1351987-32-0

Basic information

• Product Name: (2R,S)(5S)-6-benzyl 1-ethyl 5-isopropyl-2-((R)-2-(4-methoxy-3-(3-methoxypropoxy)benzyl)-3-methylbutyl)-3-oxohexanedioate
• Synonyms: (2R,S)(5S)-6-benzyl 1-ethyl 5-isopropyl-2-((R)-2-(4-methoxy-3-(3-methoxypropoxy)benzyl)-3-methylbutyl)-3-oxohexanedioate
• CAS NO: 1351987-32-0
• Molecular Weight: 598.777
• Mol File: 1351987-32-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2R,S)(5S)-6-benzyl 1-ethyl 5-isopropyl-2-((R)-2-(4-methoxy-3-(3-methoxypropoxy)benzyl)-3-methylbutyl)-3-oxohexanedioate(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,S)(5S)-6-benzyl 1-ethyl 5-isopropyl-2-((R)-2-(4-methoxy-3-(3-methoxypropoxy)benzyl)-3-methylbutyl)-3-oxohexanedioate(1351987-32-0)
• EPA Substance Registry System: (2R,S)(5S)-6-benzyl 1-ethyl 5-isopropyl-2-((R)-2-(4-methoxy-3-(3-methoxypropoxy)benzyl)-3-methylbutyl)-3-oxohexanedioate(1351987-32-0)

Safety Data

• Hazardous Substances Data: 1351987-32-0(Hazardous Substances Data)

Upstream product

• 134807-39-9 (S)-3-(benzyloxycarbonyl)-4-methylpentanoic acid 
• 900811-38-3 (R)--4-(2-(iodomethyl)--3--methylbutyl)--1--methoxy-2--(3--methoxypropoxy)benzene 
• 1351987-26-2 (S)-1-benzyl-6-ethyl-2-isopropyl-4-oxohexanedioate 
• 325154-21-0 ethyl 2-(4-methoxy-3-(3-methoxypropoxy)benzyl)-3-methylbutanoate 
• 172900-71-9 (R)-3-[4-methoxy-3-(3-methoxypropoxy)phenyl]-2-(1-methylethyl)propanoic acid 
• 1351987-18-2 butyl-2-(4-methoxy-3-(3-methoxypropoxy)benzyl)-3-methylbutanoate 
• 1351987-21-7 methyl-2-(4-methoxy-3-(3-methoxypropoxy)benzyl)-3-methylbutanoate 
• 172900-75-3 4-methoxy-3-(3-methoxypropoxy)benzaldehyde 
• 109-19-3 butyl isovalerate 
• 1351987-19-3 C₂₁H₃₄O₆ 
• 1351987-20-6 C₂₁H₃₂O₅ 
• 325154-22-1 2-isopropyl-3-{2-[3-methoxy(propyloxy)]-4-methoxyphenyl}propionic acid 
• 145589-03-3 (R)-4-benzyl-3-(3-methylbutyryl)oxazolidin-2-one 
• 172900-73-1 4-(bromomethyl)-1-methoxy-2-(3-methoxypropoxy)-benzene 

Relevant articles and documents

Rhodium-catalyzed enantioselective hydrogenation of (E)-enol acetate acids

The novel rhodium complex [Rh(S)-Phanephos(cod)]-catalyzed hydrogenation of disubstituted (E)-enol acetate carboxylic acids is reported. The catalytic cycle works under 30 bar of hydrogen under conventional heating giving different 3-acetoxy-2,3-disubstituted carboxylic acids with ee ≥90%. Hydrogenation occurred also under microwave dielectric heating without eroding the enantioselectivity but improving the overall efficiency of the process. With microwaves, hydrogen pressure and reaction time required for complete hydrogenation dropped to 5 bar and 30 min, respectively. The best performance of this catalyst under microwave irradiation was TON 100, TOF 196 h-1 with ee 99% on a 6-g scale. Copyright