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inquiryMETHYL 3-OXOTETRADECANOATE Basic information Product Name: METHYL 3-OXOTETRADECANOATE Synonyms: 3-Ketomyristic acid methyl ester;3-Oxomyristic acid methyl ester;3-Oxotetradecanoic acid methyl ester;Tetradecanoic acid, 3-oxo-, methyl ester;Methy
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We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp
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inquiryLower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe
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inquiryhigh purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
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inquiryMETHYL 3-OXOTETRADECANOATEAppearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:pharmaceutical intermediate Transportation:by air, by sea, by express
high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China
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inquiryhigh purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China
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inquiryfactory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin
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inquiryFINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the METHYL 3-OXOTETRADECANOATE, CAS:22348-97-6 with the most competitive price and the be
Metyl lauroyl acetate Application:826079
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inquiryDebyesci is here who supplied several kinds of chemical products to global pharmaceutical, drug discovery, agrochemical and biotechnology industries for four yearsOur key scientific leadership team has gained experience in top research and developmen
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inquiryhigh purity Application:Drug intermediates Materials intermediates and active molecules
High pruity and low price, bulk in stock Appearance:Coloreless liquid Storage:room temerperature, avoid heating Application:Key intermediate for pharmaceutical API
methanol
5-(1-hydroxydodecylidene)-2,2-dimethyl-1,3-dioxane-4,6-dione
methyl 3-oxotetradecanoate
Conditions | Yield |
---|---|
for 2h; Heating; | 90% |
With sulfuric acid for 12h; Reflux; |
n-dodecanoyl chloride
monomethyl monopotassium malonate
methyl 3-oxotetradecanoate
Conditions | Yield |
---|---|
Stage #1: monomethyl monopotassium malonate With triethylamine; magnesium chloride In acetonitrile at 10 - 25℃; for 2.5h; Inert atmosphere; Stage #2: n-dodecanoyl chloride With triethylamine In acetonitrile at 0 - 25℃; Inert atmosphere; | 86% |
n-dodecanoyl chloride
acetic acid methyl ester
methyl 3-oxotetradecanoate
Conditions | Yield |
---|---|
With lithium diisopropyl amide In tetrahydrofuran at -78 - -65℃; for 0.5h; | 81% |
cycl-isopropylidene malonate
n-dodecanoyl chloride
methyl 3-oxotetradecanoate
Conditions | Yield |
---|---|
Stage #1: cycl-isopropylidene malonate; n-dodecanoyl chloride With pyridine In dichloromethane at 0 - 20℃; for 3h; Stage #2: In methanol for 3h; Heating; | 77.9% |
Stage #1: cycl-isopropylidene malonate; n-dodecanoyl chloride With pyridine In dichloromethane at 0 - 20℃; for 94965h; Inert atmosphere; Stage #2: With methanol for 5h; Reflux; | 70% |
