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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

1-Naphthalenol,2-methyl-

Cas:7469-77-4

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory price Cosmetic 2-METHYL-1-NAPHTHOL 7469-77-4 Manufacturer

Cas:7469-77-4

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

2-METHYL-1-NAPHTHO Henan Tianfu Chemical Co.,LTD was built in 2009 with an ISO certificate in the past 5 years, we have grown up as a famous fine chemicals supplier in china and we had established stable business r

7469-77-4

Cas:7469-77-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 7469-77-4 with best quality

Cas:7469-77-4

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

1-Naphthalenol,2-methyl-

Cas:7469-77-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1-Naphthalenol,2-methyl-

Cas:7469-77-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

2-Methyl-1-naphthalenol

Cas:7469-77-4

Min.Order:1 Milligram

Negotiable

Type:Trading Company

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Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

2-Methyl-1-naphthol

Cas:7469-77-4

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

2-METHYL-1-NAPHTHOL

Cas:7469-77-4

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

2-Methyl-1-naphthol

Cas:7469-77-4

Min.Order:0

Negotiable

Type:Manufacturers

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Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec 2-Methyl-1-naphthol 5g

Cas:7469-77-4

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

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Antimex Chemical Limied

1-Naphthalenol,2-methyl-Appearance:detailed see specifications Storage:Keep away of light, cool place Package:25kg/drum;200kg/drum Application:Used in Synthesis, Pharmaceuticals and other fields Transportation:Sea/air/courier

1-Naphthalenol,2-methyl-

Cas:7469-77-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Guangdong Juda Chemical Industrial Co.,Limited

Factory supply high purity low priceAppearance:solid or liquid Storage:sealed in cool and dry place Package:As customer's requested Application:Pharma Intermediate Transportation:by courier/air/sea Port:Any port in China

2-Methyl-1-naphthalenol CAS No.7469-77-4

Cas:7469-77-4

Min.Order:0

Negotiable

Type:Trading Company

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Baoji Guokang Healthchem co.,ltd

Our?company?has?been?in?existence?for?658?years?since?its?establishment.?We?have?our?own?unique?team.?The??company?integrates?independent?research?and?development,?production?and?sales.?We?have?established?famous??brands?at?home?and?abroad.?At?presen

2-Methyl-1-naphthol

Cas:7469-77-4

Min.Order:0

Negotiable

Type:Trading Company

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Hangzhou Fandachem Co.,Ltd

1-Naphthalenol,2-methyl- cas 7469-77-4Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

1-Naphthalenol,2-methyl- cas 7469-77-4

Cas:7469-77-4

Min.Order:0

Negotiable

Type:Other

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Shanghai Yuanye Bio-Technology Co., Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:white powder Storage:Keep it in dry,shady and cool place Package:250mg Application:Pharma;Industry;Agricultural;chemical reaserch Transportation:by express or by sea Port:Any po

2-Methyl-1-Naphthol

Cas:7469-77-4

Min.Order:0

Negotiable

Type:Trading Company

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Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

2-Methyl-1-naphthol 7469-77-4

Cas:7469-77-4

Min.Order:0

Negotiable

Type:Trading Company

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ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

2-METHYL-1-NAPHTHOL

Cas:7469-77-4

Min.Order:0

Negotiable

Type:Trading Company

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Bide Pharmatech Ltd

Our mission is to provide high-quality and innovative products to our customers. By offering a broad range of products, custom synthesis and personalized services, Bide can help scientists speeding up their research in the chemical and pharmaceutical

2-Methyl-1-naphthol

Cas:7469-77-4

Min.Order:0

Negotiable

Type:Other

inquiry

Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

2-methyl-1-naphthalenol

Cas:7469-77-4

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai AngewChem Co., Ltd.

