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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

2-Benzylacrylic acid Manufacturer/High quality/Best price/In stock

Cas:5669-19-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2-Benzylacrylic acid supplier in China

Cas:5669-19-2

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Wuhan Fortuna Chemical Co.,Ltd

Factory supply 2-Benzylacrylic acid CAS 5669-19-2 with high purity Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Food/Feed ad

Factory supply 2-Benzylacrylic acid CAS 5669-19-2 with high purity

Cas:5669-19-2

Min.Order:10 Kilogram

FOB Price: $10.0

Type:Trading Company

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2-Benzylacrylic acid

Cas:5669-19-2

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Benzylacrylic acid

Cas:5669-19-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com/pro01en/id/618.html Product Name

2-Benzylacrylic acid

Cas:5669-19-2

Min.Order:1 Gram

FOB Price: $63.0

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

TIANFUCHEM--5669-19-2--2-Benzylacrylic acid in stock Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had established stable business relati

TIANFUCHEM--5669-19-2--2-Benzylacrylic acid in stock

Cas:5669-19-2

Min.Order:1 Metric Ton

FOB Price: $2000.0

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

High Quality 2-Benzylacry Lic Acid / Benzyl Acry Lic Acid / CAS 5669-19-2

Cas:5669-19-2

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 5669-19-2 with best quality

Cas:5669-19-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

2-Benzylacrylic acid/ LIDE PHARMA- Factory supply / Best price

Cas:5669-19-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:White Crystalline Powder Storage:Store in sealed conta

high quality 5669-19-2 2-Benzylacrylic acid with best price

Cas:5669-19-2

Min.Order:10 Gram

Negotiable

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzenepropanoicacid, a-methylene- 5669-19-2

Cas:5669-19-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Changchun Artel lmport and Export trade company

Price, service, company and transport advantage: 1.place of origin china with super quality by reasonable price. 2. it's customers' right to choose the package (ems, dhl, fedex, ups); 3. it's customers' right to

BEST PRICE/supply 2-Benzylacrylic acid CAS NO.5669-19-2

Cas:5669-19-2

Min.Order:100 Gram

Negotiable

Type:Trading Company

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzenepropanoicacid, a-methylene-

Cas:5669-19-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Lonwin Chemical Group Limited

2-BenzylAcrylicAcid CAS: 5669-19-2 Specification Item Specification Appearance White Powder Assay 98%min Density 1.120 Melting Point 66-68 °C Welcome to contact us to get c

Factory supply 2-BenzylAcrylicAcid

Cas:5669-19-2

Min.Order:1 Kilogram

Negotiable

Type:Other

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzenepropanoicacid, a-methylene-

Cas:5669-19-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou JINLAN Pharm-Drugs Technology Co., Ltd

Specification:USP/EP Month production ablity:50kg/Month Low price& High quality Manufacturer Appearance:white powder Storage:Room Temperature Application:5669-19-2

2-BenzylAcrylicAcid

Cas:5669-19-2

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We have s

2-Benzylacrylic acid

Cas:5669-19-2

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

cas 5669-19-2 2-Benzylacrylic acid

Cas:5669-19-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2-Benzylacrylic acid

Cas:5669-19-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

2-BENZYLACRYLIC ACID

Cas:5669-19-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Benzenepropanoicacid, a-methylene-

Cas:5669-19-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

2-Benzylacrylic acid

Cas:5669-19-2

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:white powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:10g/bag,or as your request Application:For medicine , pesticide intermediates Tran

2-Benzylacrylic acid

Cas:5669-19-2

Min.Order:1 Gram

Negotiable

Type:Trading Company

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

2-Benzylacrylic acid

Cas:5669-19-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

2-Benzylacrylicacid

Cas:5669-19-2

Min.Order:1 Milligram

Negotiable

Type:Trading Company

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Shanghai Minstar Chemical Co., Ltd

2-Benzylacrylic acid Chemical Properties Melting point 66-68 °C Boiling point 170-174 °C(Press: 20 Torr) density 1.120 pka 4.48±0.11(Predicted) CAS DataBase Reference 5669-19-2(CAS DataBase Reference)

2-Benzylacrylic Acid

Cas:5669-19-2

Min.Order:1 Gram

FOB Price: $66.0

Type:Lab/Research institutions

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EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

2-Benzylacrylic acid

Cas:5669-19-2

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

2-Benzylacrylic acid

Cas:5669-19-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Huarong Pharm Co., Ltd.

Hangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu

2-Benzylacrylic Acid

Cas:5669-19-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

2-Benzylacrylic acid ethyl ester
20593-63-9

2-Benzylacrylic acid ethyl ester

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

Conditions
ConditionsYield
With lithium hydroxide In tetrahydrofuran; water for 15h; Heating;100%
With ethanol; sodium hydroxide In dichloromethane at 10 - 20℃; for 3.5h; Time; Reflux;92.8%
With potassium hydroxide In methanol for 18h;80%
formaldehyd
50-00-0

formaldehyd

2-benzylmalonic acid
616-75-1

2-benzylmalonic acid

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

Conditions
ConditionsYield
With diethylamine for 5h; Mannich reaction;98%
With diethylamine In ethyl acetate at 0℃; for 3h; Reflux;90%
With diethylamine In ethyl acetate for 4h; Inert atmosphere; Reflux;87%
2-benzylmalonic acid
616-75-1

2-benzylmalonic acid

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

Conditions
ConditionsYield
Stage #1: 2-benzylmalonic acid With formaldehyd; diethylamine In ethyl acetate at 0 - 20℃; for 1.5h; Heating / reflux;
Stage #2: With hydrogenchloride; water at 10℃;
90%
Stage #1: 2-benzylmalonic acid With formaldehyd; diethylamine In ethyl acetate
Stage #2: With potassium hydroxide
Multi-step reaction with 2 steps
1: concentrated ammonia
View Scheme
(Z)-3-Phenyl-2-trimethylsilanylmethyl-acrylic acid ethyl ester
109481-98-3

(Z)-3-Phenyl-2-trimethylsilanylmethyl-acrylic acid ethyl ester

A

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

B

2-methyl-3-phenylacrylic acid
1895-97-2

2-methyl-3-phenylacrylic acid

Conditions
ConditionsYield
With potassium hydroxide; water In methanol for 3h; Reflux;A 12%
B 87%
(2-Methoxycarbonyl-3-phenyl-propyl)-trimethyl-ammonium; iodide

(2-Methoxycarbonyl-3-phenyl-propyl)-trimethyl-ammonium; iodide

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

Conditions
ConditionsYield
With sodium hydroxide at 100℃; for 2h;80%
5-benzyl-5-hydroxymethyl-2,2-dimethyl-[1,3]dioxane-4,6-dione
358382-80-6

5-benzyl-5-hydroxymethyl-2,2-dimethyl-[1,3]dioxane-4,6-dione

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

Conditions
ConditionsYield
With hydrogen bromide In water; acetic acid for 2h; Heating;76%
diethyl 2-benzyl-2(hydroxymethyl)malonate

diethyl 2-benzyl-2(hydroxymethyl)malonate

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

Conditions
ConditionsYield
With hydrogen bromide; acetic acid at 90℃; for 18h;72.4%
With hydrogen bromide; acetic acid In water at 80℃; for 72h;
benzylacrylate
2495-35-4

benzylacrylate

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

Conditions
ConditionsYield
With potassium hydroxide In methanol66%
methyl 2-benzylacrylate
3070-71-1

methyl 2-benzylacrylate

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

Conditions
ConditionsYield
With sodium hydroxide In methanol for 20h; Ambient temperature;65%
With potassium hydroxide In ethanol Heating;
With lithium hydroxide monohydrate; water In tetrahydrofuran at 70℃; for 3h;
(Z)-3-Phenyl-2-trimethylsilanylmethyl-acrylic acid ethyl ester
109481-98-3

