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Hangzhou ZeErRui Chemical Co., Ltd.

Product Name:(S)-(-)-Methyl 2-chloropropionate Reference price:USD11.15/KG for 1MT EXW(update date:2019.06.01) Synonym:(2S)-2-Chloropropanoic acid methyl ester;(S)-2-Chloropropionic acid methyl;(2S)-2-chloropropionic acid methyl ester;methyl (2

Methyl (S)-(-)-chloropropionate manufacture

Cas:73246-45-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

(S)-(-)-Methyl 2-chloropropionate Manufacturer/High quality/Best price/In stock

Cas:73246-45-4

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

(S)-(-)-Methyl 2-chloropropionate

Cas:73246-45-4

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply (S)-methyl-2-chloropropionate

Cas:73246-45-4

Min.Order:1

Negotiable

Type:Other

inquiry

COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

(S)-(-)-Methyl 2-Chloropropionate

Cas:73246-45-4

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

(S)-(-)-2-Chloropropionic acid methyl ester

Cas:73246-45-4

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

TIANFUCHEM-- 73246-45-4--(S)-(-)-Methyl 2-chloropropionate in stock Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had established stable bus

TIANFUCHEM-- 73246-45-4--(S)-(-)-Methyl 2-chloropropionate in stock

Cas:73246-45-4

Min.Order:1 Metric Ton

FOB Price: $2000.0

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 73246-45-4 with best quality

Cas:73246-45-4

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Henan Sinotech Import&Export Corporation

Product name:(S)-(-)-Methyl 2-chloropropionate CAS No:73246-45-4 Appearance: colorless liquid Content:99% Appearance:Colorless clear liquid Storage:Preserve in well-closed, light-resistant and

S)-(-)-Methyl 2-chloropropionate

Cas:73246-45-4

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Shijiazhuang Sdyano Fine Chemical Co., Ltd

1. Best prices with satisfied quality; 2. It's clients' right to choose the package's Courier (EMS, DHL, FedEx, UPS); 3.It's clients' right to choose the packing way for his produccts from many recent effective packing ways;

(S)-(-)-Methyl 2-chloropropionate

Cas:73246-45-4

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Factory Supply High Quality CAS 73246-45-4 (S)-(-)-Methyl 2-chloropropionate

Cas:73246-45-4

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

(S)-(-)-Methyl 2-chloropropionate CAS:73246-45-4 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high qualit

(S)-(-)-Methyl 2-chloropropionate CAS:73246-45-4

Cas:73246-45-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Propanoic acid,2-chloro-, methyl ester, (2S)-

Cas:73246-45-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

(S)-(-)-Methyl 2-chloropropionate

Cas:73246-45-4

Min.Order:1 Kilogram

FOB Price: $80.0 / 100.0

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Propanoic acid,2-chloro-, methyl ester, (2S)-

Cas:73246-45-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

(S)-(-)-Methyl 2-chloropropionate

Cas:73246-45-4

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

(S)-(-)-Methyl 2-chloropropionate

Cas:73246-45-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

(S)-(-)-Methyl 2-chloropropionate

Cas:73246-45-4

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Saiwante (shanghai) New Material Technology Co., Ltd.

Appearance/Colour:Colorless liquid Refractive Index:n20/D 1.417(lit.) Boiling Point:130.8 °C at 760 mmHg Flash Point:37.6 °C PSA:26.30000 Density:1.116 g/cm3 LogP:0.78670 Storage Temp.:-20°C XLogP3:1.1 Hydrogen Bond Do

73246-45-4 (S)-methyl 2-chloropropanoate Hot-selling

Cas:73246-45-4

Min.Order:1 Gram

FOB Price: $5.0

Type:Trading Company

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

(S)-(-)-Methyl 2-chloropropionate

Cas:73246-45-4

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Siwei Development Group Ltd.

Product name: S-(-)-2-Chloropropionate Methyl Ester CAS No.:73246-45-4 Molecule Formula:C4H7ClO2 Molecule Weight:122.55 Purity: 99% Package: 25kg/drum Description:Colorless liquid Manufacture Standards:Enterprise Standard TESTING

High Quality S-(-)-2-Chloropropionate Methyl Ester in stock

Cas:73246-45-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

(S)-(-)-Methyl 2-chloropropionate Basic information Product Name: (S)-(-)-Methyl 2-chloropropionate Synonyms: 2-chloro-,methylester,(s)-propanoicaci;Methyl 2-chloropropanoate;(S)-(-)-2-CHLOROPROPIONIC ACID METHYL ESTER;(S)-2-CHLOROPROPIONIC AC

