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inquiryMelting Point:43-45°C Boiling Point:359.1±15.0 °C(Predicted) PKA:13.91±0.20(Predicted) PSA:46.53000 Density:0.931±0.06 g/cm3(Predicted) LogP:3.83130 Storage Temp.:-20 C Freezer XLogP3:5 Hydrogen Bond Dono
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inquiryfactory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B
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inquiryLower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe
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inquiryAnsciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali
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inquiryTetradecanoic acid,3-hydroxy-, methyl ester, (3S)- Application:Organic Chemicals
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inquiry(R)-Methyl-3-Hydroxytetradecanoate Application:(R)-Methyl-3-Hydroxytetradecanoate
Supply top quality products with a reasonable price Application:api
(R)-METHYL-3-HYDROXYTETRADECANOATEAppearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express
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inquiryHangzhou ZeErRui Chemical Co., Ltd. is focused on customization, research and development and production of APIs and advanced intermediates, which can effectively compensate for the deficiencies of traditional CRO and CMO. Priority of high-tech barri
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inquiry(R)-Methyl-3-HydroxytetradecanoateAppearance:Off-White to Pale Yellow Solid Storage:-20 C Freezer Package:Depended Application:Pharmaceuticals Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small amount. By air(airport to airpor
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inquiryfactory?direct?sale Application:Fine chemical intermediates, used as the main raw material for the synthesis of various pesticides, medicines, surfactants, polymer monomers, and antifungal agents
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inquiryPreview CBNumber: CB61030905 Chemical Name: (R)-Methyl-3-Hydroxytetradecanoate Molecular Formula:
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inquiryPrice, service, company and transport advantage: 1. Best service, place of origin China, high quality, and reasonable price. 2. It's customers' right to choose the package (EMS, DHL, FEDEX, UPS). 3. It's customers' right
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inquirymethyl 3-oxotetradecanoate
(S)-methyl 3-hydroxymyristate
Conditions | Yield |
---|---|
With hydrogenchloride; (R)-bis(acetato)(2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl)ruthenium; hydrogen In ethanol under 76005.1 Torr; for 68h; Inert atmosphere; | 91% |
With 1,2-bis[(R,R)-2,5-diisopropylphospholano]ethane-RuBr2; hydrogen In methanol; water at 35℃; under 3102.9 Torr; for 20h; | |
With hydrogenchloride; hydrogen; (RuCl2<(S)-Binap>)2*NEt3 In methanol at 40 - 50℃; for 18h; | |
With hydrogen; (S)-ruthenium 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl In methanol at 100℃; under 3750.3 Torr; for 5h; | |
With hydrogenchloride; Ru(OCOCH3)2{(S)-2,2'-bis(diphenylphosphino)-1,1'-dinaphthyl)}; hydrogen In methanol at 65℃; under 11251.1 Torr; for 12h; enantioselective reaction; |
methyl 3-oxotetradecanoate
A