(Z)-3-Phenyl-2-trimethylsilanylmethyl-acrylic acid ethyl ester

A

(2Z)-3-phenyl-2-[(trimethylsilyl)methyl]prop 2-enoic acid
1039704-09-0

(2Z)-3-phenyl-2-[(trimethylsilyl)methyl]prop 2-enoic acid

B

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

C

2-methyl-3-phenylacrylic acid
1895-97-2

2-methyl-3-phenylacrylic acid

Conditions
ConditionsYield
With potassium hydroxide; water In methanol for 0.333333h; Reflux;A 19%
B 13%
C 64%
α-benzylacrylonitrile
28769-48-4

α-benzylacrylonitrile

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

Conditions
ConditionsYield
With sulfuric acid In water at 130℃; for 15h;62%
With hydrogenchloride
With potassium hydroxide In 2-ethoxy-ethanol Heating;
2-benzyl-2-propenal
30457-88-6

2-benzyl-2-propenal

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

Conditions
ConditionsYield
With sodium chlorite; sodium phosphate In water; tert-butyl alcohol at 20℃; for 0.5h;36%
2-methylenesuccinic acid
97-65-4

2-methylenesuccinic acid

benzene diazonium chloride
100-34-5

benzene diazonium chloride

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

Conditions
ConditionsYield
With water; sodium acetate; copper dichloride Bestrahlen des Reaktionsprodukts in Gegenwart von Brom in Aether und CHCl3;
benzyl-piperidinomethyl-malonic acid
861356-96-9

benzyl-piperidinomethyl-malonic acid

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

aminomethyl-benzyl-malonic acid
408308-23-6

aminomethyl-benzyl-malonic acid

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

Conditions
ConditionsYield
With water
benzyl-methoxymethyl-malonic acid
69858-92-0

benzyl-methoxymethyl-malonic acid

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

Conditions
ConditionsYield
With hydrogenchloride
With sulfuric acid at 170 - 175℃;
benzyl-methylaminomethyl-malonic acid
408308-33-8

benzyl-methylaminomethyl-malonic acid

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

2-benzyl-2-carboxy-3-(dimethylamino)propionic acid
24643-58-1

2-benzyl-2-carboxy-3-(dimethylamino)propionic acid

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

Conditions
ConditionsYield
Thermolysis;
beim Schmelzen im Vakuum;
allylaminomethyl-benzyl-malonic acid

allylaminomethyl-benzyl-malonic acid

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

benzyl-methanesulfonylmethyl-malonic acid diethyl ester
855653-03-1

benzyl-methanesulfonylmethyl-malonic acid diethyl ester

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

Conditions
ConditionsYield
With sodium hydroxide
2,2'-dibenzyl-2,2'-(2-aza-propanediyl)-di-malonic acid
871882-45-0

2,2'-dibenzyl-2,2'-(2-aza-propanediyl)-di-malonic acid

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

2-(1-Benzyl-vinyl)-4,4-dimethyl-4,5-dihydro-oxazole
78763-98-1

2-(1-Benzyl-vinyl)-4,4-dimethyl-4,5-dihydro-oxazole

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

Conditions
ConditionsYield
With hydrogenchloride; water; acetic acid Heating; Yield given;
(+-)-2-benzyl-2-methanesulfonylmethyl-3-oxo-butyric acid ethyl ester

