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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

3-Chloropropyne Manufacturer/High quality/Best price/In stock

Cas:624-65-7

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Wuhan Kemi-Works Chemical Co., Ltd

Superiority : 1.Powerful R & D team 2.The ability of quantized production,from grams to tons; 3.Various kinds of advanced equipment in the laboratory and plant; 4.Strict QC standard to meet the demand of customers,advanced equipment for

Propargyl Chloride/ 3-Chloropropyne

Cas:624-65-7

Min.Order:1 Kilogram

Negotiable

Type:Other

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Hunan Longxianng Runhui Trading Co.,Ltd

Runhui Chem co., lted is a leading domestic pharmaceutical, biopharmaceutical, and health care products r & d outsourcing services company. as an innovation-driven and customer-focused company, run biotech provides a broad and integrated portf

High purity propargyl chloride solution with best price Cas No: 624-65-7

Cas:624-65-7

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 3- Proparagyl Chloride supplier in China

Cas:624-65-7

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product description: Product name 3-Chloropropyne CAS number 624-65-7 Assay ≥99% Appearance Colorless transparent liquid Capacity 200mt/year Application Pesticide intermedia

3-Chloropropyne

Cas:624-65-7

Min.Order:10 Gram

FOB Price: $12.0

Type:Lab/Research institutions

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Henan Allgreen Chemical Co.,Ltd

he company has advanced technology, as well as a large number of excellent R & D team, to provide customers from the grams to one hundred kilograms and tons of high-quality products, competitive prices and quality se T rvice Appearance:

Propargyl Chloride

Cas:624-65-7

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 3-chloropropyne

Cas:624-65-7

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

3-Chloropropyne

Cas:624-65-7

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

3-Chloropropyne Basic information Product Name: 3-Chloropropyne Synonyms: 1-Chloroprop-2-yne;1-Propyne,3-chloro-;2-Propynyl chloride;2-Propynylchloride;3-Chlor-1-propin;3-chloro-1-propyn

TIANFU-CHEM CAS:624-65-7 3-Chloropropyne

Cas:624-65-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

3-Chloropropyne

Cas:624-65-7

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 624-65-7 with best quality

Cas:624-65-7

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Chemical Name Propargyl chloride Synonyms 3-Chloro-1-propyne; Propargyl chloride;3-Chloropropyne CAS No. 624-65-7 EINECS No. 210-856-9

3-Chloro-1-propyne

Cas:624-65-7

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

1-Propyne,3-chloro- 624-65-7

Cas:624-65-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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HUBEI RISON CHEMICAL CO.,LTD.

Propargyl chloride CAS No:624-65-7 Molecular formula: C3H3CL Appearance: Clear colorless to yellowish liquid Assay: 99%min 1.3 Dichloropene: 0.2% max. 2.3 Dichloropene: 0.2% max. Water: 0.1% max Propargyl chloroformate: 1% max Propargyl al

Propargyl chloride

Cas:624-65-7

Min.Order:1 Metric Ton

Negotiable

Type:Other

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Qingdao Beluga Import and Export Co., LTD

Beluga chemical professional supply High-quality 3-Chloropropyne CAS 624-65-7 1. Beluga Chemical has a professional RESEARCH and development team and strong technical force to ensure technical support and research capabilities. 2. Made in China a

High-quality 3-Chloropropyne CAS 624-65-7

Cas:624-65-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

1-Propyne,3-chloro-

Cas:624-65-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:624-65-7

Cas:624-65-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hebei Mojin Biotechnology Co.,Ltd

Hebei Mojin Biotechnology Co., Ltd, Our company is a professional chemical raw materials and chemical reagents research and development production enterprises. We have several production line,So we can control the lowest price. We also have several

3-Chloropropyne cas:624-65-7

Cas:624-65-7

Min.Order:25 Gram

FOB Price: $90.0 / 100.0

Type:Trading Company

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

3-Chloropropyne

Cas:624-65-7

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Changchun Artel lmport and Export trade company

Price, service, company and transport advantage: 1.place of origin china with super quality by reasonable price. 2. it's customers' right to choose the package (ems, dhl, fedex, ups); 3. it's custo

BEST PRICE/3-Chloropropyne

Cas:624-65-7

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

CAS624-65-7 3-Chloropropyne

Cas:624-65-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

propargyl chloride solution

Cas:624-65-7

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

3-Chloropropyne

Cas:624-65-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 3-Chloropropyne

Cas:624-65-7

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

ChemFish co.,Ltd a comprehensive enterprise, Located in High-Tech Science Park,Changsha,China. With its own R&D center and more than 10000㎡manufacturing plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equ

3-Chloropropyne

Cas:624-65-7

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

3-Chloropropyne

Cas:624-65-7

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Siwei Development Group Ltd.

