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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

2-Methylphenyl-L-alanine

Cas:80126-53-0

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

tianfu-chem-2-Methylphenyl-L-alanine,80126-53-0

Cas:80126-53-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

2-Methylphenyl-L-alanine

Cas:80126-53-0

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 80126-53-0 with competitive price

Cas:80126-53-0

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

L-Phenylalanine,2-methyl-

Cas:80126-53-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

2-METHYLPHENYL-L-ALANINE

Cas:80126-53-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply L-2-Methylphe

Cas:80126-53-0

Min.Order:0 Metric Ton

Negotiable

Type:Other

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

L-Phenylalanine,2-methyl-

Cas:80126-53-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

2-Methylphenyl-L-alanine

Cas:80126-53-0

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

2-Methyl-L-phenylalanine

Cas:80126-53-0

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

2-Methyl-L-phenylalanine

Cas:80126-53-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

2-methylphenyl-l-alanine

Cas:80126-53-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

2-Methylphenyl-L-alanine

Cas:80126-53-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Product name: Lmur2-methylphenylalanine. Synonym:2-METHYL-L-PHENYLALANINE;L-2-METHYLPHE;L-2-METHYLPHENYLALANINE;H-PHE(2-ME)-OH;H-O-ME-PHE-OH;(2S)-2-aminoChemicalbook-3-(2-methylphenyl)propanoicacid;L-2-Me-Phe-OH;2-Methylphenyl-L-alanine CAS No:

Lmur2-methylphenylalanine

Cas:80126-53-0

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

L-2-Methylphenylalanine cas no. 80126-53-0 98%

Cas:80126-53-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Research Peptide Biotechnology Co., Ltd.

High purity, high success rate, short cycle and moderate priceAppearance:White powder solid Storage:Negative 20 degrees Celsius Package:5mg, 10mg 100mg, 1gram Application:Applied to various scientific research

L-Phenylalanine,2-methyl-

Cas:80126-53-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

L-2-Methylphe

Cas:80126-53-0

Min.Order:0

Negotiable

Type:Other

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier

L-2-Methylphenylalanine

Cas:80126-53-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec 2-Methylphenyl-L-alanine 5g

Cas:80126-53-0

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

2-Methylphenyl-L-alanine

Cas:80126-53-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

GL Biochem (Shanghai) Ltd.

Application:Intermidates

H-Phe(2-Me)-OH

Cas:80126-53-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

L-2-Methylphenylalanine

Cas:80126-53-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Guangdong Juda Chemical Industrial Co.,Limited

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by courier/air/sea Port:Any port of China

2-Methyl-L-phenylalanine 80126-53-0 CAS NO.: 80126-53-0

Cas:80126-53-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:white solid Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as primary an

2-Methylphenyl-L-alanine

Cas:80126-53-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

2-Methylphenyl-L-alanine cas 80126-53-0Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

2-Methylphenyl-L-alanine cas 80126-53-0

Cas:80126-53-0

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Best quality with low price Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai

L-2-Methylphe

Cas:80126-53-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers.Appearance:Off white to white powder Application:Food addi

2-Methylphenyl-L-alanine

Cas:80126-53-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

80126-53-0

Cas:80126-53-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai Terui OP New Material Technology Co., Ltd.

The factory supplies Application:manufacturing supplies

L-Phenylalanine,2-methyl-

Cas:80126-53-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

2-Methyl-L-phenylalanine 80126-53-0

Cas:80126-53-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

2-Oxo-3-o-tolyl-propionic acid anion

2-Oxo-3-o-tolyl-propionic acid anion

(S)-2-amino-3-(o-tolyl)propanoic acid
80126-53-0

(S)-2-amino-3-(o-tolyl)propanoic acid

Conditions
ConditionsYield
With L-glutamic acid; pyridoxal 5'-phosphate In water at 40℃; for 12h; E.coli Aspartate transaminase, pH 8;30%
(E)-3-(2-methylphenyl)acrylic acid
939-57-1, 2373-76-4, 41397-71-1

(E)-3-(2-methylphenyl)acrylic acid

(S)-2-amino-3-(o-tolyl)propanoic acid
80126-53-0

(S)-2-amino-3-(o-tolyl)propanoic acid

Conditions
ConditionsYield
With carbon dioxide; Taxus chinensis phenylalanine aminomutase; ammonia In water pH=10; Kinetics; Enzymatic reaction; optical yield given as %ee; enantioselective reaction;
With ammonia at 30℃; for 17h; pH=10; Time; Reagent/catalyst;n/a
2-([(18)F]-fluoromethyl)-L-phenylalanine
1111643-38-9