Shanghai AngewChemCo., Ltd. is an innovative enterprise on fine chemicals and pharmaceuticals. Based on Shanghai R&D center and Hunan chemical manufacturing plant, we offer chemical research, process development, and large-scale production. Com

2-Methyl-1-Naphthol

Cas:7469-77-4

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Jilin haofei import and export trade Co.,Ltd

Price, service, company and transport advantage: 1. Best service, place of origin China, high quality, and reasonable price. 2. It's customers' right to choose the package (EMS, DHL, FEDEX, UPS). 3. It's customers' right

1-Naphthalenol,2-methyl- CAS NO.7469-77-4

Cas:7469-77-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Chemical Technology Co.,LTD

1. Production capacity: we have three production base with high-tech production equipment and instruments, equipped with professional production personnel, meet your requirements.2. Quality assurance: we have a first-class testing equipment and testi

2-METHYL-1-NAPHTHOL

Cas:7469-77-4

Min.Order:0

Negotiable

Type:Other

inquiry

coolpharm Ltd

Cool Pharm Ltd, found in 3241,is a high-tech enterprise which provides customer synthesis service for domestic and international pharmaceutical companies according to international standards. Our business includes research , development, process opti

2-Methyl-1-naphthol

Cas:7469-77-4

Min.Order:0

Negotiable

Type:Other

inquiry

Finetech Industry Limited

FINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the 2-METHYL-1-NAPHTHOL, CAS:7469-77-4 with the most competitive price and the best quali

2-METHYL-1-NAPHTHOL

Cas:7469-77-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Pure Chemistry Scientific Inc.

2-Methyl-1-naphthol Application:80078440

2-Methyl-1-naphthol

Cas:7469-77-4

Min.Order:1 Gram

FOB Price: $500.0

Type:Trading Company

inquiry

GZ HONESTCHEM CO., LTD

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

2-Methyl-1-naphthol

Cas:7469-77-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai PotentPharm Science and Technology Co.,Ltd

1 good quality, better price and bettter service;2 Timely delivery;3 100% refunded if parcel is not delivered or poor quality.We will try to satisfy you upon receipt of your reply. I hope that we can become a long-term cooperative partner. Applicatio

2-Methyl-1-naphthol

Cas:7469-77-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

ZHENFEI INDUSTRY CO.,LTD

2-METHYL-1-NAPHTHOL

Cas:7469-77-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI ZZBIO CO., LTD.

Comprehensive range product, High quality, Quick shippment, COA with spectras Package:1g Application:pharmaceutical industry, food industry, research

2-Methyl-1-naphthol

Cas:7469-77-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

2-methylene-1-tetralone
13203-73-1

2-methylene-1-tetralone

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

Conditions
ConditionsYield
palladium-carbon In nitrogen; toluene98.5%
4-chloronaphthalen-1-ol
604-44-4

4-chloronaphthalen-1-ol

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

Conditions
ConditionsYield
With formaldehyd; hydrogen; dimethyl amine; Pd-C In ethanol97.5%
(1α,4α)-1,2,3,4-tetrahydro-2β-methyl-1,4-epoxynaphthalen-2α-ol
135678-58-9

(1α,4α)-1,2,3,4-tetrahydro-2β-methyl-1,4-epoxynaphthalen-2α-ol

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene for 5.5h; Heating;97%
methanol
67-56-1

methanol

α-naphthol
90-15-3

α-naphthol

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

Conditions
ConditionsYield
Conversion of starting material;96%
Conversion of starting material;94%
Conversion of starting material;93%
4-chloro-2-(dimethylaminomethyl)-1-naphthol

4-chloro-2-(dimethylaminomethyl)-1-naphthol

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

Conditions
ConditionsYield
Pd-C In ethanol95%
2-methylnaphthalen-1-yl dichloroacetate
110871-49-3

2-methylnaphthalen-1-yl dichloroacetate

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

Conditions
ConditionsYield
With sodium hydroxide In ethanol at 0℃; for 0.5h;94.7%
2-methyl-1-tetralone
1590-08-5

