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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

(S)-3-Hydroxy Myristic Acid Methyl Ester

Cas:76835-67-1

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Tetradecanoic acid,3-hydroxy-, methyl ester, (3S)-

Cas:76835-67-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Factory Supply High Quality CAS 76835-67-1 (R)-Methyl-3-Hydroxytetradecanoate

Cas:76835-67-1

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Saiwante (shanghai) New Material Technology Co., Ltd.

Melting Point:43-45°C Boiling Point:359.1±15.0 °C(Predicted) PKA:13.91±0.20(Predicted) PSA:46.53000 Density:0.931±0.06 g/cm3(Predicted) LogP:3.83130 Storage Temp.:-20 C Freezer XLogP3:5 Hydrogen Bond Dono

76835-67-1(S)-Methyl 3-hydroxytetradecanoate high purity

Cas:76835-67-1

Min.Order:1 Gram

FOB Price: $5.0

Type:Trading Company

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

(R)-Methyl-3-Hydroxytetradecanoate

Cas:76835-67-1

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

(R)-Methyl-3-Hydroxytetradecanoate

Cas:76835-67-1

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

(R)-Methyl-3-Hydroxytetradecanoate

Cas:76835-67-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

(R)-Methyl-3-Hydroxytetradecanoate

Cas:76835-67-1

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

(R)-Methyl-3-Hydroxytetradecanoate

Cas:76835-67-1

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

(R)-Methyl-3-Hydroxytetradecanoate

Cas:76835-67-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Tetradecanoic acid,3-hydroxy-, methyl ester, (3S)-

Cas:76835-67-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Tetradecanoic acid,3-hydroxy-, methyl ester, (3S)- Application:Organic Chemicals

Tetradecanoic acid,3-hydroxy-, methyl ester, (3S)-

Cas:76835-67-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

We are a trading company aiming at providing high-quality services to customers. Established for many years, with good reputation in the industry Storage:Sealed and preserved Application:Fine chemical intermediates, used as the main raw material for

(R)-Methyl-3-Hydroxytetradecanoate

Cas:76835-67-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Langyou International Trading Co., Ltd

(R)-Methyl-3-Hydroxytetradecanoate Application:(R)-Methyl-3-Hydroxytetradecanoate

(R)-Methyl-3-Hydroxytetradecanoate

Cas:76835-67-1

Min.Order:0

Negotiable

Type:Other

inquiry

Changchun Artel lmport and Export trade company

Supply top quality products with a reasonable price Application:api

76835-67-1

Cas:76835-67-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

(R)-METHYL-3-HYDROXYTETRADECANOATEAppearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

(R)-METHYL-3-HYDROXYTETRADECANOATE

Cas:76835-67-1

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

(R)-Methyl-3-Hydroxytetradecanoate

Cas:76835-67-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers2. Produce products of different specifications and sizes according to your requirements.3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures sta

(R)-Methyl-3-Hydroxytetradecanoate

Cas:76835-67-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Hangzhou ZeErRui Chemical Co., Ltd. is focused on customization, research and development and production of APIs and advanced intermediates, which can effectively compensate for the deficiencies of traditional CRO and CMO. Priority of high-tech barri

(R)-Methyl-3-Hydroxytetradecanoate

Cas:76835-67-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Newgreat Chemical Co., Ltd

Wuhan Xinweiye Chemical Co., Ltd. is mainly engaged in the process development and production of customized synthesis and pharmaceutical intermediates. We have professional researchers in organic synthesis, analytical chemistry and production process

(R)-Methyl-3-Hydroxytetradecanoate

Cas:76835-67-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Longxianng Runhui Trading Co.,Ltd

(R)-Methyl-3-HydroxytetradecanoateAppearance:Off-White to Pale Yellow Solid Storage:-20 C Freezer Package:Depended Application:Pharmaceuticals Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small amount. By air(airport to airpor

(R)-Methyl-3-Hydroxytetradecanoate

Cas:76835-67-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemlyte Solutions

factory?direct?sale Application:Fine chemical intermediates, used as the main raw material for the synthesis of various pesticides, medicines, surfactants, polymer monomers, and antifungal agents

(R)-Methyl-3-Hydroxytetradecanoate

Cas:76835-67-1

Min.Order:0

Negotiable

Type:Other

inquiry

Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Application:Medical or chemical

