproine In dichloromethane at 20℃; Schlenk technique; Reflux;
90%
Bathocuproine
4733-39-5

Bathocuproine

copper(I) bromide
7787-70-4

copper(I) bromide

(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)CuBr

(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)CuBr

Conditions
ConditionsYield
In acetonitrile at 20℃; Inert atmosphere;90%
tetrafluoroboric acid diethyl ether
67969-82-8

tetrafluoroboric acid diethyl ether

Bathocuproine
4733-39-5

Bathocuproine

[(Bathocuproine)H2](BF4)2

[(Bathocuproine)H2](BF4)2

Conditions
ConditionsYield
In acetone for 0.583333h;90%
nickel(II) bromide diethylene glycol dimethyl ether

nickel(II) bromide diethylene glycol dimethyl ether

Bathocuproine
4733-39-5

Bathocuproine

(2,9-dimethyl-4,7-diphenyl-1,10-phenantroline)NiBr2
326822-02-0

(2,9-dimethyl-4,7-diphenyl-1,10-phenantroline)NiBr2

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 46h; Inert atmosphere; Sealed tube;90%
silver hexafluoroantimonate

silver hexafluoroantimonate

Bathocuproine
4733-39-5

Bathocuproine

C52H40AgN4(1+)*F6Sb(1-)

C52H40AgN4(1+)*F6Sb(1-)

Conditions
ConditionsYield
In dichloromethane at 20℃; for 16h; Inert atmosphere; Glovebox; Schlenk technique;90%
copper(II) nitrate trihydrate

copper(II) nitrate trihydrate

Bathocuproine
4733-39-5

Bathocuproine

C52H40CuN4(2+)*2NO3(1-)

C52H40CuN4(2+)*2NO3(1-)

Conditions
ConditionsYield
In dichloromethane; acetone90%
2-oxoindole
59-48-3

2-oxoindole

Bathocuproine
4733-39-5

Bathocuproine

3-hydroxy-3-((9-methyl-4,7-diphenyl-1,10-phenanthrolin-2-yl)methyl)indolin-2-one

3-hydroxy-3-((9-methyl-4,7-diphenyl-1,10-phenanthrolin-2-yl)methyl)indolin-2-one

Conditions
ConditionsYield
With iron(II) acetate In N,N-dimethyl-formamide at 80℃; for 5h; Green chemistry;90%
potassium hexafluorophosphate
17084-13-8

potassium hexafluorophosphate

cis-bis-(2,2′-bipyridine) dichlororuthenium(II) dihydrate

cis-bis-(2,2′-bipyridine) dichlororuthenium(II) dihydrate

Bathocuproine
4733-39-5

Bathocuproine

[Ru(bpy)2(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)](PF6)2

[Ru(bpy)2(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)](PF6)2

Conditions
ConditionsYield
Stage #1: cis-bis-(2,2′-bipyridine) dichlororuthenium(II) dihydrate; Bathocuproine In 1,2-dimethoxyethane at 260℃; for 6h;
Stage #2: potassium hexafluorophosphate In water
89%
Bathocuproine
4733-39-5

Bathocuproine

2,9-dicarboxaldehyde-4,7-diphenyl-1,10-phenanthroline

2,9-dicarboxaldehyde-4,7-diphenyl-1,10-phenanthroline

Conditions
ConditionsYield
With selenium(IV) oxide In 1,4-dioxane; water at 110℃; for 2h;88%
With selenium(IV) oxide In 1,4-dioxane at 80℃; for 2h; Inert atmosphere; Sealed tube;85%
tetrakis(acetonitrile)copper(I)tetrafluoroborate

tetrakis(acetonitrile)copper(I)tetrafluoroborate

Bathocuproine
4733-39-5

Bathocuproine

bis(diphenylphosphino)acetylene
5112-95-8

bis(diphenylphosphino)acetylene

[Cu2(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)2(μ-bis(diphenylphosphino)acetylene)2](BF4)2

[Cu2(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)2(μ-bis(diphenylphosphino)acetylene)2](BF4)2

Conditions
ConditionsYield
Stage #1: tetrakis(acetonitrile)copper(I)tetrafluoroborate; bis(diphenylphosphino)acetylene In dichloromethane; acetonitrile for 0.5h; Inert atmosphere;
Stage #2: Bathocuproine In dichloromethane; acetonitrile for 1h; Inert atmosphere;
88%

Raw Materials

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