methyl (R)-3-hydroxytetradecanoate
B
(S)-methyl 3-hydroxymyristate
Conditions | Yield |
---|---|
Stage #1: methyl 3-oxotetradecanoate With hydrogen; (S)-RuBINAP In hydrogenchloride; methanol under 1034.3 Torr; Stage #2: under 2585.74 Torr; for 15h; Heating; Title compound not separated from byproducts; | A 87% B n/a |
With (COD)2Ru2Cl4(NCCH3)*(R)-BIPHEMP; hydrogen In methanol; dichloromethane at 80℃; under 26252.1 Torr; for 20h; Yield given. Yields of byproduct given. Title compound not separated from byproducts; | |
With hydrogen; ultrasonicated (R,R)-tartaric acid-NaBr-modified Raney nickel catalyst <(R,R)-TA-NaBr-MRNi-U> In various solvent(s) at 100℃; under 750.06 Torr; for 48h; Title compound not separated from byproducts; |
diazomethane
3-hydroxytetradecanoic acid
A
methyl (R)-3-hydroxytetradecanoate
B
(S)-methyl 3-hydroxymyristate
C
methyl (S)-3-acetoxytetradecanoate
Conditions | Yield |
---|---|
With vinyl acetate 1.) lipase PS-30, THF, 60 deg C, 24 h, 2.) ether; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; |
diazomethane
(3S)-3-hydroxytetradecanoic acid
(S)-methyl 3-hydroxymyristate
methanol
(R)-3-hydroxytetradecanoic acid
A
methyl (R)-3-hydroxytetradecanoate
B
(S)-methyl 3-hydroxymyristate
Conditions | Yield |
---|---|
With hydrogenchloride for 2h; Ambient temperature; Yield given. Title compound not separated from byproducts; |
3-Butyryloxy-tetradecanoic acid methyl ester
A
(S)-methyl 3-hydroxymyristate
B
(R)-3-Butyryloxy-tetradecanoic acid methyl ester
Conditions | Yield |
---|---|
With Geotrichum candidum lipase |
diazomethane
methyl 3-oxotetradecanoate
A
methyl (R)-3-hydroxytetradecanoate
B
(S)-methyl 3-hydroxymyristate
Conditions | Yield |
---|---|
With Maltose 1.) yeast Saccharomyces serevisiae IFO 0565, phosphate buffer (pH 7.6), 30 deg C, 24 h, 2.) Et2O; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; |
(+/-)-3-hydroxytetradecanoic acid methyl ester
A
methyl (R)-3-hydroxytetradecanoate
B
(S)-methyl 3-hydroxymyristate
Conditions | Yield |
---|---|
Yields of byproduct given. Title compound not separated from byproducts; | |
With CHIRALPAK AD-H column In ethanol; hexane Resolution of racemate; |
methyl (S)-3-acetoxytetradecanoate
(S)-methyl 3-hydroxymyristate
Conditions | Yield |
---|---|
With hydrogenchloride In methanol at 40℃; | |
With hydrogenchloride In methanol; water at 40℃; for 48h; Deacetylation; |
vinyl acetate
(+/-)-3-hydroxytetradecanoic acid methyl ester
A
methyl (R)-3-hydroxytetradecanoate
B
(S)-methyl 3-hydroxymyristate
D
methyl (S)-3-acetoxytetradecanoate
Conditions | Yield |
---|---|
immobilized lipase (Amano PS) In tetrahydrofuran at 26 - 28℃; for 120h; Acetylation; Title compound not separated from byproducts; |
n-dodecanoyl chloride
(S)-methyl 3-hydroxymyristate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1.1: pyridine / CH2Cl2 / 3 h / 0 - 20 °C 1.2: 77.9 percent / methanol / 3 h / Heating 2.1: hydrogen / (S)-ruthenium 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl / methanol / 5 h / 100 °C / 3750.3 Torr View Scheme |
lauric acid
(S)-methyl 3-hydroxymyristate
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1.1: tetrahydrofuran / 0 - 20 °C 2.1: 14.72 g / 72 h / 20 °C 3.1: H2 / (S)-RuBINAP / methanol; aq. HCl / 1034.3 Torr 3.2: 15 h / 2585.74 Torr / Heating View Scheme |
