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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

METHYL 3-OXOTETRADECANOATE

Cas:22348-97-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Tetradecanoic acid,3-oxo-, methyl ester

Cas:22348-97-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Tetradecanoic acid,3-oxo-, methyl ester

Cas:22348-97-6

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

METHYL 3-OXOTETRADECANOATE Basic information Product Name: METHYL 3-OXOTETRADECANOATE Synonyms: 3-Ketomyristic acid methyl ester;3-Oxomyristic acid methyl ester;3-Oxotetradecanoic acid methyl ester;Tetradecanoic acid, 3-oxo-, methyl ester;Methy

METHYL 3-OXOTETRADECANOATE

Cas:22348-97-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Metyl lauroyl acetate

Cas:22348-97-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

Tetradecanoic acid,3-oxo-, methyl ester

Cas:22348-97-6

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

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Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

METHYL 3-OXOTETRADECANOATE cas no. 22348-97-6 94%

Cas:22348-97-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

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GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Methyl 3-oxotetradecanoate

Cas:22348-97-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Methyl 3-oxotetradecanoate

Cas:22348-97-6

Min.Order:0

Negotiable

Type:Other

inquiry

Hubei Taiho Chemical Co.,LTD

TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp

Methyl 3-oxotetradecanoate

Cas:22348-97-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Our own factory produces direct sales with absolute price advantage Application:Pharmaceutical industry Transportation:By sea Port:Shanghai/tianjin

Tetradecanoic acid,3-oxo-, methyl ester

Cas:22348-97-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Fandachem Co.,Ltd

METHYL 3-OXOTETRADECANOATEAppearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:pharmaceutical intermediate Transportation:by air, by sea, by express

METHYL 3-OXOTETRADECANOATE

Cas:22348-97-6

Min.Order:0

Negotiable

Type:Other

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

Metyl lauroyl acetate 22348-97-6

Cas:22348-97-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai Scochem Technology Co., Ltd.

High quality suppliers Application:healing drugs

methyl 3-oxotetradecanoate

Cas:22348-97-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shenzhen Foris Technology Co. LTD

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

Metyl lauroyl acetate 22348-97-6

Cas:22348-97-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

METHYL 3-OXOTETRADECANOATE

Cas:22348-97-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

LEAP CHEM Co., Ltd.

Best Seller, High Quality, Competitive Price, Fast Delivery, Quick ResponseAppearance:powder, or liquid Storage:Stored in room temperature, ventilated place Package:Bottle, barrel, cargo, container, etc. Application:Pharmaceuticals, intermediates, AP

METHYL 3-OXOTETRADECANOATE

Cas:22348-97-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Bide Pharmatech Ltd

Our mission is to provide high-quality and innovative products to our customers. By offering a broad range of products, custom synthesis and personalized services, Bide can help scientists speeding up their research in the chemical and pharmaceutical

Methyl 3-oxotetradecanoate

Cas:22348-97-6

Min.Order:0

Negotiable

Type:Other

inquiry

Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

Amadis Chemical offer CAS#22348-97-6;CAT#A816132

Cas:22348-97-6

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

Finetech Industry Limited

FINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the METHYL 3-OXOTETRADECANOATE, CAS:22348-97-6 with the most competitive price and the be

METHYL 3-OXOTETRADECANOATE

Cas:22348-97-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Pure Chemistry Scientific Inc.

Metyl lauroyl acetate Application:826079

Metyl lauroyl acetate

Cas:22348-97-6

Min.Order:1 Gram

FOB Price: $500.0

Type:Trading Company

inquiry

Debye Scientific

Debyesci is here who supplied several kinds of chemical products to global pharmaceutical, drug discovery, agrochemical and biotechnology industries for four yearsOur key scientific leadership team has gained experience in top research and developmen

METHYL 3-OXOTETRADECANOATE

Cas:22348-97-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

NovaChemistry

high purity Application:Drug intermediates Materials intermediates and active molecules

Methyl 3-oxotetradecanoate

Cas:22348-97-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Jinan Yixi Pharmatech Co., Ltd

