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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

2-Chloro-4-methylquinoline

Cas:634-47-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2-Chloro-4-Methylquinoline? supplier in China

Cas:634-47-9

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Chlorolepidine

Cas:634-47-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 634-47-9 with best quality

Cas:634-47-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Quinoline,2-chloro-4-methyl- 634-47-9

Cas:634-47-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

2-CHLOROLEPIDINE CAS:634-47-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermedia

2-CHLOROLEPIDINE CAS:634-47-9

Cas:634-47-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Quinoline,2-chloro-4-methyl-

Cas:634-47-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Mojin Biotechnology Co.,Ltd

Product quality: Our company have high quality product , and also the product we have good manufacture . First of all, this product is of fine quality. Every finish should be checked by quality inspection system.And every one should be also tried

2-Chloro-4-methylquinoline CAS NO.634-47-9

Cas:634-47-9

Min.Order:1 Kilogram

FOB Price: $20.0 / 30.0

Type:Trading Company

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Quinoline,2-chloro-4-methyl-

Cas:634-47-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

2-Chloro-4-Methylquinoline

Cas:634-47-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2-chlorolepidine

Cas:634-47-9

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Quinoline,2-chloro-4-methyl-

Cas:634-47-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 2-Chloro-4-Methylquinoline

Cas:634-47-9

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

2-CHLOROLEPIDINE,CAS:634-47-9

Cas:634-47-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Huarong Pharm Co., Ltd.

We Huarong Pharm can provide Customized Synthesis & Process R&D & APIs and intermediates Production & Quality Research & Registration Application, especially our GMP validation service which complies with SFDA, FDA, WHO and EU EMPA. O

2-CHLOROLEPIDINE

Cas:634-47-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

2-Chloro-4-methylquinoline

Cas:634-47-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

2-chloro-4-methylquinoline

Cas:634-47-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

Cas no.634-47-9 98% 2-CHLOROLEPIDINE

Cas:634-47-9

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

1,2,3-Trimethoxybenzene

Cas:634-47-9

Min.Order:0

Negotiable

Type:Other

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,Pharmaceutical intermediates Transportation:air,sea,courier

2-Chloro-4-methylquinoline

Cas:634-47-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

2-Chlorolepidine

Cas:634-47-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

2-Chloro-4-Methylquinoline

Cas:634-47-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Quinoline,2-chloro-4-methyl-

Cas:634-47-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:off-white powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as prima

2-Chloro-4-methylquinoline

Cas:634-47-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

2-Chloro-4-methylquinoline cas 634-47-9Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

2-Chloro-4-methylquinoline cas 634-47-9

Cas:634-47-9

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Best quality with low priceAppearance:white to light yellow crystal powder Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai

2-chlorolepidine

Cas:634-47-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

NANJING SUNNY PHARMATECH CO., LTD

We are professional supplier in China for this product, we are dedicated to providing customers with the best quality, price, and service. Please feel free to send us inquiries.Appearance:Please contact us for product details Package:As per shipment

2-CHLOROLEPIDINE

Cas:634-47-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

2-CHLOROLEPIDINE

Cas:634-47-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SAGECHEM LIMITED

634-47-9 Application:intermediate

2-chloro-4-methylquinoline

Cas:634-47-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemlyte Solutions

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

2-CHLOROLEPIDINE

Cas:634-47-9

Min.Order:0

Negotiable

Type:Other

inquiry

Synthetic route

4-methylquinoline 1-oxide
4053-40-1

4-methylquinoline 1-oxide

2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

Conditions
ConditionsYield
With trichlorophosphate In dichloromethane; N,N-dimethyl-formamide at 0 - 25℃; Inert atmosphere; regioselective reaction;81%
(4-methylquinolin-2-yl)diphenyl(6-(trifluoromethyl)pyridin-3-yl)phosphonium trifluoromethanesulfonate

(4-methylquinolin-2-yl)diphenyl(6-(trifluoromethyl)pyridin-3-yl)phosphonium trifluoromethanesulfonate

2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

Conditions
ConditionsYield
With lithium chloride In 1,4-dioxane at 80℃; for 72h; Inert atmosphere; Sealed tube; regioselective reaction;32%
4-methylquinolin-2-ol
607-66-9

4-methylquinolin-2-ol

2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

Conditions
ConditionsYield
With phosphorus pentachloride; trichlorophosphate for 24h; Chlorination; Heating;96%
With trichlorophosphate for 10h; Heating;82%
With phosphorus pentachloride; trichlorophosphate
2-Chloro-4-methylquinoline 1-oxide
10286-18-7