(+-)-2-benzyl-2-methanesulfonylmethyl-3-oxo-butyric acid ethyl ester

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

Conditions
ConditionsYield
With potassium hydroxide
methylammonium carbonate
15719-64-9, 15719-76-3, 97762-63-5

methylammonium carbonate

<β-bromo-allyl>-benzene

<β-bromo-allyl>-benzene

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

Conditions
ConditionsYield
With diethyl ether; magnesium
methoxymethyl-benzyl-malonic acid ester

methoxymethyl-benzyl-malonic acid ester

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

Conditions
ConditionsYield
With hydrogenchloride; water; acetic acid
hydrogenchloride
7647-01-0

hydrogenchloride

benzyl-methoxymethyl-malonic acid
69858-92-0

benzyl-methoxymethyl-malonic acid

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

hydrogenchloride
7647-01-0

hydrogenchloride

benzyl-methoxymethyl-malonic acid diethyl ester
69858-85-1

benzyl-methoxymethyl-malonic acid diethyl ester

water
7732-18-5

water

acetic acid
64-19-7

acetic acid

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

disodium carbaprephenate

disodium carbaprephenate

A

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

B

C11H8O4(2-)*2Na(1+)

C11H8O4(2-)*2Na(1+)

Conditions
ConditionsYield
With 50 mmol/l Tris*HCl buffer; Bacillus subtilis chorismate mutase at 30℃; pH=8.6; Product distribution; Further Variations:; Reagents;
diethyl 2-benzylmalonate
607-81-8

diethyl 2-benzylmalonate

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: KOH / aq. methanol
2.1: p-formaldehyde; diethylamine / ethyl acetate
2.2: aq. KOH
View Scheme
Multi-step reaction with 2 steps
1: KOH / ethanol / 4 h / 0 - 20 °C
2: Et3N / H2O / Heating
View Scheme
Multi-step reaction with 2 steps
1: water; potassium hydroxide / ethanol / 10 h / 20 °C
2: dimethyl amine / Reflux
View Scheme
Multi-step reaction with 2 steps
1: sodium hydroxide; water / 5 h / Reflux
2: diethylamine / ethyl acetate / 3 h / 0 °C / Reflux
View Scheme
Multi-step reaction with 2 steps
1: sodium hydroxide / methanol; water / 20 °C / Inert atmosphere
2: diethylamine / ethyl acetate / 4 h / Inert atmosphere; Reflux
View Scheme
methanol
67-56-1

methanol

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

methyl 2-benzylacrylate
3070-71-1

methyl 2-benzylacrylate

Conditions
ConditionsYield
With thionyl chloride at 0 - 20℃; for 18h;100%
With boron trifluoride diethyl etherate for 14h; Heating;94%
2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

diazomethyl-trimethyl-silane
18107-18-1

diazomethyl-trimethyl-silane

methyl 2-benzylacrylate
3070-71-1

methyl 2-benzylacrylate

Conditions
ConditionsYield
In methanol; hexane; benzene at 20℃; for 0.5h;100%
89%
2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

2-benzylpropenoyl chloride
88320-94-9

2-benzylpropenoyl chloride

Conditions
ConditionsYield
With oxalyl dichloride; N,N-dimethyl-formamide In dichloromethane for 1.5h;100%
With oxalyl dichloride; N,N-dimethyl-formamide In dichloromethane at 0 - 15℃; for 2h; Solvent; Temperature; Reagent/catalyst; Industrial scale;99.4%
With thionyl chloride at 20℃; for 3h;96%
2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

thioacetic acid
507-09-5

thioacetic acid

3-acetylthio-2-benzylpropanoic acid
91702-98-6

3-acetylthio-2-benzylpropanoic acid

Conditions
ConditionsYield
In dichloromethane for 1152h;99%
In tetrahydrofuran Heating;96%
In benzene Heating;77%
2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

