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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

1-Propene, 2-nitro-

Cas:4749-28-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

2-NITROPROPENE CAS:4749-28-4 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermedia

2-NITROPROPENE CAS:4749-28-4

Cas:4749-28-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

1-Propene, 2-nitro-

Cas:4749-28-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

1-Propene, 2-nitro-

Cas:4749-28-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

1-Propene, 2-nitro-

Cas:4749-28-4

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd

2-NITROPROPENE

Cas:4749-28-4

Min.Order:1 Kilogram

FOB Price: $50.0 / 100.0

Type:Trading Company

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

1-Propene, 2-nitro- CAS NO.4749-28-4

Cas:4749-28-4

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

1-Propene, 2-nitro- CAS NO.4749-28-4

Cas:4749-28-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

1-Propene, 2-nitro- CAS NO.4749-28-4

Cas:4749-28-4

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

1-Propene, 2-nitro- CAS NO.4749-28-4

Cas:4749-28-4

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates

1-Propene, 2-nitro-

Cas:4749-28-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

1-Propene, 2-nitro-

Cas:4749-28-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

1-Propene, 2-nitro-

Cas:4749-28-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Langyou International Trading Co., Ltd

1-Propene, 2-nitro- CAS NO.4749-28-4 Application:1-Propene, 2-nitro- CAS NO.4749-28-4

1-Propene, 2-nitro- CAS NO.4749-28-4

Cas:4749-28-4

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Fandachem Co.,Ltd

2-NITRO-1-PROPENEAppearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

2-NITRO-1-PROPENE

Cas:4749-28-4

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

2-NITROPROPENE

Cas:4749-28-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Longxianng Runhui Trading Co.,Ltd

1-Propene, 2-nitro- CAS NO.4749-28-4Appearance:off-white fine crystalline powder Storage:Dry and ventilated Package:Standard or as customer's require Application:intermediates Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small

1-Propene, 2-nitro- CAS NO.4749-28-4

Cas:4749-28-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

4749-28-4

Cas:4749-28-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

2-NITROPROPENE

Cas:4749-28-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai united Scientific Co.,Ltd.

United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

1-Propene, 2-nitro-

Cas:4749-28-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chungking Joyinchem Co., Ltd.

Joyinchem have been committed to chemical supply for several years and have built good cooperation records with multinational chemical corporations and importers from all over the world. Our services include:-Spot goods-Contract manufacturing-Custom

1-Propene, 2-nitro-

Cas:4749-28-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Jusheng Technology Co., Ltd.,

1,Best Quality: Our products have exported to Germany, Spain, UK, USA, Australia, Middle East, and so on other countries, and we have got very good feedback from our customers.so

1-Propene, 2-nitro- CAS NO.4749-28-4

Cas:4749-28-4

Min.Order:10 Gram

FOB Price: $1.0 / 2.0

Type:Trading Company

inquiry

Taizhou volsen chemical Co., Ltd

We are a trading company aiming at providing high-quality services to customers. Established for many years, with good reputation in the industry Storage:Sealed and preserved Application:Fine chemical intermediates, used as the main raw material for

1-Propene, 2-nitro- CAS NO.4749-28-4

Cas:4749-28-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Nanjing Raymon Biotech Co., Ltd.

1-Propene, 2-nitro- CAS NO.4749-28-4Appearance:off-white fine crystalline powder Storage:keep in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/pharma intermediate Transportation:By Sea,by Air,By co

1-Propene, 2-nitro- CAS NO.4749-28-4

Cas:4749-28-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hebei Minshang Biotechnology Co., Ltd

1-Propene, 2-nitro- CAS NO.4749-28-4 Application:intermediates

4749-28-4

Cas:4749-28-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Finetech Industry Limited

FINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the 2-NITROPROPENE, CAS:4749-28-4 with the most competitive price and the best quality. W

2-NITROPROPENE

Cas:4749-28-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fenjun Chemical Co Ltd.

