CAS No.7790-98-9,Ammonium perchlorate Suppliers,MSDS download

: 7601-90-3
perchloric acid

: 302-01-2
hydrazine

: 7790-98-9
ammonium perchlorate

Conditions

Conditions	Yield
ammonium molybdate In perchloric acid Kinetics; byproducts: N2, HCl; 90°C;

: 7601-90-3
perchloric acid

: ammonium nitrate

: 7790-98-9
ammonium perchlorate

Conditions

Conditions	Yield
In sulfuric acid; water heating;;

: 7601-90-3
perchloric acid

: 7664-41-7
ammonia

: 7790-98-9
ammonium perchlorate

Conditions

Conditions	Yield
In water
In not given
In not given pure NH3 introduced in dild. soln. of HClO4;

: ammonium chloride

: sodium perchlorate

: 7790-98-9
ammonium perchlorate

Conditions

Conditions	Yield
In not given
In not given

: ammonium chloride

: calcium perchlorate

: 7790-98-9
ammonium perchlorate

Conditions

Conditions	Yield
With calcium hydroxide In not given byproducts: CaCl2; addn. of aq. soln. of Mg(ClO4)2 to concd. aq. soln. of NH4Cl;; after seapration of pptd. NH4ClO4 the soln. is treated with Ca(OH)2 to free it NH4 salts; Mg(ClO4)2 is regenerated by oxidn. of the soln.;
With Ca(OH)2 In not given byproducts: CaCl2; addn. of aq. soln. of Mg(ClO4)2 to concd. aq. soln. of NH4Cl;; after seapration of pptd. NH4ClO4 the soln. is treated with Ca(OH)2 to free it NH4 salts; Mg(ClO4)2 is regenerated by oxidn. of the soln.;

: magnesium(II) perchlorate

: ammonium chloride

: 7790-98-9
ammonium perchlorate

Conditions

Conditions	Yield
With calcium hydroxide In not given byproducts: MgCl2; addn. of aq. soln. of Mg(ClO4)2 to concd. aq. soln. of NH4Cl;; after seapration of pptd. NH4ClO4 the soln. is treated with Ca(OH)2 to free it NH4 salts; Mg(ClO4)2 is regenerated by oxidn. of the soln.;
With Ca(OH)2 In not given byproducts: MgCl2; addn. of aq. soln. of Mg(ClO4)2 to concd. aq. soln. of NH4Cl;; after seapration of pptd. NH4ClO4 the soln. is treated with Ca(OH)2 to free it NH4 salts; Mg(ClO4)2 is regenerated by oxidn. of the soln.;

: 7601-90-3
perchloric acid

: 103809-62-7
bisamminesilver(I) perchlorate

A: 7790-98-9
ammonium perchlorate

B: silver perchlorate

Conditions

Conditions	Yield
In water
In water

...Expand

: ammonium carbonate

: 7601-90-3
perchloric acid

: 7790-98-9
ammonium perchlorate

Conditions

Conditions	Yield
In water addn. of a calcd. amt. of HClO4 to aq. soln. of (NH4)2CO3 made in freshly distd. water; recrystn. from water, dried in vac. above P2O5 at 110 °C;

: 15588-62-2
hydroxylammonium perchlorate

A: 7601-90-3
perchloric acid

B: 7790-98-9
ammonium perchlorate

C: 7732-18-5
water

D: 7782-50-5
chlorine

E: 10024-97-2
dinitrogen monoxide

Conditions

Conditions	Yield
With perchloric acid; ammonia In solid Kinetics; further products; in sealed glass at 80°C; rate of decomp. depends on reagent concn.;
With perchloric acid; ammonia In neat (no solvent) Kinetics; further reagents, further products; in sealed glass (P=25-30 atm.) at 113.5-150.0°C; rate of decomp. depends on conditions and reagent concn.; MAS, IR;