(S)-(-)-Methyl 2-chloropropionate

Cas:73246-45-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

(S)-(-)-Methyl 2-chloropropionate

Cas:73246-45-4

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

(S)-(-)-Methyl 2-chloropropionate

Cas:73246-45-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

(S)-(-)-Methyl 2-chloropropionate

Cas:73246-45-4

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

(S)-(-)-Methyl 2-chloropropionate

Cas:73246-45-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

(S)-(-)-Methyl 2-chloropropionate

Cas:73246-45-4

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

Methyl (S)-(-)-chloropropionate cas no. 73246-45-4 98%

Cas:73246-45-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

(S)-(-)-Methyl 2-chloropropionate

Cas:73246-45-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

L(-)-2-Chloropropionate methyl ester

Cas:73246-45-4

Min.Order:0

Negotiable

Type:Other

inquiry

Synthetic route

(R)-Methyl lactate
17392-83-5

(R)-Methyl lactate

methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

Conditions
ConditionsYield
With pyridine; thionyl chloride In N,N-dimethyl-formamide at 20 - 55℃; for 5h; Temperature; Reagent/catalyst; Solvent;90%
(R)-Methyl lactate
17392-83-5

(R)-Methyl lactate

A

methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

B

methyl (2R)-2-chloropropanoate
77287-29-7

methyl (2R)-2-chloropropanoate

Conditions
ConditionsYield
With pyridine; thionyl chloride In N,N-dimethyl-formamide at 20 - 55℃; for 6h;A 86%
B n/a
(S)-Methyl lactate
27871-49-4

(S)-Methyl lactate

methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

Conditions
ConditionsYield
With thionyl chloride at 100℃;75%
With thionyl chloride In diethyl ether at 20℃; for 16h;72%
methanol
67-56-1

methanol

(S)-2-chloropropanoic acid
29617-66-1

(S)-2-chloropropanoic acid

methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

Conditions
ConditionsYield
With thionyl chloride at 20℃; for 5h; Reflux;66%
With boron trifluoride
With thionyl chloride optical yield given as %ee;124 mg
(S)-2-chloropropanoic acid
29617-66-1

(S)-2-chloropropanoic acid

methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

Conditions
ConditionsYield
With hexane
methanol
67-56-1

methanol

L-Lactic acid
79-33-4

L-Lactic acid

methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

Conditions
ConditionsYield
With phosphorus pentachloride methyl ester of/the/ l-α-chloro-propionic acid;
methanol
67-56-1

methanol

(S)-2-chloropropionyl chloride
70110-24-6

(S)-2-chloropropionyl chloride

methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

(R)-Methyl lactate
17392-83-5

(R)-Methyl lactate

A

methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

B

methyl (2S)-2-bromopropanoate
20047-41-0, 57885-43-5, 5445-17-0, 62076-23-7

methyl (2S)-2-bromopropanoate

Conditions
ConditionsYield
With pyridine; thionyl chloride; hydrogen bromide Yield given. Multistep reaction. Yields of byproduct given;
methyl (2R)-2-chloropropanoate
77287-29-7

methyl (2R)-2-chloropropanoate

methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

Conditions
ConditionsYield
With N,N,N',N',N'',N''-hexamethylguanidinium chloride at 70℃; Product distribution; Further Variations:; Temperatures; Reagents;
methyl S-(-)-2-(chlorocarbonyloxy)propionate

methyl S-(-)-2-(chlorocarbonyloxy)propionate

A

methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

B

methyl (2R)-2-chloropropanoate
77287-29-7

methyl (2R)-2-chloropropanoate

Conditions
ConditionsYield
With N,N,N',N',N'',N''-hexamethylguanidinium chloride at 70℃; Product distribution; Further Variations:; Temperatures; Reagents;
(R)-2-chloropropionic acid
7474-05-7

(R)-2-chloropropionic acid

diazomethyl-trimethyl-silane
18107-18-1

diazomethyl-trimethyl-silane

A

methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

B

methyl (2R)-2-chloropropanoate
77287-29-7

methyl (2R)-2-chloropropanoate

Conditions
ConditionsYield
In methanol; hexane; toluene for 0.0833333h; Title compound not separated from byproducts;
2-chloro-propionic acid methyl ester
17639-93-9

2-chloro-propionic acid methyl ester

A

methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

B

methyl (2R)-2-chloropropanoate
77287-29-7

methyl (2R)-2-chloropropanoate

Conditions
ConditionsYield
With poly{N-[(1S,2S)-2-benzyloxycyclopentyl]maleimide} Resolution of racemate;
methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