76835-67-1

Cas:76835-67-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

(R)-Methyl-3-Hydroxytetradecanoate

Cas:76835-67-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

Preview CBNumber: CB61030905 Chemical Name: (R)-Methyl-3-Hydroxytetradecanoate Molecular Formula:

(R)-Methyl-3-Hydroxytetradecanoate

Cas:76835-67-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Jilin haofei import and export trade Co.,Ltd

Price, service, company and transport advantage: 1. Best service, place of origin China, high quality, and reasonable price. 2. It's customers' right to choose the package (EMS, DHL, FEDEX, UPS). 3. It's customers' right

76835-67-1 CAS NO.76835-67-1

Cas:76835-67-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Changsha Easchem Co.,Limited

Changsha EASCHEM is a leading company in marketing ang distributing chemicals and new materials with establishment in 2013 by reregistering from Easchem International from China. We, EASCHEM, are the brand with the aim for erecting up Big Chemica

High Purity (R) -3 -Hydroxytetradecanoic acid methyl ester supplier in China

Cas:76835-67-1

Min.Order:0 Gram

FOB Price: $12.0 / 50.0

Type:Lab/Research institutions

inquiry

Yinghao Pharm Co.,Ltd.

Yinghao Pharm products include: leader molecule, heterocyclic compounds,chiral compounds, photoelectric materials, biochemical reagents etc. For example:benzene, pyrimidine, boricacid,pyridine, pyrazole, imidazole, pyrrole, fluorine and other derivat

Tetradecanoic acid, 3-hydroxy-, methyl ester, (S)- Or Methyl (S)-3-hydroxytetradecanoate

Cas:76835-67-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zouping Mingxing Chemical Co.,Ltd.

Productnumber:orlistatintermediates Productname:S-(3)-hydroxynutmegacidmethylester CasNo.:76835-67-1

Tetradecanoic acid,3-hydroxy-, methyl ester, (3S)-

Cas:76835-67-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai united Scientific Co.,Ltd.

United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

Tetradecanoic acid,3-hydroxy-, methyl ester, (3S)-

Cas:76835-67-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

Conditions
ConditionsYield
With hydrogenchloride; (R)-bis(acetato)(2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl)ruthenium; hydrogen In ethanol under 76005.1 Torr; for 68h; Inert atmosphere;91%
With 1,2-bis[(R,R)-2,5-diisopropylphospholano]ethane-RuBr2; hydrogen In methanol; water at 35℃; under 3102.9 Torr; for 20h;
With hydrogenchloride; hydrogen; (RuCl2<(S)-Binap>)2*NEt3 In methanol at 40 - 50℃; for 18h;
With hydrogen; (S)-ruthenium 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl In methanol at 100℃; under 3750.3 Torr; for 5h;
With hydrogenchloride; Ru(OCOCH3)2{(S)-2,2'-bis(diphenylphosphino)-1,1'-dinaphthyl)}; hydrogen In methanol at 65℃; under 11251.1 Torr; for 12h; enantioselective reaction;
methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

A

methyl (R)-3-hydroxytetradecanoate
76062-97-0

methyl (R)-3-hydroxytetradecanoate

B

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

Conditions
ConditionsYield
Stage #1: methyl 3-oxotetradecanoate With hydrogen; (S)-RuBINAP In hydrogenchloride; methanol under 1034.3 Torr;
Stage #2: under 2585.74 Torr; for 15h; Heating; Title compound not separated from byproducts;
A 87%
B n/a
With (COD)2Ru2Cl4(NCCH3)*(R)-BIPHEMP; hydrogen In methanol; dichloromethane at 80℃; under 26252.1 Torr; for 20h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With hydrogen; ultrasonicated (R,R)-tartaric acid-NaBr-modified Raney nickel catalyst <(R,R)-TA-NaBr-MRNi-U> In various solvent(s) at 100℃; under 750.06 Torr; for 48h; Title compound not separated from byproducts;
3-hydroxytetradecanoic acid
1961-72-4

3-hydroxytetradecanoic acid

A

methyl (R)-3-hydroxytetradecanoate
76062-97-0

methyl (R)-3-hydroxytetradecanoate

B

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

C

methyl (S)-3-acetoxytetradecanoate
131486-38-9

methyl (S)-3-acetoxytetradecanoate

Conditions
ConditionsYield
With vinyl acetate 1.) lipase PS-30, THF, 60 deg C, 24 h, 2.) ether; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
(3S)-3-hydroxytetradecanoic acid
35683-15-9