...Expand

: 15588-62-2
hydroxylammonium perchlorate

: calcium carbonate

A: 7790-98-9
ammonium perchlorate

B: calcium perchlorate

Conditions

Conditions	Yield
In neat (no solvent) byproducts: N2, CO2, H2O; molar ratio (NH3OH)ClO4:CaCO3=3:1, heating in vac. (110-130°C, 3.5 h, then 130-145°C, 2 h);

...Expand

: ammonium nitrate

: sodium perchlorate

: 7790-98-9
ammonium perchlorate

Conditions

Conditions	Yield
In not given
In not given

: ammonium sulfate

: sodium perchlorate

: 7790-98-9
ammonium perchlorate

Conditions

Conditions	Yield
In water byproducts: Na2SO4; in an exothermic reaction; fractionated crsytn.;
In water byproducts: Na2SO4; in an exothermic reaction; fractionated crsytn.;

: ammonium sulfate

: barium(II) perchlorate

: 7790-98-9
ammonium perchlorate

Conditions

Conditions	Yield
In not given
In not given

: potassium perchlorate

: 7790-98-9
ammonium perchlorate

Conditions

Conditions	Yield
In not given react. of NH4-silico fluoride with KClO4-soln.;;
In not given react. of NH4-silico fluoride with KClO4-soln.;;

: ammonium hexafluorosilicate

: potassium perchlorate

: 7790-98-9
ammonium perchlorate

Conditions

Conditions	Yield
In not given
In not given

: 7601-90-3
perchloric acid

: ammonium hydroxide

: 7790-98-9
ammonium perchlorate

Conditions

Conditions	Yield
In water
In water H2O added to 70% aq. HClO4, 25% aq. soln. of NH3 slowly added; crystn. on cooling in refrigerator for 3 d;
In water NH4OH added to aq. soln. of HClO4; crystd., SEM, DTA;
In water

: 12015-53-1
perchloric anhydride

A: 10192-29-7
ammonium chlorate

B: 7790-98-9
ammonium perchlorate

Conditions

Conditions	Yield
With ammonia In tetrachloromethane byproducts: NH4Cl; vigorous reaction;; pptn. of the salts;;
With NH3 In tetrachloromethane byproducts: NH4Cl; vigorous reaction;; pptn. of the salts;;

: 7601-90-3
perchloric acid

: Ag-perchlorate*3NH3

A: 7790-98-9
ammonium perchlorate

B: silver perchlorate

Conditions

Conditions	Yield
In water
In water

...Expand

: {Cu(NH3)4}(2+)*2ClO4(1-)*2H2O={Cu(NH3)4}(ClO4)2*2H2O

A: 7790-98-9
ammonium perchlorate

B: 7664-41-7
ammonia

C: copper(II) oxide

Conditions

Conditions	Yield
In water on boiling the aq. soln.;;
In water on boiling the aq. soln.;;

...Expand

: hydroxylammonium perchlorate monohydroxylamminate

A: 7790-98-9
ammonium perchlorate

B: 7732-18-5
water

C: 10024-97-2
dinitrogen monoxide

Conditions

Conditions	Yield
In methanol Kinetics; at 106.7°C;
With hydroxyammonium sulfate; guanidine nitrate In neat (no solvent) Kinetics; in a sealed glass ampule (P=25-30 atm.) at 101.1-119.8°C; rate of decomposition depends on conditions and reagent concn.; IR;
In ethanol Kinetics; at 106.7°C;
In water Kinetics; at 106.7°C;

...Expand

: 7790-98-9
ammonium perchlorate

: 13106-69-9
caesium methoxide

: 13454-84-7
cesium perchlorate

Conditions

Conditions	Yield
In methanol byproducts: NH3, CH3OH; all manipulations in Ar atm.; soln. of CsOMe in MeOH added to soln. of NH4 compd. in MeOH at -40 - -50°C; concd., filtered or pumped to dryness at 25°C;	99%

: 7790-98-9
ammonium perchlorate

: 38819-71-5
tris(2-aminoethanol) chromium(III) complex trihydrate

: 86852-63-3
[Cr2(Eta)(EtaH)3](ClO4)3

Conditions

Conditions	Yield
In water Cr complex was added to satd. aq. NH4I; react. time 30 min; elem. anal.;	94%