1-Propene, 2-nitro- CAS NO.4749-28-4 Application:1-Propene, 2-nitro- CAS NO.4749-28-4

1-Propene, 2-nitro- CAS NO.4749-28-4

Cas:4749-28-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hebei Ruishun Trade Co.,Ltd

Supply top quality products with a reasonable price Application:api

4749-28-4

Cas:4749-28-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

AstraZeneca Global

1-Propene,2-nitro- CASNo.:4749-28-4 Storage:as prescr?be by the manufacturer Package:pack as requested

1-Propene, 2-nitro-

Cas:4749-28-4

Min.Order:60 Kilogram

Negotiable

Type:Trading Company

inquiry

Chemical Co.Ltd

1-Propene, 2-nitro-Appearance:Off white to slight yellow solid Storage:Stored in shaded, cool and dry places Package:1L 5L 10L 25L bottle Application:pharma intermediate Transportation:Handle with cares to avoid damaging the packages. Protect them fr

1-Propene, 2-nitro-

Cas:4749-28-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

2-NITROPROPANOL
2902-96-7

2-NITROPROPANOL

2-nitropropene
4749-28-4

2-nitropropene

Conditions
ConditionsYield
With phthalic anhydride Heating;94%
With phthalic anhydride at 150 - 185℃; for 1.5h;72%
With triethylamine; trifluoroacetic anhydride Inert atmosphere;56%
2-nitro-1-butanol
609-31-4

2-nitro-1-butanol

2-nitropropene
4749-28-4

2-nitropropene

Conditions
ConditionsYield
With phthalic anhydride at 150 - 200℃;52%
1-(2-nitro-propyl)-piperidine
3275-15-8

1-(2-nitro-propyl)-piperidine

2-nitropropene
4749-28-4

2-nitropropene

Conditions
ConditionsYield
With diethyl ether; Di(2-ethylhexyl)phthalate; boron trifluoride anschliessendes Erhitzen unter 1 Torr auf 105grad;
1-chloro-2-nitro-propane
2425-66-3

1-chloro-2-nitro-propane

2-nitropropene
4749-28-4

2-nitropropene

Conditions
ConditionsYield
With silica gel at 325℃;
2-nitroacetoxypropane
3750-82-1

2-nitroacetoxypropane

2-nitropropene
4749-28-4

2-nitropropene

Conditions
ConditionsYield
With sodium carbonate; benzene
benzoic acid-(2-nitro-propyl ester)
5437-73-0

benzoic acid-(2-nitro-propyl ester)

A

2-nitropropene
4749-28-4

2-nitropropene

B

benzoic acid
65-85-0

benzoic acid

Conditions
ConditionsYield
auch unter vermindertem Druck;
N-<2-nitro-propyl>-piperidine hydrochloride

N-<2-nitro-propyl>-piperidine hydrochloride

2-nitropropene
4749-28-4

2-nitropropene

Conditions
ConditionsYield
at 105 - 160℃; under 70 Torr;
2-nitroacetoxypropane
3750-82-1

2-nitroacetoxypropane

calcium magnesium phosphate

calcium magnesium phosphate

A

2-nitropropene
4749-28-4

2-nitropropene

B

acetic acid
64-19-7

acetic acid

Conditions
ConditionsYield
at 285℃;
propene
187737-37-7

propene

A

2-nitropropene
4749-28-4

2-nitropropene

B

propionaldehyde
123-38-6

propionaldehyde

C

acetone
67-64-1

acetone

Conditions
ConditionsYield
With bis(acetonitrile)chloronitropalladium(II) In chloroform at 25℃; under 0.1 Torr; for 6h; Product distribution; Further Variations:; Reagents;A 6 % Chromat.
B 1 % Chromat.
C 93 % Chromat.
N,N-bis(trimethylsilyloxy)-1-propen-2-amine
102588-22-7

N,N-bis(trimethylsilyloxy)-1-propen-2-amine

2-nitropropene
4749-28-4

2-nitropropene

Conditions
ConditionsYield
With bromine; tetrabutylammonium acetate In dichloromethane at -78 - 20℃;95 % Spectr.
2-nitropropane
79-46-9

2-nitropropane

1-Nitropropane
108-03-2

1-Nitropropane

A

2-nitropropene
4749-28-4

2-nitropropene

B

1-Nitropropen
3156-70-5

1-Nitropropen

Conditions
ConditionsYield
With nitric acid at 200℃; under 16274.9 Torr; Product distribution / selectivity;
2-nitropropyl phtalate