2-([(18)F]-fluoromethyl)-L-phenylalanine

(S)-2-amino-3-(o-tolyl)propanoic acid
80126-53-0

(S)-2-amino-3-(o-tolyl)propanoic acid

Conditions
ConditionsYield
With water at 50℃; pH=7;
2-methylcinnamic acid
2373-76-4

2-methylcinnamic acid

A

(S)-3-amino-3-(2-methylphenyl)propionic acid
736131-48-9

(S)-3-amino-3-(2-methylphenyl)propionic acid

B

(S)-2-amino-3-(o-tolyl)propanoic acid
80126-53-0

(S)-2-amino-3-(o-tolyl)propanoic acid

Conditions
ConditionsYield
With ammonium bisulphate; EncP-E293M variant at 55℃; for 22h; pH=8.3; Enzymatic reaction; stereoselective reaction;A n/a
B n/a
2-methylcinnamic acid
2373-76-4

2-methylcinnamic acid

A

(R)-3-amino-3-(2-methylphenyl)propionic acid

(R)-3-amino-3-(2-methylphenyl)propionic acid

B

(S)-3-amino-3-(2-methylphenyl)propionic acid
736131-48-9

(S)-3-amino-3-(2-methylphenyl)propionic acid

C

(S)-2-amino-3-(o-tolyl)propanoic acid
80126-53-0

(S)-2-amino-3-(o-tolyl)propanoic acid

Conditions
ConditionsYield
With ammonium bisulphate; EncP wild type enzyme at 55℃; for 22h; pH=8.3; Enzymatic reaction; stereoselective reaction;A n/a
B n/a
C n/a
3-amino-3-(2-methylphenyl)propanoic acid
68208-16-2

3-amino-3-(2-methylphenyl)propanoic acid

A

(R)-3-amino-3-(2-methylphenyl)propionic acid

(R)-3-amino-3-(2-methylphenyl)propionic acid

B

(E)-3-(2-methylphenyl)acrylic acid
939-57-1, 2373-76-4, 41397-71-1

(E)-3-(2-methylphenyl)acrylic acid

C

(S)-2-amino-3-(o-tolyl)propanoic acid
80126-53-0

(S)-2-amino-3-(o-tolyl)propanoic acid

Conditions
ConditionsYield
With phenylalanine ammonia α-lyase from Anabaena variabilis; phenylalanine ammonia lyase from Streptomyces maritimus In aq. buffer at 30℃; for 24h; pH=8; Reagent/catalyst; Resolution of racemate; Enzymatic reaction; enantioselective reaction;
(E)-3-(2-methylphenyl)acrylic acid
939-57-1, 2373-76-4, 41397-71-1

(E)-3-(2-methylphenyl)acrylic acid

A

(S)-2-amino-3-(o-tolyl)propanoic acid
80126-53-0

(S)-2-amino-3-(o-tolyl)propanoic acid

B

2-(fluoromethyl)-D-phenylalanine

2-(fluoromethyl)-D-phenylalanine

Conditions
ConditionsYield
Stage #1: (E)-3-(2-methylphenyl)acrylic acid With ammonium hydroxide; phenylalanine ammonia-lyase from Anabaena variabilis N347A mutant In aq. buffer at 35℃; for 12h; pH=8.5;
Stage #2: With borane-ammonia complex; L-amino acid deaminase from Proteus mirabilis In aq. buffer at 35℃; for 12h; pH=8.5; stereoselective reaction;
A n/a
B n/a
2-amino-3-(2-methylphenyl)propanoic acid
22888-51-3

2-amino-3-(2-methylphenyl)propanoic acid

(S)-2-amino-3-(o-tolyl)propanoic acid
80126-53-0

(S)-2-amino-3-(o-tolyl)propanoic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: phenylalanine ammonia-lyase from Pseudozyma antarctica yeast / aq. buffer / 168 h / 30 °C / pH 8.5 / Resolution of racemate
2: ammonia / 17 h / 30 °C / pH 10
View Scheme
di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

(S)-2-amino-3-(o-tolyl)propanoic acid
80126-53-0

(S)-2-amino-3-(o-tolyl)propanoic acid

Nα-tert-butyloxycarbonyl-2'-methyl-L-phenylalanine
80102-29-0, 139558-50-2, 114873-05-1

