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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

3-hydroxytetradecanoic acid

Cas:28715-21-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

(R)-3-Hydroxymyristic acid

Cas:28715-21-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages ♦ High purity, all above 98.5%, no impurities after dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available ♦ W

3-HYDROXYTETRADECANOIC ACID CAS28715-21-1

Cas:28715-21-1

Min.Order:1 Kilogram

FOB Price: $289.0 / 499.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Tetradecanoic acid,3-hydroxy-, (3R)- 28715-21-1

Cas:28715-21-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Leader Biochemical Group

About Product Details Items Specifications Test Results Appearance White to white crystalline powde

China Biggest Factory Manufacturer Supply 3-HYDROXYTETRADECANOIC ACID CAS 28715-21-1

Cas:28715-21-1

Min.Order:100 Kilogram

FOB Price: $1.0 / 2.0

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

(R)-3-Hydroxy Myristic Acid CAS:28715-21-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organ

(R)-3-Hydroxy Myristic Acid CAS:28715-21-1

Cas:28715-21-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Tetradecanoic acid,3-hydroxy-, (3R)-

Cas:28715-21-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Tetradecanoic acid,3-hydroxy-, (3R)-

Cas:28715-21-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

R-(3)-Hydroxymyristic Acid manufacturer

Cas:28715-21-1

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

3-HYDROXYTETRADECANOIC ACID Basic information Product Name: 3-HYDROXYTETRADECANOIC ACID Synonyms: DL-BETA-HYDROXYMYRISTIC ACID;HYDROXYMYRISTIC ACID, 3-;(+/-)-3-HYDROXYTETRADECANOIC ACID;3-HYDROXYTETRADECANOIC ACID;3-HYDROXY C14:0 ACID;3-HYDROXYMYRIS

(R)-3-Hydroxy myristic acid

Cas:28715-21-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

R-(3)-Hydroxymyristic Acid

Cas:28715-21-1

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Allgreen Chemical Co.,Ltd

high qualityAppearance:white crystalline powder Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

2'-FLUORO-5'-(TRIFLUOROMETHYL)ACETOPHENONE

Cas:28715-21-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM is one of China's leading providers of integrated fine chemical services including offering, research and development, Custom manufacturing business, as well as other Value-added customer services, for diversified range products of chemicals

3-HYDROXYTETRADECANOIC ACID

Cas:28715-21-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

Tetradecanoic acid,3-hydroxy-, (3R)-

Cas:28715-21-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

3-HYDROXYTETRADECANOIC ACID

Cas:28715-21-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Tetradecanoic acid,3-hydroxy-, (3R)-

Cas:28715-21-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

DB BIOTECH CO., LTD

best seller Application:API

3-HYDROXYTETRADECANOIC ACID

Cas:28715-21-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

3-HYDROXYTETRADECANOIC ACIDAppearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:pharmaceutical intermediate Transportation:by air, by sea, by express

3-HYDROXYTETRADECANOIC ACID

Cas:28715-21-1

Min.Order:0

Negotiable

Type:Other

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Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

3-HYDROXYTETRADECANOIC ACID

Cas:28715-21-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SAGECHEM LIMITED

28715-21-1 Application:intermediate

Tetradecanoic acid, 3-hydroxy-, (3R)-

Cas:28715-21-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemlyte Solutions

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

(R)-3-Hydroxy Myristic Acid

Cas:28715-21-1

Min.Order:0

Negotiable

Type:Other

inquiry

Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

28715-21-1

Cas:28715-21-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hebei Muhuang Technology Co., Ltd

best seller Application:API

3-HYDROXYTETRADECANOIC ACID

Cas:28715-21-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

3-HYDROXYTETRADECANOIC ACID

Cas:28715-21-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

3-HYDROXYTETRADECANOIC ACID Basic information Product Name: 3-HYDROXYTETRADECANOIC ACID Synonyms: DL-BETA-HYDROXYMYRISTIC ACID;HYDROXYMYRISTIC ACID, 3

3-HYDROXYTETRADECANOIC ACID

Cas:28715-21-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Shaanxi Mingqi Chemical Co., Ltd

Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers. Our advantages:1, High quality with competitive price:1) Standard:BP/USP/EP/Enterprise standard2) All Purity≥99%4) We are manufactureAp

R-(3)-Hydroxymyristic Acid manufacturer

Cas:28715-21-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HuBei Ipure Biotech CO.,ltd

HuBei ipure is a diversified product production and operation enterprise, with API, pharma intermediates, and other fine chemicals as well as R&D and pigments development and sales as one of the large enterprises, with more than 130 acres of pl

3-hydroxytetradecanoic acid

Cas:28715-21-1

Min.Order:1 Gram

FOB Price: $1.0 / 2.0

Type:Trading Company

inquiry

Yinghao Pharm Co.,Ltd.

