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Hefei TNJ chemical industry co.,ltd

ISO Certification Technology: Technology innovation is our eternal pursuit,or we will be left behind.Our technology experts,all from famous universities and institutes,has rich experience and high achievements in chemical research.This makes sure

Ammonium oxalate

Cas:6009-70-7

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Ammonium oxalate monohydrate

Cas:6009-70-7

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Ammonium Oxalate Monohydrate

Cas:6009-70-7

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co., LTD is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low carb

Ammonium oxalate

Cas:6009-70-7

Min.Order:1 Kilogram

FOB Price: $1.0 / 3.0

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Ammonium Oxalate Monohydrate

Cas:6009-70-7

Min.Order:1

Negotiable

Type:Other

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Wuhan Kemi-Works Chemical Co., Ltd

Product name: Ammonium oxalate CAS No. 6009-70-7 MF: C2H10N2O5 Assay: 99.8%min Appearance: White crystal 1.We have been specializing in special fine chemical forlong, with strong R&D strength. 2.ISO9001. 3.We have been coopera

Ammonium oxalate monohydrate

Cas:6009-70-7

Min.Order:10 Gram

Negotiable

Type:Other

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COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

Ammonium Oxalate

Cas:6009-70-7

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 6009-70-7 with competitive price

Cas:6009-70-7

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

Ammonium oxalate monohydrate

Cas:6009-70-7

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Ethanedioic acid,ammonium salt, hydrate (1:2:1) 6009-70-7

Cas:6009-70-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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EAST CHEMSOURCES LIMITED

The advantages of our company: 1、The highest quality with the competitive price. 2、Professional human services. 3、The fastest and safest delivery service. 4、The faster and safest delivery service. 5、The high purity products. 6、We have

AMMONIUM OXALATE

Cas:6009-70-7

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Qingdao Beluga Import and Export Co., LTD

Ammonium oxalate monohydrate CAS:6009-70-7 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organ

Ammonium oxalate monohydrate CAS:6009-70-7

Cas:6009-70-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Ethanedioic acid,ammonium salt, hydrate (1:2:1)

Cas:6009-70-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hubei CuiRan Biotechnology Co., Ltd

Hubei CuiRan Biotechnology Co., Ltd is a leading company in the research, development, manufacture and marketing of High Quality Phytochemicals and Extracts(especially Active Ingredients from Traditional Chinese Medicine,Traditional Chinese Medicine)

Ammonium oxalate monohydrate

Cas:6009-70-7

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

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Lonwin Chemical Group Limited

Ammonium oxalate CAS: 6009-70-7 Specification Items Technical index Product name Ammonium oxalate Synonym Ammonium oxalate monohydrate CAS No

Factory supply Ammonium oxalate

Cas:6009-70-7

Min.Order:1 Kilogram

Negotiable

Type:Other

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Changchun Artel lmport and Export trade company

1. quality & price: we offer high quality and reasonably priced products to our customers 2. payment methord: t/t, l/c, paypal, moneygram, westerm union, other 3. service: best service and after-sales service to all clients 4. delivery: v

BEST PRICE/Ammonium oxalate monohydrate

Cas:6009-70-7

Min.Order:10 Metric Ton

Negotiable

Type:Trading Company

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Ammonium Oxalate Monohydrate

Cas:6009-70-7

Min.Order:0

Negotiable

Type:Manufacturers

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Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

AMMONIUM OXALATE MONOHYDRATE

Cas:6009-70-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Ammonium oxalate monohydrate

Cas:6009-70-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Ammonium Oxalate Monohydrate

Cas:6009-70-7

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung, LG, Merck, Thermo Fisher Scientific and so o

6009-70-7 Ammonium oxalate monohydrate

Cas:6009-70-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Ammonium oxalate monohydrate

Cas:6009-70-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Kanbei Chemical Co.,LTD

High quality, competitive price, fast delivery and first-class service we possesses have won the trust and praise of customers. Standard: BP/USP/EP The purity is equal or greater than 99%. As a supplier, we can provide high-quality products. Cle