High pruity and low price, bulk in stock Appearance:Coloreless liquid Storage:room temerperature, avoid heating Application:Key intermediate for pharmaceutical API

bulk in stock

Cas:22348-97-6

Min.Order:25 Kilogram

Negotiable

Type:Trading Company

inquiry

Synthetic route

methanol
67-56-1

methanol

5-(1-hydroxydodecylidene)-2,2-dimethyl-1,3-dioxane-4,6-dione
736177-64-3

5-(1-hydroxydodecylidene)-2,2-dimethyl-1,3-dioxane-4,6-dione

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

Conditions
ConditionsYield
for 2h; Heating;90%
With sulfuric acid for 12h; Reflux;
n-dodecanoyl chloride
112-16-3

n-dodecanoyl chloride

monomethyl monopotassium malonate
38330-80-2

monomethyl monopotassium malonate

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

Conditions
ConditionsYield
Stage #1: monomethyl monopotassium malonate With triethylamine; magnesium chloride In acetonitrile at 10 - 25℃; for 2.5h; Inert atmosphere;
Stage #2: n-dodecanoyl chloride With triethylamine In acetonitrile at 0 - 25℃; Inert atmosphere;
86%
n-dodecanoyl chloride
112-16-3

n-dodecanoyl chloride

acetic acid methyl ester
79-20-9

acetic acid methyl ester

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

Conditions
ConditionsYield
With lithium diisopropyl amide In tetrahydrofuran at -78 - -65℃; for 0.5h;81%
cycl-isopropylidene malonate
2033-24-1

cycl-isopropylidene malonate

n-dodecanoyl chloride
112-16-3

n-dodecanoyl chloride

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

Conditions
ConditionsYield
Stage #1: cycl-isopropylidene malonate; n-dodecanoyl chloride With pyridine In dichloromethane at 0 - 20℃; for 3h;
Stage #2: In methanol for 3h; Heating;
77.9%
Stage #1: cycl-isopropylidene malonate; n-dodecanoyl chloride With pyridine In dichloromethane at 0 - 20℃; for 94965h; Inert atmosphere;
Stage #2: With methanol for 5h; Reflux;
70%
Stage #1: cycl-isopropylidene malonate With pyridine In dichloromethane at 0℃; for 0.333333h;
Stage #2: n-dodecanoyl chloride In dichloromethane at 0 - 20℃; for 2h;
35%
methanol
67-56-1

methanol

cycl-isopropylidene malonate
2033-24-1

cycl-isopropylidene malonate

n-dodecanoyl chloride
112-16-3

n-dodecanoyl chloride

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

Conditions
ConditionsYield
Stage #1: cycl-isopropylidene malonate; n-dodecanoyl chloride With pyridine In dichloromethane at 0 - 20℃; for 2.5h;
Stage #2: methanol Reflux;
77%
Stage #1: cycl-isopropylidene malonate; n-dodecanoyl chloride With pyridine In dichloromethane at 0 - 20℃; for 2.25h; Inert atmosphere;
Stage #2: methanol for 5h; Reflux; Inert atmosphere;
Stage #1: cycl-isopropylidene malonate; n-dodecanoyl chloride With pyridine In dichloromethane Inert atmosphere;
Stage #2: methanol In dichloromethane Heating; Inert atmosphere;
acetoacetic acid methyl ester
105-45-3

acetoacetic acid methyl ester

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

Conditions
ConditionsYield
Stage #1: acetoacetic acid methyl ester With lithium diisopropyl amide In tetrahydrofuran; hexane at 0℃; for 1h;
Stage #2: In tetrahydrofuran; hexane at -78 - 20℃; for 16h;
71%
n-dodecanoyl chloride
112-16-3

n-dodecanoyl chloride

acetoacetic acid methyl ester
105-45-3

acetoacetic acid methyl ester

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

Conditions
ConditionsYield
With hydrogenchloride; calcium hydroxide; sodium chloride; sodium carbonate In methanol; water; toluene68%
lauric acid
143-07-7

lauric acid

magnesium monomethyl malonate

magnesium monomethyl malonate

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

Conditions
ConditionsYield
Stage #1: lauric acid With 1,1'-carbonyldiimidazole In tetrahydrofuran at 20℃; for 10h;
Stage #2: magnesium monomethyl malonate In tetrahydrofuran at 20℃; for 18h; Further stages.;
62%
lauric acid
143-07-7

lauric acid

Malonic acid monomethyl ester
16695-14-0

Malonic acid monomethyl ester

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

Conditions
ConditionsYield
Stage #1: Malonic acid monomethyl ester With magnesium ethylate In 1,4-dioxane
Stage #2: lauric acid With 1,1'-carbonyldiimidazole In 1,4-dioxane at 20℃;
61%
n-dodecanoyl chloride
112-16-3

n-dodecanoyl chloride

sodium ethyl acetylacetate enolate
1007476-32-5

sodium ethyl acetylacetate enolate

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

Conditions
ConditionsYield
With diethyl ether Behandlung des Reaktionsprodukts mit Natriummethylat-Loesung;
tetradec-1-ene-1,3-dione-1-dimethylacetal
109450-50-2

tetradec-1-ene-1,3-dione-1-dimethylacetal

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

Conditions
ConditionsYield
With hydrogenchloride
2-acetyl-3-oxo-tetradecanoic acid ethyl ester
73077-96-0