Stage #1: cycl-isopropylidene malonate With pyridine In dichloromethane at 0℃; for 0.333333h; Stage #2: n-dodecanoyl chloride In dichloromethane at 0 - 20℃; for 2h; | 35% |
methanol
cycl-isopropylidene malonate
n-dodecanoyl chloride
methyl 3-oxotetradecanoate
Conditions | Yield |
---|---|
Stage #1: cycl-isopropylidene malonate; n-dodecanoyl chloride With pyridine In dichloromethane at 0 - 20℃; for 2.5h; Stage #2: methanol Reflux; | 77% |
Stage #1: cycl-isopropylidene malonate; n-dodecanoyl chloride With pyridine In dichloromethane at 0 - 20℃; for 2.25h; Inert atmosphere; Stage #2: methanol for 5h; Reflux; Inert atmosphere; | |
Stage #1: cycl-isopropylidene malonate; n-dodecanoyl chloride With pyridine In dichloromethane Inert atmosphere; Stage #2: methanol In dichloromethane Heating; Inert atmosphere; |
acetoacetic acid methyl ester
methyl 3-oxotetradecanoate
Conditions | Yield |
---|---|
Stage #1: acetoacetic acid methyl ester With lithium diisopropyl amide In tetrahydrofuran; hexane at 0℃; for 1h; Stage #2: In tetrahydrofuran; hexane at -78 - 20℃; for 16h; | 71% |
n-dodecanoyl chloride
acetoacetic acid methyl ester
methyl 3-oxotetradecanoate
Conditions | Yield |
---|---|
With hydrogenchloride; calcium hydroxide; sodium chloride; sodium carbonate In methanol; water; toluene | 68% |
Conditions | Yield |
---|---|
Stage #1: lauric acid With 1,1'-carbonyldiimidazole In tetrahydrofuran at 20℃; for 10h; Stage #2: magnesium monomethyl malonate In tetrahydrofuran at 20℃; for 18h; Further stages.; | 62% |
Conditions | Yield |
---|---|
Stage #1: Malonic acid monomethyl ester With magnesium ethylate In 1,4-dioxane Stage #2: lauric acid With 1,1'-carbonyldiimidazole In 1,4-dioxane at 20℃; | 61% |
n-dodecanoyl chloride
sodium ethyl acetylacetate enolate
methyl 3-oxotetradecanoate
Conditions | Yield |
---|---|
With diethyl ether Behandlung des Reaktionsprodukts mit Natriummethylat-Loesung; |
tetradec-1-ene-1,3-dione-1-dimethylacetal
methyl 3-oxotetradecanoate
Conditions | Yield |
---|---|
With hydrogenchloride |
2-acetyl-3-oxo-tetradecanoic acid ethyl ester
sodium methylate
methyl 3-oxotetradecanoate
Conditions | Yield |
---|---|
With methanol |
Conditions | Yield |
---|---|
for 3h; Heating; |
2,2-dimethyl-4,6-dioxo-5-dodecanoyl-1,3-dioxane
methyl 3-oxotetradecanoate
Conditions | Yield |
---|---|
In methanol for 5h; Heating; Yield given; |
Conditions | Yield |
---|---|
With pyridine; cycl-isopropylidene malonate 1) CH2Cl2, 1 h, 0 deg C, 2 h, RT, 2) 2 h, reflux; Yield given. Multistep reaction; |
Conditions | Yield |
---|---|
at 20℃; for 72h; | 14.72 g |
Conditions | Yield |
---|---|
With n-butyllithium; sodium hydride at 0 - 20℃; |
3-oxomyristic acid
diazomethyl-trimethyl-silane
methyl 3-oxotetradecanoate
Conditions | Yield |
---|---|
In methanol; diethyl ether; benzene for 0.5h; |
n-dodecanoyl chloride
methyl 3-oxotetradecanoate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: pyridine / CH2Cl2 / 3 h / 20 °C 2: 90 percent / 2 h / Heating View Scheme | |
Multi-step reaction with 2 steps 2: aqueous hydrochloric acid View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1.1: n-butyl lithium / diethyl ether / -78 - -10 °C 1.2: diethyl ether / 0.5 h / -10 °C 2.1: benzene; methanol; diethyl ether / 0.5 h View Scheme |
lauric acid
methyl 3-oxotetradecanoate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: tetrahydrofuran / 0 - 20 °C 2: 14.72 g / 72 h / 20 °C View Scheme |