Ammonium oxalate monohydrate.99%

Cas:6009-70-7

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Ammonium oxalate

Cas:6009-70-7

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

Ammonium Oxalate

Cas:6009-70-7

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

Ammonium oxalate cas no. 6009-70-7 98%

Cas:6009-70-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Jiling Chemical Co., Ltd

factory Storage:Shading, sealed and preserved. Package:Grams, Kilograms Application:An organic synthetic intermediate used Transportation:According to customer request Port:Qingdao

Ethanedioic acid,ammonium salt, hydrate (1:2:1)6009-70-7

Cas:6009-70-7

Min.Order:0

Negotiable

Type:Other

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Ammonium oxalate

Cas:6009-70-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec Ammonium oxalate monohydrate 500g

Cas:6009-70-7

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

Ammonium oxalate monohydrate

Cas:6009-70-7

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Synthetic route

oxaluric acid
585-05-7

oxaluric acid

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

Conditions
ConditionsYield
With water
oxalic acid
144-62-7

oxalic acid

urea
57-13-6

urea

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

Conditions
ConditionsYield
With water
barium oxalate

barium oxalate

(NH4)2 CO3

(NH4)2 CO3

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

Conditions
ConditionsYield
at 100℃;
ammonia
7664-41-7

ammonia

water
7732-18-5

water

oxalic acid
144-62-7

oxalic acid

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

Conditions
ConditionsYield
In water soln. of ammonia and oxalic acid in H2O slowly evapd. at room temp. overabout 15-20 d;
ammonium carbonate

ammonium carbonate

oxalic acid
144-62-7

oxalic acid

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

Conditions
ConditionsYield
In water neutralizing aq. oxalic acid soln. with (NH4)2CO3; evapn.;
In water neutralizing aq. oxalic acid soln. with (NH4)2CO3; evapn.;
hydrogen cyanide
74-90-8

hydrogen cyanide

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

Conditions
ConditionsYield
With acetone In water mixt. of acetone and 3 % aq. HCN soln.; by light;
With acetone In water mixt. of acetone and 3 % aq. HCN soln.; by light;
ammonium sulfide
12135-76-1

ammonium sulfide

NH4(1+)*HC2O4(1-)*99H2O=(NH4)HC2O4*99H2O

NH4(1+)*HC2O4(1-)*99H2O=(NH4)HC2O4*99H2O

A

NH4(1+)*3H(1+)*2C2O4(2-)*2H2O=(NH4)H3(C2O4)2*2H2O

NH4(1+)*3H(1+)*2C2O4(2-)*2H2O=(NH4)H3(C2O4)2*2H2O

B

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

Conditions
ConditionsYield
In water by standing of aq. soln. of educt;
In water by standing of aq. soln. of educt;
ammonia
7664-41-7

ammonia

oxalic acid
144-62-7

oxalic acid

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

Conditions
ConditionsYield
In water neutralizing aq. oxalic acid soln. with NH3; evapn.;
In water neutralizing aq. oxalic acid soln. with NH3; evapn.;
ammonium sulfide
12135-76-1

ammonium sulfide

lead(II) oxalate
69657-50-7

lead(II) oxalate

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

Conditions
ConditionsYield
In water with freshly pptd. Pb oxalate;
In water with freshly pptd. Pb oxalate;
nickel(II) nitrate hexahydrate

nickel(II) nitrate hexahydrate

water
7732-18-5

water

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

nickel(II) oxalate dihydrate
20161-19-7, 34729-05-0

nickel(II) oxalate dihydrate

Conditions
ConditionsYield
In water (NH4)2C2O4*H2O (48.87 g) added to 5.0 M Ni(NO3)2 (20 ml) (70-90°C); dispersed with deionized H2O; filtered; washed; dehydrated with anhyd. ethanol; dried (80-90°C); SEM;99.76%
nickel(II) nitrate hexahydrate

nickel(II) nitrate hexahydrate

water
7732-18-5

water

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

nickel oxalate * 2.5 H2O

nickel oxalate * 2.5 H2O

Conditions
ConditionsYield
In water Ni(NO3)2 soln. added to supersatd. (NH4)2C2O4; SEM;97.98%
Ir(NH3)6(3+)*PO4(3-)*4H2O=Ir(NH3)6PO4*4H2O