2-methyl-1-tetralone

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

Conditions
ConditionsYield
With (difluoroboryl)dimethylglyoximatocobalt(II) bis(acetonitrile); boron trifluoride diethyl etherate; 3-cyano-N-methyl-quinolinium perchlorate In acetonitrile at 20℃; for 0.5h; Irradiation; Inert atmosphere; Flow reactor;94%
With carbon disulfide; bromine Kochen des Reaktionsprodukts mit N.N-Dimethyl-anilin;
palladium on activated charcoal at 260℃;
Multi-step reaction with 2 steps
1: 71 percent / Et3N / dimethylformamide
2: 95 percent Chromat. / trityltetrafluoroborate, 2,6-lutidin / CH2Cl2 / 1 h / Ambient temperature; further reagents: tritylperchlorate
View Scheme
1-acetoxy-2-methylnaphthalene
5697-02-9

1-acetoxy-2-methylnaphthalene

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran at 66℃; for 4h; Cooling with ice; Inert atmosphere;88%
With lithium aluminium tetrahydride In tetrahydrofuran for 1h; Heating;70%
With lithium aluminium tetrahydride Yield given;
C15H21N2O2P
127136-78-1

C15H21N2O2P

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

Conditions
ConditionsYield
In formic acid for 1h; Heating;87.6%
With formic acid for 1h; Product distribution; Heating;87%
1-bromo-2-methylnaphtalene
2586-62-1

1-bromo-2-methylnaphtalene

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

Conditions
ConditionsYield
With cesiumhydroxide monohydrate; bis[(trimethylsilyl)methyl](1,5-cyclooctadiene)palladium(II); 2-((di-adamantan-1-yl)phosphaneyl)-1-(2,6-diisopropylphenyl)-1H-imidazole In tetrahydrofuran at 24℃; for 20h; Inert atmosphere;87%
Stage #1: 1-bromo-2-methylnaphtalene With potassium hydroxide; tris-(dibenzylideneacetone)dipalladium(0); 2-((di-adamantan-1-yl)phosphaneyl)-1-(2,6-diisopropylphenyl)-1H-imidazole In 1,4-dioxane; water at 100℃; for 20h; Inert atmosphere;
Stage #2: With hydrogenchloride In 1,4-dioxane; water at 20℃; Inert atmosphere;
83%
isopropylboronic acid
80041-89-0

isopropylboronic acid

2-methylnaphthalen-1-yl trifluoromethanesulfonate

2-methylnaphthalen-1-yl trifluoromethanesulfonate

A

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

B

1-isopropyl-2-methylnaphthalene
32114-79-7

1-isopropyl-2-methylnaphthalene

C

2-methyl-1-propylnaphthalene
54774-89-9

2-methyl-1-propylnaphthalene

Conditions
ConditionsYield
With potassium phosphate; C20H34O3P2; [Pd(cinnamyl)Cl]2 In toluene at 110℃; for 12h; Reagent/catalyst; Suzuki-Miyaura Coupling; Inert atmosphere;A 5%
B 83%
C 6%
isopropylboronic acid
80041-89-0

isopropylboronic acid

2-methylnaphthalen-1-yl trifluoromethanesulfonate

2-methylnaphthalen-1-yl trifluoromethanesulfonate

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

Conditions
ConditionsYield
With potassium phosphate; 1,3-bis-(diphenylphosphino)propane; [Pd(cinnamyl)Cl]2 In toluene at 110℃; for 12h; Reagent/catalyst; Solvent; Inert atmosphere;80%
1-hydroxy-2-naphthoic acid
86-48-6