Product name: 3-Chloropropyne CAS No.:624-65-7 Molecule Formula:C3H3Cl Molecule Weight:74.51 Purity: 99.0% Package: 200kg/drum Description:Colorless liquid Manufacture Standards:Enterprise Standard TESTING ITEMS S

High Quality 3-Chloropropyne on stock

Cas:624-65-7

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

3-Chloropropyne

Cas:624-65-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

Propargylchloride

Cas:624-65-7

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

3-Chloropropyne Chemical Properties Melting point <-50°C Boiling point 58 °C(lit.) density 1.03 g/mL at 25 °C(lit.) refractive index n20/D 1.456 Fp 7 °F storage temp. 2-8°C solubility benzene: miscib

Propargyl chloride

Cas:624-65-7

Min.Order:1 Gram

FOB Price: $66.0

Type:Lab/Research institutions

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Synthetic route

1,1-dimethylprop-3-ynylamine
2978-58-7

1,1-dimethylprop-3-ynylamine

2-propynyl chloride
624-65-7

2-propynyl chloride

Conditions
ConditionsYield
With 3,5-dichlorobenzoyl chloride; potassium carbonate In N,N-dimethyl-formamide at 20℃; for 5h; Time; Reagent/catalyst;97.98%
propargyl alcohol
107-19-7

propargyl alcohol

2-propynyl chloride
624-65-7

2-propynyl chloride

Conditions
ConditionsYield
With thionyl chloride; tetramethylurea In toluene at 40℃; for 3.16h;94%
With benzoyl chloride; N,N-dimethyl-formamide at 0 - 20℃; for 14.25h;75%
With pyridine; bis(trichloromethyl) carbonate In tetrahydrofuran Heating;63%
N,N-Dichlorobenzenesulfonamide
473-29-0

N,N-Dichlorobenzenesulfonamide

propargyl alcohol
107-19-7

propargyl alcohol

A

benzenesulfonamide
98-10-2

benzenesulfonamide

B

N-chlorobenzenesulfonamide
80-16-0

N-chlorobenzenesulfonamide

C

2-propynyl chloride
624-65-7

2-propynyl chloride

D

3-hydroxy-2,2-dichloro-1,1-di(N-benzenesulfonamide)propane

3-hydroxy-2,2-dichloro-1,1-di(N-benzenesulfonamide)propane

Conditions
ConditionsYield
In tetrachloromethane at 30 - 35℃; for 6h; Irradiation;A 32%
B 4%
C 7 % Chromat.
D 16%
phosgene
75-44-5

phosgene

propargyl alcohol
107-19-7

propargyl alcohol

2-propynyl chloride
624-65-7

2-propynyl chloride

Conditions
ConditionsYield
at 0℃; Erhitzen des erhaltenen Chlorameisensaeure-prop-2-inylesters mit Triaethylamin-hydrochlorid auf 100grad;
3-bromo-2-chloroprop-1-ene
4860-96-2

3-bromo-2-chloroprop-1-ene

A

bromoallene
10024-18-7

bromoallene

B

chloroallene
3223-70-9

chloroallene

C

2-propynyl chloride
624-65-7

2-propynyl chloride

D

propargyl bromide
106-96-7

propargyl bromide

Conditions
ConditionsYield
With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride; phenol Yield given;
2-bromo-3-chloro-propene
16400-63-8

2-bromo-3-chloro-propene

A

bromoallene
10024-18-7

bromoallene

B

chloroallene
3223-70-9

chloroallene

C

2-propynyl chloride
624-65-7

2-propynyl chloride

D

propargyl bromide
106-96-7

propargyl bromide

Conditions
ConditionsYield
With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride; phenol Yield given;
propargyl alcohol
107-19-7

propargyl alcohol

A

N,N,2-trimethylpropionamide
21678-37-5

N,N,2-trimethylpropionamide

B

2-propynyl chloride
624-65-7

2-propynyl chloride

Conditions
ConditionsYield
With 1-chloro-1-(dimethylamino)-2-methyl-1-propene In dichloromethane 1). 0 deg C; 2.) rt., 3h;A n/a
B 99 % Spectr.
propargyl bromide
106-96-7