Ir(NH3)6(3+)*PO4(3-)*4H2O=Ir(NH3)6PO4*4H2O

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

2Ir(NH3)6(3+)*3C2O4(2-)*4H2O=[Ir(NH3)6]2(C2O4)3*4H2O

2Ir(NH3)6(3+)*3C2O4(2-)*4H2O=[Ir(NH3)6]2(C2O4)3*4H2O

Conditions
ConditionsYield
In water 2 equiv. of NH4-oxalate soln. was added to aq. soln. of metal-complex; crystals were filtered, washed with EtOH, Et2O, dried in vac., elem. anal.;95%
bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]
12354-84-6, 12354-85-7

bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

[Cp*2Ir2(μ-η4-C2O4)]Cl2
280742-17-8

[Cp*2Ir2(μ-η4-C2O4)]Cl2

Conditions
ConditionsYield
In methanol; chloroform under N2 atm. (NH4)2C2O4*H2O was added to suspn. Ir complex in CHCl3-MeOH and stirred at 55°C for 5 h; solvent was evapd. to dryness in vacuo, residue was extd. with CH2Cl2; elem. anal.;91%
In methanol (N2); std. Schlenk technique; oxalate was added to suspn. of Ir complex in MeOH; stirred at 55°C for 5 h; evapd. (vac.); extd. (CH2Cl2); elem. anal.;91%
[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2
52462-29-0

[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

[(p-cymene)2Ru2(μ-η4-C2O4)]Cl2
201336-17-6, 1185317-98-9, 201425-24-3

[(p-cymene)2Ru2(μ-η4-C2O4)]Cl2

Conditions
ConditionsYield
In methanol; chloroform (N2); reflux (6 h); removal of solvents, taken up in CH2Cl2, filtration, evapn. to dryness; elem. anal.;89%
dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer

dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

[(η5-pentamethylcyclopentadienyl)2Rh2(μ-oxalato-κO)Cl2]
958667-73-7

[(η5-pentamethylcyclopentadienyl)2Rh2(μ-oxalato-κO)Cl2]

Conditions
ConditionsYield
In methanol; chloroform byproducts: ammonium chloride; (NH4)2C2O4*H2O added to CHCl3-MeOH soln. of Rh complex; refluxed for 6 h; solvent removed under vac.; dissolved in CH2Cl2; filtered; filtrate evapd. to dryness; elem. anal.;88%
aquo pentammine iridium(III) chloride

aquo pentammine iridium(III) chloride

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

2Ir(NH3)5(H2O)(3+)*3C2O4(2-)*4H2O=[Ir(NH3)5(H2O)]2(C2O4)3*4H2O

2Ir(NH3)5(H2O)(3+)*3C2O4(2-)*4H2O=[Ir(NH3)5(H2O)]2(C2O4)3*4H2O

Conditions
ConditionsYield
In water satd. aq. soln. of NH4-oxalate was added to aq. soln. of metal-complex; crystals were filtered, washed with EtOH, Et2O, dried in vac., elem. anal.;86%
dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer

dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

[Cp*2Rh2(μ-η2-η2-C2O4)]Cl2
958667-73-7

[Cp*2Rh2(μ-η2-η2-C2O4)]Cl2

Conditions
ConditionsYield
In methanol; chloroform under N2 atm. (NH4)2C2O4*H2O was added to suspn. Rh complex in CHCl3-MeOH and stirred at 55°C for 5 h; solvent was evapd. to dryness in vacuo, residue was extd. with CH2Cl2; elem. anal.;86%
[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2
52462-29-0