2-Chloro-4-methylquinoline 1-oxide

2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

Conditions
ConditionsYield
With tris(bipyridine)ruthenium(II) dichloride hexahydrate; di-tert-butyl 1,4-dihydro-2,6-dimethyl-3,5-pyridine-dicarboxylate In acetonitrile at 20℃; for 0.0833333h; Inert atmosphere; Irradiation; chemoselective reaction;82%
4-methyl-1,2-dihydroquinolin-2-one
607-66-9

4-methyl-1,2-dihydroquinolin-2-one

2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

Conditions
ConditionsYield
With phosphorus pentachloride; trichlorophosphate at 135 - 140℃;
With phosphorus pentachloride; benzoyl chloride at 250℃;
With ((1,3,5-triazine-2,4,6-triyl)tris(oxy))tris(triphenylphosphonium) chloride In neat (no solvent) at 140 - 150℃; for 2h;
With trichlorophosphate at 120℃; for 2h;
2-oxy-4-methyl-quinoline

2-oxy-4-methyl-quinoline

2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

Conditions
ConditionsYield
With trichlorophosphate at 80 - 85℃;
methylmagnesium chloride
676-58-4

methylmagnesium chloride

2,4-dichloroquinoline
703-61-7

2,4-dichloroquinoline

2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

Conditions
ConditionsYield
With zinc dibromide In tetrahydrofuran
N-phenylacetoacetamide
102-01-2

N-phenylacetoacetamide

2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: sulfuric acid / 1 h / 100 °C
2: trichlorophosphate / 2 h / 120 °C
View Scheme
Multi-step reaction with 2 steps
1: Polyphosphoric acid / 130 - 140 °C
2: trichlorophosphate; pyridine / 80 - 90 °C
View Scheme
aniline
62-53-3

aniline

[(Xantphos)2Pd(3-methyl-1-butenyl]OTf

[(Xantphos)2Pd(3-methyl-1-butenyl]OTf

2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: 0.07 h / microwave irradiation
1.2: H2SO4 / 0.08 h / microwave irradiation
2.1: 82 percent / POCl3 / 10 h / Heating
View Scheme
aniline
62-53-3

aniline

2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 3 h / 185 °C
2: sulfuric acid / 1 h / 100 °C
3: trichlorophosphate / 2 h / 120 °C
View Scheme
2-chloro-7(?)-amino-4-methyl-quinoline

2-chloro-7(?)-amino-4-methyl-quinoline

2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

Conditions
ConditionsYield
durch Ueberfuehren in 2-Chlor-7(?)-hydrazino-4-methyl-chinolin und folgendes Kochen mit Kupfersulfat-Loesung;
4-methylquinolin-2-ol
607-66-9

4-methylquinolin-2-ol

benzoyl chloride
98-88-4

benzoyl chloride

2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

Conditions
ConditionsYield
at 250℃;
2-chloro-4-methyl-7-aminoquinoline
114058-74-1

2-chloro-4-methyl-7-aminoquinoline

2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

Conditions
ConditionsYield
Reduzieren des Reaktionsprodukts mit salzsaurer Zinnchloruer-Loesung und Kochen des entstandenen Hydrazins mit Kupfersulfat-Loesung.Diazotization;
4-methylquinolin-2-ol
607-66-9

4-methylquinolin-2-ol

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

4-trifluoromethylphenylboronic acid
128796-39-4

4-trifluoromethylphenylboronic acid

4-methyl-2-(4-(trifluoromethyl)phenyl)-4-methylquinoline
863487-46-1

4-methyl-2-(4-(trifluoromethyl)phenyl)-4-methylquinoline

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In ethanol for 4h; Heating / reflux;100%
2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

4-methyl-1-naphthylboronic acid
103986-53-4

4-methyl-1-naphthylboronic acid

4-methyl-2-(4-methylnaphthalene-1-yl)quinoline

4-methyl-2-(4-methylnaphthalene-1-yl)quinoline

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 80℃; for 24h; Suzuki Coupling; Inert atmosphere;99.8%
2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

