CAS No.5821-51-2,Corannulene Suppliers

Henan Allgreen Chemical Co.,Ltd

he company has advanced technology, as well as a large number of excellent R & D team, to provide customers from the grams to one hundred kilograms and tons of high-quality products, competitive prices and quality se T rvice Appearance:Whit

Corannulene

Cas:5821-51-2

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Corannulene

Cas:5821-51-2

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 5821-51-2 with competitive price

Cas:5821-51-2

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Corannulene

Cas:5821-51-2

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Wuhan Xinhao Biotechnology Co., Ltd.

1. We can provide customers with "one-stop"packaging service,from research,development,production,export and so on 2. Powerful R&D strength let our technology in a leading level,forever,in turn,to provide customers with better service .

Pharmaceutical Grade CAS 5821-51-2 with competitive price CAS NO.5821-51-2

Cas:5821-51-2

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Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Corannulene

Cas:5821-51-2

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Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

5821-51-2

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Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

corannulene Cas no.5821-51-2 98%

Cas:5821-51-2

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GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Corannulene

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages? High purity, all above 98.5%, no impurities after dissolution? We will test each batch to ensure quality? OEM and private brand services designed for free? Various cap colors available? We can also provide MT1 peptide powder2.

Corannulene

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Antimex Chemical Limied

Our own factory produces direct sales with absolute price advantage Application:Pharmaceutical industry Transportation:By sea Port:Shanghai/tianjin

Propanoic acid, 2-oxo-3-phosphono-

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Hangzhou Fandachem Co.,Ltd

corannuleneAppearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:pharmaceutical intermediate Transportation:by air, by sea, by express

corannulene

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SAGECHEM LIMITED

5821-51-2 Application:intermediate

Dibenzo[ghi,mno]fluoranthene

Cas:5821-51-2

Min.Order:0

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Zibo Hangyu Biotechnology Development Co., Ltd

home-produced Application:medicine

Corannulene

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ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

Corannulene

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LEAP CHEM Co., Ltd.

Best Seller, High Quality, Competitive Price, Fast Delivery, Quick ResponseAppearance:powder, or liquid Storage:Stored in room temperature, ventilated place Package:Bottle, barrel, cargo, container, etc. Application:Pharmaceuticals, intermediates, AP

corannulene

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Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

Corannulene

Cas:5821-51-2

Min.Order:10 Milligram

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Beyond Pharmaceutical Co., Ltd

Used in medicine Application:Used in medicine

corannulene

Cas:5821-51-2

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Synthetic route

: 289721-44-4
1,2,5,6-tetrabromocorannulene

: 5821-51-2
Coarannulen

Conditions

Conditions	Yield
With hydrogenchloride; potassium iodide; zinc In ethanol for 6h; Heating;	91%
With potassium iodide; zinc In ethanol for 6h; Heating;	90%
With potassium iodide; zinc In N,N-dimethyl-formamide at 160℃; for 24 - 36h;	70%

: 138982-82-8
1,6,7,10-tetrakis(bromomethyl)fluoranthene

: 5821-51-2
Coarannulen

Conditions

Conditions	Yield
With titanium tetrachloride; copper; zinc In 1,2-dimethoxyethane for 48h;	80%
at 1000℃;	18%
Multi-step reaction with 3 steps 1: 75 percent / Na2S / acetone 2: 70 percent / H2O2, acetic acid 3: 400 °C View Scheme

: 244236-72-4
1,6,7,10-tetrakis(dibromomethyl)fluoranthene

: 5821-51-2
Coarannulen

Conditions

Conditions	Yield
With titanium tetrachloride; copper; zinc In 1,2-dimethoxyethane for 120h; Cyclization; Heating;	80%
With lithium aluminium tetrahydride; vanadium(III) chloride In 1,2-dimethoxyethane for 8h; Cyclization; Heating;	73%
Stage #1: 1,6,7,10-tetrakis(dibromomethyl)fluoranthene With sodium hydroxide In water; acetone for 1h; Reflux; Stage #2: With n-butyllithium In tetrahydrofuran at -78℃; for 0.5h;	55%

