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inquiryItems Standard Result Appearance Colorless or yellowish clear liquid Complies Assay (%) ≥99.0
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inquiryCASNumber: 2627-86-3 Name: Benzenemethanamine,a-methyl-,(aS)- SuperlistName: … Certification: ISO, BRC, KOSHER, HALAL Application: meidicine addictive Type: extract
Product Description Product website: http://www.finerchem.com Product Name L-1-Phenylethylamine CAS No.
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inquiryFactory supply L-1-Phenylethylamine CAS 2627-86-3 with fast delivery Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Food/Feed
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inquiryProduct Name L-1-Phenylethylamine Synonyms (-)-alpha-Phenethylamine; (S)-alpha-Methylbenzenemethanamine; (S)-(-)-1-METHYLBENZYLAMINE; (S)-(-)-1-PHENYLETHYLAMINE; (S)-1-PHENYLETHYLAMINE; (S)-1-PHENYLETHANAMI
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inquiryProduct Name: L-1-Phenylethylamine Synonyms: (-)-alpha-Phenethylamine;(S)-alpha-Methylbenzenemethanamine;Tetra-SodiumPyrophosph;(1S)-(-)-1-Phenylethylamine 99%;(s)-benzenemethanamin;(S)-1-Amino-1-phenylethane;(S)-(-)-ALPHA-METHYLBENZYLAMINE;S-
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inquiry(S)-2-methyl-N-(1-phenylethylidene)propane-2-sulfinamide
(S)-1-phenyl-ethylamine
Conditions | Yield |
---|---|
Stage #1: (S)-2-methyl-N-(1-phenylethylidene)propane-2-sulfinamide With [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; potassium tert-butylate; 2-Amino-2-methyl-1-propanol In isopropyl alcohol at 50℃; for 2h; Molecular sieve; Stage #2: With hydrogenchloride In methanol optical yield given as %ee; diastereoselective reaction; | 96% |
Stage #1: (S)-2-methyl-N-(1-phenylethylidene)propane-2-sulfinamide With [RhCl2(p-cymene)]2; potassium tert-butylate; 2-Amino-2-methyl-1-propanol; isopropyl alcohol at 50℃; for 0.5h; Inert atmosphere; Microwave irradiation; Molecular sieve; Stage #2: With hydrogenchloride In methanol at 20℃; Inert atmosphere; enantioselective reaction; | 96% |
Multi-step reaction with 2 steps 1: [RhCl2(p-cymene)]2; potassium tert-butylate; 2-Amino-2-methyl-1-propanol; isopropyl alcohol / 2 h / 50 °C / Inert atmosphere; Molecular sieve 2: hydrogenchloride / methanol / 20 °C View Scheme |
Conditions | Yield |
---|---|
With formate dehydrogenase; Arthrobacter citreus S9 ω-transaminase; ATA-113 ω-transaminase; sodium formate; isopropylamine; NADH; yeast alcohol dehydrogenase pH=7; aq. phosphate buffer; Enzymatic reaction; optical yield given as %ee; | 99% |
Stage #1: acetophenone With Ru(2+)*2C2H3O2(1-)*C77H108O6P2; ammonium acetate; hydrogen In 2,2,2-trifluoroethanol at 80℃; under 53203.6 Torr; for 24h; Inert atmosphere; Autoclave; Stage #2: With hydrogenchloride In 2,2,2-trifluoroethanol; water at 80℃; for 6h; Reagent/catalyst; Temperature; Pressure; enantioselective reaction; | 98% |
With glucose dehydrogenase; sodium hydroxide; L-alanin; ATA-103 transaminase; NADH; 2,3,4,5,6-pentahydroxy-hexanal; pyridoxal 5'-phosphate; lactate dehydrogenase at 30℃; for 10h; pH=7.5; aq. phosphate buffer; Enzymatic reaction; optical yield given as %ee; | 96% |
Conditions | Yield |
---|---|
Stage #1: acetophenone With [((R)-tol-binap)RuCl2(DMF)x]; ammonia; ammonium formate In methanol at 85℃; for 20h; Leuckart-Wallach reaction; Stage #2: With hydrogenchloride In ethanol for 1h; Heating; Title compound not separated from byproducts; | |
