(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate supplier

Name
(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate
EINECS
CAS No. 210057-23-1
Density
Solubility Insoluble in water
Melting Point
Formula C₂₆H₄₀P₂Rh^.BF₄
Boiling Point 415 °C at 760 mmHg
Molecular Weight 604.26
Flash Point 216.3 °C
Transport Information
Appearance red or red-brown crystalline powder
Safety 24/25
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols
Synonyms (-)-1,2-BIS((2R,5R)-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I) BF4;(-)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE;(-)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE(I)TETRAFLUOROBORATE;(-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(l)tetrafluoroborate;Bisdimethylphospholanobenzenecyclooctadienerho;1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO&;(-)-1,2-Bis((2R,5R)-2,5-dimethylphospholano)benzene(cyclooctadiene)rhodium(I)tetrafluoroborate,98+%(R,R)-Me-DUPHOS-Rh;(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate
PSA 27.18000
LogP 8.72020

(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate Specification

The systematic name of (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate is (1Z,5Z)-cycloocta-1,5-diene; (2R,5R)-1-[2-[(2R,5R)-2,5-dimethylphospholan-1-yl]phenyl]-2,5-dimethyl-phospholane; rhodium; tetrafluoroborate . With the CAS registry number 210057-23-1, it is also named as (R,R)-Me-DUPHOS-Rh ; Bisdimethylphospholanobenzenecyclooctadienerho ; 1,2-Bis[(2R,5R)-2,5-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate . The product's categories are chiral catalysts, ligands and reagents, DuPhos/BPE, privileged ligands and complexes.

The (-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate is red or red-brown crystalline powder and can be insoluble in water. It is irritating to eyes, respiratory system and skin. So people should avoid contact with skin and eyes.

The other characteristics of this product can be summarized as: (1)ACD/LogD (pH 5.5): 5.77 ; (2)ACD/LogD (pH 7.4): 5.77 ; (3)ACD/BCF (pH 5.5): 14243.49 ; (4)ACD/BCF (pH 7.4): 14243.49 ; (5)ACD/KOC (pH 5.5): 32714.95 ; (6)ACD/KOC (pH 7.4): 32714.95 ; (7)#Freely Rotating Bonds: 2 ; (8)Enthalpy of Vaporization: 64.2 kJ/mol ; (9)Vapour Pressure: 1.03E-06 mmHg at 25°C.

People can use the following data to convert to the molecule structure. SMILES: [Rh].F[B-](F)(F)F.c1cc(c(cc1)P2[C@@H](CC[C@H]2C)C)P3[C@H](C)CC[C@H]3C.C\1=C\CC/C=C\CC/1; InChI: InChI=1/C18H28P2.C8H12.BF4.Rh/c1-13-9-10-14(2)19(13)17-7-5-6-8-18(17)20-15(3)11-12-16(20)4;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h5-8,13-16H,9-12H2,1-4H3;1-2,7-8H,3-6H2;;/q;;-1;/b;2-1-,8-7-;;/t13-,14-,15-,16-;;;/m1.../s1.

Product Name

(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate

(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate Specification

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