[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

C12H17NO4Ru*H2O, orthorhombic

C12H17NO4Ru*H2O, orthorhombic

Conditions
ConditionsYield
With AgSO4 In water (N2); addn. of AgSO4 to the Ru complex in H2O, stirring (room temp., 3 h), filtration, addn. of (NH4)2C2O4*H2O, adjustment ot pH to 7-8, heatingto 70°C (1-2 h); evapn. to dryness, addn. of CH2Cl2, filtration, evapn., recrystn. (MeOH/Et2O); elem. anal.;84%
hexaammonium heptamolybdate tetrahydrate

hexaammonium heptamolybdate tetrahydrate

dihydrogen peroxide
7722-84-1

dihydrogen peroxide

oxalic acid dihydrate
6153-56-6

oxalic acid dihydrate

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

(NH4)2[MoO(O2)2(oxalate)]

(NH4)2[MoO(O2)2(oxalate)]

Conditions
ConditionsYield
In water ammonium heptamolybdate tetrahydrate dissolved in soln. of oxalic acid and ammonium oxalate, treated with excess of soln. of H2O2 (35 wt,-%), stirred for 2 h; EtOH added, ppt. filtered off, washed with EtOH and air-dried; elem. anal.;84%
bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]
12354-84-6, 12354-85-7

bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

[(η5-C5Me5)IrCl(μ-η2-η2-oxalato)ClIr(η5-C5Me5)]
280742-17-8

[(η5-C5Me5)IrCl(μ-η2-η2-oxalato)ClIr(η5-C5Me5)]

Conditions
ConditionsYield
In methanol; chloroform byproducts: ammonium chloride; (NH4)2C2O4*H2O added to CHCl3-MeOH soln. of Ir complex; refluxed for 6 h; solvent removed under vac.; dissolved in CH2Cl2; filtered; filtrate evapd. to dryness; elem. anal.;81%
[Co(tris(2-aminoethyl)amine)Cl2]Cl
20023-19-2

[Co(tris(2-aminoethyl)amine)Cl2]Cl

sodium perchlorate

sodium perchlorate

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

[Co(C6H18N4)(oxalato)]ClO4*0.5H2O

[Co(C6H18N4)(oxalato)]ClO4*0.5H2O

Conditions
ConditionsYield
In water slow addition of soln. of oxalate to soln. of Co complex, heating (10 min), addn. of NaClO4; filtration, pptn. (2 weeks); elem. anal.;77%
cis-dichlorobis(ethylenediamine)cobalt(III) chloride

cis-dichlorobis(ethylenediamine)cobalt(III) chloride

water
7732-18-5

water

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

cis-[Co(oxalate)(ethylenediamine)2]Cl*4H2O

cis-[Co(oxalate)(ethylenediamine)2]Cl*4H2O

Conditions
ConditionsYield
In water warm aq. soln. of (NH4)2ox (11 mmol) added to aq. soln. of Co compd. (10mmol) at 60°C, stirred for 30 min; pptd. on storage overnight, ppt. filtered off, washed (H2O, EtOH, ether), elem. anal.;73%
copper(II) tetrafluoroborate tetrahydrate

copper(II) tetrafluoroborate tetrahydrate

N-(1H-pyrrol-2-ylmethylene)-2-(pyridin-2-yl)ethanamine
1093853-11-2

N-(1H-pyrrol-2-ylmethylene)-2-(pyridin-2-yl)ethanamine

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

[Cu2(N-(1H-pyrrol-2-ylmethylene)-2-pyridine-ethaneamine)2(oxalate)]
1190210-76-4

[Cu2(N-(1H-pyrrol-2-ylmethylene)-2-pyridine-ethaneamine)2(oxalate)]

Conditions
ConditionsYield
With Et3N In methanol; water MeOH soln. of Et3N (0.3 mmol) added to meOH soln. of ligand (0.3 mmol), soln. added to meOH soln. of Cu compd. (0.3 mmol), aq. ammonium oxalate (0.15 mmol) added, mixt. stirred for 6 h; ppt. filtered off, washed (MeOH), dried (vac.), elem. anal.;71%
lanthanum(III) oxide

lanthanum(III) oxide

5-hydroxynicotinic acid
27828-71-3

5-hydroxynicotinic acid

water
7732-18-5

water

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

[La(III)(3-H-5-phenoxonicotinato)(oxalate)(H2O)2]