1-hydroxy-2-naphthoic acid

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

Conditions
ConditionsYield
Stage #1: 1-hydroxy-2-naphthoic acid With chloroformic acid ethyl ester; triethylamine In tetrahydrofuran at 0℃; for 3h;
Stage #2: With sodium tetrahydroborate In tetrahydrofuran; water at 0 - 20℃; for 4h;
73%
(i) ClCO2Et, Et3N, THF, (ii) aq. NaBH4; Multistep reaction;
With sodium tetrahydroborate; triethylamine; methyl chloroformate 1) THF; Yield given. Multistep reaction;
Multi-step reaction with 2 steps
1: Et3N / tetrahydrofuran / 2 h / 0 °C
2: aq. NaBH4 / tetrahydrofuran / 0 °C
View Scheme
Multi-step reaction with 5 steps
1: 60 percent / diethyl ether / 0 °C
2: NaBH4 / methanol / 0.08 h / 0 °C
3: 0.3 M aq. NaIO4 / tetrahydrofuran / 17 h / 23 °C
4: 2.) H2O / 1.) ether, -78 deg C, 10 min, 2.) ether, 23 deg C, 4 h
5: trifluoroacetic acid / CH2Cl2 / 24 h / 23 °C
View Scheme
1-ethynyl-2-(prop-1-yn-1-yl)benzene
849799-68-4

1-ethynyl-2-(prop-1-yn-1-yl)benzene

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

Conditions
ConditionsYield
With [(tris(1-pyrazolyl)borate)Ru(P(phenyl)3)(CH3CN)2]PF6; water In various solvent(s) at 100℃; for 24h;71%
2-benzofuran-1(3H)-one
87-41-2

2-benzofuran-1(3H)-one

methacrylic acid methyl ester
80-62-6

methacrylic acid methyl ester

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

Conditions
ConditionsYield
Stage #1: 2-benzofuran-1(3H)-one With lithium hexamethyldisilazane In tetrahydrofuran at -78℃; for 0.416667h; Inert atmosphere;
Stage #2: methacrylic acid methyl ester In tetrahydrofuran at -78 - 20℃; Inert atmosphere; regioselective reaction;
66%
2-Methylnaphthalene
91-57-6

2-Methylnaphthalene

A

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

B

7-methyl-1-naphthalenol
6939-33-9

7-methyl-1-naphthalenol

Conditions
ConditionsYield
With tetrakis(pentafluorophenyl)porphyrin manganese(III) chloride; 3-chloro-benzenecarboperoxoic acid In dichloromethane; acetonitrile at 27℃; for 1h; Inert atmosphere; regioselective reaction;A 65.5%
B 4.7%
methanol
67-56-1

methanol

carbon monoxide
201230-82-2

carbon monoxide

1-(but-3-en-1-yl)-2-iodobenzene
24892-64-6

1-(but-3-en-1-yl)-2-iodobenzene

A

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

B

1,2,3,4-tetrahydro-1-oxo-2-naphthaleneacetic acid methyl ester
7430-89-9

1,2,3,4-tetrahydro-1-oxo-2-naphthaleneacetic acid methyl ester

Conditions
ConditionsYield
With triethylamine; bis-triphenylphosphine-palladium(II) chloride In acetonitrile; benzene at 100℃; under 62057.8 Torr; for 18h;A n/a
B 55%
(R)-2-hydroxy-2-methyl-3,4-dihydronaphthalen-1(2H)-one
104322-65-8

(R)-2-hydroxy-2-methyl-3,4-dihydronaphthalen-1(2H)-one

A

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

B

(R)-2-fluoro-2-methyl-3,4-dihydro-2H-naphthalen-1-one

(R)-2-fluoro-2-methyl-3,4-dihydro-2H-naphthalen-1-one

C

(S)-2-fluoro-2-methyl-3,4-dihydro-2H-naphthalen-1-one

(S)-2-fluoro-2-methyl-3,4-dihydro-2H-naphthalen-1-one

Conditions
ConditionsYield
With dimethylaminosulphur trifluoride In dichloromethane at -78 - 20℃; Yields of byproduct given. Title compound not separated from byproducts;A 54%
B n/a
C n/a
With dimethylaminosulphur trifluoride In dichloromethane at -78 - 20℃; Yield given. Title compound not separated from byproducts;A 54%
B n/a
C n/a
vinyl pivalate
3377-92-2