(3S)-3-hydroxytetradecanoic acid

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

methanol
67-56-1

methanol

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

A

methyl (R)-3-hydroxytetradecanoate
76062-97-0

methyl (R)-3-hydroxytetradecanoate

B

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

Conditions
ConditionsYield
With hydrogenchloride for 2h; Ambient temperature; Yield given. Title compound not separated from byproducts;
3-Butyryloxy-tetradecanoic acid methyl ester
120151-85-1

3-Butyryloxy-tetradecanoic acid methyl ester

A

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

B

(R)-3-Butyryloxy-tetradecanoic acid methyl ester
120151-90-8

(R)-3-Butyryloxy-tetradecanoic acid methyl ester

Conditions
ConditionsYield
With Geotrichum candidum lipase
methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

A

methyl (R)-3-hydroxytetradecanoate
76062-97-0

methyl (R)-3-hydroxytetradecanoate

B

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

Conditions
ConditionsYield
With Maltose 1.) yeast Saccharomyces serevisiae IFO 0565, phosphate buffer (pH 7.6), 30 deg C, 24 h, 2.) Et2O; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
(+/-)-3-hydroxytetradecanoic acid methyl ester
55682-83-2

(+/-)-3-hydroxytetradecanoic acid methyl ester

A

methyl (R)-3-hydroxytetradecanoate
76062-97-0

methyl (R)-3-hydroxytetradecanoate

B

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

Conditions
ConditionsYield
Yields of byproduct given. Title compound not separated from byproducts;
With CHIRALPAK AD-H column In ethanol; hexane Resolution of racemate;
methyl (S)-3-acetoxytetradecanoate
131486-38-9

methyl (S)-3-acetoxytetradecanoate

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

Conditions
ConditionsYield
With hydrogenchloride In methanol at 40℃;
With hydrogenchloride In methanol; water at 40℃; for 48h; Deacetylation;
vinyl acetate
108-05-4

vinyl acetate

(+/-)-3-hydroxytetradecanoic acid methyl ester
55682-83-2

(+/-)-3-hydroxytetradecanoic acid methyl ester

A

methyl (R)-3-hydroxytetradecanoate
76062-97-0

methyl (R)-3-hydroxytetradecanoate

B

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

C

methyl (R)-3-acetoxytetradecanoate

methyl (R)-3-acetoxytetradecanoate

D

methyl (S)-3-acetoxytetradecanoate
131486-38-9

methyl (S)-3-acetoxytetradecanoate

Conditions
ConditionsYield
immobilized lipase (Amano PS) In tetrahydrofuran at 26 - 28℃; for 120h; Acetylation; Title compound not separated from byproducts;
n-dodecanoyl chloride
112-16-3

n-dodecanoyl chloride

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: pyridine / CH2Cl2 / 3 h / 0 - 20 °C
1.2: 77.9 percent / methanol / 3 h / Heating
2.1: hydrogen / (S)-ruthenium 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl / methanol / 5 h / 100 °C / 3750.3 Torr
View Scheme
lauric acid
143-07-7

lauric acid

monomethoxy poly(ethylene glycol)

monomethoxy poly(ethylene glycol)

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: tetrahydrofuran / 0 - 20 °C
2.1: 14.72 g / 72 h / 20 °C
3.1: H2 / (S)-RuBINAP / methanol; aq. HCl / 1034.3 Torr
3.2: 15 h / 2585.74 Torr / Heating
View Scheme
N-laurylimidazole
3867-67-2

N-laurylimidazole

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: 14.72 g / 72 h / 20 °C
2.1: H2 / (S)-RuBINAP / methanol; aq. HCl / 1034.3 Torr
2.2: 15 h / 2585.74 Torr / Heating
View Scheme
(+/-)-3-hydroxytetradecanoic acid methyl ester
55682-83-2

(+/-)-3-hydroxytetradecanoic acid methyl ester

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: lipase(Amano PS) / tetrahydrofuran
2: 6M HCl / methanol / 40 °C
View Scheme
n-dodecanoyl chloride
112-16-3

n-dodecanoyl chloride

alcoholic NaOH

alcoholic NaOH

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: pyridine / CH2Cl2 / 1 h / Ambient temperature
2: methanol / 5 h / Heating
3: H2, AcOH / (S,S)-tartaric acid-NaBr-Raney nickel / various solvent(s) / 100 °C / 76000 Torr
View Scheme
2,2-dimethyl-4,6-dioxo-5-dodecanoyl-1,3-dioxane
111861-21-3

