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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2,4-Difluorophenylboronic Acid supplier in China

Cas:144025-03-6

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co., LTD is a professional research, development and production 2-phenylacetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low carbon environ

2,4-Difluorophenylboronic acid CAS NO.144025-03-6

Cas:144025-03-6

Min.Order:100 Gram

FOB Price: $2.0

Type:Manufacturers

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

2,4-Difluorophenylboronic acid

Cas:144025-03-6

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2,4-Difluorophenylboronic Acid

Cas:144025-03-6

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 144025-03-6 2,4-difluorophenylboronic acid Manufacturer

Cas:144025-03-6

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price in China. If you are looking for the product’s supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product specifica

2,4-Difluorophenylboronic acid

Cas:144025-03-6

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2,4-Difluorobenzeneboronic acid

Cas:144025-03-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Leader Biochemical Group

About Product Technical Details

China Largest factory Manufacturer Supply Highest Quality 2,4-Difluorophenylboronic acid CAS 144025-03-6

Cas:144025-03-6

Min.Order:1 Kilogram

FOB Price: $1.0 / 3.0

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

2,4-Difluorophenylboronic acid Basic information Product Name: 2,4-Difluorophenylboronic acid Synonyms: RARECHEM AH PB 0168;2,4-DIFLUOROBENZENEBORONIC ACID;2,4-DIFLUOROPHENYLBORONIC ACID

144025-03-6

Cas:144025-03-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufactu

144025-03-6 2, 4-Difluorophenylboronic Acid

Cas:144025-03-6

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 144025-03-6 with competitive price

Cas:144025-03-6

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

CAS Number 144025-03-6 Product Name 2,4-difluorobenzeneboronic Acid Synonyms Scandium Tris(trifluoromethanesulfonate); 2,4-

2,4-Difluorophenylboronic acid

Cas:144025-03-6

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:White crystal fine powder. Storage:Store in sealed container

2,4-Difluorophenylboronic acid cas no 144025-03-6

Cas:144025-03-6

Min.Order:100 Gram

Negotiable

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

2,4-Difluorophenylboronic acid 144025-03-6

Cas:144025-03-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: 2,4-Difluorophenylboronic acid acid CAS: 144025-03-6 MF: C6H5BF2O2 MW: 157.91 EINECS: 604-390-9 Mol File: 144025-03-6.mol 2,4-Difluorophenylboronic acid Structure 2,4-Difluorophenylboronic acid Chemical Properties Me

2,4-Difluorophenylboronic acid

Cas:144025-03-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Chemical Intermediate, 2,4-Difluorophenylboronic acid CAS:144025-03-6

Cas:144025-03-6

Min.Order:1 Kilogram

FOB Price: $142.0 / 156.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

2,4-Difluorophenylboronic acid CAS: 144025-03-6 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality

2,4-Difluorophenylboronic acid CAS: 144025-03-6

Cas:144025-03-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

2,4-Difluorophenylboronic acid

Cas:144025-03-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram

2,4-Difluorophenylboronic acid CAS NO.144025-03-6 CAS NO.144025-03-6

Cas:144025-03-6

Min.Order:20 Metric Ton

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2,4-Difluorophenylboronic acid

Cas:144025-03-6

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

2,4-Difluorophenylboronic acid

Cas:144025-03-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

2,4-Difluorophenylboronic Acid

Cas:144025-03-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

4-bromo-1-butyl-3-(trifluoromethyl)-1H-pyrazole

Cas:144025-03-6

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Kunshan Push Trading Co.,LTD

2,4-difluorophenylboronic acid 144025-03-6 ADVANTAGE 1.Professional: More than 10 years chemical exporting experience. We have produced chemical more than fifteen years, 95% products are for export . More than 10 years chemical exporting experie

2,4-difluorophenylboronic acid 144025-03-6

Cas:144025-03-6

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2,4-difluorophenylboronic acid

