• Name

  [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

• EINECS 460-040-3
• CAS No. 72287-26-4
• Article Data25
• CAS DataBase
• Density
• Solubility
• Melting Point 275-280 °C(lit.)
• Formula C₃₄H₂₈Cl₂FeP₂Pd
• Boiling Point
• Molecular Weight 851.095
• Flash Point
• Transport Information
• Appearance
• Safety 23-24/25-26-36/37
• Risk Codes 20/21/22-36/37/38-40
• Molecular Structure
• Hazard Symbols Xn, Xi
• Synonyms Palladium,[1,1'-bis(diphenylphosphino)ferrocene-P,P']dichloro-, (SP-4-2)-;Ferrocene,1,1'-bis(diphenylphosphino)-, palladium complex;(Bis(h5-(diphenylphosphino)cyclopentadienyl)iron)dichloropalladium;1,1'-Bis(diphenylphosphino)ferrocenedichloropalladium(II);1,1'-Bis(diphenylphosphino)ferrocenepalladium dichloride;Dichloro(diphenylphosphinoferrocene)palladium;Dichloro[1,1'-bis(diphenylphosphine)ferrocene]palladium(II);Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium;Pd(dppf)Cl2;PdCl2(dppf);[1,1'-Bis(diphenylphosphino-kP)ferrocene]dichloropalladium;
• PSA 27.18000
• LogP 7.76790

Synthetic route

12150-46-8

1,1'-bis-(diphenylphosphino)ferrocene

14592-56-4, 21264-30-2, 90243-59-7

bis(acetonitrile)palladium(II) chloride

72287-26-4

1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct

Conditions

Conditions	Yield
In benzene stirred at room temp. for 12 h; ppt. filtered, washed with benzene, dried in vac., recrystn. (CHCl3); elem. anal.;	97%

12150-46-8

1,1'-bis-(diphenylphosphino)ferrocene

14568-12-8, 38929-74-7, 244265-98-3, 12386-08-2, 15280-84-9

Pd(DMSO)2Cl2

67-66-3

chloroform

72287-26-4

1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct

Conditions

Conditions	Yield
for 0.5h; Heating;

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sodium hexaflorophosphate

736-52-7

1-((5-nitrofuran-2-yl)methylene)-4-phenylthiosemicarbazone

72287-26-4

1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct

75-09-2

dichloromethane

[palladium(II)(1,1’-bis(diphenylphosphino)ferrocene)(5-nitrofuryl-N-phenylthiosemicarbazonato)](hexafluorophosphate)*1.5(dichloromethane)

Conditions

Conditions	Yield
Stage #1: 1-((5-nitrofuran-2-yl)methylene)-4-phenylthiosemicarbazone; 1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct In methanol at 20℃; for 1h; Stage #2: sodium hexaflorophosphate In methanol for 24h; Cooling; Stage #3: dichloromethane In methanol	71%

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sodium hexaflorophosphate

24186-28-5

4-ethyl-1-(5-nitrofuran2-yl-methylene)thiosemicarbazide

72287-26-4

1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct

75-09-2

dichloromethane

[palladium(II)(1,1’-bis(diphenylphosphino)ferrocene)(5-nitrofuryl-N-ethylthiosemicarbazonato)](hexafluorophosphate) dichloromethane disolvate

Conditions

Conditions	Yield
Stage #1: 4-ethyl-1-(5-nitrofuran2-yl-methylene)thiosemicarbazide; 1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct In methanol at 20℃; for 1h; Stage #2: sodium hexaflorophosphate In methanol for 24h; Cooling; Stage #3: dichloromethane In methanol	64%

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sodium hexaflorophosphate

24199-84-6

5-nitrofurfural 4-methyl-thiosemicarbazone

72287-26-4

1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct

75-09-2

dichloromethane

[palladium(II)(1,1’-bis(diphenylphosphino)ferrocene)(5-nitrofuryl-N-methylthiosemicarbazonato)](hexafluorophosphate) dichloromethane disolvate

Conditions

Conditions	Yield
Stage #1: 5-nitrofurfural 4-methyl-thiosemicarbazone; 1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct In methanol at 20℃; for 1h; Stage #2: sodium hexaflorophosphate In methanol for 24h; Cooling; Stage #3: dichloromethane In methanol	62%

