DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe
Cas:504-78-9
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Cas:504-78-9
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THIAZOLIDINE Basic information Product Name: THIAZOLIDINE Synonyms: THIAZOLIDINE;TETRAHYDROTHIAZOLE;1,3-Thiazolidine;1-Thia-3-azacyclopentane;THIAZOLIDINE TETRAHYDROTHIAZOLE;Thiazoli
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Min.Order:10 Gram
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Cas:504-78-9
Min.Order:10 Gram
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Type:Lab/Research institutions
inquiryProduct Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,
THIAZOLIDINE Chemical Properties Boiling point 72-75 °C/25 mmHg (lit.) density 1.131 g/mL at 25 °C (lit.) refractive index n20/D 1.5508(lit.) Fp 133 °F pka 8.84±0.20(Predicted) form Liquid color Clear col
factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B
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1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer
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Min.Order:1 Metric Ton
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We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp
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Cas:504-78-9
Min.Order:0
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inquiryLower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe
high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea
TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp
Conditions | Yield |
---|---|
With phosphate buffer In water at 25℃; for 0.5h; |
Conditions | Yield |
---|---|
With phosphate buffer at 25℃; for 0.5h; Mechanism; var. buffer systems; var. aldehydes; also in the presence of ethanol; |
1,3-thiazolidine
di-tert-butyl dicarbonate
tert-butyl thiazolidine-3-carboxylate
Conditions | Yield |
---|---|
In tetrahydrofuran; water at 20℃; for 20h; | 100% |
In tetrahydrofuran; water at 20℃; for 20h; Schlenk technique; | 99% |
With dmap In acetonitrile for 3h; Ambient temperature; | 89% |
In 1,4-dioxane; water | 86.2% |
Conditions | Yield |
---|---|
With potassium carbonate In water; N,N-dimethyl-formamide a) -5 deg C, 2 h, b) RT, 20 h; | 97% |
With potassium carbonate In hexane; ethyl acetate; N,N-dimethyl-formamide | 97.2% |
1,3-thiazolidine
(S)-[1-(3-hydroxyadamantan-1-yl)-2-oxo-2-pyrrolidin-1-ylethyl]-carbamic acid tert-butyl ester
(S)-[1-(3-hydroxyadamantan-1-yl)-2-oxo-2-thiazolidin-3-ylethyl]-carbamic acid tert-butyl ester
Conditions | Yield |
---|---|
With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine In DMF (N,N-dimethyl-formamide) at 0℃; for 22h; | 95.7% |
Conditions | Yield |
---|---|
In dichloromethane at 0℃; for 0.75h; | 95% |
1,3-thiazolidine
2-chloro-5-cyano-6-ethoxy-4-phenylpyridine-3-carboxaldehyde
2-Ethoxy-5-formyl-4-phenyl-6-thiazolidin-3-yl-nicotinonitrile
Conditions | Yield |
---|---|
With triethylamine In tetrahydrofuran for 0.166667h; Heating; | 93% |
Conditions | Yield |
---|---|
Stage #1: 1,3-thiazolidine; N-Boc pyroglutamic acid-Wang resin In tetrahydrofuran Addition; Stage #2: trifluoroacetic acid In water for 2.5h; Hydrolysis; | 93% |
1,3-thiazolidine
(S)-tert-butoxycarbonylamino-(trans-4-hydroxy-cyclohexyl)-acetic acid
Conditions | Yield |
---|---|