Stage #1: acetophenone With ammonium acetate; sodium cyanoborohydride In methanol at 20℃; reductive amination; Stage #2: racemate resolution; Further stages.; | |
With ammonia; ammonium formate In methanol optical yield given as %ee; |
(E)-acetophenone O-methyloxime
(S)-1-phenyl-ethylamine
Conditions | Yield |
---|---|
With borane-THF; 1-[([1,3,2]dioxaborolan-2-yloxy)-diphenyl-methyl]-2-methylpropylamine In 1,4-dioxane at 0℃; Product distribution / selectivity; | 85% |
With borane-THF; (1S,2R)-1-amino-2-indanol In tetrahydrofuran at -20 - 70℃; Reduction; | |
With dimethylsulfide borane complex; enantiopure spiroborate ester In tetrahydrofuran at 25℃; for 36h; |
(E)-acetophenone O-(2-nitrobenzyl) oxime
(S)-1-phenyl-ethylamine
Conditions | Yield |
---|---|
With borane-THF; 1-[([1,3,2]dioxaborolan-2-yloxy)-diphenyl-methyl]-2-methylpropylamine In 1,4-dioxane at 0℃; Product distribution / selectivity; | 95% |
With dimethylsulfide borane complex; enantiopure spiroborate ester In tetrahydrofuran at 25℃; for 36h; |
(S)-(-)-α-methylbenzylamine hydrochloride
(S)-1-phenyl-ethylamine
Conditions | Yield |
---|---|
With sodium hydroxide In dichloromethane | 97.4% |
With sodium hydroxide In water Large scale; |
(S)-1-phenyl-ethylamine
Conditions | Yield |
---|---|
With hydrogenchloride; D-sorbitol; choline chloride In water at 25℃; for 3h; | 98% |
Stage #1: (SS,S)-N-(tert-butanesulfinyl) 1-phenylethylamine With thionyl chloride In methanol at 20℃; Inert atmosphere; Stage #2: With hydrogenchloride In water Inert atmosphere; Stage #3: With ammonia; ammonium chloride In water Inert atmosphere; optical yield given as %ee; enantioselective reaction; | |
Stage #1: (SS,S)-N-(tert-butanesulfinyl) 1-phenylethylamine With hydrogenchloride In methanol at 20℃; Stage #2: With ammonia; ammonium chloride In water |
(E)-acetophenone O-(4-methoxybenzyl) oxime
(S)-1-phenyl-ethylamine
Conditions | Yield |
---|---|
With borane-THF; 1-[([1,3,2]dioxaborolan-2-yloxy)-diphenyl-methyl]-2-methylpropylamine In 1,4-dioxane at 0℃; Product distribution / selectivity; | 70% |
With dimethylsulfide borane complex; enantiopure spiroborate ester In tetrahydrofuran at 25℃; for 36h; |
(S)-N-(1-phenylethyl)benzamide
(S)-1-phenyl-ethylamine
Conditions | Yield |
---|---|
With ammonium bromide; ethylenediamine at 80℃; for 10h; Reagent/catalyst; Microwave irradiation; | 93% |
(E)-acetophenone O-(4-trifluoromethyl benzyl) oxime
(S)-1-phenyl-ethylamine
Conditions | Yield |
---|---|
With borane-THF; 1-[([1,3,2]dioxaborolan-2-yloxy)-diphenyl-methyl]-2-methylpropylamine In 1,4-dioxane at 0℃; Product distribution / selectivity; | 60% |
With dimethylsulfide borane complex; enantiopure spiroborate ester In tetrahydrofuran at 25℃; for 36h; |
methyl methoxyacetate
rac-methylbenzylamine
A
(S)-1-phenyl-ethylamine
B
(R)-2-methoxy-N-(1-phenylethyl)acetamide
Conditions | Yield |
---|---|
With novozyme 435 In 1,2-dimethoxyethane at 40℃; for 19h; Molecular sieve; Enzymatic reaction; optical yield given as %ee; enantioselective reaction; | |
With Candida antarctica lipase B immobilized on acrylic resin In toluene at 25℃; for 0.0666667h; Resolution of racemate; Flow reactor; | A n/a B n/a |
With 5% palladium on barium sulphate; Lipase B from Candida antarctica immobilized on SiO2 nanoparticles functionalized with 1 % Pd and (3-aminopropyl)triethoxysilane; ammonium formate; sodium carbonate In toluene at 70℃; for 17h; Molecular sieve; Enzymatic reaction; | A n/a B n/a |