Yinghao Pharm products include: leader molecule, heterocyclic compounds,chiral compounds, photoelectric materials, biochemical reagents etc. For example:benzene, pyrimidine, boricacid,pyridine, pyrazole, imidazole, pyrrole, fluorine and other derivat

3-HYDROXYTETRADECANOIC ACID

Cas:28715-21-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Share Chemical Co., Ltd

At Share Chemical Company, we scrupulously abide by our policy of “Excellent Quality at a Reasonable Price”. We strive to satisfy all of our customers by providing the finest quality products supported by the finest in customer servi

(R)-3-Hydroxymyristic acid

Cas:28715-21-1

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Shanghai united Scientific Co.,Ltd.

United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

Tetradecanoic acid,3-hydroxy-, (3R)-

Cas:28715-21-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

methyl 3-oxotetradecanoate
22348-97-6

methyl 3-oxotetradecanoate

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

Conditions
ConditionsYield
Stage #1: methyl 3-oxotetradecanoate With hydrogen; (R)-2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl; ruthenium trichloride In methanol at 40 - 50℃; under 3361.46 Torr; for 20h;
Stage #2: With lithium hydroxide In tetrahydrofuran; water
100%
With sodium hydroxide; hydrogen; acetic acid; L-Tartaric acid; (R,R)-tartaric acid-NaBr-Raney nickel ((R,R)-TA-NaBr-MRNi); sodium bromide 1.) C2H5COOCH3, 100 deg C, 100 kg/cm2; Yield given. Multistep reaction;
Multi-step reaction with 2 steps
1: 95.6 percent / H2 / (R)-ruthenium 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl / methanol / 5 h / 100 °C / 3750.3 Torr
2: 97.6 percent / lithium hydroxide monohydrate / methanol; H2O / 12 h
View Scheme
methyl (R)-3-hydroxytetradecanoate
76062-97-0

methyl (R)-3-hydroxytetradecanoate

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

Conditions
ConditionsYield
With lithium hydroxide monohydrate In tetrahydrofuran; water at 20℃; for 2h;98%
With lithium hydroxide In methanol; water for 12h;97.6%
With sodium hydroxide In tetrahydrofuran; water Reflux;96%
(R)-1-cyanotridecan-2-ol
259799-90-1

(R)-1-cyanotridecan-2-ol

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

Conditions
ConditionsYield
With hydrogenchloride In dichloromethane at 100℃; for 12h; Hydrolysis;95%
(R)-tert-butyl 3-hydroxytetradecanoate
79816-65-2

(R)-tert-butyl 3-hydroxytetradecanoate

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

Conditions
ConditionsYield
With triethylsilane; trifluoroacetic acid In dichloromethane at 20℃; for 0.75h;87%
(R)-3-hydroxytetradecanoic acid ethyl ester
151763-75-6

(R)-3-hydroxytetradecanoic acid ethyl ester

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

Conditions
ConditionsYield
With potassium hydroxide In ethanol76%
With ethanol; potassium hydroxide
3-hydroxytetradecanoic acid
1961-72-4

3-hydroxytetradecanoic acid

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

Conditions
ConditionsYield
With dexamfetamine
Ethyl 3-hydroxytetradecanoate
126679-29-6

Ethyl 3-hydroxytetradecanoate

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

Conditions
ConditionsYield
In diethyl ether (saponification);
vinyl acetate
108-05-4

vinyl acetate

3-hydroxytetradecanoic acid
1961-72-4

3-hydroxytetradecanoic acid

A

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

B

(S)-3-acetoxytetradecanoic acid
151378-83-5

(S)-3-acetoxytetradecanoic acid

Conditions
ConditionsYield
With di-tert-butyl-4-methylphenol In tetrahydrofuran at 65℃; for 3h; Pseudomonas lipase;
3-oxomyristic acid
88222-72-4