: 7790-98-9
ammonium perchlorate

: 1226763-88-7
[Co(1,7-bis(2-pyridyl)-2,6-bis(2-hydroxy-3-hydroxymethyl-5-methylbenzyl)-2,6-diazaheptane(-2H))]

: [Co(1,7-bis(2-pyridyl)-2,6-bis(2-hydroxy-3-hydroxymethyl-5-methylbenzyl)-2,6-diazaheptane(-2H))]ClO4*4H2O

Conditions

Conditions	Yield
With O2 In acetonitrile O2 bubbled through a suspn. of Co complex, stirred; filtered, a soln. of NH4ClO4 in MeCN added, sepd., washed (EtOH, Et2O, hexane), dried (vac.), recrystd. (MeCN/EtOH); elem. anal.;	94%

: 7790-98-9
ammonium perchlorate

: 3375-31-3
palladium diacetate

: 16-ethyl-5,6,7,8,9,14-hexahydrodibenzo<1,4,8,11>tetraazacyclotetradecine

: 186396-02-1
(16-ethyl-5,6,7,8-tetrahydro-9H-dibenzo[b,i][1,4,8,11]tetraazacyclotetradecinato)palladium(II) perchlorate

Conditions

Conditions	Yield
In methanol; water (N2); treating the Pd salt with the ligand 2 h at 20°C in MeOH with stirring, filtration, addn. of H2O and NH4ClO4; filtration, washing (H2O); elem. anal.;	92%

...Expand

: 1633-05-2
strontium(II) carbonate

: 7790-98-9
ammonium perchlorate

: strontium(II) perchlorate

Conditions

Conditions	Yield
In neat (no solvent) heating equimolar mixture of SrCO3 and NH4ClO4 12 h at 250°C (.+-.5°C) and 1 - 10 torr;;	90%
In neat (no solvent) heating equimolar mixture of SrCO3 and NH4ClO4 12 h at 250°C (.+-.5°C) and 1 - 10 torr;;	90%
In neat (no solvent) heating equimolar mixture of SrCO3 and NH4ClO4 at 250°C;; extraction with organic solvents like n-butanol or acetone;;	50%
In neat (no solvent) heating equimolar mixture of SrCO3 and NH4ClO4 at 250°C;; extraction with organic solvents like n-butanol or acetone;;	50%

: 7790-98-9
ammonium perchlorate

: 60648-70-6
bis(tri-tert-butylphosphine)platinum(0)

: 85944-38-3
{PtH(NH3)(P(C(CH3)3)3)2}(1+)*ClO4(1-)={PtH(NH3)(P(C(CH3)3)3)2}ClO4

Conditions

Conditions	Yield
In tetrahydrofuran stirring of starting compounds in THF under Ar at 25°C for 48 h; all operations under Ar: evapn., addn. of CH2Cl2, filtration (florisil), addn. of pentane, cooling, elem. anal.;	90%
In acetone under Ar at 25°C; elem. anal.;	>99

: 7790-98-9
ammonium perchlorate

: cis-bis(acetonitrile)bis(acetylacetonato)ruthenium(II)

: Ru(C5H7O2)2(CH3CN)2(1+)*ClO4(1-)=[Ru(C5H7O2)2(CH3CN)2]ClO4

Conditions

Conditions	Yield
With Ce(SO4)2 In dichloromethane; water stirring (room temp., 30 min), filtration, stirring (1 h); liquid sepn., washing (water), CH2Cl2 evapn. (room temp.), cryst., washing (diethyl ether), drying (vac.); elem. anal.;	87.3%

: 7790-98-9
ammonium perchlorate

: 95420-20-5
(4S)-2,4,8-trimethyl-5-(3-methyl-3-azabutyl)-2,5,8-triazanonane

: copper(II) perchlorate

: 78063-15-7
{Cu(NH3)(2,4,8-trimethyl-5-(3-methyl-3-azabutyl)-2,5,8-triaza-4(S)-nonane)}(ClO4)2