vinyl pivalate

2-bromo-1-phenyl-1-propanone
2114-00-3

2-bromo-1-phenyl-1-propanone

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

Conditions
ConditionsYield
Stage #1: vinyl pivalate; 2-bromo-1-phenyl-1-propanone With fac-tris[2-phenylpyridinato-C2,N]iridium(III); potassium carbonate In acetonitrile at 20℃; for 8h; Inert atmosphere; Irradiation;
Stage #2: With toluene-4-sulfonic acid In toluene Dean-Stark; Reflux;
53%
isopropylboronic acid
80041-89-0

isopropylboronic acid

2-methylnaphthalen-1-yl trifluoromethanesulfonate

2-methylnaphthalen-1-yl trifluoromethanesulfonate

A

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

B

1-isopropyl-2-methylnaphthalene
32114-79-7

1-isopropyl-2-methylnaphthalene

C

2-Methylnaphthalene
91-57-6

2-Methylnaphthalene

Conditions
ConditionsYield
With potassium phosphate; C20H34O3P2; [Pd(cinnamyl)Cl]2 In toluene at 110℃; for 12h; Suzuki-Miyaura Coupling; Inert atmosphere;A 51%
B 38%
C 6 %Chromat.
N,N-dimethyl-o-crotylbenzamide
99618-30-1

N,N-dimethyl-o-crotylbenzamide

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

Conditions
ConditionsYield
With methyllithium In tetrahydrofuran at -78 - 25℃; for 8h;50%
isopropylboronic acid
80041-89-0

isopropylboronic acid

2-methylnaphthalen-1-yl trifluoromethanesulfonate

2-methylnaphthalen-1-yl trifluoromethanesulfonate

A

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

B

2-methyl-1-propylnaphthalene
54774-89-9

2-methyl-1-propylnaphthalene

C

2-Methylnaphthalene
91-57-6

2-Methylnaphthalene

Conditions
ConditionsYield
With potassium phosphate; 4- (9-anthryl) -3-(tert-butyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole; [Pd(cinnamyl)Cl]2 In toluene at 110℃; for 12h; Reagent/catalyst; Inert atmosphere;A 50%
B 35%
C 9 %Chromat.
isopropylboronic acid
80041-89-0

isopropylboronic acid

2-methylnaphthalen-1-yl trifluoromethanesulfonate

2-methylnaphthalen-1-yl trifluoromethanesulfonate

A

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

B

2-Methylnaphthalene
91-57-6

2-Methylnaphthalene

Conditions
ConditionsYield
With potassium phosphate; [Pd(cinnamyl)Cl]2; triphenylphosphine In toluene at 110℃; for 12h; Reagent/catalyst; Inert atmosphere;A 44%
B 51 %Chromat.
methanol
67-56-1

methanol

α-naphthol
90-15-3

α-naphthol

A

4-methyl-1-naphthol
10240-08-1

4-methyl-1-naphthol

B

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

Conditions
ConditionsYield
ferric oxide Conversion of starting material;A n/a
B 40%
magnesium oxide Conversion of starting material;A n/a
B 31%
(+/-)-2-hydroxy-2-methyl-3,4-dihydro-2H-naphthalen-1-one
78506-98-6