3-oxomyristic acid

A

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

B

tridecan-2-one
593-08-8

tridecan-2-one

Conditions
ConditionsYield
With potassium dihydrogenphosphate; baker's yeast; D-glucose In water at 28℃; for 48h; Yield given. Yields of byproduct given;
(3R)-1-trimethylsilyl-tetradec-1-yn-3-ol
74794-26-6

(3R)-1-trimethylsilyl-tetradec-1-yn-3-ol

A

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

B

(3S)-3-hydroxytetradecanoic acid
35683-15-9

(3S)-3-hydroxytetradecanoic acid

Conditions
ConditionsYield
With sodium hydroxide; bis(cyclohexanyl)borane; dihydrogen peroxide 1) THF, 0 deg C; 2) 40-50 deg C; Yield given. Multistep reaction. Title compound not separated from byproducts;
n-dodecanoyl chloride
112-16-3

n-dodecanoyl chloride

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: pyridine / CH2Cl2 / 3 h / 0 - 20 °C
1.2: 77.9 percent / methanol / 3 h / Heating
2.1: 95.6 percent / H2 / (R)-ruthenium 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl / methanol / 5 h / 100 °C / 3750.3 Torr
3.1: 97.6 percent / lithium hydroxide monohydrate / methanol; H2O / 12 h
View Scheme
1-tridecene
2437-56-1

1-tridecene

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: K3Fe(CN)6; K2CO3; water / 4,6-bis(9-O-dihydroquinidinyl)-2,5-diphenylpyrimidine; OsO4 / 2-methyl-propan-2-ol; toluene / 24 h / 20 °C
2: 92 percent / pyridine; thionyl chloride / 5 h / 0 °C
3: 86 percent / dimethylformamide / 12 h / 90 °C
4: 95 percent / aq. HCl / CH2Cl2 / 12 h / 100 °C
View Scheme
(R)-1,2-dihydroxytridecane
96883-16-8

(R)-1,2-dihydroxytridecane

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 92 percent / pyridine; thionyl chloride / 5 h / 0 °C
2: 86 percent / dimethylformamide / 12 h / 90 °C
3: 95 percent / aq. HCl / CH2Cl2 / 12 h / 100 °C
View Scheme
(4R)-4-undecyl-1,3,2-dioxathiolane-2-oxide
259799-88-7

(4R)-4-undecyl-1,3,2-dioxathiolane-2-oxide

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 86 percent / dimethylformamide / 12 h / 90 °C
2: 95 percent / aq. HCl / CH2Cl2 / 12 h / 100 °C
View Scheme
n-decyl magnesium bromide
17049-50-2

n-decyl magnesium bromide

HgBr2

HgBr2

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 1.) CuI / 1.) THF, -30 deg C, 30 min, 2.) THF, a) -30 deg C, 1 h, b) RT, overnight
2: 76 percent / aq. KOH / ethanol
View Scheme
n-dodecanoyl chloride
112-16-3

n-dodecanoyl chloride

alcoholic NaOH

alcoholic NaOH

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
2: di-t-butyl-p-cresol / tetrahydrofuran / 3 h / 65 °C / Pseudomonas lipase
View Scheme
2,2-dimethyl-4,6-dioxo-5-dodecanoyl-1,3-dioxane
111861-21-3

2,2-dimethyl-4,6-dioxo-5-dodecanoyl-1,3-dioxane

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: methanol / 5 h / Heating
2: 1.) H2, AcOH, 2.) NaOH / 1.) (R,R)-tartaric acid-NaBr-Raney nickel ((R,R)-TA-NaBr-MRNi) / 1.) C2H5COOCH3, 100 deg C, 100 kg/cm2
View Scheme
(R)-(-)-1-tetradecyn-3-ol
77889-04-4, 136022-04-3, 73501-38-9

(R)-(-)-1-tetradecyn-3-ol

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 1) 2.4 eq. n-BuLi; 2) 1.4 M H2SO4 / 1) THF, -78 deg C; 2) from -20 deg C to room temperature
2: 1) 2 eq. dicyclohexylborane; 2) NaOH, H2O2 / 1) THF, 0 deg C; 2) 40-50 deg C
View Scheme
tetradec-1-yn-3-one
73501-40-3

tetradec-1-yn-3-one

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 1.4 eq. R-Alpine-Borane / neat (no solvent) / 8 h / 0 - 20 °C
2: 1) 2.4 eq. n-BuLi; 2) 1.4 M H2SO4 / 1) THF, -78 deg C; 2) from -20 deg C to room temperature
3: 1) 2 eq. dicyclohexylborane; 2) NaOH, H2O2 / 1) THF, 0 deg C; 2) 40-50 deg C
View Scheme
1,4-dioxane
123-91-1