Stage #1: (S)-tert-butoxycarbonylamino-(trans-4-hydroxy-cyclohexyl)-acetic acid With 4-methyl-morpholine; 2-chloro-4,6-dimethoxy-1 ,3,5-triazine In Isopropyl acetate at 0℃; for 2h; Stage #2: 1,3-thiazolidine In Isopropyl acetate at 0 - 20℃; for 18h; | 93% |
With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In tetrahydrofuran at 20℃; for 12h; |
1,3-thiazolidine
3-((2R,3S,4R,5R,6R)-3,4,5-Triacetoxy-6-acetoxymethyl-tetrahydro-pyran-2-yl)-propionic acid pentafluorophenyl ester
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 0℃; | 92% |
Conditions | Yield |
---|---|
In dichloromethane at 0℃; for 0.75h; | 92% |
With triethylamine In dichloromethane |
1,3-thiazolidine
(E)-β-methylcinnamaldehyde
Conditions | Yield |
---|---|
Stage #1: (E)-β-methylcinnamaldehyde With 1,4-diaza-bicyclo[2.2.2]octane; 1H-imidazole; BF4(1-)*C21H22N3O(1+); 1,1'-biphenyl-2,2'-diyl hydrogen phosphate In toluene at 40℃; for 14h; Molecular sieve; Sealed tube; Inert atmosphere; Stage #2: 1,3-thiazolidine In toluene at 20℃; for 10h; Molecular sieve; Sealed tube; Inert atmosphere; enantioselective reaction; | 92% |
1,3-thiazolidine
di-tert-butyl dicarbonate
1-aminocyclohexanecarboxylic acid benzyl ester
Conditions | Yield |
---|---|
Stage #1: di-tert-butyl dicarbonate; 1-aminocyclohexanecarboxylic acid benzyl ester With dmap In dichloromethane at 20℃; for 0.666667h; Stage #2: 1,3-thiazolidine With triethylamine In dichloromethane at 20℃; for 19h; | 91% |
Conditions | Yield |
---|---|
With sodium carbonate | 90% |
With potassium carbonate In N,N-dimethyl-formamide at 110℃; for 4h; |
1,3-thiazolidine
Conditions | Yield |
---|---|
With potassium carbonate In 1,4-dioxane at 100℃; for 16h; | 90% |
1,3-thiazolidine
(2S,3R)-3-benzyloxycarbonylamino-2-hydroxy-4-phenyl-butanoic acid
Conditions | Yield |
---|---|
With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 4 - 20℃; | 90% |
1,3-thiazolidine
(S)-3-(4-((((9H-fluoren-9-yl)methoxy)carbonyl)amino)phenyl)-2-((tert-butoxycarbonyl)amino)propanoic acid
C32H35N3O5S
Conditions | Yield |
---|---|
With N-(3-dimethylaminopropyl)-N-ethylcarbodiimide In tetrahydrofuran at 0 - 20℃; for 8h; | 90% |
1,3-thiazolidine
(S)-1-tert-butyl 2-methyl 4-oxopyrrolidine-1,2-dicarboxylate
(2S)-4-oxo-2-(3-thiazolidinylcarbonyl)-1-pyrrolidinecarboxylic acid tert-butyl ester
Conditions | Yield |
---|---|
With acetic acid In methanol at 0 - 30℃; for 2.5h; Large scale; | 90% |
1,3-thiazolidine
(R)-7-[3-tertbutoxycarbonylamino-4-(2,4,5-tri-fluorophenyl)butyryl]-3-trifluoromethyl-5,6,7,8-tetrahydro-imidazo[1,5-a]pyrazine-1-carboxylic acid
(R)-[3-oxo-3-[1-(thiazolidine-3-carbonyl)-3-trifluoromethyl-5,6-dihydro-8H-imidazo[1,5-a]pyrazin-7-yl]-1-(2,4,5-trifluoro-benzyl)-propyl]-carbamic acid tert-butyl ester
Conditions | Yield |
---|---|
With bis-(2-oxo-3-oxazolidinyl)phosphoryl chloride; triethylamine In dichloromethane at 20℃; for 2h; | 89% |
1,3-thiazolidine
carbon disulfide
2,3-bis(chloromethyl)-1,4-naphthoquinone
Conditions | Yield |
---|---|
Stage #1: 1,3-thiazolidine; carbon disulfide In acetonitrile at 20℃; for 0.5h; Stage #2: 2,3-bis(chloromethyl)-1,4-naphthoquinone In acetonitrile at 20℃; for 48h; | 88.8% |
1,3-thiazolidine
1-Naphthylacetyl-thioproline
(1-Naphthyl)acetyl-Thiopro-thiazolidine
Conditions | Yield |
---|---|
With dicyclohexyl-carbodiimide | 88% |
1,3-thiazolidine