N-laurylimidazole
(S)-methyl 3-hydroxymyristate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1.1: 14.72 g / 72 h / 20 °C 2.1: H2 / (S)-RuBINAP / methanol; aq. HCl / 1034.3 Torr 2.2: 15 h / 2585.74 Torr / Heating View Scheme |
(+/-)-3-hydroxytetradecanoic acid methyl ester
(S)-methyl 3-hydroxymyristate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: lipase(Amano PS) / tetrahydrofuran 2: 6M HCl / methanol / 40 °C View Scheme |
n-dodecanoyl chloride
(S)-methyl 3-hydroxymyristate
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: pyridine / CH2Cl2 / 1 h / Ambient temperature 2: methanol / 5 h / Heating 3: H2, AcOH / (S,S)-tartaric acid-NaBr-Raney nickel / various solvent(s) / 100 °C / 76000 Torr View Scheme |
2,2-dimethyl-4,6-dioxo-5-dodecanoyl-1,3-dioxane
(S)-methyl 3-hydroxymyristate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: methanol / 5 h / Heating 2: H2, AcOH / (S,S)-tartaric acid-NaBr-Raney nickel / various solvent(s) / 100 °C / 76000 Torr View Scheme |
(R)-(-)-1-tetradecyn-3-ol
(S)-methyl 3-hydroxymyristate
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 1) 2.4 eq. n-BuLi; 2) 1.4 M H2SO4 / 1) THF, -78 deg C; 2) from -20 deg C to room temperature 2: 1) 2 eq. dicyclohexylborane; 2) NaOH, H2O2 / 1) THF, 0 deg C; 2) 40-50 deg C 3: HCl / 2 h / Ambient temperature View Scheme |
tetradec-1-yn-3-one
(S)-methyl 3-hydroxymyristate
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: 1.4 eq. R-Alpine-Borane / neat (no solvent) / 8 h / 0 - 20 °C 2: 1) 2.4 eq. n-BuLi; 2) 1.4 M H2SO4 / 1) THF, -78 deg C; 2) from -20 deg C to room temperature 3: 1) 2 eq. dicyclohexylborane; 2) NaOH, H2O2 / 1) THF, 0 deg C; 2) 40-50 deg C 4: HCl / 2 h / Ambient temperature View Scheme |
(3R)-1-trimethylsilyl-tetradec-1-yn-3-ol
(S)-methyl 3-hydroxymyristate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 1) 2 eq. dicyclohexylborane; 2) NaOH, H2O2 / 1) THF, 0 deg C; 2) 40-50 deg C 2: HCl / 2 h / Ambient temperature View Scheme |
Conditions | Yield |
---|---|
In methanol; diethyl ether; dichloromethane; oxygen |
(+/-)-3-hydroxytetradecanoic acid methyl ester
A
(R)-3-hydroxytetradecanoic acid
B
(S)-methyl 3-hydroxymyristate
Conditions | Yield |
---|---|
With Porcine Pancreas Lipase; water In aq. phosphate buffer at 36℃; for 7h; pH=7.6; enantioselective reaction; | A n/a B n/a |
With Porcine Pancreas Lipase; water In aq. phosphate buffer at 36℃; for 7h; pH=7.6; Resolution of racemate; enantioselective reaction; | A n/a B n/a |
(+/-)-3-hydroxytetradecanoic acid methyl ester
A
(R)-3-hydroxytetradecanoic acid
B
(S)-methyl 3-hydroxymyristate
C
(3S)-3-hydroxytetradecanoic acid
Conditions | Yield |
---|---|
With Porcine Pancreas Lipase; water In aq. phosphate buffer at 36℃; for 7h; pH=7.6; Resolution of racemate; enantioselective reaction; | A n/a B n/a C n/a |
acetoacetic acid methyl ester
A
methyl (R)-3-hydroxytetradecanoate
B
(S)-methyl 3-hydroxymyristate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1.1: lithium diisopropyl amide / tetrahydrofuran; hexane / 1 h / 0 °C 1.2: undecyl halide / 16 h / -78 - 20 °C 2.1: dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; sodium formate; (R,R)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine / water / 6 h / 25 °C View Scheme |