2,2-dimethyl-4,6-dioxo-5-dodecanoyl-1,3-dioxane

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: methanol / 5 h / Heating
2: H2, AcOH / (S,S)-tartaric acid-NaBr-Raney nickel / various solvent(s) / 100 °C / 76000 Torr
View Scheme
(R)-(-)-1-tetradecyn-3-ol
77889-04-4, 136022-04-3, 73501-38-9

(R)-(-)-1-tetradecyn-3-ol

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 1) 2.4 eq. n-BuLi; 2) 1.4 M H2SO4 / 1) THF, -78 deg C; 2) from -20 deg C to room temperature
2: 1) 2 eq. dicyclohexylborane; 2) NaOH, H2O2 / 1) THF, 0 deg C; 2) 40-50 deg C
3: HCl / 2 h / Ambient temperature
View Scheme
tetradec-1-yn-3-one
73501-40-3

tetradec-1-yn-3-one

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 1.4 eq. R-Alpine-Borane / neat (no solvent) / 8 h / 0 - 20 °C
2: 1) 2.4 eq. n-BuLi; 2) 1.4 M H2SO4 / 1) THF, -78 deg C; 2) from -20 deg C to room temperature
3: 1) 2 eq. dicyclohexylborane; 2) NaOH, H2O2 / 1) THF, 0 deg C; 2) 40-50 deg C
4: HCl / 2 h / Ambient temperature
View Scheme
(3R)-1-trimethylsilyl-tetradec-1-yn-3-ol
74794-26-6

(3R)-1-trimethylsilyl-tetradec-1-yn-3-ol

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 1) 2 eq. dicyclohexylborane; 2) NaOH, H2O2 / 1) THF, 0 deg C; 2) 40-50 deg C
2: HCl / 2 h / Ambient temperature
View Scheme
(R,S)-P-cyclohexyl-P-phenyl-P',P'-diphenyl-(6,6'-dimethylbiphenyl-2,2'-diyl) diphosphine

(R,S)-P-cyclohexyl-P-phenyl-P',P'-diphenyl-(6,6'-dimethylbiphenyl-2,2'-diyl) diphosphine

Ru2 (COD)2 Cl(mCl)3 (CH3 CN)

Ru2 (COD)2 Cl(mCl)3 (CH3 CN)

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

Conditions
ConditionsYield
In methanol; diethyl ether; dichloromethane; oxygen
(+/-)-3-hydroxytetradecanoic acid methyl ester
55682-83-2

(+/-)-3-hydroxytetradecanoic acid methyl ester

A

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

B

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

Conditions
ConditionsYield
With Porcine Pancreas Lipase; water In aq. phosphate buffer at 36℃; for 7h; pH=7.6; enantioselective reaction;A n/a
B n/a
With Porcine Pancreas Lipase; water In aq. phosphate buffer at 36℃; for 7h; pH=7.6; Resolution of racemate; enantioselective reaction;A n/a
B n/a
(+/-)-3-hydroxytetradecanoic acid methyl ester
55682-83-2

(+/-)-3-hydroxytetradecanoic acid methyl ester

A

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

B

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

C

(3S)-3-hydroxytetradecanoic acid
35683-15-9

(3S)-3-hydroxytetradecanoic acid

Conditions
ConditionsYield
With Porcine Pancreas Lipase; water In aq. phosphate buffer at 36℃; for 7h; pH=7.6; Resolution of racemate; enantioselective reaction;A n/a
B n/a
C n/a
acetoacetic acid methyl ester
105-45-3

acetoacetic acid methyl ester

A

methyl (R)-3-hydroxytetradecanoate
76062-97-0

methyl (R)-3-hydroxytetradecanoate

B

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: lithium diisopropyl amide / tetrahydrofuran; hexane / 1 h / 0 °C
1.2: undecyl halide / 16 h / -78 - 20 °C
2.1: dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; sodium formate; (R,R)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine / water / 6 h / 25 °C
View Scheme
2-Methoxypropene
116-11-0

2-Methoxypropene

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

methyl (S)-3-(2-methoxyprop-2-oxy)tetradecanoate
239136-78-8

methyl (S)-3-(2-methoxyprop-2-oxy)tetradecanoate

Conditions
ConditionsYield
With pyridinium p-toluenesulfonate at 0℃; for 0.166667h;98%
O-benzyl 2,2,2-trichloroacetimidate
81927-55-1