2-acetyl-3-oxo-tetradecanoic acid ethyl ester

sodium methylate
124-41-4

sodium methylate

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

Conditions
ConditionsYield
With methanol
methanol
67-56-1

methanol

3-oxomyristic acid
88222-72-4

3-oxomyristic acid

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

Conditions
ConditionsYield
for 3h; Heating;
2,2-dimethyl-4,6-dioxo-5-dodecanoyl-1,3-dioxane
111861-21-3

2,2-dimethyl-4,6-dioxo-5-dodecanoyl-1,3-dioxane

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

Conditions
ConditionsYield
In methanol for 5h; Heating; Yield given;
methanol
67-56-1

methanol

tetradecanoyl chloride
112-64-1

tetradecanoyl chloride

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

Conditions
ConditionsYield
With pyridine; cycl-isopropylidene malonate 1) CH2Cl2, 1 h, 0 deg C, 2 h, RT, 2) 2 h, reflux; Yield given. Multistep reaction;
magnesium monomethyl malonate

magnesium monomethyl malonate

N-laurylimidazole
3867-67-2

N-laurylimidazole

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

Conditions
ConditionsYield
at 20℃; for 72h;14.72 g
Iododecane
2050-77-3

Iododecane

acetoacetic acid methyl ester
105-45-3

acetoacetic acid methyl ester

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

Conditions
ConditionsYield
With n-butyllithium; sodium hydride at 0 - 20℃;
3-oxomyristic acid
88222-72-4

3-oxomyristic acid

diazomethyl-trimethyl-silane
18107-18-1

diazomethyl-trimethyl-silane

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

Conditions
ConditionsYield
In methanol; diethyl ether; benzene for 0.5h;
n-dodecanoyl chloride
112-16-3

n-dodecanoyl chloride

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: pyridine / CH2Cl2 / 3 h / 20 °C
2: 90 percent / 2 h / Heating
View Scheme
Multi-step reaction with 2 steps
2: aqueous hydrochloric acid
View Scheme
n-dodecanoyl chloride
112-16-3

n-dodecanoyl chloride

HCl

HCl

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: n-butyl lithium / diethyl ether / -78 - -10 °C
1.2: diethyl ether / 0.5 h / -10 °C
2.1: benzene; methanol; diethyl ether / 0.5 h
View Scheme
lauric acid
143-07-7

lauric acid

monomethoxy poly(ethylene glycol)

monomethoxy poly(ethylene glycol)

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: tetrahydrofuran / 0 - 20 °C
2: 14.72 g / 72 h / 20 °C
View Scheme
n-dodecanoyl chloride
112-16-3

n-dodecanoyl chloride

glycerol-1-caprinate-3-stearate

glycerol-1-caprinate-3-stearate

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: pyridine / CH2Cl2 / 0 deg C, 1 h then r.t., 4 h
2: 3 h / Heating
View Scheme
n-dodecanoyl chloride
112-16-3

n-dodecanoyl chloride

alcoholic NaOH

alcoholic NaOH

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: pyridine / CH2Cl2 / 1 h / Ambient temperature
2: methanol / 5 h / Heating
View Scheme
methanol
67-56-1

methanol

5-(1-hydroxydecylidene)-2,2-dimethyl-1,3-dioxane-4,6-dione
429675-23-0

5-(1-hydroxydecylidene)-2,2-dimethyl-1,3-dioxane-4,6-dione

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

Conditions
ConditionsYield
for 5h; Inert atmosphere; Reflux;4.47 g
n-decanoyl chloride
112-13-0

n-decanoyl chloride

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: pyridine / dichloromethane / 0.33 h / 0 °C / Inert atmosphere
1.2: 3 h / 0 - 20 °C / Inert atmosphere
2.1: 5 h / Inert atmosphere; Reflux
View Scheme
lauric acid
143-07-7

lauric acid

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: dmap; dicyclohexyl-carbodiimide / dichloromethane / 0.5 h
1.2: 24 h / 20 °C
2.1: sulfuric acid / 12 h / Reflux
View Scheme
methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