2-methyl-3-phenylpropionic acid
14367-67-0

2-methyl-3-phenylpropionic acid

Conditions
ConditionsYield
With C54H72IrNP(1+)*C32H12BF24(1-); hydrogen; caesium carbonate In methanol at 45℃; under 4500.45 Torr; for 0.25h; Pressure; Glovebox;99%
With disodium hydrogen phosphite pentahydrate; phosphite dehydrogenase; water; nicotinamide adenine dinucleotide phosphate; ene-reductase 36 at 25℃; pH=6.5; Catalytic behavior; Reagent/catalyst; pH-value; Temperature; Enzymatic reaction; enantioselective reaction;99%
With C32H12BF24(1-)*C54H71IrNP(1+); hydrogen; caesium carbonate In methanol at 45℃; for 4h; optical yield given as %ee; enantioselective reaction;98%
Stage #1: 2-Benzyl-2-propenoic acid With hydrogen; caesium carbonate; [(Sa-DTB-SIPHOX)Ir(COD)]BARF In methanol at 20℃; under 4500.45 Torr; for 12h;
Stage #2: With hydrogenchloride In water pH=< 3; Product distribution / selectivity;
94%
2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

2-methyl-3-phenylpropionic acid
1009-67-2, 5628-72-8, 14367-54-5, 14367-67-0

2-methyl-3-phenylpropionic acid

Conditions
ConditionsYield
With C48H50Cl4N2O2P2Ru3; hydrogen; sodium hydrogencarbonate In methanol at 20℃; under 3750.38 Torr; for 24h; Autoclave; enantioselective reaction;99%
2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

2-(phenyl-λ3-iodaneylidene)cyclohexane-1,3-dione
86396-02-3

2-(phenyl-λ3-iodaneylidene)cyclohexane-1,3-dione

3-benzyl-7,8-dihydro-2H-chromene-2,5(6H)-dione
1000697-64-2

3-benzyl-7,8-dihydro-2H-chromene-2,5(6H)-dione

Conditions
ConditionsYield
With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; sodium acetate at 80℃; for 12h; Catalytic behavior; Mechanism; Temperature; Reagent/catalyst; Sealed tube;99%
With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; sodium acetate at 80℃; for 9h; Temperature; Reagent/catalyst;99%
2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

(2,6-dioxo-4-phenylcyclohexyl)phenyliodonium inner salt
86396-05-6

(2,6-dioxo-4-phenylcyclohexyl)phenyliodonium inner salt

3-benzyl-7-phenyl-7,8-dihydro-2H-chromene-2,5(6H)-dione

3-benzyl-7-phenyl-7,8-dihydro-2H-chromene-2,5(6H)-dione

Conditions
ConditionsYield
With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; sodium acetate at 80℃; for 12h;98%
2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

thioacetic acid
507-09-5

thioacetic acid

2-acetylthio-3-phenyl-propionic acid
149603-85-0

2-acetylthio-3-phenyl-propionic acid

Conditions
ConditionsYield
In CaCl295%
2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

2-hydroxy-N,N-diiso-propylbenzamide
82860-53-5

2-hydroxy-N,N-diiso-propylbenzamide

2-(N,N-diisopropylcarbamoyl)phenyl 2-methylene-3-phenylpropionate

2-(N,N-diisopropylcarbamoyl)phenyl 2-methylene-3-phenylpropionate

Conditions
ConditionsYield
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In toluene at 80℃; for 9h;95%
2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

diphenyl acetylene
501-65-5

diphenyl acetylene

3-benzyl-5,6-diphenyl-2H-pyran-2-one

3-benzyl-5,6-diphenyl-2H-pyran-2-one

Conditions
ConditionsYield
With bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; tetrabutylammonium acetate In methanol at 60℃; for 12h; Electrochemical reaction;95%
With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; silver carbonate at 80℃; for 8h;60%
2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

N-(cyclopentylsulfinyl)benzamide

N-(cyclopentylsulfinyl)benzamide

2-benzyl-3-cyclopentylpropanoic acid

2-benzyl-3-cyclopentylpropanoic acid

Conditions
ConditionsYield
With dipotassium hydrogenphosphate; [Ir(ppy)2(dtbbpy)]PF6 In acetone at 0 - 40℃; for 6h; Michael Addition; Inert atmosphere; Irradiation;93%
2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