[La(III)(3-H-5-phenoxonicotinato)(oxalate)(H2O)2]

Conditions
ConditionsYield
With Et3N In water High Pressure; mixt. of La2O3, (NH4)2C2O4*H2O, C6H5O3N and H2O in molar ratio of 1:1:1:290 adjusted to pH of 4.5 (Et3N) at room temp.; treated in autoclave at 170°C for 5 d; cooled to room temp. at a rate of 5°C/h; elem. anal., detd. by XRD;68%
dysprosium((III) oxide

dysprosium((III) oxide

5-hydroxynicotinic acid
27828-71-3

5-hydroxynicotinic acid

water
7732-18-5

water

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

[Dy(III)(3-H-5-phenoxonicotinato)(oxalate)1.5(H2O)]*H2O

[Dy(III)(3-H-5-phenoxonicotinato)(oxalate)1.5(H2O)]*H2O

Conditions
ConditionsYield
With Et3N In water High Pressure; mixt. of Dy2O3, (NH4)2C2O4*H2O, C6H5O3N and H2O in molar ratio of 1:1:1:290 adjusted to pH of 4.6 (Et3N) at room temp.; treated in autoclave at 180°C for 2 d; cooled to room temp. at a rate of 2°C/h; elem. anal., detd. by XRD;67%
(((meso-tetra(4-pyridyl)porphyrin)(IrCl(C5(Me)5))4)2(CF3SO3)8

(((meso-tetra(4-pyridyl)porphyrin)(IrCl(C5(Me)5))4)2(CF3SO3)8

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

(((meso-tetra(4-pyridyl)porphyrin)(Ir(C5(Me)5))4)2(μ-oxalato)4(CF3SO3)8

(((meso-tetra(4-pyridyl)porphyrin)(Ir(C5(Me)5))4)2(μ-oxalato)4(CF3SO3)8

Conditions
ConditionsYield
In methanol under N2 atm.; (NH4)2C2O4*H2O added to soln. of Ir complex in MeOH, stirred at 55°C for 5 h;65%
1h-benzotriazole-5-carboxylic acid
23814-12-2

1h-benzotriazole-5-carboxylic acid

samarium(III) nitrate hexahydrate

samarium(III) nitrate hexahydrate

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

[samarium(III)(benzotriazole-5-carboxylate)(oxalate)(H2O)2] monohydrate

[samarium(III)(benzotriazole-5-carboxylate)(oxalate)(H2O)2] monohydrate

Conditions
ConditionsYield
In water; acetonitrile at 140℃; for 72h; Autoclave;56%
5-hydroxynicotinic acid
27828-71-3

5-hydroxynicotinic acid

terbium(III) oxide

terbium(III) oxide

water
7732-18-5

water

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

[Tb(III)(3-H-5-hydroxynicotinato)(oxalate)1.5(H2O)]*H2O

[Tb(III)(3-H-5-hydroxynicotinato)(oxalate)1.5(H2O)]*H2O

Conditions
ConditionsYield
With Et3N In water High Pressure; mixt. of Tb2O3, (NH4)2C2O4*H2O, C6H5O3N and H2O in molar ratio of 1:1.5:1:290 adjusted to pH of 4.0 (Et3N) at room temp.; treated in autoclave at 170°C for 3 d; cooled to room temp. at a rate of 2.5°C/h; elem. anal., detd. by XRD;54%
samarium(III) oxide

samarium(III) oxide

5-hydroxynicotinic acid
27828-71-3

5-hydroxynicotinic acid

water
7732-18-5

water

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

[Sm(III)(3-H-5-hydroxynicotinato)(oxalate)1.5(H2O)]*H2O

[Sm(III)(3-H-5-hydroxynicotinato)(oxalate)1.5(H2O)]*H2O

Conditions
ConditionsYield
With Et3N In water High Pressure; mixt. of Sm2O3, (NH4)2C2O4*H2O, C6H5O3N and H2O in molar ratio of 1:1.5:1:290 adjusted to pH of 4.0 (Et3N) at room temp.; treated in autoclave at 170°C for 3 d; cooled to room temp. at a rate of 2.5°C/h; elem. anal., detd. by XRD;52%
1h-benzotriazole-5-carboxylic acid
23814-12-2