O-benzyl 2,2,2-trichloroacetimidate

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

methyl (S)-3-benzyloxytetradecanoate
112031-18-2

methyl (S)-3-benzyloxytetradecanoate

Conditions
ConditionsYield
With trifluorormethanesulfonic acid In dichloromethane; cyclohexane at 20℃; for 1h; Inert atmosphere;86%
trifluorormethanesulfonic acid In dichloromethane; cyclohexane for 3h; Ambient temperature;79%
(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

(3S)-3-hydroxytetradecanoic acid
35683-15-9

(3S)-3-hydroxytetradecanoic acid

Conditions
ConditionsYield
Stage #1: (S)-methyl 3-hydroxymyristate With potassium hydroxide In water for 1h; Reflux;
Stage #2: With hydrogenchloride In water pH=2;
80%
With sodium hydroxide In methanol Heating; Yield given;
With lithium hydroxide In tetrahydrofuran for 4h; Ambient temperature; Yield given;
With sodium hydroxide In methanol; water at 90℃; for 0.5h; Hydrolysis;11.6 g
With lithium hydroxide In methanol; water for 12h;
3,4-dihydro-2H-pyran
110-87-2

3,4-dihydro-2H-pyran

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

methyl (S)-3-tetrahydropyranyloxytetradecanoate
94953-84-1, 94992-69-5, 104871-96-7

methyl (S)-3-tetrahydropyranyloxytetradecanoate

Conditions
ConditionsYield
With toluene-4-sulfonic acid
(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

(S)-3-O-triethylsilyl myristic acid
915406-29-0

(S)-3-O-triethylsilyl myristic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: lithium hydroxide monohydrate / methanol; H2O / 12 h
2: pyridine / 2 h / 60 °C
View Scheme
(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

benzyl (S)-3-O-triethylsilyl-hydroxymyristate
915406-31-4

benzyl (S)-3-O-triethylsilyl-hydroxymyristate

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: lithium hydroxide monohydrate / methanol; H2O / 12 h
2: pyridine / 2 h / 60 °C
3: 81 percent / N-(3-dimethylaminopropyl)-N'-ethyl carbodiimide HCl; DMAP / CH2Cl2 / 12 h / 20 °C
View Scheme
(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

(S)-Benzyl 3-hydroxytetradecanoate

(S)-Benzyl 3-hydroxytetradecanoate

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: lithium hydroxide monohydrate / methanol; H2O / 12 h
2: pyridine / 2 h / 60 °C
3: 81 percent / N-(3-dimethylaminopropyl)-N'-ethyl carbodiimide HCl; DMAP / CH2Cl2 / 12 h / 20 °C
4: 98 percent / trifluoroacetic acid / CH2Cl2 / 0.17 h
View Scheme
(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 98 percent / pyridinium p-toluenesulfonate / 0.17 h / 0 °C
2: 13.7 g / DIBAL / toluene / 0.5 h / -70 °C
3: 2.) 2N HCl / 1.) THF, -100 to -95 deg C, 30 min; warm to room temperature, overnight, 2.) 0 deg C, 20 min
View Scheme
(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

(S)-3-(2-methoxyprop-2-oxy)tetradecanal
239136-79-9

(S)-3-(2-methoxyprop-2-oxy)tetradecanal

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 98 percent / pyridinium p-toluenesulfonate / 0.17 h / 0 °C
2: 13.7 g / DIBAL / toluene / 0.5 h / -70 °C
View Scheme
(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

(3R,4R)-3-hexyl-4-<(2S)-2-hydroxytridecyl>oxetan-2-one

(3R,4R)-3-hexyl-4-<(2S)-2-hydroxytridecyl>oxetan-2-one

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 98 percent / pyridinium p-toluenesulfonate / 0.17 h / 0 °C
2: 13.7 g / DIBAL / toluene / 0.5 h / -70 °C
3: 2.) 2N HCl / 1.) THF, -100 to -95 deg C, 30 min; warm to room temperature, overnight, 2.) 0 deg C, 20 min
View Scheme
(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

tert-butyldimethylsilyl chloride
18162-48-6

tert-butyldimethylsilyl chloride

methyl (S)-3-(tert-butyldimethylsilyloxy)tetradecanoate
108052-02-4

methyl (S)-3-(tert-butyldimethylsilyloxy)tetradecanoate

Conditions
ConditionsYield
With 1H-imidazole In DMF (N,N-dimethyl-formamide) at 5 - 20℃; for 8 - 10h;

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