propargyl bromide

2-propynyl chloride
624-65-7

2-propynyl chloride

Conditions
ConditionsYield
With pyridine; tributyltin chloride at 50℃; Thermodynamic data; Equilibrium constant; Δ G;
propargyl iodide
659-86-9

propargyl iodide

A

chloroallene
3223-70-9

chloroallene

B

2-propynyl chloride
624-65-7

2-propynyl chloride

Conditions
ConditionsYield
With pyridine; tributyltin chloride at 50℃; Thermodynamic data; Equilibrium constant; Δ G;
chloroallene
3223-70-9

chloroallene

2-propynyl chloride
624-65-7

2-propynyl chloride

Conditions
ConditionsYield
at 661.85℃; under 125 Torr; Equilibrium constant; var. temp. and pressures;
propargyl alcohol
107-19-7

propargyl alcohol

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

2-propynyl chloride
624-65-7

2-propynyl chloride

2-propynyl chloride
624-65-7

2-propynyl chloride

ethyl 4-(benzyloxy)-7-bromo-1H-indole-2-carboxylate
290333-14-1

ethyl 4-(benzyloxy)-7-bromo-1H-indole-2-carboxylate

ethyl 4-(benzyloxy)-7-bromo-1-prop-2-ynyl-1H-indole-2-carboxylate
922507-01-5

ethyl 4-(benzyloxy)-7-bromo-1-prop-2-ynyl-1H-indole-2-carboxylate

Conditions
ConditionsYield
With potassium carbonate; sodium iodide In N,N-dimethyl-formamide at 50℃; for 24h;100%
cyclopropyl phenyl ketone
3481-02-5

cyclopropyl phenyl ketone

2-propynyl chloride
624-65-7

2-propynyl chloride

1-cyclopropyl-1-phenyl-3-butyn-1-ol
91909-17-0

1-cyclopropyl-1-phenyl-3-butyn-1-ol

Conditions
ConditionsYield
With 2,4,6-trimethyl-pyridine; bis(cyclopentadienyl)titanium dichloride; manganese; chloro-trimethyl-silane In tetrahydrofuran for 6h; Barbier type propargylation; Inert atmosphere;100%
1-methyl-1H-imidazole
616-47-7

1-methyl-1H-imidazole

2-propynyl chloride
624-65-7

2-propynyl chloride

1-methyl-3-(2-propyn-1-yl)-imidazolium chloride
98379-44-3

1-methyl-3-(2-propyn-1-yl)-imidazolium chloride

Conditions
ConditionsYield
In toluene Reflux;99%
In benzene for 5h; Heating;
p-cresol
106-44-5

p-cresol

2-propynyl chloride
624-65-7

2-propynyl chloride

A

dipropargyl ether
6921-27-3

dipropargyl ether

B

1-methyl-4-(2-propynyloxy)benzene
5651-90-1

1-methyl-4-(2-propynyloxy)benzene

Conditions
ConditionsYield
With sodium hydroxide; tetra-(n-butyl)ammonium iodideA n/a
B 99%
1-(2-chlorophenyl)ethanone
2142-68-9

1-(2-chlorophenyl)ethanone

2-propynyl chloride
624-65-7

2-propynyl chloride

C11H11ClO
1340170-80-0

C11H11ClO

Conditions
ConditionsYield
With 2,4,6-trimethyl-pyridine; bis(cyclopentadienyl)titanium dichloride; manganese; chloro-trimethyl-silane In tetrahydrofuran at 20℃; for 7h; Barbier Coupling Reaction; Inert atmosphere; chemoselective reaction;99%
caprinaldehyde
112-31-2

caprinaldehyde

Decan-2-one
693-54-9

Decan-2-one

2-propynyl chloride
624-65-7

2-propynyl chloride

tridec-1-yn-4-ol
74646-37-0

tridec-1-yn-4-ol

Conditions
ConditionsYield
With 2,4,6-trimethyl-pyridine; bis(cyclopentadienyl)titanium dichloride; manganese; chloro-trimethyl-silane In tetrahydrofuran at 20℃; for 7h; Barbier Coupling Reaction; Inert atmosphere; chemoselective reaction;99%
2-propynyl chloride
624-65-7

2-propynyl chloride

triethylamine
121-44-8

triethylamine

C9H18N(1+)*Cl(1-)