1,4-dioxane

methyl (R)-3-hydroxytetradecanoate
76062-97-0

methyl (R)-3-hydroxytetradecanoate

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

Conditions
ConditionsYield
With hydrogenchloride; sodium hydroxide In methanol; water
n-tetradecanoic acid
544-63-8

n-tetradecanoic acid

A

2-hydroxytetradecanoic acid
2507-55-3

2-hydroxytetradecanoic acid

B

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

Conditions
ConditionsYield
With recombinant Bacillus subtilis cytochrome P450(BSβ) F79L mutant; dihydrogen peroxide at 37℃; for 0.0166667h; pH=7; Kinetics; Concentration; Reagent/catalyst; aq. phosphate buffer; Enzymatic reaction; regioselective reaction;
jagaricin
1422729-34-7

jagaricin

A

D-allo-threonine
24830-94-2

D-allo-threonine

B

(2S,3S)-2-amino-3-hydroxybutanoic acid
28954-12-3

(2S,3S)-2-amino-3-hydroxybutanoic acid

C

L-threonine
72-19-5

L-threonine

D

D-Glutamin
5959-95-5

D-Glutamin

E

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

F

dehydrobutyrine
20748-08-7

dehydrobutyrine

G

tyrosine
556-02-5

tyrosine

H

glycine
56-40-6

glycine

I

L-histidine
71-00-1

L-histidine

Conditions
ConditionsYield
With hydrogenchloride; phenol In water at 105℃; Reagent/catalyst;
(+/-)-3-hydroxytetradecanoic acid methyl ester
55682-83-2

(+/-)-3-hydroxytetradecanoic acid methyl ester

A

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

B

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

Conditions
ConditionsYield
With Porcine Pancreas Lipase; water In aq. phosphate buffer at 36℃; for 7h; pH=7.6; enantioselective reaction;A n/a
B n/a
With Porcine Pancreas Lipase; water In aq. phosphate buffer at 36℃; for 7h; pH=7.6; Resolution of racemate; enantioselective reaction;A n/a
B n/a
(+/-)-3-hydroxytetradecanoic acid methyl ester
55682-83-2

(+/-)-3-hydroxytetradecanoic acid methyl ester

A

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

B

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

C

(3S)-3-hydroxytetradecanoic acid
35683-15-9

(3S)-3-hydroxytetradecanoic acid

Conditions
ConditionsYield
With Porcine Pancreas Lipase; water In aq. phosphate buffer at 36℃; for 7h; pH=7.6; Resolution of racemate; enantioselective reaction;A n/a
B n/a
C n/a
lauric acid
143-07-7

lauric acid

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: magnesium ethylate / 1,4-dioxane
1.2: 20 °C
2.1: hydrogen; dichloro-R-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl ruthenium / methanol / 20 h / 50 °C / 3102.97 Torr / Inert atmosphere
3.1: lithium hydroxide monohydrate / water; tetrahydrofuran / 2 h / 20 °C
View Scheme
C37H66N4O8

C37H66N4O8

A

L-leucine
61-90-5

L-leucine

B

L-glutamic acid
56-86-0

L-glutamic acid

C

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

Conditions
ConditionsYield
With hydrogenchloride In water at 123℃; for 23h;
1-hydroxy-pyrrolidine-2,5-dione
6066-82-6

1-hydroxy-pyrrolidine-2,5-dione

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

N-<(R)-3-hydroxytetradecanoyloxy>succinimide

N-<(R)-3-hydroxytetradecanoyloxy>succinimide

Conditions
ConditionsYield
With 2`,3`-dideoxycytidine In tetrahydrofuran for 12h; Ambient temperature;100%
methanol
67-56-1

methanol

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

methyl (R)-3-hydroxytetradecanoate
76062-97-0

methyl (R)-3-hydroxytetradecanoate

Conditions
ConditionsYield
With boron trifluoride at 100℃; for 0.0333333h;100%
With boron trifluoride at 105℃; for 0.75h;
(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