: 243853-48-7
1,3,5,7,9-pentachlorocorannulene

: 5821-51-2
Coarannulen

Conditions

Conditions	Yield
With copper(l) iodide; 1,10-Phenanthroline; caesium carbonate; tert-butyl alcohol In N,N-dimethyl-formamide at 220℃; for 2h; Microwave irradiation;	71%

: 135584-70-2
7,10-Bis-(2,2-dibromo-vinyl)-fluoranthene

: 5821-51-2
Coarannulen

Conditions

Conditions	Yield
at 1000℃;	40%
at 1000℃; under 0.6 Torr;	21%
Multi-step reaction with 2 steps 1: 80 percent / LDA / tetrahydrofuran / 5 h / -78 °C 2: 10 percent / 18 h / 1000 °C / 0.6 Torr View Scheme
Multi-step reaction with 2 steps 1: 80 percent / lithium diisopropylamide / tetrahydrofuran / 5 h / -78 °C 2: 10 percent / 1000 °C View Scheme

: 7,10-bis(1-chlorovinyl)fluoranthene

: 5821-51-2
Coarannulen

Conditions

Conditions	Yield
at 1100℃; under 1 Torr; for 24h;	39%
at 1100℃;	11.4%

: 253801-43-3
7,10-bis(trimethylsilylethynyl)fluoroanthrene

: 5821-51-2
Coarannulen

Conditions

Conditions	Yield
at 1000℃; under 0.900072 Torr; Cyclization; flash vacuum pyrolysis;	36%

: 135584-70-2
7,10-Bis-(2,2-dibromo-vinyl)-fluoranthene

A: 5821-51-2
Coarannulen

B: 138816-09-8
monobromocorannulene

C: 138816-10-1
1,6-dibromocorannulene

Conditions

Conditions	Yield
at 900℃;	A 23% B 29% C 2.4%
at 900℃; under 0.6 Torr; for 24h;	A 23% B 29% C 2.4%

...Expand

: 157729-37-8
3-(4H-cyclopentaphenanthrylidene)-1,5-bis(trimethylsilyl)-1,4-pentadiyne

A: 129-00-0
pyrene

B: 192-97-2
benzo[e]pyrene

C: 203-64-5
4H-Cyclopenta[def]phenanthrene

D: 27208-37-3
cyclopenta[c,d]pyrene

E: 203-12-3
benzo[ghi]fluoranthene

F: 5821-51-2
Coarannulen

Conditions

Conditions	Yield
With hydrogen In gas at 900℃; Product distribution; electrically heated vertical laboratory tubular furnace;	A n/a B n/a C n/a D n/a E n/a F 15%

...Expand

: 157729-37-8
3-(4H-cyclopentaphenanthrylidene)-1,5-bis(trimethylsilyl)-1,4-pentadiyne

A: 129-00-0
pyrene

B: 192-97-2
benzo[e]pyrene

C: 27208-37-3
cyclopenta[c,d]pyrene

D: 5821-51-2
Coarannulen

Conditions

Conditions	Yield
With hydrogen In gas at 900℃; electrically heated vertical laboratory tubular furnace; Further byproducts given;	A n/a B n/a C n/a D 15%