Conditions
ConditionsYield
Stage #1: methyl 3-oxotetradecanoate With hydrogen; (R)-2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl; ruthenium trichloride In methanol at 40 - 50℃; under 3361.46 Torr; for 20h;
Stage #2: With lithium hydroxide In tetrahydrofuran; water
100%
With sodium hydroxide; hydrogen; acetic acid; L-Tartaric acid; (R,R)-tartaric acid-NaBr-Raney nickel ((R,R)-TA-NaBr-MRNi); sodium bromide 1.) C2H5COOCH3, 100 deg C, 100 kg/cm2; Yield given. Multistep reaction;
Multi-step reaction with 2 steps
1: 95.6 percent / H2 / (R)-ruthenium 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl / methanol / 5 h / 100 °C / 3750.3 Torr
2: 97.6 percent / lithium hydroxide monohydrate / methanol; H2O / 12 h
View Scheme
methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

methyl (R)-3-hydroxytetradecanoate
76062-97-0

methyl (R)-3-hydroxytetradecanoate

Conditions
ConditionsYield
With hydrogen; [(R)-BINAP]RuBr2 In methanol at 50℃; under 760.051 Torr; for 48h;100%
With [Ir(H)2((R)-N-((1,3-dithian-2-yl)methyl)-7'-(bis(3,5-di-tert-butylphenyl)phosphanyl)-1,1'-spirobiindanyl-7-amine)Cl]; hydrogen; sodium hydroxide In methanol at 25 - 30℃; under 7600.51 Torr; for 2h; Autoclave; enantioselective reaction;98%
With hydrogenchloride; bis(acetato){(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl}rutenium(II); hydrogen In methanol at 65℃; under 11251.1 Torr; for 12h; enantioselective reaction;98%
methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

(4S)-3-exo-(1-naphthyl)-4,7,7-trimethylbicyclo[2.2.1]heptan-2-exo-ol
86835-18-9

(4S)-3-exo-(1-naphthyl)-4,7,7-trimethylbicyclo[2.2.1]heptan-2-exo-ol

4,7,7-trimethyl-3-exo-(1-naphthyl)bicyclo<2.2.1>heptan-2-exo-yl 3-oxotetradecanoate
110971-14-7

4,7,7-trimethyl-3-exo-(1-naphthyl)bicyclo<2.2.1>heptan-2-exo-yl 3-oxotetradecanoate

Conditions
ConditionsYield
With dmap In toluene for 40h; Heating;99%
methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

ethylene glycol
107-21-1

ethylene glycol

methyl 2-(2-undecyl-1,3-dioxolan-2-yl)acetate

methyl 2-(2-undecyl-1,3-dioxolan-2-yl)acetate

Conditions
ConditionsYield
With toluene-4-sulfonic acid; trimethyl orthoformate at 20℃; for 5h; Inert atmosphere;94%
With toluene-4-sulfonic acid In benzene for 24h; Heating;
3-hydroxymethylpyridin
100-55-0

3-hydroxymethylpyridin

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

3-oxotetradecanoic acid nicotinyl ester

3-oxotetradecanoic acid nicotinyl ester

Conditions
ConditionsYield
In toluene for 24h; Reflux; Molecular sieve;92%
methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

Conditions
ConditionsYield
With hydrogenchloride; (R)-bis(acetato)(2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl)ruthenium; hydrogen In ethanol under 76005.1 Torr; for 68h; Inert atmosphere;91%
With 1,2-bis[(R,R)-2,5-diisopropylphospholano]ethane-RuBr2; hydrogen In methanol; water at 35℃; under 3102.9 Torr; for 20h;
With hydrogenchloride; hydrogen; (RuCl2<(S)-Binap>)2*NEt3 In methanol at 40 - 50℃; for 18h;
With hydrogen; (S)-ruthenium 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl In methanol at 100℃; under 3750.3 Torr; for 5h;
With hydrogenchloride; Ru(OCOCH3)2{(S)-2,2'-bis(diphenylphosphino)-1,1'-dinaphthyl)}; hydrogen In methanol at 65℃; under 11251.1 Torr; for 12h; enantioselective reaction;
methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