With ammonium formate; sodium carbonate In toluene at 70℃; for 9h; Temperature; Reagent/catalyst; Molecular sieve; Flow reactor; Resolution of racemate; |
Conditions | Yield |
---|---|
With lipase B from Candida antarctica immobilized on acrylic beads In toluene at 30℃; for 8h; Temperature; Concentration; Resolution of racemate; Flow reactor; Enzymatic reaction; enantioselective reaction; | A n/a B 45% |
N-[(1S)-1-phenylethan-1-yl]-4-methylbenzenesulfonamide
(S)-1-phenyl-ethylamine
Conditions | Yield |
---|---|
With ammonia; lithium In tetrahydrofuran at -78℃; for 0.25h; | 79% |
With pyrrolidine; samarium diiodide; water In tetrahydrofuran at 20℃; Inert atmosphere; | 98 %Chromat. |
Conditions | Yield |
---|---|
With pyridoxal 5'-phosphate; NADP+ In dimethyl sulfoxide at 37℃; for 16h; pH=9; Reagent/catalyst; Enzymatic reaction; |
(E)-ethanone-1-phenyl-O-(phenylmethyl)oxime
A
(S)-1-phenyl-ethylamine
B
(R)-1-phenyl-ethyl-amine
Conditions | Yield |
---|---|
With sodium tetrahydroborate; (S)-valinol; zirconium(IV) chloride 1) THF, r.t., 2) THF, r.t.; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; | |
Stage #1: (E)-ethanone-1-phenyl-O-(phenylmethyl)oxime With borane-THF; (S)-proline (R)-1,1'-bi(2-naphthyl)dioxyboryl ester In tetrahydrofuran at 0 - 5℃; for 48h; Stage #2: With hydrogenchloride In tetrahydrofuran Title compound not separated from byproducts; | |
With dimethylsulfide borane complex; 2-[(1,3,2-dioxaborolan-2-yloxy)diphenylmethyl]pyrrolidine In toluene at 50 - 110℃; for 15h; Product distribution / selectivity; | A n/a B n/a |
(E)-ethanone-1-phenyl-O-(phenylmethyl)oxime
(S)-1-phenyl-ethylamine
Conditions | Yield |
---|---|
Stage #1: (E)-ethanone-1-phenyl-O-(phenylmethyl)oxime With borane; (1R,2S)-norephedrine In tetrahydrofuran at 20℃; for 20h; Stage #2: With hydrogenchloride In tetrahydrofuran at 20℃; for 30h; Further stages.; | 85% |
With sodium tetrahydroborate; borane-THF; enantiopure spiroborate ester In 1,4-dioxane at 0℃; for 36h; | 100 % Turnov. |
With dimethylsulfide borane complex; 1-[([1,3,2]dioxaborolan-2-yloxy)-diphenyl-methyl]-2-methylpropylamine In toluene at 50 - 110℃; for 5 - 15h; Product distribution / selectivity; | n/a |
ethyl 2-cyanoacetate
rac-methylbenzylamine
A
(R)-2-cyano-N-(1-phenylethyl)acetamide
B
(S)-1-phenyl-ethylamine
C
(R)-1-phenyl-ethyl-amine
Conditions | Yield |
---|---|
With Novozym, lipase B from Candida antarctica, recombinant, expressed in Aspergillus niger, adsorbed on acrylic resin In tetrahydrofuran; toluene at 25℃; for 24h; Reagent/catalyst; Resolution of racemate; Enzymatic reaction; enantioselective reaction; | A 29% B n/a C n/a |
acetophenone
A
1-Phenylethanol
B
(S)-1-phenyl-ethylamine
C
(R)-1-phenyl-ethyl-amine
Conditions | Yield |
---|---|
With ammonium fluoride; Ru(2+)*C41H36O2P2*2C2H3O2(1-); hydrogen; sodium acetate In 2,2,2-trifluoroethanol at 80℃; under 41254.1 Torr; for 20h; Reagent/catalyst; Autoclave; enantioselective reaction; | A n/a B n/a C n/a |
With aluminium(III) triflate; (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II); ammonia; hydrogen; (R)-segphos In toluene at 120℃; for 16h; Reagent/catalyst; Autoclave; enantioselective reaction; | A 13 %Chromat. B n/a C n/a |