Cas:144025-03-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

2,4-Difluorophenylboronic acid

Cas:144025-03-6

Min.Order:100 Gram

Negotiable

Type:Other

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

2,4-Difluorophenylboronic acid

Cas:144025-03-6

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

B-(2,4-Difluorophenyl)boronic acid

Cas:144025-03-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

2,4-Difluorophenylboronic acid

Cas:144025-03-6

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

2,4-Difluorophenylboronic acid

Cas:144025-03-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

Trimethyl borate
121-43-7

Trimethyl borate

(2,4-difluorophenyl)magnesium bromide
144025-04-7

(2,4-difluorophenyl)magnesium bromide

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

Conditions
ConditionsYield
With sulfuric acid In tetrahydrofuran; water84.3%
With sulfuric acid In tetrahydrofuran; water84.3%
In tetrahydrofuran74.8%
In tetrahydrofuran74.8%
Stage #1: Trimethyl borate; (2,4-difluorophenyl)magnesium bromide In tetrahydrofuran at -60℃; for 5h;
Stage #2: With hydrogenchloride In tetrahydrofuran; water at 0℃; pH=1; Inert atmosphere;
40%
2,4-difluorobromobenzene
348-57-2

2,4-difluorobromobenzene

Trimethyl borate
121-43-7

Trimethyl borate

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

Conditions
ConditionsYield
With n-butyllithium In diethyl ether; hexane n-BuLi (2.5 M, hexane) was added to C6F2BrH3 in Et2O at -70 °C, 1.5 equiv. of cold soln. of B(OMe)3 was added in Et2O, stirring at -60 °C for 1 h, mixt. was allowed to warm to 15 °C within 1 h; poured into 5 % HCl, org. layer was sepd., aq. layer was twice extd. with ether, extracts were combined, dried with MgSO4, evapn., solid was stored over water at 15 °C for 1 month;77%
C6H3BF5(1-)
871300-65-1

C6H3BF5(1-)

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

Conditions
ConditionsYield
In phosphate buffer pH=6.9 - 7.0; Kinetics;
tris(2,4-difluorophenyl)boroxine
512198-16-2

tris(2,4-difluorophenyl)boroxine

water
7732-18-5

water

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

Conditions
ConditionsYield
In acetonitrile
In diethyl ether
2-methoxy-ethanol
109-86-4

2-methoxy-ethanol

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

Conditions
ConditionsYield
With sodium carbonate In water; acetylacetone
diisopropyl 2,4-difluorophenylboronate

diisopropyl 2,4-difluorophenylboronate

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

Conditions
ConditionsYield
With hydrogenchloride In water1.15 g
2,4-difluorobromobenzene
348-57-2

2,4-difluorobromobenzene

tri-n-propyl borate
688-71-1

tri-n-propyl borate

water
7732-18-5

water

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

Conditions
ConditionsYield
Stage #1: 2,4-difluorobromobenzene With magnesium
Stage #2: tri-n-propyl borate
Stage #3: water Acidic conditions;
2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

3-Iodobenzoic acid
618-51-9

3-Iodobenzoic acid

2',4'-difluoro-[1,1'-biphenyl]-3-carboxylic acid

2',4'-difluoro-[1,1'-biphenyl]-3-carboxylic acid

Conditions
ConditionsYield
Stage #1: 3-Iodobenzoic acid With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; N-ethyl-N,N-diisopropylamine; Wang resin In dichloromethane at 20℃; for 22h;
Stage #2: 2,4-difluorophenylboronic acid With tris(dibenzylideneacetone)dipalladium (0); potassium carbonate In N,N-dimethyl-formamide at 20℃;
Stage #3: With trifluoroacetic acid In dichloromethane at 20℃; for 13h;
100%
2-bromo-pyridine
109-04-6