(R)-Phenylglycinol
56613-80-0

(R)-Phenylglycinol

(R)-N-(4-methyl-2-quinolyl)-phenylglycinol

(R)-N-(4-methyl-2-quinolyl)-phenylglycinol

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine In isopropyl alcohol at 130℃; for 46h;99%
thiophene boronic acid
6165-68-0

thiophene boronic acid

2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

4-(4-methylquinolin-4-yl)-diphenylaniline
20364-67-4

4-(4-methylquinolin-4-yl)-diphenylaniline

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water at 80℃; for 24h; Suzuki Coupling; Inert atmosphere;99%
With potassium carbonate; sodium tetrachloropalladate(II) In water; butan-1-ol at 100℃; for 12h; Suzuki cross-coupling;95%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In methanol; water; toluene at 85℃; for 8h; Suzuki Coupling; Inert atmosphere;87%
2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

4-methyl-2-(4'-methylphenyl)quinoline

4-methyl-2-(4'-methylphenyl)quinoline

Conditions
ConditionsYield
With ((C6H4)(PPh2)(NCHPhP(O)Ph2))NiCl In diethyl ether at 25℃; for 12h; Kumada cross-coupling; Inert atmosphere;99%
With C32H26ClN2NiP In tetrahydrofuran at 30℃; for 12h; Kumada Cross-Coupling; Schlenk technique; Inert atmosphere;95%
2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

p-tolylzinc(II) chloride
90252-89-4

p-tolylzinc(II) chloride

4-methyl-2-(4'-methylphenyl)quinoline

4-methyl-2-(4'-methylphenyl)quinoline

Conditions
ConditionsYield
With C26H24ClN2NiP*0.1C7H8 In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 80℃; for 24h; Negishi Coupling; Schlenk technique; Inert atmosphere;99%
With C38H34Br2N4Ni2P2 In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 40℃; for 12h; Reagent/catalyst; Negishi Coupling; Inert atmosphere; Schlenk technique;99%
With C27H22Cl2N3NiP In tetrahydrofuran; 1-methyl-pyrrolidin-2-one for 6h; Inert atmosphere; Schlenk technique; Heating;99%
2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

2-methylphenylzinc chloride
84109-17-1

2-methylphenylzinc chloride

4-methyl-2-(2'-methylphenyl)quinoline

4-methyl-2-(2'-methylphenyl)quinoline

Conditions
ConditionsYield
With C27H22Cl2N3NiP In tetrahydrofuran; 1-methyl-pyrrolidin-2-one for 24h; Inert atmosphere; Heating; Schlenk technique;99%
2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

cyclopentylzinc bromide lithium chloride

cyclopentylzinc bromide lithium chloride

2-cyclopentyl-4-methylquinoline

2-cyclopentyl-4-methylquinoline

Conditions
ConditionsYield
With Pd-PEPPSI-IPrAn In tetrahydrofuran; 1,4-dioxane at 0 - 20℃; for 6h; Negishi Coupling; Schlenk technique; Inert atmosphere;99%
2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

o-tolylmagnesium bromide

o-tolylmagnesium bromide

4-methyl-2-(2'-methylphenyl)quinoline

4-methyl-2-(2'-methylphenyl)quinoline

Conditions
ConditionsYield
With C32H26ClN2NiP In tetrahydrofuran at 30℃; for 12h; Kumada Cross-Coupling; Schlenk technique; Inert atmosphere;99%
2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

4-dimethylaminophenylmagnesium bromide
7353-91-5

4-dimethylaminophenylmagnesium bromide

N,N-dimethyl-4-(4-methylquinolin-2-yl)benzenamine
863487-47-2

N,N-dimethyl-4-(4-methylquinolin-2-yl)benzenamine

Conditions
ConditionsYield
With C32H26ClN2NiP In tetrahydrofuran at 30℃; for 24h; Time; Kumada Cross-Coupling; Schlenk technique; Inert atmosphere;99%
2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

mesitylzinc halide

mesitylzinc halide

2-mesityl-4-methylquinoline
1448351-76-5

2-mesityl-4-methylquinoline

Conditions
ConditionsYield
With silica supported Pd-PEPPSI-IPent In tetrahydrofuran at 25℃; for 0.111667h; Negishi Coupling; Flow reactor; Inert atmosphere;99%
1-methyl-piperazine
109-01-3