With sodium hexaflorophosphate; (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II); ammonia; hydrogen; (R)-2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl In toluene at 120℃; for 16h; Autoclave; enantioselective reaction; | A 23 %Chromat. B n/a C n/a |
N-butylamine
acetophenone
A
(S)-1-phenyl-ethylamine
B
(R)-1-phenyl-ethyl-amine
C
butan-1-ol
Conditions | Yield |
---|---|
With pyridoxal 5'-phosphate; NADP+ In dimethyl sulfoxide at 37℃; for 16h; pH=9; Enzymatic reaction; |
Conditions | Yield |
---|---|
With lipase B from Candida antarctica immobilized on acrylic beads In toluene at 30℃; for 8h; Resolution of racemate; Enzymatic reaction; enantioselective reaction; | A n/a B 23% |
(S)-N-acetyl-1-phenylethylamine
(S)-1-phenyl-ethylamine
Conditions | Yield |
---|---|
With ammonium bromide; ethylenediamine at 80℃; for 10h; Microwave irradiation; Inert atmosphere; neat (no solvent); | 94% |
Stage #1: (S)-N-acetyl-1-phenylethylamine With Schwartz's reagent In tetrahydrofuran at 20℃; for 0.0333333h; Inert atmosphere; Stage #2: With water In tetrahydrofuran Inert atmosphere; | 93% |
1-Phenylethanol
(S)-1-phenyl-ethylamine
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: oxygen; sodium anthraquinone-2-sulfonate / water / 30 °C / Irradiation 2: (S)-amine trans-aminase / acetonitrile / 28 h / 20 °C / Enzymatic reaction View Scheme | |
With ammonium hydroxide; alcohol dehydrogenase from Paracoccus pantotrophus; amine dehydrogenase from Exiguobacterium sibiricum; nicotinamide adenine dinucleotide; ammonium chloride enantioselective reaction; | n/a |
With pyridoxal 5'-phosphate; alcohol dehydrogenase from Candida parapsilosis-W286A mutant; Bacillus megaterium ω-transaminase; diisopropylamine In aq. acetate buffer at 30℃; for 21h; pH=8; Reagent/catalyst; Green chemistry; Enzymatic reaction; enantioselective reaction; | 93 mg |
Multi-step reaction with 2 steps 1: diisopropylamine; NAD; alcohol dehydrogenase from Candida parapsilosis-W286A mutant; NADH oxidase / aq. acetate buffer / 24 h / 30 °C / pH 8 / Green chemistry; Enzymatic reaction 2: diisopropylamine; pyridoxal 5'-phosphate; NAD; alcohol dehydrogenase from Candida parapsilosis-W286A mutant; Bacillus megaterium ω-transaminase / aq. acetate buffer / 24 h / 30 °C / pH 8 / Green chemistry; Enzymatic reaction View Scheme |
(+)-(S)(C)-(S)(S)-N-(1-Phenylethyl)-p-toluolsulfinamid
(S)-1-phenyl-ethylamine
Conditions | Yield |
---|---|
With trifluoroacetic acid In methanol at 25℃; for 3h; | 92% |
(E)-1-phenylethanone oxime
(S)-1-phenyl-ethylamine
Conditions | Yield |
---|---|
Stage #1: (E)-1-phenylethanone oxime With borane-THF; (S)-proline (R)-1,1'-bi(2-naphthyl)dioxyboryl ester In tetrahydrofuran at 0 - 5℃; for 48h; Stage #2: With hydrogenchloride In tetrahydrofuran | 74% |
Multi-step reaction with 2 steps 1: tetrahydrofuran / 20 °C 2: BH3; (-)-norephedrine / tetrahydrofuran / 24 h / 0 °C View Scheme |
sodium pyruvate
rac-methylbenzylamine
A
D-Alanine
B
(S)-1-phenyl-ethylamine
C
acetophenone
Conditions | Yield |
---|---|
With pyridoxal 5'-phosphate In aq. phosphate buffer; dimethyl sulfoxide at 30℃; for 24h; pH=7.5; Reagent/catalyst; Resolution of racemate; Enzymatic reaction; enantioselective reaction; | A n/a B n/a C n/a |
3-phenoxy-2-propanone
rac-methylbenzylamine
A
(S)-1-phenyl-ethylamine
B
(R)-1-phenyl-ethyl-amine
C
acetophenone
D
R-(-)-1-phenoxy-2-propanamine
Conditions | Yield |
---|---|