...Expand

: 135584-68-8
7,10-diethynylfluoranthene

: 5821-51-2
Coarannulen

Conditions

Conditions	Yield
at 1000℃;	10%
at 1000℃; under 0.6 Torr; for 18h;	10%

: 7,10-Bis-(1-trimethylsilanyloxy-vinyl)-fluoranthene

: 5821-51-2
Coarannulen

Conditions

Conditions	Yield
at 1000℃;	8%

: 189299-72-7
2-((E)-2-Chloro-vinyl)-benzo[c]phenanthrene

: 5821-51-2
Coarannulen

Conditions

Conditions	Yield
at 1200℃; under 0.5 Torr;	8%

: 189299-73-8
2-(1-Chloro-vinyl)-benzo[c]phenanthrene

: 5821-51-2
Coarannulen

Conditions

Conditions	Yield
at 1200℃; under 0.5 Torr;	8%

: 189299-70-5
2-ethynylbenzo[c]phenanthrene

: 5821-51-2
Coarannulen

Conditions

Conditions	Yield
at 1200℃; under 0.5 Torr;	4%

: 189299-75-0
(1-Benzo[c]phenanthren-2-yl-vinyloxy)-trimethyl-silane

: 5821-51-2
Coarannulen

Conditions

Conditions	Yield
at 1200℃; under 0.5 Torr;	4%

: 1-Hydroxy-1,2,5,6,6a,7,8,8a,9,10,10a,10b,10e,10f-tetradekahydro-dibenzo-fluoranthen

: 5821-51-2
Coarannulen

Conditions

Conditions	Yield
With palladium on activated charcoal

: 138982-84-0
C20H14O4S2

A: 5821-51-2
Coarannulen

B: 138955-80-3
5,6-dimethylbenzofluoranthene

C: 138955-78-9
1,2-dihydrocorannulene

D: 138955-79-0
C20H14

Conditions

Conditions	Yield
palladium on activated charcoal 1.) 400 deg C, 2.) xylene, reflux; Multistep reaction;
at 400℃; Yield given. Yields of byproduct given;

...Expand

: 148918-54-1
5,8-bis(1-chloroethenyl)-1,2-dihydrocyclopentafluoranthene

A: 5821-51-2
Coarannulen

B: 148918-55-2
cyclopenta[bc]corannulene

Conditions

Conditions	Yield
at 1000℃; under 1.5 Torr; Yield given. Yields of byproduct given;
at 1000℃; for 3h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
at 1000℃; for 3h; Yield given. Yields of byproduct given;

: C20H22O

: 5821-51-2
Coarannulen

Conditions

Conditions	Yield
(i) NaBH4, (ii) Pd-C; Multistep reaction;

: 18636-38-9
7,10-diethylfluoranthene

: 5821-51-2
Coarannulen

Conditions

Conditions	Yield
With N-Bromosuccinimide; dibenzoyl peroxide 1.) benzene, reflux, irradiation, 4 d, 2.) 1100 deg C, 0.5-0.6 Torr; Yield given. Multistep reaction;

: C21H10Cl2

: 110-83-8
cyclohexene

A: 1541-20-4
bicyclohexyl-2,2'-diene

B: 5821-51-2
Coarannulen

Conditions

Conditions	Yield
Product distribution; Heating;

...Expand

: 197150-83-7
7,10-diacetylfluoranthene

: 5821-51-2
Coarannulen

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 49 percent / PCl5 / CH2Cl2 / 144 h / 20 °C 2: 11.4 percent / 1100 °C View Scheme
Multi-step reaction with 2 steps 1: 83 percent / phosphorus pentachloride / toluene / 7 h / 90 - 100 °C 2: 39 percent / 24 h / 1100 °C / 1 Torr View Scheme
Multi-step reaction with 2 steps 1: 42 percent / LDA / tetrahydrofuran / 0.5 h / -78 °C / then 3 h room temperature 2: 8 percent / 1000 °C View Scheme

: 146885-80-5, 138955-77-8
1,6,7,10-tetramethylfluoranthene

: 5821-51-2
Coarannulen

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 100 percent / NBS / CCl4 / Irradiation 2: 80 percent / TiCl4; Zn-Cu / 1,2-dimethoxy-ethane / 48 h View Scheme
Multi-step reaction with 2 steps 1: 80 percent / N-bromosuccinimide (NBS) / CCl4 / 24 h / Irradiation 2: 18 percent / 1000 °C View Scheme
Multi-step reaction with 4 steps 1: 80 percent / N-bromosuccinimide (NBS) / CCl4 / 24 h / Irradiation 2: 75 percent / Na2S / acetone 3: 70 percent / H2O2, acetic acid 4: 400 °C View Scheme