Conditions

Conditions	Yield
With ammonia In water mixt. of ligand, 1 M Cu(ClO4)2, 1 M NH4ClO4 and 25% aq. ammonia stood in refrigerator for more than 3 h; filtered, washed with chilled soln. of 0.3 M NH4ClO4 contained a small amt. of NH3, washed with EtOH and H2O, recrystd. by dissolving in warm 0.5 M HClO4 followed by addition of 25% NH3 (5 times); elem. anal.;	85%

...Expand

: 7790-98-9
ammonium perchlorate

: nickel(II) chloride hexahydrate

: 14267-17-5, 1079097-20-3, 52610-81-8
nickel(II) diethyldithiocarbamate

: 1038-95-5
Tri(p-tolyl)phosphine

: 858518-03-3
bis[tri(4-methylphenyl)phosphine](diethyldithiocarbamato)nickel(II) perchlorate

Conditions

Conditions	Yield
In methanol; acetonitrile a mixture of Ni-complex, NiCl2*6H2O, the phosphine, and NH4ClO4 in acetonitrile-methanol (1:1) refluxed for about 3 h; soln. concentrated; soln. left undisturbed for two days;	85%

...Expand

: 553-26-4
4,4'-bipyridine

: 7790-98-9
ammonium perchlorate

: Ru(2,2'-bipyridine)2Cl2*2H2O

: [((bipy)2(Cl)Ru)2(μ-4,4'-bipyridine)](ClO4)2

Conditions

Conditions	Yield
In water; ethylene glycol heating of mixt. of 4,4'-bipyridine (1 equiv.) and (RuCl2(bipy)2)*2H2O (2 equiv.) in ethylene glycol on water bath for 7 h; cooling, addn. of satd. aq. soln. of NH4ClO4; centrifuging, washing 3 times with ethanol, drying in vac., elem. anal.;	83%

...Expand

: 7790-98-9
ammonium perchlorate

: dinitramide potassium salt

: ammonium dinitramide

Conditions

Conditions	Yield
In methanol saturated soln. pouring together; ppt. filtration off, filtrate concn. (vacuum evapn.), residue recrystn. (dioxane-ethyl acetate);	82%

: 7790-98-9
ammonium perchlorate

: (CH2N(CH2C5H4N)(CH2C6H2Br(O)CHO))2Zn

: 111-40-0
1,5-diamino-3-azapentane

: (CH2N(CH2C5H4N)(CH2C6H2Br(OH)CHNCH2CH2))2NZn(2+)*2ClO4(1-)=[(CH2N(CH2C5H4N)(CH2C6H2Br(OH)CHNCH2CH2))2NZn](ClO4)2

Conditions

Conditions	Yield
With catalyst: CH3COOH In methanol; ethanol 1 equiv. of amine and 2 equiv. of acetic acid in EtOH were added to stirred suspn. of Zn-salt in MeOH over 1 h, stirring for 3 h, EtOH soln. of excess of NH4ClO4 was added; solid was collected, washed twice with EtOH, twice with Et2O and twice with hexane, recrystn., elem. anal.;	80%

...Expand

: 7790-98-9
ammonium perchlorate

: 872993-25-4
[(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)Ni(H2O)(benzoato)2]

: 7732-18-5
water

: 932703-94-1
[(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)Ni(H2O)(benzoato)]ClO4

Conditions

Conditions	Yield
In acetonitrile under N2; soln. of NH4ClO4 (1 equiv.) in MeCN added to Ni complex in MeCN; N2 purged for 1 h; stirred at ambient temp. overnight; solvent removed under reduced pressure; recrystd. by n-pentane diffusioninto CH2Cl2-H2O soln.; elem. anal.;	80%