2-bromo-pyridine

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

2-(2,4-difluorophenyl)pyridine
391604-55-0

2-(2,4-difluorophenyl)pyridine

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In tetrahydrofuran at 70℃; for 24h; Suzuki coupling;100%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In tetrahydrofuran; water at 70℃; Inert atmosphere;98%
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran; water at 70℃; for 24h;97%
trifluoromethanesulfonic acid 6-methoxy-1-[4-(2-piperidin-1-ylethoxy)phenoxy]naphthalen-2-yl ester
648904-46-5

trifluoromethanesulfonic acid 6-methoxy-1-[4-(2-piperidin-1-ylethoxy)phenoxy]naphthalen-2-yl ester

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

1-(2-{4-[2-(2,4-difluoro-phenyl)-6-methoxy-naphthalen-1-yloxy]-phenoxy}-ethyl)-piperidine hydrochloride

1-(2-{4-[2-(2,4-difluoro-phenyl)-6-methoxy-naphthalen-1-yloxy]-phenoxy}-ethyl)-piperidine hydrochloride

Conditions
ConditionsYield
Stage #1: trifluoromethanesulfonic acid 6-methoxy-1-[4-(2-piperidin-1-ylethoxy)phenoxy]naphthalen-2-yl ester; 2,4-difluorophenylboronic acid With cesium fluoride; tricyclohexylphosphine; palladium diacetate In acetonitrile at 90℃; for 0.166667h; Suzuki Coupling;
Stage #2: With hydrogenchloride In diethyl ether
100%
4-Iodophenol
540-38-5

4-Iodophenol

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

4-(2,4-difluorophenyl)-phenol
59089-68-8

4-(2,4-difluorophenyl)-phenol

Conditions
ConditionsYield
With potassium carbonate; palladium(0)bis(tricyclohexylphosphine) In water; N,N-dimethyl-formamide Inert atmosphere; Reflux;100%
(6-Bromopyridin-2-yl)-[5-(2-tert-butyl-pyrimidin-4-yl)-2-methylphenyl]amine
1380281-66-2

(6-Bromopyridin-2-yl)-[5-(2-tert-butyl-pyrimidin-4-yl)-2-methylphenyl]amine

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

[5-(2-tert-Butyl-pyrimidin-4-yl)-2-methylphenyl]-[6-(2,4-difluorophenyl)-pyridin-2-yl]amine
1380281-67-3

[5-(2-tert-Butyl-pyrimidin-4-yl)-2-methylphenyl]-[6-(2,4-difluorophenyl)-pyridin-2-yl]amine

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In ethanol; water at 75℃; for 3h; Suzuki Coupling;100%
2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

2-bromo-6-(2,4-difluorophenyl)pyridine
1380281-57-1

2-bromo-6-(2,4-difluorophenyl)pyridine

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In ethanol; water at 75℃; for 2.5h; Product distribution / selectivity; Suzuki Coupling;100%
3-fluoro-5-iodosalicylic acid

3-fluoro-5-iodosalicylic acid

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

2′,4′,5-trifluoro-4-hydroxy-[1,1′-biphenyl]-3-carboxylic acid

2′,4′,5-trifluoro-4-hydroxy-[1,1′-biphenyl]-3-carboxylic acid

Conditions
ConditionsYield
With palladium diacetate; sodium carbonate In water at 20℃; for 3h; Suzuki Coupling; Inert atmosphere;100%
para-nitrophenyl bromide
586-78-7

para-nitrophenyl bromide

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

2,4-difluoro-4′-nitrobiphenyl
1178888-74-8

2,4-difluoro-4′-nitrobiphenyl

Conditions
ConditionsYield
With 1,1',1'',1'''-benzene-1,2,4,5-tetrayltetrakis(methylene)tetrakis-(piperidin-4-ol); palladium diacetate; potassium carbonate In ethanol; water at 20℃; Suzuki-Miyaura Coupling;100%
5-ethyl-4-iodo-2(5H)-furanone
1015792-46-7

5-ethyl-4-iodo-2(5H)-furanone

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

4-(2,4-difluorophenyl)-5-ethylfuran-2(5H)-one

4-(2,4-difluorophenyl)-5-ethylfuran-2(5H)-one

Conditions
ConditionsYield
With 1,1',1'',1'''-benzene-1,2,4,5-tetrayltetrakis(methylene)tetrakis-(piperidin-4-ol); palladium diacetate; potassium carbonate In ethanol; water at 20℃; for 0.25h; Suzuki-Miyaura Coupling;100%
4-(methylcyclohexyloxy)-2-chloropyridine