1-methyl-piperazine

2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

4-methyl-2-(4-methylpiperazin-1-yl)quinoline
100949-89-1

4-methyl-2-(4-methylpiperazin-1-yl)quinoline

Conditions
ConditionsYield
at 100℃; for 16h;98%
With ethanol
In toluene Heating;
2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

aniline
62-53-3

aniline

4-methyl-N-phenylquinolin-2-amine
10562-04-6

4-methyl-N-phenylquinolin-2-amine

Conditions
ConditionsYield
With C48H56ClN3Pd; potassium tert-butylate In tetrahydrofuran at 70℃; for 24h; Schlenk technique; Inert atmosphere;98%
In ethanol for 12h; Heating;74%
In butan-1-ol Heating;70%
2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

pyridin-2-ylzinc(II) bromide

pyridin-2-ylzinc(II) bromide

4-methyl-2-(α-pyridyl)quinoline
20364-45-8

4-methyl-2-(α-pyridyl)quinoline

Conditions
ConditionsYield
Stage #1: 2-chloro-4-methylquinoline; pyridin-2-ylzinc(II) bromide With dichloro(1,3-bis(2,6-bis(3-pentyl)phenyl)imidazolin-2-ylidene)(3-chloropyridyl)palladium(II); zinc(II) chloride In tetrahydrofuran at 23℃; for 24h; Negishi coupling; Inert atmosphere;
Stage #2: With sodium hydrogencarbonate; trisodium Edetate In tetrahydrofuran; water pH=8;
98%
tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 60℃; for 24h; Negishi reaction;92%
2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

trimethoxonium tetrafluoroborate
420-37-1

trimethoxonium tetrafluoroborate

2-chloro-4-methyl-N-methylquinolinium tetrafluoroborate

2-chloro-4-methyl-N-methylquinolinium tetrafluoroborate

Conditions
ConditionsYield
In dichloromethane; acetonitrile at 20℃; for 1.5h;98%
2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

2-(2,4-difluorophenyl)-4-methylquinoline

2-(2,4-difluorophenyl)-4-methylquinoline

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene at 110℃; for 16h; Suzuki-Miyaura Coupling; Inert atmosphere;98%
Suzuki Coupling; Inert atmosphere; Schlenk technique;
morpholine
110-91-8

morpholine

2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

4-(4-methylquinolin-2-yl)morpholine
79140-31-1

4-(4-methylquinolin-2-yl)morpholine

Conditions
ConditionsYield
With C48H56ClN3Pd; potassium tert-butylate In tetrahydrofuran at 70℃; for 24h; Schlenk technique; Inert atmosphere;97%
With aluminum oxide for 0.0319444h; microwave irradiation;91%
Stage #1: morpholine With C40H50BrCl2N3Pd; potassium tert-butylate at 20℃; Schlenk technique; Inert atmosphere;
Stage #2: 2-chloro-4-methylquinoline In toluene at 100℃; for 24h; Schlenk technique; Inert atmosphere;
82%
2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

3-methyl-5-oxo-2,5-dihydro-isoxazole-4-carboxylic acid ethyl ester
146037-86-7

3-methyl-5-oxo-2,5-dihydro-isoxazole-4-carboxylic acid ethyl ester

ethyl 3-methyl-2-(4-methylquinolin-2-yl)-5-oxo-2,5-dihydroisoxazole-4-carboxylate
153704-40-6

ethyl 3-methyl-2-(4-methylquinolin-2-yl)-5-oxo-2,5-dihydroisoxazole-4-carboxylate

Conditions
ConditionsYield
In nitrobenzene at 140℃; for 0.5h;97%
2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

N,N-dimethylethylenediamine
108-00-9

N,N-dimethylethylenediamine

N1,N1-dimethyl-N2-(4-methylquinolin-2-yl)ethane-1,2-diamine
141268-28-2

N1,N1-dimethyl-N2-(4-methylquinolin-2-yl)ethane-1,2-diamine

Conditions
ConditionsYield
With 2,6-di-tert-butyl-4-methyl-phenol; [1,3-bis(2,6-diisopentylphenyl)-4,5-dichloroimidazol-2-ylidene](3-chloropyridyl)palladium(II) dichloride; sodium hydride In toluene at 60℃; for 8h; Inert atmosphere; Schlenk technique;97%
at 100℃; for 16h;69%
2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

hex-1-yne
693-02-7

hex-1-yne

2-hex-1-ynyl-4-methyl-quinoline

2-hex-1-ynyl-4-methyl-quinoline

Conditions
ConditionsYield
With copper(l) iodide; triethylamine; bis-triphenylphosphine-palladium(II) chloride at 80℃; for 24h;97%
2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

m-phenylenediamine
108-45-2

m-phenylenediamine

N-(4-methylquinolin-2-yl)benzene-1,3-diamine
1436858-72-8

N-(4-methylquinolin-2-yl)benzene-1,3-diamine

Conditions
ConditionsYield
With hydrogenchloride In ethanol; water Heating;97%
2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