1-(prop-2-yn-1-yloxy)-(1,1'-biphenyl)-4(1H)-one

1-(prop-2-yn-1-yloxy)-(1,1'-biphenyl)-4(1H)-one

(Z)-2-benzyl-4-((E)-5-oxo-7a-phenyl-3a,4,5,7a-tetrahydrobenzofuran-3(2H)-ylidene)but-2-enoic acid

(Z)-2-benzyl-4-((E)-5-oxo-7a-phenyl-3a,4,5,7a-tetrahydrobenzofuran-3(2H)-ylidene)but-2-enoic acid

Conditions
ConditionsYield
With Cp*Rh(OAc)2·H2O In 1,2-dichloro-ethane at 60℃; for 9h; stereoselective reaction;92%
2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

1-(prop-2-yn-1-yloxy)-(1,1'-biphenyl)-4(1H)-one

1-(prop-2-yn-1-yloxy)-(1,1'-biphenyl)-4(1H)-one

C20H20O4

C20H20O4

Conditions
ConditionsYield
With (pentamethylcyclopentadienyl)*Rh(OAc)2 In 1,2-dichloro-ethane at 60℃; for 9h;92%
2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

2,4-dimethyl-4-(prop-2-yn-1-yloxy)cyclohexa-2,5-dien-1-one

2,4-dimethyl-4-(prop-2-yn-1-yloxy)cyclohexa-2,5-dien-1-one

(Z)-2-benzyl-4-((E)-6,7a-dimethyl-5-oxo-3a,4,5,7a-tetrahydrobenzofuran-3(2H)-ylidene)but-2-enoic acid

(Z)-2-benzyl-4-((E)-6,7a-dimethyl-5-oxo-3a,4,5,7a-tetrahydrobenzofuran-3(2H)-ylidene)but-2-enoic acid

Conditions
ConditionsYield
With Cp*Rh(OAc)2·H2O In 1,2-dichloro-ethane at 60℃; for 9h; stereoselective reaction;91%
2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

4'-bromo-1-(prop-2-yn-1-yloxy)-[1,1'-biphenyl]-4(1H)-one

4'-bromo-1-(prop-2-yn-1-yloxy)-[1,1'-biphenyl]-4(1H)-one

(Z)-2-benzyl-4-((E)-7a-(4-bromophenyl)-5-oxo-3a,4,5,7a-tetrahydrobenzofuran-3(2H)-ylidene)but-2-enoic acid

(Z)-2-benzyl-4-((E)-7a-(4-bromophenyl)-5-oxo-3a,4,5,7a-tetrahydrobenzofuran-3(2H)-ylidene)but-2-enoic acid

Conditions
ConditionsYield
With Cp*Rh(OAc)2·H2O In 1,2-dichloro-ethane at 60℃; for 9h; stereoselective reaction;91%
2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

2,4-dimethyl-4-(prop-2-yn-1-yloxy)cyclohexa-2,5-dien-1-one

2,4-dimethyl-4-(prop-2-yn-1-yloxy)cyclohexa-2,5-dien-1-one

C21H22O4

C21H22O4

Conditions
ConditionsYield
With (pentamethylcyclopentadienyl)*Rh(OAc)2 In 1,2-dichloro-ethane at 60℃; for 9h;91%
2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

2-methyl-3-phenylpropanoic acid
1009-67-2

2-methyl-3-phenylpropanoic acid

Conditions
ConditionsYield
With phenylsilane; C12H23N2O2P In tetrahydrofuran at 23℃; for 2h;91%
With hydrogen
2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

2-benzyl-3-(hydroxyhydrophosphoryl)propanoic acid
865703-11-3

2-benzyl-3-(hydroxyhydrophosphoryl)propanoic acid

Conditions
ConditionsYield
With bis(trimethylsilyl)phosphonite In dichloromethane at 0 - 20℃; for 25h; Inert atmosphere;91%
thioacetic acid
507-09-5

thioacetic acid

2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

3-acetylthio-2-benzylpropanoic acid
91702-98-6

3-acetylthio-2-benzylpropanoic acid

Conditions
ConditionsYield
at 100℃; for 2h;90%
2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