...Expand

: 7790-98-9
ammonium perchlorate

: 3-[(triphenylphosphine)gold]pentane-2,4-dione

: 194206-63-8
Au(NH3)(P(C6H5)3)(1+)*ClO4(1-)=[Au(NH3)(P(C6H5)3)]ClO4

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: acetylacetone; dropwise addn. of soln. of Au-complex to suspn. of slight stoich. excessNH4ClO4, stirring at room temp. for 1 h; filtration (Celite), concn., pptn. on Et2O addn., collection (filtration), washing (Et2O), recrystn. (THF and Et2O), washing (pentane); elem. anal.;	76%

: 7790-98-9
ammonium perchlorate

: cis-{ruthenium(III) (2,2'-bipyridine)2 Cl2}Cl*2H2O

: 67968-72-3, 76654-78-9
cis-{ruthenium(III) (2,2'-bipyridine)2 Cl2}ClO4

Conditions

Conditions	Yield
In methanol To a soln. of the ruthenium complex, a soln. of NH4ClO4 was added and the mixt. refluxed for 15 min.; concg., cooling, centrifugation, washing with ether, drying in vacuo, elem. anal.;	75%

: 7790-98-9
ammonium perchlorate

: 138980-34-4
[Au(acetylacetonato-κC(2))(P(C6H4OMe-4)3)]

: 194206-70-7
[Au(NH3)(P(C6H4OMe-4)3)]ClO4

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: acetylacetone; dropwise addn. of soln. of Au-complex to suspn. of NH4ClO4 at room temp.; filtration, concn., pptn. on Et2O addn.; elem. anal.;	75%

: 7790-98-9
ammonium perchlorate

: 71682-43-4
1-hydroxy-5-aza-2,8,9-oxa-1-germatricycloundecane

: 1-perchloratogermatrane

Conditions

Conditions	Yield
In not given reaction in water or MeCN; elem. anal.;	75%

: 7790-98-9
ammonium perchlorate

: nickel(II) chloride hexahydrate

: 1395880-11-1
bis(N-allylcyclohexylcarbodithioato)nickel(II)

: 141-78-6
ethyl acetate

: 603-35-0
triphenylphosphine

: bis(triphenylphosphine)(N-allylcyclohexylcarbodithioato)nickel(II) perchlorate - ethyl acetate (1/0.5)

Conditions

Conditions	Yield
In dichloromethane; ethyl acetate mixt. of Ni complex, PPh3, NiCl2*6H2O and NH4ClO4 heated at reflux in CH2Cl2/EtOAc (3/1) for ca. 2 h; soln. concd. and filtered, filtrate allowed to evap., ppt. filtered, dried, recrystd. from CH2Cl2/EtOAc; elem. anal.;	75%

...Expand

: 7790-98-9
ammonium perchlorate

: nickel(II) perchlorate hexahydrate

: Zn((CH3C6H2(O)(CHNHCH3)CH2N(CH2C5H4N)CH2)2)(2+)*2ClO4(1-)=[Zn((CH3C6H2(O)(CHNHCH3)CH2N(CH2C5H4N)CH2)2)](ClO4)2

: [Zn(HNCHC6H2(O)(CH3)CH2N(CH2C5H4N)CH2CH2N(CH2C5H4N)CH2C6H2(CH3)(O)CHNCH3)Ni](2+)*2ClO4(1-)=[ZnC33H36NiN6O2](ClO4)2

Conditions

Conditions	Yield
With LiOHH2O In methanol; propan-1-ol; acetonitrile soln. of Ni(ClO)46H2O in propanol and LiOH*H2O in MeOH added dropwise to soln. of Zn complex in MeCN, mixt. stirred for 30 min, soln. of NH4ClO4 in propanol added; concd., THF added, washed (propanol, THF, hexane), recrystd. by diffusion of THF into CH3CN, elem. anal.;	72%

...Expand

: 7790-98-9
ammonium perchlorate

: 3-[(triphenylphosphine)gold]pentane-2,4-dione

: 7732-18-5
water

A [(AuPPh3)3(μ-O)]ClO4: [(AuPPh3)3(μ-O)]ClO4

B: [(AuPPh3)4(μ4-N)]ClO4

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: acetylacetone; stoich. amts., stirring at room temp. for 1.5 h (source of water unclear); removal of volatiles (vac.), stirring with Et2O for 3 h, collection (filtration), washing (Et2O), drying under N2; elem. anal.;	A n/a B 70%