4-(methylcyclohexyloxy)-2-chloropyridine

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

2-(2,4-difluorophenyl)-4-(methylcyclohexyloxy)pyridine

2-(2,4-difluorophenyl)-4-(methylcyclohexyloxy)pyridine

Conditions
ConditionsYield
With palladium diacetate; sodium carbonate; triphenylphosphine In 1,4-dioxane; water Suzuki-Miyaura Coupling; Inert atmosphere; Reflux;100%
5-bromosalicyclic acid
89-55-4

5-bromosalicyclic acid

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

2',4'-difluoro-4-hydroxybiphenyl-3-carboxylic acid
22494-42-4

2',4'-difluoro-4-hydroxybiphenyl-3-carboxylic acid

Conditions
ConditionsYield
With 2-[5-(4-methylphenyl)isoxazol-3-yl]-5-(5-phenylisoxazol-3-yl)-1,3,4-oxadiazole·2PdCl2; potassium carbonate In water; N,N-dimethyl-formamide at 100℃; for 0.0166667h; Suzuki Coupling;99%
With potassium carbonate; palladium dichloride In water; N,N-dimethyl-formamide at 75℃; Temperature; Solvent; Reagent/catalyst; Sonication; Cooling;98.37%
With C11H8Cl4N2O3Pd; potassium carbonate In methanol; water; N,N-dimethyl-formamide at 100℃; for 0.0833333h; Suzuki Coupling;97%
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

2,4-difluoro-4'-methoxybiphenyl
90101-30-7

2,4-difluoro-4'-methoxybiphenyl

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; palladium diacetate In toluene at 80℃; for 16h; Suzuki-Miyaura coupling;99%
With potassium carbonate; 2-(dicyclohexylphosphino)-2'-methylbiphenyl; palladium on activated charcoal In N,N-dimethyl acetamide; water at 100℃; for 2h; Suzuki-Miyaura cross-coupling;64%
C29H29N3O4S
1144042-97-6

C29H29N3O4S

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

A

2-(2,4-difluorophenylthio)-N-isopropylbenzamide
1144043-13-9

2-(2,4-difluorophenylthio)-N-isopropylbenzamide

B

(+)-(S)-2-(benzyloxycarbonylamino)-1-(2,4-difluorophenyl)-3-(1H-indol-3-yl)propan-1-one
1144042-90-9

(+)-(S)-2-(benzyloxycarbonylamino)-1-(2,4-difluorophenyl)-3-(1H-indol-3-yl)propan-1-one

Conditions
ConditionsYield
With copper(I) 2-hydroxy-3-methylbenzoate; oxygen In N,N-dimethyl-formamide at 23℃; for 3h; optical yield given as %ee;A 99%
B 97%
4-bromo-5H-furan-2-one
56634-50-5

4-bromo-5H-furan-2-one

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

4-(2,4-difluorophenyl)furan-2(5H)-one

4-(2,4-difluorophenyl)furan-2(5H)-one

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; potassium fluoride In tetrahydrofuran; water for 5h; Inert atmosphere; Reflux;99%
C17H18BrNS2
1201683-05-7

C17H18BrNS2

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

2-(2,4-difluorophenyl)-4-(5-hexylthieno[3,2-b]thien-2-yl)pyridine
1341232-96-9

2-(2,4-difluorophenyl)-4-(5-hexylthieno[3,2-b]thien-2-yl)pyridine

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In tetrahydrofuran; water at 70℃; for 0.333333h; Suzuki coupling; Inert atmosphere; Microwave irradiation;99%
4-methoxyphenyl p-toluenesulfonate
3899-91-0