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sodium hexaflorophosphate

72287-26-4

1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct

75-09-2

dichloromethane

831-71-0, 146827-83-0

5-nitro-furfural thiosemicarbazone

[palladium(II)(1,1’-bis(diphenylphosphino)ferrocene)(5-nitrofuryl-thiosemicarbazonato)](hexafluorophosphate) dichloromethane monosolvate

Conditions

Conditions	Yield
Stage #1: 1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct; 5-nitro-furfural thiosemicarbazone In methanol at 20℃; for 1h; Stage #2: sodium hexaflorophosphate In methanol for 24h; Cooling; Stage #3: dichloromethane In methanol	61%

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sodium hexaflorophosphate

72287-26-4

1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct

42887-08-1

Sodium salt of tropolone

[Pd(Trop)(1,1′-bis(dipheny1phosphino)ferrocene)](hexafluorophosphate)

Conditions

Conditions	Yield
Stage #1: 1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct; Sodium salt of tropolone In methanol at 20℃; for 24h; Stage #2: sodium hexaflorophosphate In methanol for 24h;	49%

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sodium hexaflorophosphate

72287-26-4

1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct

17387-01-8

sodium salt of 4-isopropyltropolone

[Pd(Hino)(1,1′-bis(dipheny1phosphino)ferrocene)](hexafluorophosphate)

Conditions

Conditions	Yield
Stage #1: 1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct; sodium salt of 4-isopropyltropolone In methanol for 6h; Reflux; Stage #2: sodium hexaflorophosphate In methanol for 24h;	44%

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sodium hexaflorophosphate

72287-26-4

1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct

4008-48-4

nitroxoline

[PdII(5-nitro-8-quinolinolynate)(1,1’-bis(diphenylphosphino)ferrocene)](PF6)

Conditions

Conditions	Yield
Stage #1: 1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct; nitroxoline With triethylamine In methanol for 5h; Reflux; Stage #2: sodium hexaflorophosphate In methanol for 0.25h;	41%

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sodium hexaflorophosphate

72287-26-4

1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct

773-76-2

chloroxine

[PdII(5,7-dichloro-8-quinolinolynate)(1,1’-bis(diphenylphosphino)ferrocene)](PF6)

Conditions

Conditions	Yield
Stage #1: 1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct; chloroxine With triethylamine In methanol at 20℃; for 15 - 24h; Stage #2: sodium hexaflorophosphate In methanol for 0.25h;	37%

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148-24-3

8-quinolinol

sodium hexaflorophosphate

72287-26-4

1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct

[PdII(8-hydroxyquinolynate)(1,1’-bis(diphenylphosphino)ferrocene)](PF6)

Conditions

Conditions	Yield
Stage #1: 8-quinolinol; 1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct With triethylamine In methanol at 20℃; for 15 - 24h; Stage #2: sodium hexaflorophosphate In methanol for 0.25h;	35%

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sodium hexaflorophosphate

72287-26-4

1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct

130-26-7

5-chloro-7-iodoquinolin-8-ol

[PdII(5-chloro-7-iodo-8-quinolinolynate)(1,1’-bis(diphenylphosphino)ferrocene)](PF6)

Conditions

Conditions	Yield
Stage #1: 1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct; 5-chloro-7-iodoquinolin-8-ol With triethylamine In methanol at 20℃; for 4 - 5h; Stage #2: sodium hexaflorophosphate In methanol for 0.25h;	30%

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sodium hexaflorophosphate

72287-26-4

1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct

83-73-8

5,7-diiodo-8-hydroxyquinoline

[PdII(5,7-diiodo-8-quinolinolynate)(1,1’-bis(diphenylphosphino)ferrocene)](PF6)

Conditions

Conditions	Yield
Stage #1: 1,1'-bis(diphenylphosphino)ferrocene-palladium(ii)dichloride-chloroform adduct; 5,7-diiodo-8-hydroxyquinoline With triethylamine In methanol at 20℃; for 15 - 24h; Stage #2: sodium hexaflorophosphate In methanol for 0.25h;	26%

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[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Chemical Properties

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Safety Profile

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Specification