...Expand

: 7790-98-9
ammonium perchlorate

: 14592-16-6
[Ni(N,N-dicyclohexyldithiocarbamate)2]

: 603-35-0
triphenylphosphine

: 880549-31-5
[Ni(N,N-dicyclohexyldithiocarbamate)(PPh3)2]ClO4

Conditions

Conditions	Yield
With NiCl26H2O In dichloromethane; acetonitrile mixt. of Ni complex, PPh3, NiCl26H2O and NH4ClO4 in MeCN/CH2Cl2 (1/1) was refluxed for 2 h; coincd.; kept for 2 d; filtered; dried over CaCl2; recrystd. (MeCN); elem. anal.;	70%

...Expand

: 7790-98-9
ammonium perchlorate

: [Ru(η5-cyclopentadienyl)(triphenylarsine)2Cl]

: 14916-09-7
(P(C6H5)3)2Ni(S2CNCN)

: (P(C6H5)3)2Ni(S2CNCN)Ru(C5H5)(As(C6H5)3)2(1+)*ClO4(1-) = [(P(C6H5)3)2Ni(S2CNCN)Ru(C5H5)(As(C6H5)3)2](ClO4)

Conditions

Conditions	Yield
In methanol; acetone byproducts: NH4Cl; (N2); refluxing 1:1 mixt. of metal complexes (4 h), evapn., extraction (benzene), methanolic ammonium salt addn.; elem. anal.;	70%

...Expand

: 7790-98-9
ammonium perchlorate

: 872993-25-4
[(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)Ni(H2O)(benzoato)2]

: 932703-85-0
[(6-Ph2TPA)Ni(O2CPh)]ClO4

Conditions

Conditions	Yield
In acetonitrile byproducts: benzoic acid, H2O, NH3; under N2; soln. of NH4ClO4 (1 equiv.) in MeCN added to Ni complex in MeCN; N2 purged for 1 h; stirred at ambient temp. overnight; solvent removed under reduced pressure; recrystd. by Et2O diffusion intoMeOH-MeCN soln.; detd. by (1)H NMR spectra;	70%

: zinc(II) perchlorate

: 7790-98-9
ammonium perchlorate

: 16-ethyl-5,6,7,8,9,14-hexahydrodibenzo<1,4,8,11>tetraazacyclotetradecine

: (16-ethyl-5,6,7,8-tetrahydro-9H-dibenzo[b,i][1,4,8,11]tetraazacyclotetradecinato)zinc(II) perchlorate

Conditions

Conditions	Yield
In methanol; water heating the Zn salt and the ligand 1 h in MeOH with stirring to 50°C, addn. of H2O and NH4ClO4; filtration, washing (H2O); elem. anal.;	69%

...Expand

: 32993-05-8
chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II)

: 7790-98-9
ammonium perchlorate

: 14916-09-7
(P(C6H5)3)2Ni(S2CNCN)

: (P(C6H5)3)2Ni(S2CNCN)Ru(C5H5)(P(C6H5)3)2(1+)*ClO4(1-) = [(P(C6H5)3)2Ni(S2CNCN)Ru(C5H5)(P(C6H5)3)2](ClO4)

Conditions

Conditions	Yield
In methanol; acetone byproducts: NH4Cl; (N2); refluxing 1:1 mixt. of metal complexes (4 h), evapn., extraction (benzene), methanolic ammonium salt addn.; elem. anal.;	68%

...Expand

: 7790-98-9
ammonium perchlorate

: nickel(II) chloride hexahydrate

: bis(4-methylpiperazinecarbodithioato) nickel(II)

: 603-35-0
triphenylphosphine

: 935742-17-9
bis(triphenylphosphine)(4-methylpiperazinecarbodithioato)nickel(II) perchlorate monohydrate