1h-benzotriazole-5-carboxylic acid

holmium(III) nitrate hexahydrate

holmium(III) nitrate hexahydrate

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

[holmium(III)(benzotriazole-5-carboxylate)(oxalate)(H2O)2] monohydrate

[holmium(III)(benzotriazole-5-carboxylate)(oxalate)(H2O)2] monohydrate

Conditions
ConditionsYield
In water; acetonitrile at 140℃; for 72h; Autoclave;46%
5-hydroxynicotinic acid
27828-71-3

5-hydroxynicotinic acid

praseodymium(III) oxide

praseodymium(III) oxide

water
7732-18-5

water

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

[Pr(III)(3-H-5-phenoxonicotinato)(oxalate)(H2O)2]

[Pr(III)(3-H-5-phenoxonicotinato)(oxalate)(H2O)2]

Conditions
ConditionsYield
With Et3N In water High Pressure; mixt. of Pr2O3, (NH4)2C2O4*H2O, C6H5O3N and H2O in molar ratio of 1:1:1:290 adjusted to pH of 4.5 (Et3N) at room temp.; treated in autoclave at 170°C for 5 d; cooled to room temp. at a rate of 5°C/h; elem. anal., detd. by XRD;42%
erbium(III) oxide

erbium(III) oxide

5-hydroxynicotinic acid
27828-71-3

5-hydroxynicotinic acid

water
7732-18-5

water

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

[Er(III)(3-H-5-phenoxonicotinato)(oxalate)1.5(H2O)]*H2O

[Er(III)(3-H-5-phenoxonicotinato)(oxalate)1.5(H2O)]*H2O

Conditions
ConditionsYield
With Et3N In water High Pressure; mixt. of Er2O3, (NH4)2C2O4*H2O, C6H5O3N and H2O in molar ratio of 1:1:1:290 adjusted to pH of 4.6 (Et3N) at room temp.; treated in autoclave at 180°C for 2 d; cooled to room temp. at a rate of 2°C/h; elem. anal., detd. by XRD;41%
gadolinium(III) oxide

gadolinium(III) oxide

5-hydroxynicotinic acid
27828-71-3

5-hydroxynicotinic acid

water
7732-18-5

water

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

[Gd(III)(3-H-5-hydroxynicotinato)(oxalate)1.5(H2O)]*H2O

[Gd(III)(3-H-5-hydroxynicotinato)(oxalate)1.5(H2O)]*H2O

Conditions
ConditionsYield
With Et3N In water High Pressure; mixt. of Gd2O3, (NH4)2C2O4*H2O, C6H5O3N and H2O in molar ratio of 1:1.5:1:290 adjusted to pH of 4.0 (Et3N) at room temp.; treated in autoclave at 170°C for 3 d; cooled to room temp. at a rate of 2.5°C/h; elem. anal., detd. by XRD;41%
5-hydroxynicotinic acid
27828-71-3

5-hydroxynicotinic acid

neodymium(III) oxide

neodymium(III) oxide

water
7732-18-5

water

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

[Nd(III)(3-H-5-phenoxonicotinato)(oxalate)(H2O)2]

[Nd(III)(3-H-5-phenoxonicotinato)(oxalate)(H2O)2]

Conditions
ConditionsYield
With Et3N In water High Pressure; mixt. of Nd2O3, (NH4)2C2O4*H2O, C6H5O3N and H2O in molar ratio of 1:1:1:290 adjusted to pH of 4.5 (Et3N) at room temp.; treated in autoclave at 170°C for 5 d; cooled to room temp. at a rate of 5°C/h; elem. anal., detd. by XRD;41%
Pyridine-2,6-dicarboxylic acid
499-83-2