n-dodecanoyl chloride
methyl 3-oxotetradecanoate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: pyridine / CH2Cl2 / 0 deg C, 1 h then r.t., 4 h 2: 3 h / Heating View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: pyridine / CH2Cl2 / 1 h / Ambient temperature 2: methanol / 5 h / Heating View Scheme |
methanol
5-(1-hydroxydecylidene)-2,2-dimethyl-1,3-dioxane-4,6-dione
methyl 3-oxotetradecanoate
Conditions | Yield |
---|---|
for 5h; Inert atmosphere; Reflux; | 4.47 g |
n-decanoyl chloride
methyl 3-oxotetradecanoate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1.1: pyridine / dichloromethane / 0.33 h / 0 °C / Inert atmosphere 1.2: 3 h / 0 - 20 °C / Inert atmosphere 2.1: 5 h / Inert atmosphere; Reflux View Scheme |
lauric acid
methyl 3-oxotetradecanoate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1.1: dmap; dicyclohexyl-carbodiimide / dichloromethane / 0.5 h 1.2: 24 h / 20 °C 2.1: sulfuric acid / 12 h / Reflux View Scheme |
methyl 3-oxotetradecanoate
(R)-3-hydroxytetradecanoic acid
Conditions | Yield |
---|---|
Stage #1: methyl 3-oxotetradecanoate With hydrogen; (R)-2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl; ruthenium trichloride In methanol at 40 - 50℃; under 3361.46 Torr; for 20h; Stage #2: With lithium hydroxide In tetrahydrofuran; water | 100% |
With sodium hydroxide; hydrogen; acetic acid; L-Tartaric acid; (R,R)-tartaric acid-NaBr-Raney nickel ((R,R)-TA-NaBr-MRNi); sodium bromide 1.) C2H5COOCH3, 100 deg C, 100 kg/cm2; Yield given. Multistep reaction; | |
Multi-step reaction with 2 steps 1: 95.6 percent / H2 / (R)-ruthenium 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl / methanol / 5 h / 100 °C / 3750.3 Torr 2: 97.6 percent / lithium hydroxide monohydrate / methanol; H2O / 12 h View Scheme |
methyl 3-oxotetradecanoate
methyl (R)-3-hydroxytetradecanoate
Conditions | Yield |
---|---|
With hydrogen; [(R)-BINAP]RuBr2 In methanol at 50℃; under 760.051 Torr; for 48h; | 100% |
With [Ir(H)2((R)-N-((1,3-dithian-2-yl)methyl)-7'-(bis(3,5-di-tert-butylphenyl)phosphanyl)-1,1'-spirobiindanyl-7-amine)Cl]; hydrogen; sodium hydroxide In methanol at 25 - 30℃; under 7600.51 Torr; for 2h; Autoclave; enantioselective reaction; | 98% |
With hydrogenchloride; bis(acetato){(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl}rutenium(II); hydrogen In methanol at 65℃; under 11251.1 Torr; for 12h; enantioselective reaction; | 98% |
methyl 3-oxotetradecanoate
(4S)-3-exo-(1-naphthyl)-4,7,7-trimethylbicyclo[2.2.1]heptan-2-exo-ol
4,7,7-trimethyl-3-exo-(1-naphthyl)bicyclo<2.2.1>heptan-2-exo-yl 3-oxotetradecanoate
Conditions | Yield |
---|---|
With dmap In toluene for 40h; Heating; | 99% |
methyl 3-oxotetradecanoate
ethylene glycol
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid; trimethyl orthoformate at 20℃; for 5h; Inert atmosphere; | 94% |
With toluene-4-sulfonic acid In benzene for 24h; Heating; |
3-hydroxymethylpyridin
methyl 3-oxotetradecanoate
Conditions | Yield |
---|---|
In toluene for 24h; Reflux; Molecular sieve; | 92% |
methyl 3-oxotetradecanoate
(S)-methyl 3-hydroxymyristate
Conditions | Yield |
---|---|
With hydrogenchloride; (R)-bis(acetato)(2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl)ruthenium; hydrogen In ethanol under 76005.1 Torr; for 68h; Inert atmosphere; | 91% |