C8H10MgO

C8H10MgO

4-methyl-2-(4'-methoxyphenyl)quinoline
14428-50-3

4-methyl-2-(4'-methoxyphenyl)quinoline

Conditions
ConditionsYield
With C32H26ClN2NiP In tetrahydrofuran at 30℃; for 12h; Kumada Cross-Coupling; Schlenk technique; Inert atmosphere;97%
2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

ethyl 5-oxo-2,5-dihydroisoxazole-4-carboxylate
54535-14-7

ethyl 5-oxo-2,5-dihydroisoxazole-4-carboxylate

ethyl 2-(4-methylquinolin-2-yl)-5-oxo-2,5-dihydroisoxazole-4-carboxylate
153704-35-9

ethyl 2-(4-methylquinolin-2-yl)-5-oxo-2,5-dihydroisoxazole-4-carboxylate

Conditions
ConditionsYield
In nitrobenzene at 140℃; for 0.0833333h;96%
(2-hydroxyethyl)(methyl)amine
109-83-1

(2-hydroxyethyl)(methyl)amine

2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

2-[methyl-(4-methyl-quinolin-2-yl)-amino]-ethanol
95876-56-5

2-[methyl-(4-methyl-quinolin-2-yl)-amino]-ethanol

Conditions
ConditionsYield
Heating;96%
2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

m-tolylboronic acid
17933-03-8

m-tolylboronic acid

4-methyl-2-(m-tolyl)quinoline
1039775-39-7

4-methyl-2-(m-tolyl)quinoline

Conditions
ConditionsYield
With sodium tetrachloropalladate(II); dicyclohexyl {2-sulfo-9-[3-(4-sulfophenyl)propyl]-9H-fluoren-9-yl}phosphonium hydrogen sulfate; potassium carbonate In water; butan-1-ol at 100℃; for 12h; Suzuki coupling; Inert atmosphere;96%
2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

(meta-(trifluoromethyl)phenyl)boronic acid
1423-26-3

(meta-(trifluoromethyl)phenyl)boronic acid

4-methyl-2-(3-trifluoromethyl-phenyl)-quinoline
1039775-40-0

4-methyl-2-(3-trifluoromethyl-phenyl)-quinoline

Conditions
ConditionsYield
With sodium tetrachloropalladate(II); dicyclohexyl {2-sulfo-9-[3-(4-sulfophenyl)propyl]-9H-fluoren-9-yl}phosphonium hydrogen sulfate; potassium carbonate In water; butan-1-ol at 100℃; for 12h; Suzuki coupling; Inert atmosphere;96%
Suzuki Coupling; Inert atmosphere; Schlenk technique;
2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

(2,6-dimethylphenyl)magnesium bromide
21450-64-6

(2,6-dimethylphenyl)magnesium bromide

2-(2,6-dimethylphenyl)-4-methylquinoline
1224595-40-7

2-(2,6-dimethylphenyl)-4-methylquinoline

Conditions
ConditionsYield
Stage #1: (2,6-dimethylphenyl)magnesium bromide With dichloro(1,3-bis(2,6-bis(3-pentyl)phenyl)imidazolin-2-ylidene)(3-chloropyridyl)palladium(II); zinc(II) chloride In tetrahydrofuran at 23℃; for 0.333333h; Inert atmosphere;
Stage #2: 2-chloro-4-methylquinoline In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at 23℃; for 24h; Negishi coupling; Inert atmosphere;
96%
2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

2-furylzinc chloride
81745-86-0

2-furylzinc chloride

2-(furan-2-yl)-4-methylquinoline
20364-42-5

2-(furan-2-yl)-4-methylquinoline

Conditions
ConditionsYield
With C27H22Cl2N3NiP In tetrahydrofuran; 1-methyl-pyrrolidin-2-one for 2h; Inert atmosphere; Heating; Schlenk technique;96%
2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

(1,1'-biphenyl)-4,4'-dithiol
6954-27-4

(1,1'-biphenyl)-4,4'-dithiol

2,2'-(biphenyl-4,4'-diylbissulfanediyl)bis-(4-methylquinoline)
1608504-45-5

2,2'-(biphenyl-4,4'-diylbissulfanediyl)bis-(4-methylquinoline)

Conditions
ConditionsYield
In ethanol Reflux;96%

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