Nα-tert-butyloxycarbonyl-2'-methyl-L-phenylalanine

Conditions
ConditionsYield
With triethylamine In 1,4-dioxane; water at 20℃; for 2h;89.2%
1,10-Phenanthroline
66-71-7

1,10-Phenanthroline

sodium perchlorate

sodium perchlorate

(S)-2-amino-3-(o-tolyl)propanoic acid
80126-53-0

(S)-2-amino-3-(o-tolyl)propanoic acid

palladium dichloride

palladium dichloride

[Pd(L-(o-methyl)phenylalaninate)(1,10-phenanthroline)]ClO4

[Pd(L-(o-methyl)phenylalaninate)(1,10-phenanthroline)]ClO4

Conditions
ConditionsYield
With NaOH; HCl In hydrogenchloride; methanol addn. of 2 equiv. aminoacid to PdCl2 (in 1 M HCl), pH-adjustment to 6-7 (aq. NaOH), addn. of 1 equiv. phenanthroline (in aq. MeOH), stirring at 40°C overnight, pptn. on addn. of aq. NaClO4;89%
1,10-Phenanthroline
66-71-7

1,10-Phenanthroline

copper(II) perchlorate hexahydrate

copper(II) perchlorate hexahydrate

(S)-2-amino-3-(o-tolyl)propanoic acid
80126-53-0

(S)-2-amino-3-(o-tolyl)propanoic acid

[Cu(L-(o-methyl)phenylalaninate)(1,10-phenanthroline)]ClO4 * H2O

[Cu(L-(o-methyl)phenylalaninate)(1,10-phenanthroline)]ClO4 * H2O

Conditions
ConditionsYield
With NaOH In methanol; water addn. of 1 equiv. aminoacid (in 1 M NaOH) to equimolar mixt. of Cu-salt and phenanthroline (in 50% aq. MeOH), stirring at room temp. to dissoln.; crystn., collection, recrystn. (aq. MeOH); elem. anal.;86%
(S)-2-amino-3-(o-tolyl)propanoic acid
80126-53-0

(S)-2-amino-3-(o-tolyl)propanoic acid

2-(fluoromethyl)-D-phenylalanine

2-(fluoromethyl)-D-phenylalanine

Conditions
ConditionsYield
With D-glucose; nicotinamide adenine dinucleotide phosphate; ammonium chloride In aq. buffer at 20℃; for 24h; pH=9; Microbiological reaction; enantioselective reaction;83%
With D-glucose; D-amino acid aminotransferase from Bacillus sp mutant T242G; L-aminoacid deaminase from Proteus mirabilis In aq. phosphate buffer at 37℃; for 4h; pH=8; Enzymatic reaction; enantioselective reaction;n/a
potassium cyanate
590-28-3

potassium cyanate

(S)-2-amino-3-(o-tolyl)propanoic acid
80126-53-0

(S)-2-amino-3-(o-tolyl)propanoic acid

(S)-5-(2-methylbenzyl)imidazolidine-2,4-dione

(S)-5-(2-methylbenzyl)imidazolidine-2,4-dione

Conditions
ConditionsYield
With hydrogenchloride In water for 5h; Reflux;67%
(S)-2-amino-3-(o-tolyl)propanoic acid
80126-53-0

(S)-2-amino-3-(o-tolyl)propanoic acid

(R)-3-amino-3-(2-methylphenyl)propionic acid

(R)-3-amino-3-(2-methylphenyl)propionic acid

Conditions
ConditionsYield
With phenylalanine aminomutase at 31℃; for 2h; Enzyme kinetics;
(S)-2-amino-3-(o-tolyl)propanoic acid
80126-53-0

(S)-2-amino-3-(o-tolyl)propanoic acid

Nα-tert-butyloxycarbonyl-2'-methyl-L-phenylalanyl-L-phenylalanylamide
943726-70-3

Nα-tert-butyloxycarbonyl-2'-methyl-L-phenylalanyl-L-phenylalanylamide

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 89.2 percent / triethylamine / dioxane; H2O / 2 h / 20 °C
2: 97 percent / diisopropylethylamine; benzotriazol-1-yloxytrispyrrolidinophosphonium*PF6 / dimethylformamide / 4 h / 20 °C
View Scheme
(S)-2-amino-3-(o-tolyl)propanoic acid
80126-53-0