2-Methoxypropene
(S)-methyl 3-hydroxymyristate
methyl (S)-3-(2-methoxyprop-2-oxy)tetradecanoate
Conditions | Yield |
---|---|
With pyridinium p-toluenesulfonate at 0℃; for 0.166667h; | 98% |
O-benzyl 2,2,2-trichloroacetimidate
(S)-methyl 3-hydroxymyristate
methyl (S)-3-benzyloxytetradecanoate
Conditions | Yield |
---|---|
With trifluorormethanesulfonic acid In dichloromethane; cyclohexane at 20℃; for 1h; Inert atmosphere; | 86% |
trifluorormethanesulfonic acid In dichloromethane; cyclohexane for 3h; Ambient temperature; | 79% |
(S)-methyl 3-hydroxymyristate
(3S)-3-hydroxytetradecanoic acid
Conditions | Yield |
---|---|
Stage #1: (S)-methyl 3-hydroxymyristate With potassium hydroxide In water for 1h; Reflux; Stage #2: With hydrogenchloride In water pH=2; | 80% |
With sodium hydroxide In methanol Heating; Yield given; | |
With lithium hydroxide In tetrahydrofuran for 4h; Ambient temperature; Yield given; | |
With sodium hydroxide In methanol; water at 90℃; for 0.5h; Hydrolysis; | 11.6 g |
With lithium hydroxide In methanol; water for 12h; |
3,4-dihydro-2H-pyran
(S)-methyl 3-hydroxymyristate
methyl (S)-3-tetrahydropyranyloxytetradecanoate
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid |
(S)-methyl 3-hydroxymyristate
(S)-3-O-triethylsilyl myristic acid
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: lithium hydroxide monohydrate / methanol; H2O / 12 h 2: pyridine / 2 h / 60 °C View Scheme |
(S)-methyl 3-hydroxymyristate
benzyl (S)-3-O-triethylsilyl-hydroxymyristate
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: lithium hydroxide monohydrate / methanol; H2O / 12 h 2: pyridine / 2 h / 60 °C 3: 81 percent / N-(3-dimethylaminopropyl)-N'-ethyl carbodiimide HCl; DMAP / CH2Cl2 / 12 h / 20 °C View Scheme |
(S)-methyl 3-hydroxymyristate
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: lithium hydroxide monohydrate / methanol; H2O / 12 h 2: pyridine / 2 h / 60 °C 3: 81 percent / N-(3-dimethylaminopropyl)-N'-ethyl carbodiimide HCl; DMAP / CH2Cl2 / 12 h / 20 °C 4: 98 percent / trifluoroacetic acid / CH2Cl2 / 0.17 h View Scheme |
(S)-methyl 3-hydroxymyristate
(3S,4S)-3-hexyl-4-[(2S)-2-hydroxytridecyl]oxetan-2-one
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 98 percent / pyridinium p-toluenesulfonate / 0.17 h / 0 °C 2: 13.7 g / DIBAL / toluene / 0.5 h / -70 °C 3: 2.) 2N HCl / 1.) THF, -100 to -95 deg C, 30 min; warm to room temperature, overnight, 2.) 0 deg C, 20 min View Scheme |
(S)-methyl 3-hydroxymyristate
(S)-3-(2-methoxyprop-2-oxy)tetradecanal
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 98 percent / pyridinium p-toluenesulfonate / 0.17 h / 0 °C 2: 13.7 g / DIBAL / toluene / 0.5 h / -70 °C View Scheme |
(S)-methyl 3-hydroxymyristate
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 98 percent / pyridinium p-toluenesulfonate / 0.17 h / 0 °C 2: 13.7 g / DIBAL / toluene / 0.5 h / -70 °C 3: 2.) 2N HCl / 1.) THF, -100 to -95 deg C, 30 min; warm to room temperature, overnight, 2.) 0 deg C, 20 min View Scheme |
(S)-methyl 3-hydroxymyristate
tert-butyldimethylsilyl chloride
methyl (S)-3-(tert-butyldimethylsilyloxy)tetradecanoate
Conditions | Yield |
---|---|
With 1H-imidazole In DMF (N,N-dimethyl-formamide) at 5 - 20℃; for 8 - 10h; |
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