(+/-)-2-hydroxy-2-methyl-3,4-dihydro-2H-naphthalen-1-one

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

Conditions
ConditionsYield
With pyridine; thionyl chloride at -10℃; for 1h;36%
tetrahydrofuran
109-99-9

tetrahydrofuran

4-Diazo-2-methylbenzo-2,5-cyclohexadienone
99230-11-2

4-Diazo-2-methylbenzo-2,5-cyclohexadienone

A

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

B

3'-methyl-4'-oxo-1',4'-dihydronaphthalene-1'-spiro-2-pyrane

3'-methyl-4'-oxo-1',4'-dihydronaphthalene-1'-spiro-2-pyrane

C

2-methyl-4-(tetrahydrofuran-2-yl)naphthol

2-methyl-4-(tetrahydrofuran-2-yl)naphthol

D

polymer; monomer(s): 2-methyl-4-diazonaphthalen-1(4H)-one; tetrahydrofuran

polymer; monomer(s): 2-methyl-4-diazonaphthalen-1(4H)-one; tetrahydrofuran

Conditions
ConditionsYield
at 0℃; Product distribution; Photolysis;A 17%
B 32%
C 8%
D 35%
2-benzofuran-1(3H)-one
87-41-2

2-benzofuran-1(3H)-one

2-methylpropenal
78-85-3

2-methylpropenal

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

Conditions
ConditionsYield
With lithium diisopropyl amide In tetrahydrofuran at -78 - 20℃; regioselective reaction;34%
2-methyl-1-tetralone
1590-08-5

2-methyl-1-tetralone

A

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

B

2-Bromo-2-methyl-1,2,3,4-tetrahydro-naphthalin-1-ol
72181-94-3

2-Bromo-2-methyl-1,2,3,4-tetrahydro-naphthalin-1-ol

Conditions
ConditionsYield
With Oxone; ammonium bromide In dichloromethaneA 27%
B 8%
isopropylboronic acid
80041-89-0

isopropylboronic acid

2-methylnaphthalen-1-yl trifluoromethanesulfonate

2-methylnaphthalen-1-yl trifluoromethanesulfonate

A

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

B

1-isopropyl-2-methylnaphthalene
32114-79-7

1-isopropyl-2-methylnaphthalene

Conditions
ConditionsYield
With potassium phosphate; C20H34O3P2; [Pd(cinnamyl)Cl]2 In toluene at 80℃; for 12h; Suzuki-Miyaura Coupling; Inert atmosphere;A 7%
B 24%
isopropylboronic acid
80041-89-0

isopropylboronic acid

2-methylnaphthalen-1-yl methanesulfonate

2-methylnaphthalen-1-yl methanesulfonate

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

Conditions
ConditionsYield
With potassium phosphate; C20H34O3P2; [Pd(cinnamyl)Cl]2 In toluene at 110℃; for 12h; Inert atmosphere;18%
2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

menadione
58-27-5

menadione

Conditions
ConditionsYield
With Co(salN-Medpt); oxygen In acetonitrile for 0.5h;100%
With methylene blue In methanol; water at 20℃; under 7500.75 Torr; for 0.266667h; Irradiation; Flow reactor;98%
Stage #1: 2-methylnaphthalen-1-ol In acetonitrile at 74.84℃;
Stage #2: With dihydrogen peroxide In acetonitrile for 0.75h; Reflux; chemoselective reaction;
97.3%
2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

2-Hydroxy-2-methyl-2H-naphthalene-1-one
141982-21-0

2-Hydroxy-2-methyl-2H-naphthalene-1-one

Conditions
ConditionsYield
With 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione In tetrahydrofuran at 20℃; for 14h;100%
With tert.-butylhydroperoxide; 3 A molecular sieve; MoO5*pyridine*HMPA In dichloromethane at 22℃; for 3.5h; other ortho-alkylated α- and β-Naphthols;93%
With tert.-butylhydroperoxide; 3 A molecular sieve; MoO5*pyridine*HMPA In dichloromethane at 22℃; for 3.5h;93%
2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