: 253801-42-2
7,10-diidofluoranthrene

: 5821-51-2
Coarannulen

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 98 percent / Pd(PPh3)2Cl2; CuI; (iPr)2EtN / 0.5 h / 90 °C 2: 36 percent / 1000 °C / 0.9 Torr / flash vacuum pyrolysis View Scheme

: 253801-41-1
7,10-bis(trimethylsilyl)fluoroanthrene

: 5821-51-2
Coarannulen

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: 98 percent / ICl / CCl4 / 20 h / 25 °C 2: 98 percent / Pd(PPh3)2Cl2; CuI; (iPr)2EtN / 0.5 h / 90 °C 3: 36 percent / 1000 °C / 0.9 Torr / flash vacuum pyrolysis View Scheme

: 20852-11-3
Dimethyl-fluoranthen-7,10-dicarboxylat

: 5821-51-2
Coarannulen

Conditions

Conditions	Yield
Multi-step reaction with 4 steps 1: 95 percent / lithium aluminum hydride / tetrahydrofuran / 6 h / Ambient temperature 2: 70 percent / pyridinium chlorochromate / tetrahydrofuran / 5 h / Ambient temperature 3: 60 percent / zinc powder, triphenylphosphine / CH2Cl2 / 8 h / Ambient temperature 4: 21 percent / 1000 °C / 0.6 Torr View Scheme
Multi-step reaction with 5 steps 1: 95 percent / lithium aluminum hydride / tetrahydrofuran / 6 h / Ambient temperature 2: 70 percent / pyridinium chlorochromate / tetrahydrofuran / 5 h / Ambient temperature 3: 60 percent / zinc powder, triphenylphosphine / CH2Cl2 / 8 h / Ambient temperature 4: 80 percent / LDA / tetrahydrofuran / 5 h / -78 °C 5: 10 percent / 18 h / 1000 °C / 0.6 Torr View Scheme
Multi-step reaction with 4 steps 1: 95 percent / lithium aluminum hydride / tetrahydrofuran / 6 h / 25 °C 2: 70 percent / pyridinium chlorochromate / tetrahydrofuran / 5 h / 25 °C 3: 1.) Ph3P, Zn / 1.) CH2Cl2, 25 deg C, 36 h, 2.) CH2Cl2, a) 25 deg C, 5 h, b) reflux, 12 h 4: 40 percent / 1000 °C View Scheme
Multi-step reaction with 5 steps 1: 95 percent / lithium aluminum hydride / tetrahydrofuran / 6 h / 25 °C 2: 70 percent / pyridinium chlorochromate / tetrahydrofuran / 5 h / 25 °C 3: 1.) Ph3P, Zn / 1.) CH2Cl2, 25 deg C, 36 h, 2.) CH2Cl2, a) 25 deg C, 5 h, b) reflux, 12 h 4: 80 percent / lithium diisopropylamide / tetrahydrofuran / 5 h / -78 °C 5: 10 percent / 1000 °C View Scheme

: 135584-69-9
7,10-diformylfluoranthene

: 5821-51-2
Coarannulen

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 60 percent / zinc powder, triphenylphosphine / CH2Cl2 / 8 h / Ambient temperature 2: 21 percent / 1000 °C / 0.6 Torr View Scheme
Multi-step reaction with 3 steps 1: 60 percent / zinc powder, triphenylphosphine / CH2Cl2 / 8 h / Ambient temperature 2: 80 percent / LDA / tetrahydrofuran / 5 h / -78 °C 3: 10 percent / 18 h / 1000 °C / 0.6 Torr View Scheme
Multi-step reaction with 2 steps 1: 1.) Ph3P, Zn / 1.) CH2Cl2, 25 deg C, 36 h, 2.) CH2Cl2, a) 25 deg C, 5 h, b) reflux, 12 h 2: 40 percent / 1000 °C View Scheme
Multi-step reaction with 3 steps 1: 1.) Ph3P, Zn / 1.) CH2Cl2, 25 deg C, 36 h, 2.) CH2Cl2, a) 25 deg C, 5 h, b) reflux, 12 h 2: 80 percent / lithium diisopropylamide / tetrahydrofuran / 5 h / -78 °C 3: 10 percent / 1000 °C View Scheme