4-methoxyphenyl p-toluenesulfonate

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

2,4-difluoro-4'-methoxybiphenyl
90101-30-7

2,4-difluoro-4'-methoxybiphenyl

Conditions
ConditionsYield
With potassium phosphate; nickelocene; tricyclohexylphosphine In tetrahydrofuran at 20℃; for 8h; Reagent/catalyst; Glovebox; Inert atmosphere;99%
naphthalen-2-yl tosylate
7385-85-5

naphthalen-2-yl tosylate

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

2-(2,4-difluorophenyl)naphthalene

2-(2,4-difluorophenyl)naphthalene

Conditions
ConditionsYield
With potassium phosphate; bis(tricyclohexylphosphine)nickel(II) bromide In tetrahydrofuran; water at 20℃; Reagent/catalyst; Glovebox;99%
2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

3-methoxycarbonylphenyl tosylate

3-methoxycarbonylphenyl tosylate

methyl 3-(2,4-difluorophenyl)benzoate

methyl 3-(2,4-difluorophenyl)benzoate

Conditions
ConditionsYield
With potassium phosphate; bis(tricyclohexylphosphine)nickel(II) bromide In tetrahydrofuran; water at 20℃; Glovebox;99%
2,6-dichloro-4-iodopyridine
98027-84-0

2,6-dichloro-4-iodopyridine

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

2,6-dichloro-4-(2,4-difluorophenyl)pyridine

2,6-dichloro-4-(2,4-difluorophenyl)pyridine

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium hydrogencarbonate In 1,2-dimethoxyethane; water at 90℃; for 1h; Inert atmosphere;98.5%
para-bromoacetophenone
99-90-1

para-bromoacetophenone

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

1-(2',4'difluoro[1,1']biphenyl-4-yl)ethanone
53591-79-0

1-(2',4'difluoro[1,1']biphenyl-4-yl)ethanone

Conditions
ConditionsYield
With C20H12N2O8PdS2(2-)*2Na(1+); sodium hydroxide In water at 100℃; for 6h;98%
With C40H56Cl2FeN2O4P2; sodium carbonate In water; acetone at 20℃; for 4h; Suzuki coupling;92%
With [Pd(N-(3-chloro-2-quinoxalinyl)-N'-(2,6-diisopropylphenyl)imidazolium)(PPh3)Cl2]; potassium carbonate In water at 70℃; for 3h; Catalytic behavior; Suzuki-Miyaura Coupling;55%
With cis,cis,cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclope; potassium carbonate; bis(η3-allyl-μ-chloropalladium(II)) In xylene at 130℃; for 20h; Suzuki cross-coupling reaction;
With (R,R)-N,N'-bis[(2,4-dimethoxyphenyl)methyl]-1,2-cyclohexanediamine PdCl2 complex; potassium carbonate In N,N-dimethyl-formamide at 120℃; for 24h; Reactivity; Reagent/catalyst; Suzuki coupling; Aerobic conditions;99 %Spectr.
6-bromo-N-phenyl-N-(pyridin-2-yl)pyridin-2-amine
1246612-19-0

6-bromo-N-phenyl-N-(pyridin-2-yl)pyridin-2-amine

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

F2C6H3C5H3NN(C6H5)C5H4N
1246612-18-9

F2C6H3C5H3NN(C6H5)C5H4N

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate; triphenylphosphine In 1,2-dimethoxyethane; water for 6h; Inert atmosphere; Reflux;98%
n-butyldiethanolamine
102-79-4

n-butyldiethanolamine

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

6-butyl-2-(2',4'-difluorophenyl)-(N-B)-1,3,6,2-dioxazaborocane

6-butyl-2-(2',4'-difluorophenyl)-(N-B)-1,3,6,2-dioxazaborocane

Conditions
ConditionsYield
With magnesium sulfate In acetone at 35℃; for 1h;98%
2-chloro-4-methylquinoline
634-47-9