3,3’-dimethyl-1,1’-binaphthalenylidene-4,4’-dione
14453-57-7

3,3’-dimethyl-1,1’-binaphthalenylidene-4,4’-dione

Conditions
ConditionsYield
With 5% Bi/5% Pt on active charcoal; dihydrogen peroxide In methanol; water at 60℃; for 0.333333h; Reagent/catalyst;99.4%
2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

t-butyldimethylsiyl triflate
69739-34-0

t-butyldimethylsiyl triflate

1-(tert-butyldimethylsiloxy)-2-methylnaphthalene

1-(tert-butyldimethylsiloxy)-2-methylnaphthalene

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20 - 25℃; for 0.5h;99%
2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

4-amino-benzoic acid
150-13-0

4-amino-benzoic acid

4-((4-hydroxy-3-methylnaphthalen-1-yl)diazenyl)benzoic acid

4-((4-hydroxy-3-methylnaphthalen-1-yl)diazenyl)benzoic acid

Conditions
ConditionsYield
Stage #1: 4-amino-benzoic acid With hydrogenchloride; sodium nitrite In water at 0 - 5℃; for 0.25h;
Stage #2: 2-methylnaphthalen-1-ol With sodium hydroxide In ethanol; water
94%
Stage #1: 4-amino-benzoic acid With hydrogenchloride; sodium nitrite In water at 0℃; for 0.25h;
Stage #2: 2-methylnaphthalen-1-ol With sodium hydroxide In ethanol at 0 - 5℃;
92%
trifluoromethylsulfonic anhydride
358-23-6

trifluoromethylsulfonic anhydride

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

2-methylnaphthalen-1-yl trifluoromethanesulfonate

2-methylnaphthalen-1-yl trifluoromethanesulfonate

Conditions
ConditionsYield
With triethylamine In dichloromethane92%
With triethylamine In dichloromethane at -78℃; for 2h; Inert atmosphere;80%
With triethylamine In dichloromethane at -78 - 20℃; for 14h; Inert atmosphere;61%
2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

C11H10O3

C11H10O3

Conditions
ConditionsYield
With o-iodophenylacetic acid; 3-chloro-benzenecarboperoxoic acid In dichloromethane at 20℃; for 3h; Inert atmosphere;91%
4-methyl-morpholine
109-02-4

4-methyl-morpholine

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

Methandiphosphonsaeuretetrapropylester
28254-31-1

Methandiphosphonsaeuretetrapropylester

1,1-dichloromethyl-methyl ether
1191-17-9

1,1-dichloromethyl-methyl ether

1-Hydroxy-2-methyl-4-naphthaldehyd

1-Hydroxy-2-methyl-4-naphthaldehyd

A

tetra-n-propyl 2-(3-methyl-1-naphthyl)ethenylidene-1,1-diphosphonate

tetra-n-propyl 2-(3-methyl-1-naphthyl)ethenylidene-1,1-diphosphonate

B

Tetra-n-propyl 2-[4-hydroxy-3-methyl-1-naphthyl]-ethenylidene-1,1-diphosphonate
134787-49-8

Tetra-n-propyl 2-[4-hydroxy-3-methyl-1-naphthyl]-ethenylidene-1,1-diphosphonate

Conditions
ConditionsYield
titanium tetrachloride; tin(IV) chloride In tetrahydrofuran; dichloromethane; ethyl acetateA 90%
B n/a
2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

1,1,1-trifluoro-2-(1H-indol-3-yl)-4-phenylbut-3-yn-2-ol
1417717-41-9

1,1,1-trifluoro-2-(1H-indol-3-yl)-4-phenylbut-3-yn-2-ol

(S)-2-methyl-4-(4,4,4-trifluoro-3-(1H-indol-3-yl)-1-phenylbuta-1,2-dien-1-yl)naphthalen-1-ol

(S)-2-methyl-4-(4,4,4-trifluoro-3-(1H-indol-3-yl)-1-phenylbuta-1,2-dien-1-yl)naphthalen-1-ol