: 20852-13-5
(10-Hydroxymethyl-fluoranthen-7-yl)-methanol

: 5821-51-2
Coarannulen

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: 70 percent / pyridinium chlorochromate / tetrahydrofuran / 5 h / Ambient temperature 2: 60 percent / zinc powder, triphenylphosphine / CH2Cl2 / 8 h / Ambient temperature 3: 21 percent / 1000 °C / 0.6 Torr View Scheme
Multi-step reaction with 4 steps 1: 70 percent / pyridinium chlorochromate / tetrahydrofuran / 5 h / Ambient temperature 2: 60 percent / zinc powder, triphenylphosphine / CH2Cl2 / 8 h / Ambient temperature 3: 80 percent / LDA / tetrahydrofuran / 5 h / -78 °C 4: 10 percent / 18 h / 1000 °C / 0.6 Torr View Scheme
Multi-step reaction with 3 steps 1: 70 percent / pyridinium chlorochromate / tetrahydrofuran / 5 h / 25 °C 2: 1.) Ph3P, Zn / 1.) CH2Cl2, 25 deg C, 36 h, 2.) CH2Cl2, a) 25 deg C, 5 h, b) reflux, 12 h 3: 40 percent / 1000 °C View Scheme
Multi-step reaction with 4 steps 1: 70 percent / pyridinium chlorochromate / tetrahydrofuran / 5 h / 25 °C 2: 1.) Ph3P, Zn / 1.) CH2Cl2, 25 deg C, 36 h, 2.) CH2Cl2, a) 25 deg C, 5 h, b) reflux, 12 h 3: 80 percent / lithium diisopropylamide / tetrahydrofuran / 5 h / -78 °C 4: 10 percent / 1000 °C View Scheme

: 138982-83-9
C20H14S2

: 5821-51-2
Coarannulen

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 70 percent / H2O2, acetic acid 2: 400 °C View Scheme

: 5821-51-2
Coarannulen

: 75-36-5
acetyl chloride

: 1-acetylcorannulene

Conditions

Conditions	Yield
With aluminum (III) chloride In dichloromethane at 0 - 20℃; Friedel-Crafts Acylation; Inert atmosphere;	100%
With aluminum (III) chloride In dichloromethane at 0 - 20℃; Inert atmosphere;	94%

: 4885-02-3
Dichloromethyl methyl ether

: 5821-51-2
Coarannulen

: 695179-12-5
2-dibenzo[ghi,mno]fluoranthenecarbaldehyde

Conditions

Conditions	Yield
With titanium tetrachloride	100%
With titanium tetrachloride In dichloromethane at 0 - 20℃; for 21h; Rieche Formylation; Inert atmosphere;	95%
With titanium tetrachloride In dichloromethane at 0 - 20℃; for 21h; Inert atmosphere;	93%

: 439859-38-8, 172036-52-1
cis-[Rh(acetone)2(cyclooctene)2]PF6

: 5821-51-2
Coarannulen

: 910465-97-3
[(cyclooctene)2Rh(η6-corranulene)]PF6

Conditions

Conditions	Yield
In diethyl ether byproducts: (CH3)2CO; at room temp. for 12 h; washed, dried (vac.);	99%

: 399031-09-5
[Ir(cyclooctene)2(acetone)2][PF6]

: 5821-51-2
Coarannulen

: 910465-99-5
[(cyclooctene)2Ir(η6-corranulene)]PF6

Conditions

Conditions	Yield
In diethyl ether byproducts: (CH3)2CO; at room temp. for 12 h; washed, dried (vac.);	99%