2-nitropropyl phtalate

2-nitropropene
4749-28-4

2-nitropropene

Conditions
ConditionsYield
Pyrolysis;
2-nitropropene
4749-28-4

2-nitropropene

N-(3α-acetoxy-11-oxonorcholan-23-ylcarbonyloxy)pyridine-2-thione
89025-69-4

N-(3α-acetoxy-11-oxonorcholan-23-ylcarbonyloxy)pyridine-2-thione

3α-acetoxy, 25-nitro-25-(pyridine-2-thiyl)-11-oxo,27-nor-5β-cholestane
104543-15-9

3α-acetoxy, 25-nitro-25-(pyridine-2-thiyl)-11-oxo,27-nor-5β-cholestane

Conditions
ConditionsYield
With camphor-10-sulfonic acid In benzene at -20 - -10℃; for 0.5h; Irradiation;100%
2-nitropropene
4749-28-4

2-nitropropene

Phenylselenyl chloride
5707-04-0

Phenylselenyl chloride

silver trifluoroacetate
2966-50-9

silver trifluoroacetate

2-nitro-2-phenylseleno-propyl-trifluoroacetate
104313-35-1

2-nitro-2-phenylseleno-propyl-trifluoroacetate

Conditions
ConditionsYield
In dichloromethane Ambient temperature;97%
2-nitropropene
4749-28-4

2-nitropropene

2-methylcyclohexane-1,3-dione
1193-55-1

2-methylcyclohexane-1,3-dione

2-Methyl-2-(2-oxopropyl)-1,3-cyclohexanedione
32561-57-2

2-Methyl-2-(2-oxopropyl)-1,3-cyclohexanedione

Conditions
ConditionsYield
potassium fluoride In xylene at 120℃; for 19h;96%
2-nitropropene
4749-28-4

2-nitropropene

4-benzyloxy-1H-indole
20289-26-3

4-benzyloxy-1H-indole

1-<4-(benzyloxy)indol-3-yl>-2-nitropropane
2873-49-6

1-<4-(benzyloxy)indol-3-yl>-2-nitropropane

Conditions
ConditionsYield
In benzene Heating;96%
In benzene Heating;59%
2-nitropropene
4749-28-4

2-nitropropene

cyclohexanone
108-94-1

cyclohexanone

acetic anhydride
108-24-7

acetic anhydride

2-(2-acetyl-aci-nitropropyl)cyclohexanone
125405-73-4, 125405-74-5, 132336-66-4

2-(2-acetyl-aci-nitropropyl)cyclohexanone

Conditions
ConditionsYield
With lithium diisopropyl amide In tetrahydrofuran 1.) -78 deg C, 2 h; 2.) -78 to 20 deg C over 2 h;96%
Yield given. Multistep reaction;
2-nitropropene
4749-28-4

2-nitropropene

α-(2-ethyl acetate) Meldrum's acid
1374824-30-2

α-(2-ethyl acetate) Meldrum's acid

(S)-2-(2,2-dimethyl-5-(2-nitropropyl)-4,6-dioxo-1,3-dioxan-5-yl)ethyl acetate
1374824-20-0

(S)-2-(2,2-dimethyl-5-(2-nitropropyl)-4,6-dioxo-1,3-dioxan-5-yl)ethyl acetate

Conditions
ConditionsYield
With (R)-2,4,6-triisopropyl-N-((2-methyl-2-morpholinopropyl)carbamoyl)benzenesulfinamide In cyclopentyl methyl ether at -30℃; Molecular sieve; Inert atmosphere; optical yield given as %ee; enantioselective reaction;95%
2-nitropropene
4749-28-4

2-nitropropene

thioacetic acid
507-09-5

thioacetic acid

S-2-nitropropyl thiolacetate
1365479-49-7

S-2-nitropropyl thiolacetate

Conditions
ConditionsYield
With tributyl-amine In diethyl ether for 1h; Michael addition; Cooling with ice;94%
2-nitropropene
4749-28-4