α-bromoacetophenone
70-11-1

α-bromoacetophenone

(3R)-3-hydroxytetradecanoic acid phenacyl ester
87357-65-1

(3R)-3-hydroxytetradecanoic acid phenacyl ester

Conditions
ConditionsYield
With triethylamine In ethyl acetate98%
With triethylamine In ethyl acetate 1.) 0 deg C, 10 min, 2.) room temp.;94%
With triethylamine In ethyl acetate93%
(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

benzyl chloride
100-44-7

benzyl chloride

3-hydroxy-D-tetradecanoic acid benzyl ester
88862-84-4

3-hydroxy-D-tetradecanoic acid benzyl ester

Conditions
ConditionsYield
In tetrahydrofuran; dimethyl sulfoxide at 50℃;97%
(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

benzyl 2-amino-2-deoxy-4,6-O-isopropylidene-β-D-glucopyranoside
102794-17-2

benzyl 2-amino-2-deoxy-4,6-O-isopropylidene-β-D-glucopyranoside

benzyl 2-deoxy-2-<(3R)-3-hydroxytetradecanamido>-4,6-O-isopropylidene-β-D-glucopyranoside
104640-20-2

benzyl 2-deoxy-2-<(3R)-3-hydroxytetradecanamido>-4,6-O-isopropylidene-β-D-glucopyranoside

Conditions
ConditionsYield
With 3-{[(ethylimino)methylene]-amino}-N,N,N-trimethyl-1-propanaminium iodide In dichloromethane95%
With dicyclohexyl-carbodiimide In dichloromethane for 3h; Ambient temperature; Yield given;
(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

{(2R,3R,4S,5S,6S)-6-[(2R,3S,4R,5R,6S)-5-Amino-6-((2R,3S,4R,5R,6R)-5-amino-3,4-bis-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylmethoxy)-4-benzyloxy-2-hydroxymethyl-tetrahydro-pyran-3-yloxy]-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-yl}-methanol
96961-24-9

{(2R,3R,4S,5S,6S)-6-[(2R,3S,4R,5R,6S)-5-Amino-6-((2R,3S,4R,5R,6R)-5-amino-3,4-bis-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylmethoxy)-4-benzyloxy-2-hydroxymethyl-tetrahydro-pyran-3-yloxy]-3,4,5-tris-benzyloxy-tetrahydro-pyran-2-yl}-methanol

C89H124N2O18
96961-25-0

C89H124N2O18

Conditions
ConditionsYield
With N-ethylmorpholine;; benzotriazol-1-ol; dicyclohexyl-carbodiimide In 1,4-dioxane at 20℃; for 2h;88%
(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

triethylsilyl chloride
994-30-9

triethylsilyl chloride

(R)-3-O-triethylsilyl myristic acid
915406-25-6

(R)-3-O-triethylsilyl myristic acid

Conditions
ConditionsYield
In pyridine at 60℃; for 2h;85.6%
(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

2-(trimethylsilyl)ethyl 2-amino-2-deoxy-4,6-O-isopropylidene-β-D-glucopyranoside
122078-72-2

2-(trimethylsilyl)ethyl 2-amino-2-deoxy-4,6-O-isopropylidene-β-D-glucopyranoside

2-(trimethylsilyl)ethyl 2-deoxy-2-<(3R)-3-hydroxytetradecanamido>-4,6-O-isopropylidene-β-D-glucopyranoside
122078-73-3

2-(trimethylsilyl)ethyl 2-deoxy-2-<(3R)-3-hydroxytetradecanamido>-4,6-O-isopropylidene-β-D-glucopyranoside

Conditions
ConditionsYield
With N-(3-dimethylaminopropyl)-N-ethylcarbodiimide In dichloromethane Ambient temperature;84%
1-hydroxy-pyrrolidine-2,5-dione
6066-82-6

1-hydroxy-pyrrolidine-2,5-dione

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

N-(R)-3-hydroxytetradecanoyloxysuccinimide
33796-65-5

N-(R)-3-hydroxytetradecanoyloxysuccinimide

Conditions
ConditionsYield
With dicyclohexyl-carbodiimide In ethyl acetate at 0℃; for 16h;80%
1H-imidazole
288-32-4

1H-imidazole

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

tert-butyldimethylsilyl chloride
18162-48-6

tert-butyldimethylsilyl chloride

(R)-3-t-Butyldimethyl-Silyloxytetradecanoic Acid

(R)-3-t-Butyldimethyl-Silyloxytetradecanoic Acid

Conditions
ConditionsYield
In methanol; dichloromethane; chloroform79%
(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