A

methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

B

methyl (2R)-2-chloropropanoate
77287-29-7

methyl (2R)-2-chloropropanoate

Conditions
ConditionsYield
With Saccharomyces cerevisiae Old Yellow Enzyme 3 ene-reductase; nicotinamine adenine dinucleotide at 30℃; for 24h; pH=7.5; aq. buffer; Enzymatic reaction; optical yield given as %ee; stereoselective reaction;
methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

hydroquinone
123-31-9

hydroquinone

(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
96562-58-2

(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 80 - 90℃; for 3h; Temperature;95%
methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

potassium thioacetate
10387-40-3

potassium thioacetate

methyl (2R)‐2‐(acetylthio)propanoate
33302-03-3

methyl (2R)‐2‐(acetylthio)propanoate

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 20℃;94.8%
In acetone
methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

4-chloro-phenol
106-48-9

4-chloro-phenol

(R)-2-(4-chlorophenoxy)propanoic acid
3307-39-9, 20421-33-4, 20421-35-6, 20421-34-5

(R)-2-(4-chlorophenoxy)propanoic acid

Conditions
ConditionsYield
Stage #1: 4-chloro-phenol With potassium hydroxide In water at 60℃; for 0.5h;
Stage #2: methyl-(S)-2-chloropropionate In water at 60℃; for 4h; Reagent/catalyst;
92.2%
methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

cesium thioacetate
56827-86-2

cesium thioacetate

(S)-methyl 2-(acetylsulfanyl)propionate

(S)-methyl 2-(acetylsulfanyl)propionate

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 25℃;89%
methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

thioacetic acid
507-09-5

thioacetic acid

methyl (2R)‐2‐(acetylthio)propanoate
33302-03-3

methyl (2R)‐2‐(acetylthio)propanoate

Conditions
ConditionsYield
Stage #1: tiolacetic acid With caesium carbonate In N,N-dimethyl-formamide at 20℃; for 0.5h;
Stage #2: methyl-(S)-2-chloropropionate In N,N-dimethyl-formamide for 3h;
88%
Stage #1: tiolacetic acid With caesium carbonate In N,N-dimethyl-formamide for 0.5h;
Stage #2: methyl-(S)-2-chloropropionate In N,N-dimethyl-formamide at 20℃; for 1h;
82%
Stage #1: tiolacetic acid With caesium carbonate In N,N-dimethyl-formamide for 0.5h;
Stage #2: methyl-(S)-2-chloropropionate In N,N-dimethyl-formamide at 20℃; for 1h;
82%
methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

2,2-Dimethyl-1,3-diaminopropane
7328-91-8

2,2-Dimethyl-1,3-diaminopropane

dimethyl 2,2'-((2,2-dimethylpropane-1,3-diyl)bis(azanediyl))(2R,2'R)-dipropionate

dimethyl 2,2'-((2,2-dimethylpropane-1,3-diyl)bis(azanediyl))(2R,2'R)-dipropionate

Conditions
ConditionsYield
With potassium carbonate In acetonitrile for 24h; Reflux;85.9%
methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

9H-carbazole
86-74-8

9H-carbazole

C16H15NO2

C16H15NO2

Conditions
ConditionsYield
Stage #1: 9H-carbazole With sodium hydride In N,N-dimethyl-formamide; mineral oil at 25℃; for 1.5h; Inert atmosphere;
Stage #2: methyl-(S)-2-chloropropionate In N,N-dimethyl-formamide; mineral oil at 25℃; for 12h; Inert atmosphere;
84%
4-bromo-1H-pyrazole
2075-45-8

4-bromo-1H-pyrazole

methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

2-(4-bromo-pyrazol-1-yl)-propionic acid methyl ester
877399-68-3

2-(4-bromo-pyrazol-1-yl)-propionic acid methyl ester

Conditions
ConditionsYield
Stage #1: 4-bromo-1H-pyrazole With sodium hydride In N,N-dimethyl-formamide for 0.166667h;
Stage #2: methyl-(S)-2-chloropropionate In N,N-dimethyl-formamide for 4h;
77%
methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

5-(3-(3-ethyl-4-(2-(piperidin-4-yl)ethoxy)phenyl)-4,4-dimethyl-5-oxo-2-thioxoimidazolidin-1-yl)-3-(trifluoromethyl)picolinonitrile hydrochloride

5-(3-(3-ethyl-4-(2-(piperidin-4-yl)ethoxy)phenyl)-4,4-dimethyl-5-oxo-2-thioxoimidazolidin-1-yl)-3-(trifluoromethyl)picolinonitrile hydrochloride