2-chloro-4-methylquinoline

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

2-(2,4-difluorophenyl)-4-methylquinoline

2-(2,4-difluorophenyl)-4-methylquinoline

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene at 110℃; for 16h; Suzuki-Miyaura Coupling; Inert atmosphere;98%
Suzuki Coupling; Inert atmosphere; Schlenk technique;
C16H19NO4S

C16H19NO4S

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

C20H19F2NO2S

C20H19F2NO2S

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; potassium phosphate In 1,4-dioxane at 50℃; for 8h; Inert atmosphere; regioselective reaction;98%
2-bromo-9H-fluorene
1133-80-8

2-bromo-9H-fluorene

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

C19H12F2

C19H12F2

Conditions
ConditionsYield
With C35H40N4O9(2+)*2Cl(1-); palladium diacetate; potassium hydroxide In ethanol at 100℃; for 1.5h; Suzuki Coupling; Green chemistry;98%
2-hydroxy-5-iodobenzoic acid
119-30-2

2-hydroxy-5-iodobenzoic acid

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

2',4'-difluoro-4-hydroxybiphenyl-3-carboxylic acid
22494-42-4

2',4'-difluoro-4-hydroxybiphenyl-3-carboxylic acid

Conditions
ConditionsYield
With C32H26Cl2N8O4Pd2; potassium carbonate In methanol; water for 0.0833333h; Suzuki-Miyaura Coupling; Reflux;98%
With choline chloride; palladium diacetate; sodium carbonate; glycerol at 60℃; for 5h; Suzuki-Miyaura Coupling;52%
7-{[(6-bromopyridin-2-yl)oxy]methyl}-7-methyl-2-nitro-6,7-dihydro-5H-imidazo[2,1-b][1,3]oxazine

7-{[(6-bromopyridin-2-yl)oxy]methyl}-7-methyl-2-nitro-6,7-dihydro-5H-imidazo[2,1-b][1,3]oxazine

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

7-({[6-(2,4-difluorophenyl)pyridin-2-yl]oxy}methyl)-7-methyl-2-nitro-6,7-dihydro-5H-imidazo[2,1-b][1,3]oxazine

7-({[6-(2,4-difluorophenyl)pyridin-2-yl]oxy}methyl)-7-methyl-2-nitro-6,7-dihydro-5H-imidazo[2,1-b][1,3]oxazine

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium carbonate In ethanol; water; N,N-dimethyl-formamide; toluene at 86℃; for 2.66667h; Suzuki Coupling; Inert atmosphere;97%
2-bromo-5-chlorobenzaldehyde
174265-12-4

2-bromo-5-chlorobenzaldehyde

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

4-chloro-2',4'-difluoro-[1,1'-biphenyl]-2-carbaldehyde

4-chloro-2',4'-difluoro-[1,1'-biphenyl]-2-carbaldehyde

Conditions
ConditionsYield
With potassium phosphate monohydrate; C66H84O10P2Pd In water; toluene at 45℃; for 3h; Reagent/catalyst; Solvent; Suzuki-Miyaura Coupling; Inert atmosphere;97%
With potassium phosphate monohydrate; C50H64NO6PPdS In water at 45℃; for 3h; Suzuki-Miyaura Coupling; Inert atmosphere; Sealed tube;
m-bromobenzoic acid
585-76-2

m-bromobenzoic acid

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

2',4'-difluoro-[1,1'-biphenyl]-3-carboxylic acid

2',4'-difluoro-[1,1'-biphenyl]-3-carboxylic acid

Conditions
ConditionsYield
With 4-(di-tert-butylphosphino)ethyltrimethylammonium chloride; sodium carbonate; sodium tetrachloropalladate(II) In water at 20℃; Suzuki reaction;96%
4-chloro-aniline
106-47-8

4-chloro-aniline

2,4-difluorophenylboronic acid
144025-03-6

2,4-difluorophenylboronic acid

2',4'-difluoro[1,1'-biphenyl]-4-amine

2',4'-difluoro[1,1'-biphenyl]-4-amine

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; palladium diacetate In toluene at 80℃; for 10h; Suzuki-Miyaura coupling;96%

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