Pyridine-2,6-dicarboxylic acid

erbium(III) nitrate hexahydrate

erbium(III) nitrate hexahydrate

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

[Er4(2,6-pyridinedicarboxylate)2(μ4-oxalate)4(H2O)8](H2O)6

[Er4(2,6-pyridinedicarboxylate)2(μ4-oxalate)4(H2O)8](H2O)6

Conditions
ConditionsYield
With HNO3 In sodium hydroxide; water aq. NaOH; High Pressure; dicarboxylic acid and (NH4)2C2O4 (1:2) in aq.NaOH mixed with aq. soln. of Er salt (2 equiv.), pH adjusted to 5 (HNO3), stirred for 8 min (air), heated in an autoclave at 160°C for 72 h; cooled to room temp. over 12 h, elem. anal.;36%
ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

iron(III) chloride
7705-08-0

iron(III) chloride

A

ammonium trioxalatoferrate(III) trihydrate

ammonium trioxalatoferrate(III) trihydrate

B

((NH4)2[Fe2O(ox)2Cl2]*2H2O)n

((NH4)2[Fe2O(ox)2Cl2]*2H2O)n

Conditions
ConditionsYield
In water (NH4)2C2O4*H2O was added to aq. soln. FeCl3, gently warmed for 10 min, soln. was allowed to stand at room temp. for several days; crystals were filtered and washed with EtOH and Et2O; elem. anal.;A n/a
B 30%
potassium permanganate
7722-64-7

potassium permanganate

water
7732-18-5

water

1,2-diaminoethane dihydrochloride
333-18-6

1,2-diaminoethane dihydrochloride

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

cobalt
7440-48-4

cobalt

[Co(III)(tris(((2-aminoethyl)amino)methyl)amine][Mn(C2O4)2]Cl*3H2O

[Co(III)(tris(((2-aminoethyl)amino)methyl)amine][Mn(C2O4)2]Cl*3H2O

Conditions
ConditionsYield
With CH3OH; air In methanol mixt. of Co powder, KMnO4, C2H4(NH2)2(HCl)2, (NH4)2C2O4*H2O and methanolheated at 50-60°C in air with stirring for 8 h; ppt. filtered off, washed with 2-propanol and dried under vac. at room temp.; recrystn. from H2O; elem. anal.;30%
potassium permanganate
7722-64-7

potassium permanganate

water
7732-18-5

water

1,2-diaminoethane dihydrochloride
333-18-6

1,2-diaminoethane dihydrochloride

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

cobalt
7440-48-4

cobalt

[Co(III)(tris(1,2-diaminoethane)]2[Mn2(C2O4)5]*6H2O

[Co(III)(tris(1,2-diaminoethane)]2[Mn2(C2O4)5]*6H2O

Conditions
ConditionsYield
With CH3OH; air In N,N-dimethyl-formamide mixt. of Co powder, KMnO4, C2H4(NH2)2(HCl)2, (NH4)2C2O4*H2O and DMF/methanol (20/0.1) heated at 50-60°C in air with stirring for 8 h; ppt. filtered off, washed with 2-propanol and dried under vac. at room temp.; elem. anal.;27%
hexaammonium heptamolybdate tetrahydrate

hexaammonium heptamolybdate tetrahydrate

dihydrogen peroxide
7722-84-1

dihydrogen peroxide

oxalic acid dihydrate
6153-56-6

oxalic acid dihydrate

ammonium oxalate monohydrate
6009-70-7

ammonium oxalate monohydrate

A

(NH4)2[MoO2(O2)(oxalate)]*H2O

(NH4)2[MoO2(O2)(oxalate)]*H2O

(NH4)2[Mo2O2(O2)2(OH)2(oxalate)2]

(NH4)2[Mo2O2(O2)2(OH)2(oxalate)2]

Conditions
ConditionsYield
In water ammonium heptamolybdate tetrahydrate dissolved in soln. of oxalic acid and ammonium oxalate, treated with soln. of H2O2 (35 wt.-%); EtOH added, stored at 5°C for 1 week, ppt. filtered off, washed with EtOH and air-dried ((NH4)2(MoO2(O2)(ox))*H2O), slow evapn. of filtrate yields (NH4)2(Mo2O2(O2)2(OH)2(ox)2); elem. anal.;A 16%
B n/a

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