: 26042-63-7
silver(I) hexafluorophosphate

: [RuCl2(hexamethylbenzene)]2

: 5821-51-2
Coarannulen

: [(η6-C6Me6)Ru(η6-corannulene)][PF6]2

Conditions

Conditions	Yield
In nitromethane-d3; acetone byproducts: AgCl; (Ar); Schlenk technique; Ag salt was added to soln. of Ru complex in acetone; soln. was stirred at room temp. for 10 min; filtered; corannulene (1 equiv.) was added; evapd. (vac.); dissolved in CD3NO2; stirred at 60°C for 0.5 h; concd. (vac.); Et2O added; pptd.; washed (Et2O); dried (vac.); elem. anal.;	99%

...Expand

: silver hexafluoroantimonate

: 219650-68-7
[Ru(η6-C6Me5H)Cl2]2

: 5821-51-2
Coarannulen

: [(η6-C6HMe5)Ru(η6-corannulene)][SbF6]2

Conditions

Conditions	Yield
In nitromethane-d3; acetone byproducts: AgCl; (Ar); Schlenk technique; Ag salt was added to soln. of Ru complex in acetone; soln. was stirred at room temp. for 10 min; filtered; corannulene (1 equiv.) was added; evapd. (vac.); dissolved in CD3NO2; stirred at 60°C for 0.5 h; concd. (vac.); Et2O added; pptd.; washed (Et2O); dried (vac.); elem. anal.;	99%

...Expand

: silver hexafluoroantimonate

: 934760-16-4
[(η6-C6EtMe5)RuCl2]2

: 5821-51-2
Coarannulen

: [(η6-C6EtMe5)Ru(η6-corannulene)][SbF6]2

Conditions

Conditions	Yield
In nitromethane-d3; acetone byproducts: AgCl; (Ar); Schlenk technique; Ag salt was added to soln. of Ru complex in acetone; soln. was stirred at room temp. for 10 min; filtered; corannulene (1 equiv.) was added; evapd. (vac.); dissolved in CD3NO2; stirred at 60°C for 0.5 h; concd. (vac.); Et2O added; pptd.; washed (Et2O); dried (vac.); elem. anal.;	99%

...Expand

: silver hexafluoroantimonate

: [RuCl2(hexamethylbenzene)]2

: 5821-51-2
Coarannulen

: [(η6-C6Me6)Ru(η6-corannulene)](SbF6)2

Conditions

Conditions	Yield
In nitromethane-d3; acetone byproducts: AgCl; (Ar); Schlenk technique; Ag salt was added to soln. of Ru complex in acetone; soln. was stirred at room temp. for 10 min; filtered; corannulene (1 equiv.) was added; evapd. (vac.); dissolved in CD3NO2; stirred at 60°C for 0.5 h; concd. (vac.); Et2O added; pptd.; washed (Et2O); dried (vac.); elem. anal.;	99%

...Expand

: 14104-20-2
silver tetrafluoroborate

: [RuCl2(hexamethylbenzene)]2

: 5821-51-2
Coarannulen

: [(η6-C6Me6)Ru(η6-corannulene)][BF4]2

Conditions

Conditions	Yield
In nitromethane-d3; acetone byproducts: AgCl; (Ar); Schlenk technique; Ag salt was added to soln. of Ru complex in acetone; soln. was stirred at room temp. for 10 min; filtered; corannulene (1 equiv.) was added; evapd. (vac.); dissolved in CD3NO2; stirred at 60°C for 0.5 h; concd. (vac.); Et2O added; pptd.; washed (Et2O); dried (vac.); elem. anal.;	99%

...Expand

: silver hexafluoroantimonate

: [osmium(II)dichloride(η6-p-cymene)]2

: 5821-51-2
Coarannulen

: [(η6-cymene)Os(η6-corannulene)][SbF6]2

Conditions

Conditions	Yield
In nitromethane-d3; acetone byproducts: AgCl; (Ar); Schlenk technique; Ag salt was added to soln. of Os complex in acetone; soln. was stirred at room temp. for 10 min; filtered; corannulene (1 equiv.) was added; evapd. (vac.); dissolved in CD3NO2; stirred at 60°C for 0.5 h; concd. (vac.); Et2O added; pptd.; washed (Et2O); dried (vac.); elem. anal.;	99%