(R)-methyl 2-(4-(2-(4-(3-(6-cyano-5-(trifluoromethyl)pyridin-3-yl)-5,5-dimethyl-4-oxo-2-thioxoimidazolidin-1-yl)-2-ethylphenoxy)ethyl)piperidin-1-yl)propanoate

(R)-methyl 2-(4-(2-(4-(3-(6-cyano-5-(trifluoromethyl)pyridin-3-yl)-5,5-dimethyl-4-oxo-2-thioxoimidazolidin-1-yl)-2-ethylphenoxy)ethyl)piperidin-1-yl)propanoate

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran at 85℃; for 48h;76%
methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

[(Ir(μ-pyrazolate)(CNBu(t))2)2]
185223-00-1

[(Ir(μ-pyrazolate)(CNBu(t))2)2]

(+/-)-[(CNBu-t)2(Cl)Ir(μ-pyrazolato)2Ir(η1-CH(Me)CO2Me)(CNBu-t)2]
203636-13-9, 315178-95-1

(+/-)-[(CNBu-t)2(Cl)Ir(μ-pyrazolato)2Ir(η1-CH(Me)CO2Me)(CNBu-t)2]

Conditions
ConditionsYield
In benzene CH3CO2CH(CH3)Cl was added to a soln. of complex in benzene, 30 min in the dark (Ar); the soln. was layered with hexane, allowed to stand 2 d in the darkness, crystals were sepd. by decantation, washed with cold hexane and vac.-dried; elem. anal.;65%
methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

hexafluoroacetone oxime
1645-76-7

hexafluoroacetone oxime

(R)-2-(2,2,2-Trifluoro-1-trifluoromethyl-ethylideneaminooxy)-propionic acid methyl ester
213010-46-9

(R)-2-(2,2,2-Trifluoro-1-trifluoromethyl-ethylideneaminooxy)-propionic acid methyl ester

Conditions
ConditionsYield
With potassium carbonate In acetonitrile 1) 0-5 deg C, 10 h; 2) 20 deg C, 10 h;64%
methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

methyl 2,4,6-tri-O-benzyl-β-D-galactopyranoside
55697-53-5

methyl 2,4,6-tri-O-benzyl-β-D-galactopyranoside

A

(R)-2-((2R,3S,4S,5R,6R)-3,5-Bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-4-yloxy)-propionic acid methyl ester
177421-03-3

(R)-2-((2R,3S,4S,5R,6R)-3,5-Bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-4-yloxy)-propionic acid methyl ester

B

(S)-2-((2R,3S,4S,5R,6R)-3,5-Bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-4-yloxy)-propionic acid methyl ester
177421-02-2

(S)-2-((2R,3S,4S,5R,6R)-3,5-Bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-4-yloxy)-propionic acid methyl ester

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide 1.) 60 deg C, 1 h, 2.) 60 deg C, 24 h;A 8.4%
B 57.2%
carbon disulfide
75-15-0

carbon disulfide

methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

2(R)-((R)-2-Methoxymethylpyrrolidin-1-ylthiocarbonylthio)-propansaeuremethylester

2(R)-((R)-2-Methoxymethylpyrrolidin-1-ylthiocarbonylthio)-propansaeuremethylester

Conditions
ConditionsYield
With sodium acetate In methanol56.8%
methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

4-(3-(3-chloro-4-(2-(piperazin-1-yl)ethoxy)phenyl)-4,4-dimethyl-5-oxo-2-thioxoimidazolidin-1-yl)-2-(trifluoromethyl)benzonitrile hydrochloride

4-(3-(3-chloro-4-(2-(piperazin-1-yl)ethoxy)phenyl)-4,4-dimethyl-5-oxo-2-thioxoimidazolidin-1-yl)-2-(trifluoromethyl)benzonitrile hydrochloride

(R)-methyl 2-(4-(2-(2-chloro-4-(3-(4-cyano-3-(trifluoromethyl)phenyl)-5,5-dimethyl-4-oxo-2-thioxoimidazolidin-1-yl)phenoxy)ethyl)piperazin-1-yl)propanoate

(R)-methyl 2-(4-(2-(2-chloro-4-(3-(4-cyano-3-(trifluoromethyl)phenyl)-5,5-dimethyl-4-oxo-2-thioxoimidazolidin-1-yl)phenoxy)ethyl)piperazin-1-yl)propanoate

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran at 80℃; for 6h;48.4%
methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

4-(3-(3-ethyl-4-(2-(piperidin-4-yl)ethoxy)phenyl)-4,4-dimethyl-5-oxo-2-thioxoimidazolidin-1-yl)-2-(trifluoromethyl)benzonitrile