(S)-2-amino-3-(o-tolyl)propanoic acid

C19H23N3O2*HCl

C19H23N3O2*HCl

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 89.2 percent / triethylamine / dioxane; H2O / 2 h / 20 °C
2: 97 percent / diisopropylethylamine; benzotriazol-1-yloxytrispyrrolidinophosphonium*PF6 / dimethylformamide / 4 h / 20 °C
3: HCl / dioxane / 0.5 h / 20 °C
View Scheme
(S)-2-amino-3-(o-tolyl)propanoic acid
80126-53-0

(S)-2-amino-3-(o-tolyl)propanoic acid

Nα-tert-butyloxycarbonyl-L-tyrosyl-L-prolyl-2'-methyl-L-phenylalanyl-L-phenylalanylamide
943726-76-9

Nα-tert-butyloxycarbonyl-L-tyrosyl-L-prolyl-2'-methyl-L-phenylalanyl-L-phenylalanylamide

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 89.2 percent / triethylamine / dioxane; H2O / 2 h / 20 °C
2: 97 percent / diisopropylethylamine; benzotriazol-1-yloxytrispyrrolidinophosphonium*PF6 / dimethylformamide / 4 h / 20 °C
3: HCl / dioxane / 0.5 h / 20 °C
4: 289 mg / diisopropylethylamine; benzotriazol-1-yloxytrispyrrolidinophosphonium*PF6 / dimethylformamide / 4 h / 20 °C
View Scheme
(S)-2-amino-3-(o-tolyl)propanoic acid
80126-53-0

(S)-2-amino-3-(o-tolyl)propanoic acid

Nα-tert-butyloxycarbonyl-2',6'-dimethyl-L-tyrosyl-L-prolyl-2'-methyl-L-phenylalanyl-L-phenylalanylamide
943726-77-0

Nα-tert-butyloxycarbonyl-2',6'-dimethyl-L-tyrosyl-L-prolyl-2'-methyl-L-phenylalanyl-L-phenylalanylamide

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 89.2 percent / triethylamine / dioxane; H2O / 2 h / 20 °C
2: 97 percent / diisopropylethylamine; benzotriazol-1-yloxytrispyrrolidinophosphonium*PF6 / dimethylformamide / 4 h / 20 °C
3: HCl / dioxane / 0.5 h / 20 °C
4: 266 mg / diisopropylethylamine; benzotriazol-1-yloxytrispyrrolidinophosphonium*PF6 / dimethylformamide / 4 h / 20 °C
View Scheme
(S)-2-amino-3-(o-tolyl)propanoic acid
80126-53-0

(S)-2-amino-3-(o-tolyl)propanoic acid

L-tyrosyl-L-prolyl-2'-methyl-L-phenylalanyl-L-phenylalanylamide

L-tyrosyl-L-prolyl-2'-methyl-L-phenylalanyl-L-phenylalanylamide

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: 89.2 percent / triethylamine / dioxane; H2O / 2 h / 20 °C
2: 97 percent / diisopropylethylamine; benzotriazol-1-yloxytrispyrrolidinophosphonium*PF6 / dimethylformamide / 4 h / 20 °C
3: HCl / dioxane / 0.5 h / 20 °C
4: 289 mg / diisopropylethylamine; benzotriazol-1-yloxytrispyrrolidinophosphonium*PF6 / dimethylformamide / 4 h / 20 °C
5: trifluoroacetic acid; anisole / 1 h / 20 °C
View Scheme
(S)-2-amino-3-(o-tolyl)propanoic acid
80126-53-0

(S)-2-amino-3-(o-tolyl)propanoic acid

2',6'-dimethyl-L-tyrosyl-L-prolyl-2'-methyl-L-phenylalanyl-L-phenylalanylamide

2',6'-dimethyl-L-tyrosyl-L-prolyl-2'-methyl-L-phenylalanyl-L-phenylalanylamide

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: 89.2 percent / triethylamine / dioxane; H2O / 2 h / 20 °C
2: 97 percent / diisopropylethylamine; benzotriazol-1-yloxytrispyrrolidinophosphonium*PF6 / dimethylformamide / 4 h / 20 °C
3: HCl / dioxane / 0.5 h / 20 °C
4: 266 mg / diisopropylethylamine; benzotriazol-1-yloxytrispyrrolidinophosphonium*PF6 / dimethylformamide / 4 h / 20 °C
5: trifluoroacetic acid; anisole / 1 h / 20 °C
View Scheme
(S)-2-amino-3-(o-tolyl)propanoic acid
80126-53-0