With 1,2-bis[(R,R)-2,5-diisopropylphospholano]ethane-RuBr2; hydrogen In methanol; water at 35℃; under 3102.9 Torr; for 20h; | |
With hydrogenchloride; hydrogen; (RuCl2<(S)-Binap>)2*NEt3 In methanol at 40 - 50℃; for 18h; | |
With hydrogen; (S)-ruthenium 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl In methanol at 100℃; under 3750.3 Torr; for 5h; | |
With hydrogenchloride; Ru(OCOCH3)2{(S)-2,2'-bis(diphenylphosphino)-1,1'-dinaphthyl)}; hydrogen In methanol at 65℃; under 11251.1 Torr; for 12h; enantioselective reaction; |
methyl 3-oxotetradecanoate
N-cyclohexyl-cyclohexanamine
Conditions | Yield |
---|---|
Stage #1: methyl 3-oxotetradecanoate With hydrogenchloride; [(R)-Ru(Binap)Cl]2.NEt3 In methanol; water at 40 - 50℃; for 18h; Stage #2: With lithium hydroxide In tetrahydrofuran at 20℃; for 4h; Stage #3: N-cyclohexyl-cyclohexanamine In acetonitrile at 60℃; for 1h; | 91% |
methyl 3-oxotetradecanoate
A
methyl (R)-3-hydroxytetradecanoate
B
(S)-methyl 3-hydroxymyristate
Conditions | Yield |
---|---|
Stage #1: methyl 3-oxotetradecanoate With hydrogen; (S)-RuBINAP In hydrogenchloride; methanol under 1034.3 Torr; Stage #2: under 2585.74 Torr; for 15h; Heating; Title compound not separated from byproducts; | A 87% B n/a |
With (COD)2Ru2Cl4(NCCH3)*(R)-BIPHEMP; hydrogen In methanol; dichloromethane at 80℃; under 26252.1 Torr; for 20h; Yield given. Yields of byproduct given. Title compound not separated from byproducts; | |
With hydrogen; ultrasonicated (R,R)-tartaric acid-NaBr-modified Raney nickel catalyst <(R,R)-TA-NaBr-MRNi-U> In various solvent(s) at 100℃; under 750.06 Torr; for 48h; Title compound not separated from byproducts; |
methyl 3-oxotetradecanoate
(+/-)-3-hydroxytetradecanoic acid methyl ester
Conditions | Yield |
---|---|
With sodium tetrahydroborate In methanol at 0℃; | 86% |
With sodium tetrahydroborate In methanol at 5 - 10℃; for 2h; | |
With sodium tetrahydroborate In tetrahydrofuran; methanol |
methyl 3-oxotetradecanoate
Conditions | Yield |
---|---|
With hydroxylamine hydrochloride In ethanol | 75% |
methyl 3-oxotetradecanoate
Acetanilid
Conditions | Yield |
---|---|
With dipotassium peroxodisulfate; palladium(II) trifluoroacetate; acetic acid at 60℃; for 24h; regioselective reaction; | 68% |
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In hexane for 12h; Molecular sieve; Reflux; | 61% |
2,3-dihydro-benzofuran-6,7-diol
methyl 3-oxotetradecanoate
9-hydroxy-5-undecyl-2,3-dihydro-furo[3,2-g]chromen-7-one
Conditions | Yield |
---|---|
With sulfuric acid |
ethyl 5-iodopentanoate
methyl 3-oxotetradecanoate
7-oxooctadecanoic acid
Conditions | Yield |
---|---|
With potassium carbonate; 2-Pentanone Erwaermen des Reaktionsprodukts mit wss.-methanol. Kalilauge; |
methyl 3-oxotetradecanoate
3-hydroxytetradecanoic acid
Conditions | Yield |
---|---|
With 1,4-dioxane; methanol; nickel at 100℃; under 73550.8 Torr; Hydrogenation.und Erwaermen des Reaktionsprodukts mit aethanol.Kalilauge; | |
Multi-step reaction with 2 steps 1: NaBH4 / methanol / 2 h / 5 - 10 °C 2: NaOH / methanol / Ambient temperature View Scheme |
methyl 3-oxotetradecanoate
3-oxomyristic acid
Conditions | Yield |
---|---|
With hydrogenchloride; acetic acid |
methyl 3-oxotetradecanoate
Conditions | Yield |
---|---|
With sodium hydrogencarbonate at 215℃; |
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