4-(3-(3-ethyl-4-(2-(piperidin-4-yl)ethoxy)phenyl)-4,4-dimethyl-5-oxo-2-thioxoimidazolidin-1-yl)-2-(trifluoromethyl)benzonitrile

trifluoroacetic acid
76-05-1

trifluoroacetic acid

(R)-methyl 2-(4-(2-(4-(3-(4-cyano-3-(trifluoromethyl)phenyl)-5,5-dimethyl-4-oxo-2-thioxoimidazolidin-1-yl)-2-ethylphenoxy)ethyl)piperidin-1-yl)propanoate trifluoroacetate

(R)-methyl 2-(4-(2-(4-(3-(4-cyano-3-(trifluoromethyl)phenyl)-5,5-dimethyl-4-oxo-2-thioxoimidazolidin-1-yl)-2-ethylphenoxy)ethyl)piperidin-1-yl)propanoate trifluoroacetate

Conditions
ConditionsYield
Stage #1: methyl-(S)-2-chloropropionate; 4-(3-(3-ethyl-4-(2-(piperidin-4-yl)ethoxy)phenyl)-4,4-dimethyl-5-oxo-2-thioxoimidazolidin-1-yl)-2-(trifluoromethyl)benzonitrile With triethylamine In tetrahydrofuran at 85℃; for 48h;
Stage #2: trifluoroacetic acid In acetonitrile
47.5%
carbon disulfide
75-15-0

carbon disulfide

methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

(2S)-2-(methoxymethyl)-1-pyrrolidine
63126-47-6

(2S)-2-(methoxymethyl)-1-pyrrolidine

2(R)-((S)-2-Methoxymethylpyrrolidin-1-ylthiocarbonylthio)-propansaeuremethylester

2(R)-((S)-2-Methoxymethylpyrrolidin-1-ylthiocarbonylthio)-propansaeuremethylester

Conditions
ConditionsYield
With sodium acetate In methanol47.3%
methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

3-(4,5,6,7-tetrahydro-2H-indazol-2-yl)phenol

3-(4,5,6,7-tetrahydro-2H-indazol-2-yl)phenol

methyl (R)-2-(3-(4,5,6,7-tetrahydro-2H-indazol-2-yl)phenoxy)propanoate

methyl (R)-2-(3-(4,5,6,7-tetrahydro-2H-indazol-2-yl)phenoxy)propanoate

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 80℃; for 6h; Inert atmosphere;39%
methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

ethanolamine
141-43-5

ethanolamine

2-methyl-morpholin-3-one
13882-80-9

2-methyl-morpholin-3-one

Conditions
ConditionsYield
With sodium In 1,4-dioxane for 3h; Reflux;14.2%
methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

(R)-methyl p-tolyl sulfoxide
1519-39-7

(R)-methyl p-tolyl sulfoxide

(+)-SC,RS-3-chloro-1-(4-methylphenyl)sulphinyl-2-butanone
104891-12-5

(+)-SC,RS-3-chloro-1-(4-methylphenyl)sulphinyl-2-butanone

methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

methyl (2S)-2-amino-3-phenylpropanoate hydrochloride
7524-50-7

methyl (2S)-2-amino-3-phenylpropanoate hydrochloride

(2S,2'R)-dimethyl 3-phenyl-2,2'-iminodipropionate

(2S,2'R)-dimethyl 3-phenyl-2,2'-iminodipropionate

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide at 80 - 100℃; for 48h;
methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

aluminum isopropoxide
555-31-7

aluminum isopropoxide

iso-propyl-2-chloropropanoate
40058-87-5

iso-propyl-2-chloropropanoate

Conditions
ConditionsYield
at 25℃; Product distribution; also with titanium isopropoxide;
methyl-(S)-2-chloropropionate
73246-45-4

methyl-(S)-2-chloropropionate

A

methanol
67-56-1

methanol

B

(S)-2-chloropropanoic acid
29617-66-1

(S)-2-chloropropanoic acid

Conditions
ConditionsYield
subtilisin In water at 30℃; Kinetics;
With 2-(di(2-hydroxyethyl)amino)ethanesulfonic acid; esterase from Pseudomonas fluorescens In water at 25℃; pH=7.20; Enzyme kinetics;
With 2-(di(2-hydroxyethyl)amino)ethanesulfonic acid; lipase from Ophiostoma piliferum In water at 25℃; pH=7.20; Enzyme kinetics;
With 2-(di(2-hydroxyethyl)amino)ethanesulfonic acid; lipase from Bacillus thermocatenulanatus In water at 40℃; pH=7.20; Enzyme kinetics;

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