(3S)-2-tert-butoxycarbonyl-1,2,3,4-tetrahydroisoquinole-3-carboxylic acid
3-(thiazolidine-3-carbonyl)-3,4-dihydro-1H-isoquinoline-2-carboxylic acid tert-butyl ester
Conditions | Yield |
---|---|
With benzotriazol-1-ol; dicyclohexyl-carbodiimide In dichloromethane; N,N-dimethyl-formamide at 20℃; for 1.5h; | 88% |
1,3-thiazolidine
phenylbutyric acid chloride
N-(4-phenylbutanoyl)thiazolidine
Conditions | Yield |
---|---|
With sodium chloride; triethylamine In dichloromethane | 88% |
1,3-thiazolidine
S-6-bromohexanoic acid N-α-methylbenzylamide
S-6-(3-thiazolidinyl)hexanoic acid N-α-methylbenzylamide
Conditions | Yield |
---|---|
With triethylamine In isopropyl alcohol for 6h; Heating; | 87% |
1,3-thiazolidine
R-6-bromohexanoic acid N-α-methylbenzylamide
R-6-(3-thiazolidinyl)hexanoic acid N-α-methylbenzylamide
Conditions | Yield |
---|---|
With triethylamine In isopropyl alcohol for 6h; Heating; | 87% |
1,3-thiazolidine
(2S,4S)-1-tert-butoxycarbonyl-4-ethoxycarbonyl-2-pyrrolidinecarboxylic acid
1-tert-butyl 3-ethyl (3S,5S)-5-(1,3-thiazolidin-3-ylcarbonyl)-1,3-pyrrolidinedicarboxylate
Conditions | Yield |
---|---|
With 4-methyl-morpholine; benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; for 19h; | 86% |
Conditions | Yield |
---|---|
With N-(3-dimethylaminopropyl)-N-ethylcarbodiimide In tetrahydrofuran at 0 - 20℃; for 4h; | 86% |
1,3-thiazolidine
N-tert-butoxycarbonyl-4-oxo-L-proline
(2S)-4-oxo-2-(3-thiazolidinylcarbonyl)-1-pyrrolidinecarboxylic acid tert-butyl ester
Conditions | Yield |
---|---|
With 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane-2,4,6-trioxide; N-ethyl-N,N-diisopropylamine In ethyl acetate at 2 - 7℃; for 2h; Large scale; | 86% |
Stage #1: N-tert-butoxycarbonyl-4-oxo-L-proline With pivaloyl chloride; N-ethyl-N,N-diisopropylamine In ethyl acetate at 10℃; for 0.5h; Large scale; Stage #2: 1,3-thiazolidine In ethyl acetate at 0 - 10℃; for 1h; Reagent/catalyst; Temperature; Solvent; Large scale; | 86% |
Stage #1: N-tert-butoxycarbonyl-4-oxo-L-proline With dicyclohexyl-carbodiimide In toluene at -10 - -5℃; Stage #2: 1,3-thiazolidine With dmap In toluene at -6 - 5℃; for 1.33333h; | 81.7% |
With dmap; dicyclohexyl-carbodiimide In toluene at -6 - 5℃; for 1.33333h; | 81.7% |
Stage #1: N-tert-butoxycarbonyl-4-oxo-L-proline With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In toluene at 0℃; for 3h; Large scale; Stage #2: 1,3-thiazolidine With dmap at 0℃; for 2h; Reagent/catalyst; Large scale; | 50 kg |
Conditions | Yield |
---|---|
With N-ethyl-N,N-diisopropylamine; N-[(dimethylamino)-3-oxo-1H-1,2,3-triazolo[4,5-b]pyridin-1-yl-methylene]-N-methylmethanaminium hexafluorophosphate In N,N-dimethyl-formamide at 20℃; for 18h; | 85% |
Conditions | Yield |
---|---|
With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine In N,N-dimethyl-formamide at 20℃; for 24h; | 83% |
Conditions | Yield |
---|---|
With potassium carbonate In ethanol | 82% |
1,3-thiazolidine
(S)-{trans-4-[(3-amino-pyrazine-2-carbonyl)-amino]-cyclohexyl}-tert-butoxycarbonylamino-acetic acid
(S)-(1-{trans-4-[(3-amino-pyrazine-2-carbonyl)-amino]-cyclohexyl}-2-oxo-2-thiazolidin-3-yl-ethyl)-carbamic acid tert-butyl ester
Conditions | Yield |
---|---|
With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; for 4h; | 82% |
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