2-nitropropene

5-ethyl-2,2-dimethyl-[1,3]dioxane-4,6-dione
17216-65-8

5-ethyl-2,2-dimethyl-[1,3]dioxane-4,6-dione

(S)-5-ethyl-2,2-dimethyl-5-(2-nitropropyl)-1,3-dioxane-4,6-dione
1374824-13-1

(S)-5-ethyl-2,2-dimethyl-5-(2-nitropropyl)-1,3-dioxane-4,6-dione

Conditions
ConditionsYield
With (R)-2,4,6-triisopropyl-N-((2-methyl-2-morpholinopropyl)carbamoyl)benzenesulfinamide In cyclopentyl methyl ether at -30℃; Molecular sieve; Inert atmosphere; optical yield given as %ee; enantioselective reaction;94%
2-nitropropene
4749-28-4

2-nitropropene

2,2,5-trimethyl-1,3-dioxane-4,6-dione
3709-18-0

2,2,5-trimethyl-1,3-dioxane-4,6-dione

(S)-2,2,5-trimethyl-5-(2-nitropropyl)-1,3-dioxane-4,6-dione
1374824-11-9

(S)-2,2,5-trimethyl-5-(2-nitropropyl)-1,3-dioxane-4,6-dione

Conditions
ConditionsYield
With (R)-2,4,6-triisopropyl-N-((2-methyl-2-morpholinopropyl)carbamoyl)benzenesulfinamide In cyclopentyl methyl ether at -30℃; Molecular sieve; Inert atmosphere; optical yield given as %ee; enantioselective reaction;93%
2-nitropropene
4749-28-4

2-nitropropene

2,2-dimethyl-5-phenethyl-[1,3]dioxane-4,6-dione
3709-38-4

2,2-dimethyl-5-phenethyl-[1,3]dioxane-4,6-dione

(S)-2,2-dimethyl-5-(2-nitropropyl)-5-phenethyl-1,3-dioxane-4,6-dione
1374824-15-3

(S)-2,2-dimethyl-5-(2-nitropropyl)-5-phenethyl-1,3-dioxane-4,6-dione

Conditions
ConditionsYield
With (R)-2,4,6-triisopropyl-N-((2-methyl-2-morpholinopropyl)carbamoyl)benzenesulfinamide In cyclopentyl methyl ether at -30℃; Molecular sieve; Inert atmosphere; optical yield given as %ee; enantioselective reaction;93%
2-nitropropene
4749-28-4

2-nitropropene

2-morpholinopent-1-en-3-one
136368-54-2

2-morpholinopent-1-en-3-one

1-ethyl-5-methyl-2-morpholino-5-nitrocyclopent-2-enol
136368-57-5

1-ethyl-5-methyl-2-morpholino-5-nitrocyclopent-2-enol

Conditions
ConditionsYield
at -20℃; for 2h;92%
2-nitropropene
4749-28-4

2-nitropropene

2-morpholin-4-yl-1,3-diphenyl-propenone
57310-73-3

2-morpholin-4-yl-1,3-diphenyl-propenone

5-methyl-2-morpholino-5-nitro-1,3-diphenyl-cyclopent-2-enol
136368-82-6

5-methyl-2-morpholino-5-nitro-1,3-diphenyl-cyclopent-2-enol

Conditions
ConditionsYield
for 2h;92%
2-nitropropene
4749-28-4

2-nitropropene

3-(n-butylimino)-butan-2-one
140405-47-6

3-(n-butylimino)-butan-2-one

5-(n-butylimino)-1,2-dimethyl-2-nitrocyclopentan-1-ol
140405-49-8

5-(n-butylimino)-1,2-dimethyl-2-nitrocyclopentan-1-ol

Conditions
ConditionsYield
for 0.5h;90%
2-nitropropene
4749-28-4

2-nitropropene

2,2-dimethyl-5-(2-(methylthio)ethyl)-1,3-dioxane-4,6-dione
1094204-79-1

2,2-dimethyl-5-(2-(methylthio)ethyl)-1,3-dioxane-4,6-dione

(S)-2,2-dimethyl-5-(2-(methylthio)ethyl)-5-(2-nitropropyl)-1,3-dioxane-4,6-dione
1374824-19-7