Conditions
ConditionsYield
With (11aR)-3,7-di-9-anthracenyl-10,11,12,13-tetrahydro-5-hydroxy-5-oxide diindeno[7,1de:10,70-fg][1,3,2] dioxaphosphocin In dichloromethane at 20℃; for 48h; Molecular sieve; enantioselective reaction;90%
2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

lead(IV) tetraacetate
546-67-8

lead(IV) tetraacetate

A

menadione
58-27-5

menadione

B

2-acetoxy-2-methylnaphthalen-1(2H)-one
76274-21-0

2-acetoxy-2-methylnaphthalen-1(2H)-one

Conditions
ConditionsYield
In benzene Ambient temperature;A 3%
B 88%
triphenyl phosphite
101-02-0

triphenyl phosphite

2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

ethylamine
75-04-7

ethylamine

N-Ethyl(2-methyl-1-naphthyl)amine
60632-35-1

N-Ethyl(2-methyl-1-naphthyl)amine

Conditions
ConditionsYield
85%
2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

N,N-dimethyl(methylene)ammonium chloride
30354-18-8

N,N-dimethyl(methylene)ammonium chloride

4-Dimethylaminomethyl-2-methyl-1-naphthol-hydrochlorid
81479-10-9

4-Dimethylaminomethyl-2-methyl-1-naphthol-hydrochlorid

Conditions
ConditionsYield
In acetonitrile84%
2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

2-methylnaphthalen-1-yl 4-methylbenzenesulfonate2-methyl-1-naphthol

2-methylnaphthalen-1-yl 4-methylbenzenesulfonate2-methyl-1-naphthol

Conditions
ConditionsYield
Stage #1: 2-methylnaphthalen-1-ol With potassium hydroxide In tetrahydrofuran at 20℃; for 0.0833333h; Inert atmosphere;
Stage #2: p-toluenesulfonyl chloride In tetrahydrofuran at 60℃; Inert atmosphere;
79%
Stage #1: 2-methylnaphthalen-1-ol With potassium hydroxide In tetrahydrofuran at 20℃; for 0.0833333h; Inert atmosphere;
Stage #2: p-toluenesulfonyl chloride In tetrahydrofuran at 20 - 60℃; Inert atmosphere;
79%
2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

4-fluorobenzylisocyanate
132740-43-3

4-fluorobenzylisocyanate

2-methylnaphthalen-1-yl 4-fluorobenzylcarbamate

2-methylnaphthalen-1-yl 4-fluorobenzylcarbamate

Conditions
ConditionsYield
With triethylamine In toluene Heating;78%
2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

3,5-dimethylphenyl isocyanate
54132-75-1

3,5-dimethylphenyl isocyanate

2-methylnaphthalen-1-yl 3,5-dimethylphenylcarbamate

2-methylnaphthalen-1-yl 3,5-dimethylphenylcarbamate

Conditions
ConditionsYield
With triethylamine In toluene Heating;78%
2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

A

menadione
58-27-5

menadione

B

2-acetoxy-2-methylnaphthalen-1(2H)-one
76274-21-0

2-acetoxy-2-methylnaphthalen-1(2H)-one

Conditions
ConditionsYield
With lead(IV) acetate In acetonitrile Ambient temperature;A 16%
B 74%
2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

A

phthiocol
483-55-6

phthiocol

B

menadione
58-27-5

menadione

Conditions
ConditionsYield
With dihydrogen peroxide; methyltrioxorhenium(VII) In acetic acid at 20℃; for 2h;A 6%
B 74%
2-methylnaphthalen-1-ol
7469-77-4

2-methylnaphthalen-1-ol

4‐bromo‐2‐methylnaphthalen‐1‐ol

4‐bromo‐2‐methylnaphthalen‐1‐ol

Conditions
ConditionsYield
With N-Bromosuccinimide In acetonitrile at 20 - 25℃; for 0.5h;74%
With N-Bromosuccinimide In acetonitrile at 20℃; for 0.5h;55%

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