(R)-1,3-dihydroxytetradecane
139623-13-5

(R)-1,3-dihydroxytetradecane

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran for 2.5h; Ambient temperature;76%
(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

1,3,4,6-tetra-O-acetyl-D-glucosamine hydrochloride
5432-46-2, 10034-19-2, 10034-20-5, 34948-62-4, 110253-00-4

1,3,4,6-tetra-O-acetyl-D-glucosamine hydrochloride

1,3,4,6-tetra-O-acetyl-2-deoxy-<(3R)-3-hydroxytetradecanamido>-β-D-glucopyranose
74660-52-9, 77448-50-1, 121700-61-6

1,3,4,6-tetra-O-acetyl-2-deoxy-<(3R)-3-hydroxytetradecanamido>-β-D-glucopyranose

Conditions
ConditionsYield
With triethylamine; dicyclohexyl-carbodiimide In pyridine for 48h; Ambient temperature;68%
(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

(S)-methyl 3-(tert-butoxy)-2-((R)-2-((tert-butoxycarbonyl)amino)-3-((2-hydroxyethyl)thio)propanamido)propanoate
1346422-43-2

(S)-methyl 3-(tert-butoxy)-2-((R)-2-((tert-butoxycarbonyl)amino)-3-((2-hydroxyethyl)thio)propanamido)propanoate

methyl (L-(thio-((R)-ethyl 3-hydroxytetradecanoate))-N-(tert-butoxycarbonyl))cysteyl-L-(3-O-(tert-butyl))serate
1620278-76-3

methyl (L-(thio-((R)-ethyl 3-hydroxytetradecanoate))-N-(tert-butoxycarbonyl))cysteyl-L-(3-O-(tert-butyl))serate

Conditions
ConditionsYield
With 4-methyl-morpholine; dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃;63%
(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

benzyl bromide
100-39-0

benzyl bromide

3-hydroxy-D-tetradecanoic acid benzyl ester
88862-84-4

3-hydroxy-D-tetradecanoic acid benzyl ester

Conditions
ConditionsYield
With triethylamine In ethyl acetate for 72h; Ambient temperature;61%
With tetra-(n-butyl)ammonium iodide; triethylamine In ethyl acetate at 20℃; for 18h;
(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

Fmoc-Leu-OH
35661-60-0

Fmoc-Leu-OH

L-Asn(Trt)
132388-59-1

L-Asn(Trt)

Fmoc-L-Gln(Trt)-OH
132327-80-1

Fmoc-L-Gln(Trt)-OH

deoxy-fellutamide D

deoxy-fellutamide D

Conditions
ConditionsYield
Stage #1: Fmoc-Leu-OH With N-ethyl-N,N-diisopropylamine; HATU In N,N-dimethyl-formamide at 20℃; for 6h; Weinreb amide resin;
Stage #2: With piperidine In N,N-dimethyl-formamide for 0.05h; Weinreb amide resin;
Stage #3: (R)-3-hydroxytetradecanoic acid; L-Asn(Trt); Fmoc-L-Gln(Trt)-OH Further stages;
60%
(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

Fmoc-Val-OH
68858-20-8

Fmoc-Val-OH

L-Asn(Trt)
132388-59-1

L-Asn(Trt)

Fmoc-L-Gln(Trt)-OH
132327-80-1

Fmoc-L-Gln(Trt)-OH

deoxy-fellutamide C

deoxy-fellutamide C

Conditions
ConditionsYield
Stage #1: Fmoc-Val-OH With N-ethyl-N,N-diisopropylamine; HATU In N,N-dimethyl-formamide at 20℃; for 6h; Weinreb amide resin;
Stage #2: With piperidine In N,N-dimethyl-formamide for 0.05h; Weinreb amide resin;
Stage #3: (R)-3-hydroxytetradecanoic acid; L-Asn(Trt); Fmoc-L-Gln(Trt)-OH Further stages;
53%
(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

methyl (R)-3-hydroxytetradecanoate
76062-97-0

methyl (R)-3-hydroxytetradecanoate

Conditions
ConditionsYield
In diethyl ether Yield given;
methanol
67-56-1

methanol

(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

A

methyl (R)-3-hydroxytetradecanoate
76062-97-0

methyl (R)-3-hydroxytetradecanoate

B

(S)-methyl 3-hydroxymyristate
76835-67-1

(S)-methyl 3-hydroxymyristate

Conditions
ConditionsYield
With hydrogenchloride for 2h; Ambient temperature; Yield given. Title compound not separated from byproducts;
(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