(S)-2,2-dimethyl-5-(2-(methylthio)ethyl)-5-(2-nitropropyl)-1,3-dioxane-4,6-dione

Conditions
ConditionsYield
With (R)-2,4,6-triisopropyl-N-((2-methyl-2-morpholinopropyl)carbamoyl)benzenesulfinamide In cyclopentyl methyl ether at -30℃; Molecular sieve; Inert atmosphere; optical yield given as %ee; enantioselective reaction;90%
2-nitropropene
4749-28-4

2-nitropropene

5-Acetoxy-2,2-dimethyl-1,3-dioxan-4,6-dion
75307-63-0

5-Acetoxy-2,2-dimethyl-1,3-dioxan-4,6-dion

(S)-2,2-dimethyl-5-(2-nitropropyl)-4,6-dioxo-1,3-dioxan-5-yl acetate
1374824-22-2

(S)-2,2-dimethyl-5-(2-nitropropyl)-4,6-dioxo-1,3-dioxan-5-yl acetate

Conditions
ConditionsYield
With (R)-2,4,6-triisopropyl-N-((2-methyl-2-morpholinopropyl)carbamoyl)benzenesulfinamide In cyclopentyl methyl ether at -30℃; Molecular sieve; Inert atmosphere; optical yield given as %ee; enantioselective reaction;90%
5-methoxylindole
1006-94-6

5-methoxylindole

2-nitropropene
4749-28-4

2-nitropropene

1-(5-methoxyindol-3-yl)-2-nitropropane
113997-50-5

1-(5-methoxyindol-3-yl)-2-nitropropane

Conditions
ConditionsYield
In benzene Heating;89%
2-nitropropene
4749-28-4

2-nitropropene

C13H12O3

C13H12O3

C15H17NO3

C15H17NO3

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; (S,Rp)-FeUrPhos In 1,4-dioxane at 25℃; for 72h; Inert atmosphere; Glovebox; stereoselective reaction;89%
formaldehyd
50-00-0

formaldehyd

2-nitropropene
4749-28-4

2-nitropropene

thiophenol
108-98-5

thiophenol

2-Methyl-2-nitro-3-phenylsulfanyl-propan-1-ol
94421-42-8

2-Methyl-2-nitro-3-phenylsulfanyl-propan-1-ol

Conditions
ConditionsYield
With 1,1,3,3-tetramethylguanidine for 5h; Ambient temperature;88%
2-nitropropene
4749-28-4

2-nitropropene

α-(4-(trifluoromethoxy)phenethyl) Meldrum's acid
1374824-28-8

α-(4-(trifluoromethoxy)phenethyl) Meldrum's acid

(S)-2,2-dimethyl-5-(2-nitropropyl)-5-(4-(trifluoromethoxy)phenethyl)-1,3-dioxane-4,6-dione
1374824-17-5

(S)-2,2-dimethyl-5-(2-nitropropyl)-5-(4-(trifluoromethoxy)phenethyl)-1,3-dioxane-4,6-dione

Conditions
ConditionsYield
With (R)-2,4,6-triisopropyl-N-((2-methyl-2-morpholinopropyl)carbamoyl)benzenesulfinamide In cyclopentyl methyl ether at -30℃; Molecular sieve; Inert atmosphere; optical yield given as %ee; enantioselective reaction;88%
2-nitropropene
4749-28-4

2-nitropropene

acetic anhydride
108-24-7

acetic anhydride

pentan-3-one
96-22-0

pentan-3-one

Conditions
ConditionsYield
With lithium diisopropyl amide In tetrahydrofuran 1.) -78 deg C, 2 h; 2.) -78 to 20 deg C over 2 h;87%
Yield given. Multistep reaction;
2-nitropropene
4749-28-4

2-nitropropene

benzene
71-43-2

benzene

1-phenyl-acetone
103-79-7

1-phenyl-acetone

Conditions
ConditionsYield
With trifluorormethanesulfonic acid In dichloromethane at -40℃; for 0.0166667h;85%
2-nitropropene
4749-28-4