7-methyl-7-(prop-2-yn-1-yloxy)-1,2,3,7-tetrahydro-4H-inden-4-one

7-methyl-7-(prop-2-yn-1-yloxy)-1,2,3,7-tetrahydro-4H-inden-4-one

(2Z,4E)-2-benzyl-4-(8b-methyl-5-oxo-4,5,6,7,8,8b-hexahydro-2H-indeno[4,5-b]furan-3(3aH)-ylidene)but-2-enoic acid

(2Z,4E)-2-benzyl-4-(8b-methyl-5-oxo-4,5,6,7,8,8b-hexahydro-2H-indeno[4,5-b]furan-3(3aH)-ylidene)but-2-enoic acid

Conditions
ConditionsYield
With Cp*Rh(OAc)2·H2O In 1,2-dichloro-ethane at 60℃; for 9h; stereoselective reaction;90%
2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

7-methyl-7-(prop-2-yn-1-yloxy)-1,2,3,7-tetrahydro-4H-inden-4-one

7-methyl-7-(prop-2-yn-1-yloxy)-1,2,3,7-tetrahydro-4H-inden-4-one

C23H24O4

C23H24O4

Conditions
ConditionsYield
With (pentamethylcyclopentadienyl)*Rh(OAc)2 In 1,2-dichloro-ethane at 60℃; for 9h;90%
2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

(2,6-dioxo-4-methylcyclohexyl)phenyliodonium inner salt
86396-03-4

(2,6-dioxo-4-methylcyclohexyl)phenyliodonium inner salt

3-benzyl-7-methyl-7,8-dihydro-2H-chromene-2,5(6H)-dione

3-benzyl-7-methyl-7,8-dihydro-2H-chromene-2,5(6H)-dione

Conditions
ConditionsYield
With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; sodium acetate at 80℃; for 12h;90%
2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

2-benzyl-N-[(1S,2R)-2-hydroxy-indan-1-yl]acrylamide
872703-52-1

2-benzyl-N-[(1S,2R)-2-hydroxy-indan-1-yl]acrylamide

Conditions
ConditionsYield
With (benzotriazo-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate; triethylamine89%
Stage #1: 2-Benzyl-2-propenoic acid With 4-methyl-morpholine; benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In ethyl acetate at 20℃; for 0.5h;
Stage #2: (1S,2R)-1-amino-2-indanol In ethyl acetate at 20℃;
68%
2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

4-butyl-4-(prop-2-yn-1-yloxy)cyclohexa-2,5-dien-1-one

4-butyl-4-(prop-2-yn-1-yloxy)cyclohexa-2,5-dien-1-one

(Z)-2-benzyl-4-((E)-7a-butyl-5-oxo-3a,4,5,7a-tetrahydrobenzofuran-3(2H)-ylidene)but-2-enoic acid

(Z)-2-benzyl-4-((E)-7a-butyl-5-oxo-3a,4,5,7a-tetrahydrobenzofuran-3(2H)-ylidene)but-2-enoic acid

Conditions
ConditionsYield
With Cp*Rh(OAc)2·H2O In 1,2-dichloro-ethane at 60℃; for 9h; stereoselective reaction;88%
2-Benzyl-2-propenoic acid
5669-19-2

2-Benzyl-2-propenoic acid

tert-butyl 4-(benzamidosulfinyl)piperidine-1-carboxylate

tert-butyl 4-(benzamidosulfinyl)piperidine-1-carboxylate

2-benzyl-3-(1-(tert-butoxycarbonyl)piperidin-4-yl)propanoic acid

2-benzyl-3-(1-(tert-butoxycarbonyl)piperidin-4-yl)propanoic acid

Conditions
ConditionsYield
With dipotassium hydrogenphosphate; [Ir(ppy)2(dtbbpy)]PF6 In acetone at 0 - 40℃; for 5h; Michael Addition; Inert atmosphere; Irradiation;87%

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