C9H18N(1+)*Cl(1-)

Conditions
ConditionsYield
In toluene Reflux;99%
2-propynyl chloride
624-65-7

2-propynyl chloride

3-chloroprop-1-ene
107-05-1

3-chloroprop-1-ene

Conditions
ConditionsYield
With piperazine; hydrogen In ethanol at 80℃; under 4500.45 Torr; for 24h;99%
With piperazine; hydrogen In ethanol at 100℃; under 4500.45 Torr; for 15h; Green chemistry;
With hydrogen In ethanol at 100℃; under 4500.45 Torr; for 24h; chemoselective reaction;87 %Chromat.
dimethyl iminodiacetate hydrochloride
39987-25-2, 62491-02-5

dimethyl iminodiacetate hydrochloride

2-propynyl chloride
624-65-7

2-propynyl chloride

N,N-bis(methoxycarbonylmethyl)propargylamine

N,N-bis(methoxycarbonylmethyl)propargylamine

Conditions
ConditionsYield
With potassium carbonate; potassium iodide In N,N-dimethyl-formamide at 80℃; for 5h; Inert atmosphere;99%
4-(4-chlorophenyl)-4-hydroxypiperidine
39512-49-7

4-(4-chlorophenyl)-4-hydroxypiperidine

2-propynyl chloride
624-65-7

2-propynyl chloride

N-propargyl-4-(4'-chlorophenyl)-4-piperidinol
43141-21-5

N-propargyl-4-(4'-chlorophenyl)-4-piperidinol

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide Ambient temperature;98%
3-vinyloxy-propan-1-ol
6118-22-5

3-vinyloxy-propan-1-ol

2-propynyl chloride
624-65-7

2-propynyl chloride

3-(3-vinyloxy-propoxy)-propyne
6188-75-6

3-(3-vinyloxy-propoxy)-propyne

Conditions
ConditionsYield
With sodium hydroxide; tributyl-amine In water at 50 - 60℃; for 3h;98%
trans-benzoic acid 4-oxo-but-2-enyl ester
118017-13-3

trans-benzoic acid 4-oxo-but-2-enyl ester

2-propynyl chloride
624-65-7

2-propynyl chloride

rac-1-benzoyloxy-7-chlorohept-2(E)-en-5-yn-4-ol
213545-10-9

rac-1-benzoyloxy-7-chlorohept-2(E)-en-5-yn-4-ol

Conditions
ConditionsYield
Stage #1: 2-propynyl chloride With n-butyllithium In diethyl ether; hexane at -78℃; for 0.166667h; Metallation;
Stage #2: trans-benzoic acid 4-oxo-but-2-enyl ester In diethyl ether at -78℃; for 0.5h; Condensation;
98%
2-propynyl chloride
624-65-7

2-propynyl chloride

4-methoxy-phenol
150-76-5

4-methoxy-phenol

1-methoxy-4-(2-propynyloxy)benzene
17061-86-8

1-methoxy-4-(2-propynyloxy)benzene

Conditions
ConditionsYield
Stage #1: 4-methoxy-phenol With sodium hydride In N,N-dimethyl-formamide at 0 - 20℃;
Stage #2: 2-propynyl chloride In N,N-dimethyl-formamide at 0 - 20℃;
98%
With potassium carbonate In N,N-dimethyl-formamide at 50℃; for 16h;93%
trans-PdEt2(PMe2Ph)2
75108-70-2

trans-PdEt2(PMe2Ph)2

2-propynyl chloride
624-65-7

2-propynyl chloride

trans-[ClPd(η1-allenyl)(PMe2Ph)2]
1428586-22-4

trans-[ClPd(η1-allenyl)(PMe2Ph)2]

Conditions
ConditionsYield
Stage #1: trans-PdEt2(PMe2Ph)2 With styrene In tetrahydrofuran at 55℃; for 1h; Schlenk technique; Inert atmosphere;
Stage #2: 2-propynyl chloride In tetrahydrofuran at 20℃; for 3h; Inert atmosphere; Schlenk technique;
98%
2-propynyl chloride
624-65-7

2-propynyl chloride

(Z,Z)-bis(2,3-dichloroprop-1-en-1-yl)tellurium dichloride

(Z,Z)-bis(2,3-dichloroprop-1-en-1-yl)tellurium dichloride

Conditions
ConditionsYield
With tellurium tetrachloride In benzene at 80℃; for 4h; stereospecific reaction;98%
[Pd(η2-dmfu)(Ph2PC9H5(Me)N)
1038998-45-6