Benzyl-6-O-<6-O-acetyl-2-amino-3-O-<α,α-D2>benzyl-2-desoxy-4-O-(diphenoxyphosphoryl)-β-D-glucopyranosyl>-2-amino-3,4-di-O-<α,α-D2>benzyl-2-desoxy-β-D-glucopyranosid-dihydrochlorid
106115-93-9

Benzyl-6-O-<6-O-acetyl-2-amino-3-O-<α,α-D2>benzyl-2-desoxy-4-O-(diphenoxyphosphoryl)-β-D-glucopyranosyl>-2-amino-3,4-di-O-<α,α-D2>benzyl-2-desoxy-β-D-glucopyranosid-dihydrochlorid

Benzyl-6-O-<6-O-acetyl-3-O-<α,α-D2>benzyl-2-desoxy-4-O-(diphenoxyphosphoryl)-2-<(R)-3-hydroxytetradecanoylamino>-β-D-glucopyranosyl>-3,4-di-O-<α,α-D2>benzyl-2-desoxy-2-<(R)-3-hydroxytetradecanoylamino>-β-D-glucopyranosid
106115-95-1

Benzyl-6-O-<6-O-acetyl-3-O-<α,α-D2>benzyl-2-desoxy-4-O-(diphenoxyphosphoryl)-2-<(R)-3-hydroxytetradecanoylamino>-β-D-glucopyranosyl>-3,4-di-O-<α,α-D2>benzyl-2-desoxy-2-<(R)-3-hydroxytetradecanoylamino>-β-D-glucopyranosid

Conditions
ConditionsYield
With cyclohexyl(2-morpholinoethyl)carbodiimide metho-p-toluenesulfonate; benzotriazol-1-ol; triethylamine 1.) DMF, 60 min, 2.) DMF, 1 h; Yield given. Multistep reaction;
(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

Benzyl-O-
106115-86-0

Benzyl-O-

C85H116(2)H6N2O24
106115-87-1

C85H116(2)H6N2O24

Conditions
ConditionsYield
With cyclohexyl-(2-morpholinoethyl)carbodiimide metho-p-toluenesulfonate; benzotriazol-1-ol; triethylamine 1.) DMF, 60 min, RT, 2.) DMF, 8 h, RT; Yield given. Multistep reaction;
(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

C34H34(2)H2NO9P*ClH
106139-09-7

C34H34(2)H2NO9P*ClH

Benzyl-6-O-acetyl-3-O-<α,α-D2>benzyl-2-desoxy-4-O-(diphenoxyphosphoryl)-2-<(R)-3-hydroxytetradecanoylamino>-β-D-glucopyranosid
106115-91-7

Benzyl-6-O-acetyl-3-O-<α,α-D2>benzyl-2-desoxy-4-O-(diphenoxyphosphoryl)-2-<(R)-3-hydroxytetradecanoylamino>-β-D-glucopyranosid

Conditions
ConditionsYield
With cyclohexyl(2-morpholinoethyl)carbodiimide metho-p-toluenesulfonate; benzotriazol-1-ol; triethylamine 1.) DMF, 60 min, 2.) DMF, 40 min, RT; Yield given. Multistep reaction;
(R)-3-hydroxytetradecanoic acid
28715-21-1

(R)-3-hydroxytetradecanoic acid

1,3-di-O-acetyl-2-amino-4,6-O-benzylidene-2-deoxy-β-D-glucopyranose hydrochloride
85065-28-7

1,3-di-O-acetyl-2-amino-4,6-O-benzylidene-2-deoxy-β-D-glucopyranose hydrochloride

Acetic acid (4aR,6S,7R,8R,8aS)-6-acetoxy-7-((R)-3-hydroxy-tetradecanoylamino)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl ester

Acetic acid (4aR,6S,7R,8R,8aS)-6-acetoxy-7-((R)-3-hydroxy-tetradecanoylamino)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl ester

Conditions
ConditionsYield
With triethylamine; dicyclohexyl-carbodiimide In pyridine
With triethylamine; dicyclohexyl-carbodiimide In pyridine

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