(S)-2-amino-3-(o-tolyl)propanoic acid

palladium dichloride

palladium dichloride

[Pd(L-(o-methyl)phenylalaninate)2]

[Pd(L-(o-methyl)phenylalaninate)2]

Conditions
ConditionsYield
With NaOH; HCl In hydrogenchloride addn. of 2 equiv. ligand to PdCl2, pH-adjustment to 6-7 (aq. NaOH);
(S)-2-amino-3-(o-tolyl)propanoic acid
80126-53-0

(S)-2-amino-3-(o-tolyl)propanoic acid

(E)-3-(2-methylphenyl)acrylic acid
939-57-1, 2373-76-4, 41397-71-1

(E)-3-(2-methylphenyl)acrylic acid

Conditions
ConditionsYield
With Taxus phenylalanine aminomutase at 31℃; for 1h; Kinetics; Enzymatic reaction;
(S)-2-amino-3-(o-tolyl)propanoic acid
80126-53-0

(S)-2-amino-3-(o-tolyl)propanoic acid

3-(4-methoxybenzyl)-5-(2-methylbenzyl)imidazolidine-2,4-dione

3-(4-methoxybenzyl)-5-(2-methylbenzyl)imidazolidine-2,4-dione

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: hydrogenchloride / water / 5 h / Reflux
2: potassium carbonate / N,N-dimethyl-formamide / 12 h / 20 °C
View Scheme
acetic acid tert-butyl ester
540-88-5

acetic acid tert-butyl ester

(S)-2-amino-3-(o-tolyl)propanoic acid
80126-53-0

(S)-2-amino-3-(o-tolyl)propanoic acid

(S)-tert-butyl 2-amino-3-(o-tolyl)propanoate

(S)-tert-butyl 2-amino-3-(o-tolyl)propanoate

Conditions
ConditionsYield
With perchloric acid In water at 20 - 30℃; for 16h; Inert atmosphere;
ethanol
64-17-5

ethanol

(S)-2-amino-3-(o-tolyl)propanoic acid
80126-53-0

(S)-2-amino-3-(o-tolyl)propanoic acid

C12H17NO2
1212275-99-4

C12H17NO2

Conditions
ConditionsYield
With thionyl chloride at 0 - 75℃; for 3h;
(S)-2-amino-3-(o-tolyl)propanoic acid
80126-53-0

(S)-2-amino-3-(o-tolyl)propanoic acid

N-((2S)-4-chloro-3-hydroxy-1-(o-tolyl)butan-2-yl)benzamide

N-((2S)-4-chloro-3-hydroxy-1-(o-tolyl)butan-2-yl)benzamide

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: thionyl chloride / 3 h / 0 - 75 °C
2.1: triethylamine / dichloromethane / 0 - 20 °C
3.1: lithium diisopropyl amide / tetrahydrofuran / 0.17 h / -78 - -70 °C
3.2: -78 - -65 °C
4.1: sodium tetrahydroborate
View Scheme
(S)-2-amino-3-(o-tolyl)propanoic acid
80126-53-0

(S)-2-amino-3-(o-tolyl)propanoic acid

N-((2S,3R)-4-chloro-3-hydroxy-1-(o-tolyl)butan-2-yl)benzamide

N-((2S,3R)-4-chloro-3-hydroxy-1-(o-tolyl)butan-2-yl)benzamide

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: thionyl chloride / 3 h / 0 - 75 °C
2.1: triethylamine / dichloromethane / 0 - 20 °C
3.1: lithium diisopropyl amide / tetrahydrofuran / 0.17 h / -78 - -70 °C
3.2: -78 - -65 °C
4.1: C38H40ClN2O3RhS; / dichloromethane / 1 h / 25 °C / Schlenk technique
View Scheme
(S)-2-amino-3-(o-tolyl)propanoic acid
80126-53-0

(S)-2-amino-3-(o-tolyl)propanoic acid

(S)-N-(4-chloro-3-oxo-1-(o-tolyl)butan-2-yl)benzamide

(S)-N-(4-chloro-3-oxo-1-(o-tolyl)butan-2-yl)benzamide

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: thionyl chloride / 3 h / 0 - 75 °C
2.1: triethylamine / dichloromethane / 0 - 20 °C
3.1: lithium diisopropyl amide / tetrahydrofuran / 0.17 h / -78 - -70 °C
3.2: -78 - -65 °C
View Scheme

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