[Pd(η2-dmfu)(Ph2PC9H5(Me)N)

2-propynyl chloride
624-65-7

2-propynyl chloride

C25H21ClNPPd

C25H21ClNPPd

Conditions
ConditionsYield
In dichloromethane for 0.333333h; Kinetics; Inert atmosphere; regioselective reaction;98%
(S)-N-(2-formyl-benzyl-4-chlorophenyl)-1-benzyl-pyrrolidine-2-carboxamide-glycine nickel complex

(S)-N-(2-formyl-benzyl-4-chlorophenyl)-1-benzyl-pyrrolidine-2-carboxamide-glycine nickel complex

2-propynyl chloride
624-65-7

2-propynyl chloride

(S)-2-((E)-((2-((S)-1-benzylpyrrolidine-2-carboxamido)-5-chlorophenyl) (phenyl)methylene)amino)pent-4-ynoic acid nickel complex

(S)-2-((E)-((2-((S)-1-benzylpyrrolidine-2-carboxamido)-5-chlorophenyl) (phenyl)methylene)amino)pent-4-ynoic acid nickel complex

Conditions
ConditionsYield
Stage #1: (S)-N-(2-formyl-benzyl-4-chlorophenyl)-1-benzyl-pyrrolidine-2-carboxamide-glycine nickel complex With sodium hydroxide In water; N,N-dimethyl-formamide at -10℃; for 0.5h;
Stage #2: 2-propynyl chloride In water; N,N-dimethyl-formamide Solvent; Temperature; enantioselective reaction;
97.8%
With sodium hydroxide In water; N,N-dimethyl-formamide at -10℃; for 1.5h; Solvent;93.87 %Chromat.
2-propynyl chloride
624-65-7

2-propynyl chloride

2-Fluoro-2-phenyl-2-phenylthioacetonitrile
210217-98-4

2-Fluoro-2-phenyl-2-phenylthioacetonitrile

2-Fluoro-2-phenyl-pent-4-ynenitrile

2-Fluoro-2-phenyl-pent-4-ynenitrile

Conditions
ConditionsYield
With Triethylgermyl-natrium In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide 1.) -60 deg C, 0.25 h, 2.) -80 deg C, 0.5 h;97%
5-(hydroxymethyl)benzene-1,3-diol
29654-55-5

5-(hydroxymethyl)benzene-1,3-diol

2-propynyl chloride
624-65-7

2-propynyl chloride

3,5-dipropargyloxybenzyl alcohol
176038-84-9

3,5-dipropargyloxybenzyl alcohol

Conditions
ConditionsYield
With potassium carbonate; potassium iodide In acetone Heating / reflux;97%
With Ki; potassium carbonate In acetone97%
With potassium carbonate; potassium iodide In acetone Heating / reflux;97%
With potassium carbonate; potassium iodide In acetone Heating;88%
4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-3-buten-2-one
79-77-6

4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-3-buten-2-one

2-propynyl chloride
624-65-7

2-propynyl chloride

(E)-3-Methyl-1-(2,6,6-trimethyl-cyclohex-1-enyl)-hex-1-en-5-yn-3-ol
14168-34-4

(E)-3-Methyl-1-(2,6,6-trimethyl-cyclohex-1-enyl)-hex-1-en-5-yn-3-ol

Conditions
ConditionsYield
With 2,4,6-trimethyl-pyridine; bis(cyclopentadienyl)titanium dichloride; manganese; chloro-trimethyl-silane In tetrahydrofuran for 6h; Barbier type propargylation; Inert atmosphere;97%
2-propynyl chloride
624-65-7

2-propynyl chloride

N-acetyl-5-methoxy-2,4,6-tribromotryptamine
300662-21-9

N-acetyl-5-methoxy-2,4,6-tribromotryptamine

N-acetyl-5-methoxy-1-propargyl-2,4,6-tribromotryptamine

N-acetyl-5-methoxy-1-propargyl-2,4,6-tribromotryptamine

Conditions
ConditionsYield
Stage #1: N-acetyl-5-methoxy-2,4,6-tribromotryptamine With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 0.0833333h;
Stage #2: 2-propynyl chloride In N,N-dimethyl-formamide at 20℃; for 4h;
97%
tris-(trimethylsilyl)silane
1873-77-4

tris-(trimethylsilyl)silane

2-propynyl chloride
624-65-7

2-propynyl chloride

A

(Me3SiO)2Si(H)SiMe3

(Me3SiO)2Si(H)SiMe3

B

2-((Z)-3-chloroprop-1-enyl)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane

2-((Z)-3-chloroprop-1-enyl)-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane

Conditions
ConditionsYield
With oxygen; 2-hydroxyethanethiol In water at 20℃; for 24h; optical yield given as %de; stereoselective reaction;A 5 %Chromat.
B 97%
trans-diethylbis(Et3phosphine)palladium(II)
60885-31-6

trans-diethylbis(Et3phosphine)palladium(II)

2-propynyl chloride
624-65-7

2-propynyl chloride

trans-[ClPd(η1-allenyl)(PEt3)2]
1428586-21-3

trans-[ClPd(η1-allenyl)(PEt3)2]

Conditions
ConditionsYield
Stage #1: trans-diethylbis(Et3phosphine)palladium(II) With styrene In tetrahydrofuran at 55℃; for 1h; Schlenk technique; Inert atmosphere;
Stage #2: 2-propynyl chloride In tetrahydrofuran at 20℃; for 3h; Inert atmosphere; Schlenk technique;
97%
p-9-(2-methylisoxazolidin-5-yl)non-1-yloxycinnamaldehyde

p-9-(2-methylisoxazolidin-5-yl)non-1-yloxycinnamaldehyde

2-propynyl chloride
624-65-7

2-propynyl chloride

p-9-[2-methyl-2-(2-popyn-1-yl) isoxazolidinium-5-yl]non-1-yloxycinnamaldehyde chloride

p-9-[2-methyl-2-(2-popyn-1-yl) isoxazolidinium-5-yl]non-1-yloxycinnamaldehyde chloride

Conditions
ConditionsYield
In acetone at 20℃; for 24h;97%
pyrrolidine
123-75-1

pyrrolidine

2-propynyl chloride
624-65-7

2-propynyl chloride

1-(prop-2-yn-1-yl)pyrrolidine
7223-42-9

1-(prop-2-yn-1-yl)pyrrolidine

Conditions
ConditionsYield
In acetonitrile at 60℃; for 48.5h;97%
With sodium hydrogencarbonate In ethanol at 25℃; for 3h;
5,7-dihydroxy-2H-chromen-2-one
2732-18-5

5,7-dihydroxy-2H-chromen-2-one

2-propynyl chloride
624-65-7

2-propynyl chloride

5,7-bis(prop-2-yn-1-yloxy)-2H-chromene-2-one

5,7-bis(prop-2-yn-1-yloxy)-2H-chromene-2-one

Conditions
ConditionsYield
With caesium carbonate In acetone at 110℃; for 2h; Microwave irradiation;97%
benzyl 4-oxo-1-piperidinecarboxylate
19099-93-5

benzyl 4-oxo-1-piperidinecarboxylate

2-propynyl chloride
624-65-7

2-propynyl chloride

benzyl 4-(3-chloroprop-1-ynyl)-4-hydroxypiperidine-1-carboxylate

benzyl 4-(3-chloroprop-1-ynyl)-4-hydroxypiperidine-1-carboxylate

Conditions
ConditionsYield
Stage #1: 2-propynyl chloride With n-butyllithium In tetrahydrofuran; hexane at -78℃; Inert atmosphere;
Stage #2: benzyl 4-oxo-1-piperidinecarboxylate In tetrahydrofuran; hexane at -78℃; for 6h; Inert atmosphere;
97%
2-hydroxyethyl vinyl ether
764-48-7

2-hydroxyethyl vinyl ether

2-propynyl chloride
624-65-7

2-propynyl chloride

ethylene glycol vinyl propargyl diether
14846-79-8

ethylene glycol vinyl propargyl diether

Conditions
ConditionsYield
With sodium hydroxide; tributyl-amine In water at 50 - 60℃; for 3h; Product distribution; other catalyst;96.8%
With sodium hydroxide; tributyl-amine In water at 50 - 60℃; for 3h;96.8%
ethylene glycol
107-21-1

ethylene glycol

2-propynyl chloride
624-65-7

2-propynyl chloride

α,ω-bis(O-propargyl)ethylene glycol
40842-04-4

α,ω-bis(O-propargyl)ethylene glycol

Conditions
ConditionsYield
With potassium hydroxide In dimethyl sulfoxide at 29 - 32℃; for 2h;96%

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