...Expand

: 7065-46-5
3,3-dimethylbutanoic acid chloride

: 5821-51-2
Coarannulen

: 1073651-82-7
(3,3-dimethylbutan-1-on-1-yl)corannulene

Conditions

Conditions	Yield
With aluminum (III) chloride In dichloromethane at -78 - 0℃; for 1.5h; Friedel Crafts acylation; Inert atmosphere;	99%

: 5821-51-2
Coarannulen

: 138816-09-8
monobromocorannulene

Conditions

Conditions	Yield
With bromine In dichloromethane at -80 - 20℃; for 4h; Bromination;	95%
With bromine; iron(III) chloride In dichloromethane	95%
With iron(III) chloride; bromine In dichloromethane at -78 - 20℃; for 6h;	95%

: 5821-51-2
Coarannulen

: 73183-34-3
bis(pinacol)diborane

: 1398052-93-1
1,3,5,7,9-pentakis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)corannulene

Conditions

Conditions	Yield
With 4,4'-dimethyl-2,2'-bipyridines; (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; potassium tert-butylate In tetrahydrofuran at 85℃; for 96h;	95%
Stage #1: bis(pinacol)diborane With 4,4'-dimethyl-2,2'-bipyridines; (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; potassium tert-butylate In tetrahydrofuran at 50℃; Inert atmosphere; Stage #2: Coarannulen In tetrahydrofuran at 85℃; for 96h; Solvent; Temperature; Reagent/catalyst; Inert atmosphere;

: 26042-63-7
silver(I) hexafluorophosphate

: 126821-58-7
chloro(pentamethylcyclopentadienyl)ruthenium(II) tetramer

: 5821-51-2
Coarannulen

: 865799-39-9
[(η5-C5Me5)Ru(η6-C20H10)]PF6

Conditions

Conditions	Yield
In nitromethane-d3 byproducts: AgCl; (Ar); std. Schlenk technique; CD3NO2 was added to mixt. of Ru complex, corannulene (4 equiv.) and Ag salt (4 equiv.); soln. was stirred at room temp. for 15 min; filtered; evapd. (vac.); residue washed (Et2O); dried (vac.); dissolved in CH2Cl2; filtered into hexane;	91%

...Expand

: 5821-51-2
Coarannulen

: 1380666-08-9
1-iododibenzo[ghi,mno]fluoranthene

Conditions

Conditions	Yield
With gold(III) chloride; N-iodo-succinimide In 1,2-dichloro-ethane at 20℃; for 54h; Reflux; Inert atmosphere;	90%
With N-iodo-succinimide; boron trifluoride diethyl etherate In 1,2-dichloro-ethane at 80℃; Inert atmosphere;	80%

: 5821-51-2
Coarannulen

: monochlorocorannulene

Conditions

Conditions	Yield
With gold(III) chloride; N-chloro-succinimide In 1,2-dichloro-ethane at 60℃; for 24h; Inert atmosphere;	90%

: 5821-51-2
Coarannulen

: 6C66H52N4Ni*4Fe(2+)*8C2F6NO4S2(1-)*3C24H8O4

: 6C66H52N4Ni*4Fe(2+)*8C2F6NO4S2(1-)*C24H8O4*2C20H10

Conditions

Conditions	Yield
In [D3]acetonitrile at 60℃; for 3h;	90%

: 5821-51-2
Coarannulen

: 1313497-83-4
3,6‐di‐tert‐butyl‐1,8‐diethynylcarbazole

: C42H58Au2I2N4

: C20H10*C132H162Au4N10

Conditions

Conditions	Yield
Stage #1: 3,6‐di‐tert‐butyl‐1,8‐diethynylcarbazole With sodium hydroxide In methanol at 80℃; for 1h; Stage #2: Coarannulen; C42H58Au2I2N4 In methanol at 80℃; for 4h;	90%