N-cyclohexyl-cyclohexanamine
101-83-7

N-cyclohexyl-cyclohexanamine

dicyclohexylammonium (R)-3-hydroxytetradecanoate

dicyclohexylammonium (R)-3-hydroxytetradecanoate

Conditions
ConditionsYield
Stage #1: methyl 3-oxotetradecanoate With hydrogenchloride; [(R)-Ru(Binap)Cl]2.NEt3 In methanol; water at 40 - 50℃; for 18h;
Stage #2: With lithium hydroxide In tetrahydrofuran at 20℃; for 4h;
Stage #3: N-cyclohexyl-cyclohexanamine In acetonitrile at 60℃; for 1h;
91%
methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

A

methyl (R)-3-hydroxytetradecanoate
76062-97-0

methyl (R)-3-hydroxytetradecanoate

B

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

Conditions
ConditionsYield
Stage #1: methyl 3-oxotetradecanoate With hydrogen; (S)-RuBINAP In hydrogenchloride; methanol under 1034.3 Torr;
Stage #2: under 2585.74 Torr; for 15h; Heating; Title compound not separated from byproducts;
A 87%
B n/a
With (COD)2Ru2Cl4(NCCH3)*(R)-BIPHEMP; hydrogen In methanol; dichloromethane at 80℃; under 26252.1 Torr; for 20h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With hydrogen; ultrasonicated (R,R)-tartaric acid-NaBr-modified Raney nickel catalyst <(R,R)-TA-NaBr-MRNi-U> In various solvent(s) at 100℃; under 750.06 Torr; for 48h; Title compound not separated from byproducts;
methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

(+/-)-3-hydroxytetradecanoic acid methyl ester
55682-83-2

(+/-)-3-hydroxytetradecanoic acid methyl ester

Conditions
ConditionsYield
With sodium tetrahydroborate In methanol at 0℃;86%
With sodium tetrahydroborate In methanol at 5 - 10℃; for 2h;
With sodium tetrahydroborate In tetrahydrofuran; methanol
methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

3-undecyl-4H-isoxazol-5-one

3-undecyl-4H-isoxazol-5-one

Conditions
ConditionsYield
With hydroxylamine hydrochloride In ethanol75%
methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

Acetanilid
103-84-4

Acetanilid

methyl 1-acetyl-2-undecyl-1H-indole-3-carboxylate

methyl 1-acetyl-2-undecyl-1H-indole-3-carboxylate

Conditions
ConditionsYield
With dipotassium peroxodisulfate; palladium(II) trifluoroacetate; acetic acid at 60℃; for 24h; regioselective reaction;68%
methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

aniline
62-53-3

aniline

methyl (Z)-3-(phenylamino)tetradec-2-enoate

methyl (Z)-3-(phenylamino)tetradec-2-enoate

Conditions
ConditionsYield
With toluene-4-sulfonic acid In hexane for 12h; Molecular sieve; Reflux;61%
2,3-dihydro-benzofuran-6,7-diol
42484-95-7

2,3-dihydro-benzofuran-6,7-diol

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

9-hydroxy-5-undecyl-2,3-dihydro-furo[3,2-g]chromen-7-one
114327-18-3

9-hydroxy-5-undecyl-2,3-dihydro-furo[3,2-g]chromen-7-one

Conditions
ConditionsYield
With sulfuric acid
ethyl 5-iodopentanoate
41302-32-3

ethyl 5-iodopentanoate

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

7-oxooctadecanoic acid
16694-32-9

7-oxooctadecanoic acid

Conditions
ConditionsYield
With potassium carbonate; 2-Pentanone Erwaermen des Reaktionsprodukts mit wss.-methanol. Kalilauge;
methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

3-hydroxytetradecanoic acid
1961-72-4

3-hydroxytetradecanoic acid

Conditions
ConditionsYield
With 1,4-dioxane; methanol; nickel at 100℃; under 73550.8 Torr; Hydrogenation.und Erwaermen des Reaktionsprodukts mit aethanol.Kalilauge;
Multi-step reaction with 2 steps
1: NaBH4 / methanol / 2 h / 5 - 10 °C
2: NaOH / methanol / Ambient temperature
View Scheme
methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

3-oxomyristic acid
88222-72-4

3-oxomyristic acid

Conditions
ConditionsYield
With hydrogenchloride; acetic acid
methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

3-lauroyl-6-undecyl-pyran-2,4-dione

3-lauroyl-6-undecyl-pyran-2,4-dione

Conditions
ConditionsYield
With sodium hydrogencarbonate at 215℃;
methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

aniline
62-53-3

aniline

2-n-undecyl-4-hydroxyquinoline

2-n-undecyl-4-hydroxyquinoline

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