Product Name:Methyl (R)-(+)-2-(4-hydroxyphenoxy)propanoate Synonym:MAQ-Me;DHPPMe;(R)-2-(4-hydroxyphenoxy)-propionic acid methyl ester Cas No:96562-58-2 Molecular Formula:C10H12O4 Molecular Weight:196.2 Appearance:White or white crystalline Puri
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inquiryhigh quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai
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inquiryMethyl (R)-(+)-2-(4-hydroxyphenoxy)propanoate Basic information Product Name: Methyl (R)-(+)-2-(4-hydroxyphenoxy)propanoate Synonyms: METHYL-[(R)-(+)-2-(4-HYDROXYPH
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inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
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inquiryCAS Number 96562-58-2 Product Name Methyl (r)-2-(4-hydroxyphenoxy)propionate Molecular Formula C10H12O4
Cas:96562-58-2
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inquiryAppearance:White to Orange to Green powder Storage:room temperature Package:25kg/drum Application:Methyl 2-(4-Hydroxyphenoxy)propionate is an intermediate in the synthesis of (±)-Fluazifop (F407430), a grass-selective herbicide which inhibits acety
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inquiryProduct Name: Methyl (R)-(+)-2-(4-hydroxyphenoxy)propanoate CAS: 96562-58-2 MF: C10H12O4 MW: 196.2 EINECS: 411-950-4 P Mol File: 96562-58-2.mol Methyl (R)-(+)-2-(4-hydroxyphenoxy)propanoate Structure Methyl (R)-(+)-2-(4-hydroxyphen
Cas:96562-58-2
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Min.Order:1 Gram
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inquiryProduct name: Methyl (R)-(+)-2-(4-Hydroxyphenoxy)propionate CAS No.:96562-58-2 Molecule Formula:C10H12O4 Molecule Weight:196.20 Purity: 98.5% Package: 25kg/drum Description:Off-white crystalline powder Manufacture Standards:Enterprise
Cas:96562-58-2
Min.Order:1 Kilogram
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inquiryfactory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B
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inquirymethanol
(R)-2-(4-hydroxyphenoxy)propionic acid
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
Conditions | Yield |
---|---|
With catalyst prepared from tetra-N-propyl zirconate, n-propanol, r-Al2O3, H2PtCl6, and (NH4)2SO4 In toluene at 110℃; for 2h; Reagent/catalyst; | 95.2% |
With sulfuric acid In toluene at 70℃; for 3h; | 90% |
methyl-(S)-2-chloropropionate
hydroquinone
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 80 - 90℃; for 3h; Temperature; | 95% |
methyl (2S)-2-bromopropanoate
hydroquinone
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 80 - 90℃; for 3h; | 95% |
(RS)-methyl 2-(4-hydroxyphenoxy)propionate
A
(S)-(-)-2-(4-hydroxyphenoxy)propionic acid
B
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
Conditions | Yield |
---|---|
With Aspergillus oryzae WZ007; sodium hydroxide In water at 35℃; pH=7; Enzymatic reaction; | A 86.5% B 88.4% |
With lyophilized mycelium of Aspergillus oryzae WZ007 In aq. phosphate buffer at 30℃; pH=8; Enzymatic reaction; enantioselective reaction; | A n/a B n/a |
methyl (R)-2-(4-acetoxyphenoxy)propionate
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
Conditions | Yield |
---|---|
With hydrogenchloride In methanol | 96% (94-95% enantiomeric excess) |
hydroquinone
A
(S)-(-)-2-(4-hydroxyphenoxy)propionic acid
B
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: potassium hydroxide / dimethyl sulfoxide / 0 - 30 °C / Inert atmosphere 2: lyophilized mycelium of Aspergillus oryzae WZ007 / aq. phosphate buffer / 30 °C / pH 8 / Enzymatic reaction View Scheme | |
Multi-step reaction with 2 steps 1.1: sodium sulfite; sodium methylate / methanol / 0.5 h / 30 °C / Inert atmosphere 1.2: 6 h / Inert atmosphere 2.1: Aspergillus oryzae WZ007; sodium hydroxide / water / 35 °C / pH 7 / Enzymatic reaction View Scheme |
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
(R)-2-(4-hydroxyphenoxy)propionic acid
Conditions | Yield |
---|---|
With sodium hydroxide In water at 20℃; for 3h; | 92.3% |
1,3-benzodioxol-5-ylmethyl amine
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
Conditions | Yield |
---|---|
for 4.5h; Heating; | 87% |
2-iodophenylamine
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
Conditions | Yield |
---|---|
Stage #1: 2-iodophenylamine With diisobutylaluminium hydride In tetrahydrofuran; hexane at 0℃; for 0.5h; Inert atmosphere; Stage #2: (R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester In tetrahydrofuran; hexane at 0 - 20℃; for 12h; Inert atmosphere; | 87% |