2-nitropropene

2,2-Dimethyl-5-(2-methylpropyl)-1,3-dioxane-4,6-dione
74965-92-7

2,2-Dimethyl-5-(2-methylpropyl)-1,3-dioxane-4,6-dione

(S)-5-isobutyl-2,2-dimethyl-5-(2-nitropropyl)-1,3-dioxane-4,6-dione
1374824-14-2

(S)-5-isobutyl-2,2-dimethyl-5-(2-nitropropyl)-1,3-dioxane-4,6-dione

Conditions
ConditionsYield
With (R)-2,4,6-triisopropyl-N-((2-methyl-2-morpholinopropyl)carbamoyl)benzenesulfinamide In cyclopentyl methyl ether at -30℃; Molecular sieve; Inert atmosphere; optical yield given as %ee; enantioselective reaction;85%
2-nitropropene
4749-28-4

2-nitropropene

C14H14O3

C14H14O3

C16H19NO3

C16H19NO3

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; (S,Rp)-FeUrPhos In 1,4-dioxane at 25℃; for 72h; Inert atmosphere; Glovebox; stereoselective reaction;85%
2-nitropropene
4749-28-4

2-nitropropene

C10H14O3

C10H14O3

C12H19NO3

C12H19NO3

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; (S,Rp)-FeUrPhos In 1,4-dioxane at 25℃; for 60h; Inert atmosphere; Glovebox; stereoselective reaction;85%
2-nitropropene
4749-28-4

2-nitropropene

C11H14O3

C11H14O3

C13H19NO3

C13H19NO3

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; (S,Rp)-FeUrPhos In 1,4-dioxane at 25℃; for 60h; Inert atmosphere; Glovebox; stereoselective reaction;84%
2-nitropropene
4749-28-4

2-nitropropene

piperonal
120-57-0

piperonal

methyl (2S)-pyrrolidine carboxylate
2577-48-2

methyl (2S)-pyrrolidine carboxylate

methyl 1-(benzo[d][1,3]dioxol-5-yl)-2-methyl-2-nitrohexahydro-1H-pyrrolizine-7a-carboxylate

methyl 1-(benzo[d][1,3]dioxol-5-yl)-2-methyl-2-nitrohexahydro-1H-pyrrolizine-7a-carboxylate

Conditions
ConditionsYield
Stage #1: 2-nitropropene; piperonal; methyl (2S)-pyrrolidine carboxylate With sodium sulfate; triethylamine In acetonitrile at 80℃; for 0.333333h;
Stage #2: In acetonitrile at 80℃; for 0.75h;
Stage #3: In acetonitrile
83%
indole
120-72-9

indole

2-nitropropene
4749-28-4

2-nitropropene

α-methyl-β-(3-indolyl)-1-nitroethane
4771-72-6

α-methyl-β-(3-indolyl)-1-nitroethane

Conditions
ConditionsYield
In benzene Heating;81%
In benzene Heating;
2-nitropropene
4749-28-4

2-nitropropene

n-hexan-2-one
591-78-6

n-hexan-2-one

acetic anhydride
108-24-7

acetic anhydride

Conditions
ConditionsYield
With lithium diisopropyl amide In tetrahydrofuran 1.) -78 deg C, 2 h; 2.) -78 to 20 deg C over 2 h;81%
multistep reaction, other nitroalkenes, other ketones, synthesis of acetic nitronic anhydrides;
Yield given. Multistep reaction;
2-nitropropene
4749-28-4

2-nitropropene

α-(3-methoxyphenethyl) Meldrum's acid
1374824-27-7

α-(3-methoxyphenethyl) Meldrum's acid

(S)-5-(3-methoxyphenethyl)-2,2-dimethyl-5-(2-nitropropyl)-1,3-dioxane-4,6-dione
1374824-16-4

(S)-5-(3-methoxyphenethyl)-2,2-dimethyl-5-(2-nitropropyl)-1,3-dioxane-4,6-dione

Conditions
ConditionsYield
With (R)-2,4,6-triisopropyl-N-((2-methyl-2-morpholinopropyl)carbamoyl)benzenesulfinamide In cyclopentyl methyl ether at -30℃; Molecular sieve; Inert atmosphere; optical yield given as %ee; enantioselective reaction;81%

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