Conditions

Conditions	Yield
In methanol; dichloromethane Ni-complex, PPh3, NiCl2*6H2O and NH4ClO4 refluxed for .apprx.2 h in CH3OH/CH2Cl2 1:1 mixt.; concd.; filtered; kept for evapn.; filtered; dried; recrystallized from CH3OH/CH2Cl2 1:1 mixt.; elem. anal.;	65%

...Expand

: 7790-98-9
ammonium perchlorate

: nickel(II) chloride hexahydrate

: bis(4-methylpiperazinecarbodithioato) nickel(II)

: 1663-45-2
1,2-bis-(diphenylphosphino)ethane

: 935742-19-1
1,2-bis((diphenylphosphino)ethane)(4-methylpiperazinecarbodithioato)nickel(II) perchlorate

Conditions

Conditions	Yield
In methanol; dichloromethane Ni-complex, organic ligand, NiCl2*6H2O and NH4ClO4 refluxed for .apprx.4h in CH3OH/CH2Cl2 1:1 mixt.; concd.; filtered; kept for evapn.; sepd. out after 2 days; recrystallized from CH3OH/CH2Cl2 1:1 mixt.; elem. anal.;	65%

...Expand

: 7790-98-9
ammonium perchlorate

: 17252-51-6
1,3-di(4-pyridyl)propane

: 7732-18-5
water

: 6147-53-1
cobalt(II) diacetate tetrahydrate

: [cobalt(II)(1,3-bis(4-pyridyl)propane)2*2H2O](ClO4)2*H2O*3(1,3-bis(pyridyl)propane)

Conditions

Conditions	Yield
With 1,3,4-thiadiazole-2,5-di-3-pyridyl In methanol; chloroform; water to soln. of 1,3-bis(4-pyridyl) and 1,3,4-thiadiazole-2,5-di-3-pyridyl inCHCl3/MeOH added soln. of Co(CH3COO)2*4H2O in MeOH and mixt. stirred fo r 20 min; aq. soln. of NH4ClO4 added dropwise and mixt. stirred for 5 min and then filtered; filtrate evapd. at room temp. for 20 d and compd. crystd.; elem. anal.;	65%

...Expand

: 7790-98-9
ammonium perchlorate

: (η5-C5H5)RuCl(SbPh3)2

: 14916-09-7
(P(C6H5)3)2Ni(S2CNCN)

: (P(C6H5)3)2Ni(S2CNCN)Ru(C5H5)(Sb(C6H5)3)2(1+)*ClO4(1-) = [(P(C6H5)3)2Ni(S2CNCN)Ru(C5H5)(Sb(C6H5)3)2](ClO4)

Conditions

Conditions	Yield
In methanol; acetone byproducts: NH4Cl; (N2); refluxing 1:1 mixt. of metal complexes (4 h), evapn., extraction (benzene), methanolic ammonium salt addn.; elem. anal.;	64%

...Expand

: 7790-98-9
ammonium perchlorate

: {Co(1,4,7-triazacyclononane)(3-thiapentane-1,5-diamine)}Cl3*H2O

: {μ-1,4-diaza-7-azanidocyclononane-1κ(2)N(1),N(4),1:2κ(2)N(7)-μ2-4-thiapentane-1,5-amido-1κS,1:2κ(4)N,N'-1,4,7-triazacyclononane-2κ(3)N(1),N(4),N(7)dicobalt(III)} perchlorate hydrate

Conditions

Conditions	Yield
With OH(1-) In sodium hydroxide byproducts: H2O; aq. NaOH; soln. Co-complex in 4 M NaOH heated (60°C, 1 h) in a closed teflon tube, cooled (ice), addn. ice-cold water with stirring and cooling (ice), addn. ice-cold 1 M soln. NH4ClO4, pptn.; after 20 min ppt. filtered off, washed (1. ice-cold water, 2. 96% EtOH (3 times), 3. Et2O), dried (air), elem. anal.;	63%

Products

Refine

Business Type

Certificate

Display

Synthetic route

Related products

Raw Materials

Downstream Products

Hot Products