Stage #1: 2-iodophenylamine With diisobutylaluminium hydride In tetrahydrofuran; hexane at 0℃; for 0.5h; Inert atmosphere; Stage #2: (R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester In tetrahydrofuran; hexane at 20℃; for 12h; Inert atmosphere; | 87% |
2,6-dichloroquinoxaline
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
(R)-(+)-methyl-2-[4-(6-chloro-2-quinoxalinyloxy)-phenoxy]-propionate
Conditions | Yield |
---|---|
With potassium carbonate In acetonitrile Heating; | 85.2% |
(2-aminomethylpyridine)
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
Conditions | Yield |
---|---|
for 7.5h; Heating; | 85% |
Cyclopropylamine
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
Conditions | Yield |
---|---|
for 8h; Heating; | 84% |
2,3-dichlorophenol
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
methyl (S)-2-(2,3-dichlorophenoxy)propionate
Conditions | Yield |
---|---|
Stage #1: 2,3-dichlorophenol; (R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester With triphenylphosphine In dichloromethane at 0℃; for 0.166667h; Mitsunobu Displacement; Inert atmosphere; Stage #2: With diethylazodicarboxylate In dichloromethane at 20℃; for 24h; Mitsunobu Displacement; | 83% |
Stage #1: 2,3-dichlorophenol; (R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester With triphenylphosphine In dichloromethane at 0℃; for 0.166667h; Inert atmosphere; Stage #2: With diethylazodicarboxylate In dichloromethane at 20℃; for 12h; Inert atmosphere; |
4-(aminomethyl)pyridine
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
Conditions | Yield |
---|---|
for 3.5h; Heating; | 81% |
cyclopropanemethylamine
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
Conditions | Yield |
---|---|
for 10h; Heating; | 78% |
3-Aminomethylpyridine
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
Conditions | Yield |
---|---|
for 5.5h; Heating; | 72% |
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 85.2 percent / K2CO3 / acetonitrile / Heating 2: 97 percent / 10 h / Heating View Scheme |
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 85.2 percent / K2CO3 / acetonitrile / Heating 2: 87 percent / 3 h / Heating View Scheme |
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 85.2 percent / K2CO3 / acetonitrile / Heating 2: 76 percent / 7 h / Heating View Scheme |
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 85.2 percent / K2CO3 / acetonitrile / Heating 2: 80 percent / 14 h / Heating View Scheme |
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 85.2 percent / K2CO3 / acetonitrile / Heating 2: 83 percent / 14 h / Heating View Scheme |
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 84 percent / 8 h / Heating 2: 68 percent / potassium carbonate / acetonitrile / 2 h / Heating View Scheme |
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 78 percent / 10 h / Heating 2: 88 percent / potassium carbonate / acetonitrile / 1.5 h / Heating View Scheme |
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 81 percent / 3.5 h / Heating 2: 65 percent / potassium carbonate / acetonitrile / 3 h / Heating View Scheme |
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 72 percent / 5.5 h / Heating 2: 62 percent / potassium carbonate / acetonitrile / 9 h / Heating View Scheme |
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 85 percent / 7.5 h / Heating 2: 88 percent / potassium carbonate / acetonitrile / 4 h / Heating View Scheme |
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 87 percent / 4.5 h / Heating 2: 67 percent / potassium carbonate / acetonitrile / 10 h / Heating View Scheme |
methyl chloroacetate
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
C13H16O6
Conditions | Yield |
---|---|
With disodium hydrogen phosphate; potassium carbonate; sodium iodide In acetone for 10h; Reflux; |
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: potassium carbonate; sodium iodide; disodium hydrogen phosphate / acetone / 10 h / Reflux 2: hydrogenchloride / ethanol; water / 5 - 6 h / 60 °C 3: N,N-dimethyl-formamide; water / 48 h / 90 °C / Autoclave View Scheme |
(R)-(+)-2-(4-hydroxyphenoxy)propionic acid methyl ester
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: potassium carbonate; sodium iodide; disodium hydrogen phosphate / acetone / 10 h / Reflux 2: hydrogenchloride / ethanol; water / 5 - 6 h / 60 °C 3: water; methanol / 1 h / Autoclave View Scheme |
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