...Expand

: 110-86-1
pyridine

: 5821-51-2
Coarannulen

: C20H10*C5H5N

Conditions

Conditions	Yield
With iridium(III) chloride trihydrate In ethylene glycol at 250℃; for 0.5h; Inert atmosphere; Microwave irradiation;	89%

: 67-56-1
methanol

: 5821-51-2
Coarannulen

: C128H152Cl4Cu4N4O24Rh4(4+)*4CF3O3S(1-)

: 7732-18-5
water

: 4CF3O3S(1-)*9CH4O*C20H10*C128H152Cl4Cu4N4O24Rh4(4+)*(x)H2O

Conditions

Conditions	Yield
at 20℃; for 6h; Inert atmosphere; Schlenk technique;	86.1%

...Expand

: 26042-63-7
silver(I) hexafluorophosphate

: 75-09-2
dichloromethane

: [(C5(CH3)5)2Ru(μ3-Cl)]

: 5821-51-2
Coarannulen

: [(C5(CH3)5Ru)2(μ2-η6,η6-C20H10](PF6)2*CH2Cl2

Conditions

Conditions	Yield
In nitromethane-d3 byproducts: AgCl; (Ar) 0.081 mmol AgPF6 added to soln. of 0.020 mmol (Cp*Ru(μ3-Cl))4 and 0.040 mmol corannulene; stirred at room temp. for 1 h; AgCl removed by filtration; (vac.) evapd. to dryness; washed (diethyl ether); (vac.) dried; dissolved in 1-2 mL CH2Cl2; added to hexane;	85%

...Expand

: 109-99-9
tetrahydrofuran

: 17455-13-9
18-crown-6 ether

: 5821-51-2
Coarannulen

: 2C4H8O*2C12H24NaO6(1+)*C20H10(2-)

Conditions

Conditions	Yield
With sodium at 20℃; for 12h; Inert atmosphere;	85%

...Expand

: 17455-13-9
18-crown-6 ether

: 5821-51-2
Coarannulen

: 2C12H24KO6(1+)*C20H10(2-)

Conditions

Conditions	Yield
With potassium In tetrahydrofuran at 20℃; for 12h; Inert atmosphere;	85%

: 26042-63-7
silver(I) hexafluorophosphate

: 5821-51-2
Coarannulen

: [(R,R-2,5-dimethyl-bicyclo[2.2.1]hepta-2,5-diene)RhCl]2

: [(R,R-2,5-dimethyl-bicyclo[2.2.1]hepta-2,5-diene)RhCl](C20H10)

Conditions

Conditions	Yield
In dichloromethane reaction of (Rh(I)(nbd)Cl)2 derivative with corannulene activated by Ag(I) in CH2Cl2 at room temp. for 30 min;	82%

...Expand

: 17455-13-9
18-crown-6 ether

: 5821-51-2
Coarannulen

: C12H24NaO6(1+)*C20H10(1-)

Conditions

Conditions	Yield
Stage #1: 18-crown-6 ether; Coarannulen With sodium In tetrahydrofuran at 20℃; for 12h; Inert atmosphere; Stage #2: Coarannulen In tetrahydrofuran Inert atmosphere;	80%

: 111-96-6
diethylene glycol dimethyl ether

: 5821-51-2
Coarannulen

: 7439-93-2
lithium

: [Li(diglyme)2+]2[corannulene2-]

Conditions

Conditions	Yield
Stage #1: Coarannulen; lithium In diethylene glycol dimethyl ether at 20℃; for 72h; Inert atmosphere; Stage #2: diethylene glycol dimethyl ether; Coarannulen Inert atmosphere;	80%

...Expand

: 5821-51-2
Coarannulen

: 1407965-84-7
corannulene-1,2,3,4,5,6,7,8,9,10-d10

Conditions

Conditions	Yield
With d7-N,N-dimethylformamide; potassium tert-butylate at 170℃; for 1h; Microwave irradiation;	80%
With (2)H8-toluene; C24BCl20(1-)*C9H13(1+) at 20℃; for 336h; Reagent/catalyst; Inert atmosphere;	76%

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