With disodium phosphate heptahydrate; disodium phosphite pentahydrate In toluene at 25℃; for 72h; Time; Enzymatic reaction; | A n/a B n/a C n/a D n/a |
ethyl acetoacetate
rac-methylbenzylamine
A
(S)-1-phenyl-ethylamine
B
(R)-1-phenyl-ethyl-amine
C
ethyl 3-(R)-methyl-β-alanine
D
acetophenone
Conditions | Yield |
---|---|
With disodium phosphate heptahydrate; disodium phosphite pentahydrate In toluene at 25℃; for 72h; Enzymatic reaction; | A n/a B n/a C n/a D n/a |
Methoxyacetone
rac-methylbenzylamine
A
(S)-1-phenyl-ethylamine
B
(R)-1-phenyl-ethyl-amine
C
(R)-2-methoxy-1-methylethylamine
D
acetophenone
Conditions | Yield |
---|---|
With disodium phosphate heptahydrate; disodium phosphite pentahydrate In toluene at 25℃; for 72h; Enzymatic reaction; | A n/a B n/a C n/a D n/a |
Conditions | Yield |
---|---|
With (SS,S)-N-(tert-butanesulfinyl) 1-phenylethylamine; hydrogenchloride In methanol at 20℃; for 0.5h; stereoselective reaction; | 97% |
With sodium tetrahydroborate In aq. phosphate buffer at 30℃; for 3h; pH=8; Enzymatic reaction; stereoselective reaction; | 64.5% |
With sodium pyruvate at 30℃; for 24h; aq. phosphate buffer; Resolution of racemate; Enzymatic reaction; optical yield given as %ee; enantioselective reaction; | 41% |
(1S)-N-1-Phenethyl-3-hydroxy-2,2-dimethylpropanamide
(S)-1-phenyl-ethylamine
Conditions | Yield |
---|---|
With sodium hydroxide In water; ethylene glycol at 110℃; for 13h; | 80% |
With potassium hydroxide In methanol; water for 44h; Heating; |
Conditions | Yield |
---|---|
With (S)-(-)-2-amino-3-(p-benzyloxy)phenyl-1,1-diphenylpropanol*borane In tetrahydrofuran at 30℃; | 100% |
With sodium tetrahydroborate; (S)-valinol; zirconium(IV) chloride In tetrahydrofuran for 48h; Product distribution; Ambient temperature; effect of other Lewis acids, solvents, chiral amino alcohols and reaction temperature on enantioselectivity; other substrates; | 95% |
With borane; (2S)-(-)-2-amino-3-methyl-1,1-diphenylbutan-1-ol-borane In tetrahydrofuran for 20h; Ambient temperature; | 90% |
(S)-N-(1-phenylethyl)prop-2-en-1-amine
(S)-1-phenyl-ethylamine
Conditions | Yield |
---|---|
With Thiosalicylic acid; 1,4-di(diphenylphosphino)-butane; bis(dibenzylideneacetone)-palladium(0) In tetrahydrofuran at 60℃; for 0.25h; | 100% |
A
(S)-1-phenyl-ethylamine
B
(R)-1-phenyl-ethyl-amine
C
(R)-(-)-o-(1-pivaloylaminoethyl)benzene sulfinic acid
Conditions | Yield |
---|---|
With trifluoroacetic acid In methanol Yields of byproduct given; | A n/a B n/a C 96% |
O-methyl acetophenone oxime
A
(S)-1-phenyl-ethylamine
B
(R)-1-phenyl-ethyl-amine
Conditions | Yield |
---|---|
With sodium tetrahydroborate; (S)-valinol; zirconium(IV) chloride In tetrahydrofuran for 48h; Ambient temperature; Title compound not separated from byproducts; | A 95% B n/a |
With lithium aluminium tetrahydride; chiral borane In tetrahydrofuran for 24h; Product distribution; Ambient temperature; enantioselectivity; further hydrides; |
1-decanoic acid
rac-methylbenzylamine
A
N-[(R)-(+)-1-phenylethyl]decanamide
B
(S)-1-phenyl-ethylamine
Conditions | Yield |
---|---|
With Candida antarctica lipase B; molecular sieve In various solvent(s) at 45℃; for 24h; | A 95% B 13.7 mg |
ethanone-1-phenyl-O-(phenylmethyl)oxime
A
(S)-1-phenyl-ethylamine
B
(R)-1-phenyl-ethyl-amine
Conditions | Yield |
---|---|
With sodium tetrahydroborate; (S)-valinol; zirconium(IV) chloride In tetrahydrofuran Ambient temperature; Title compound not separated from byproducts; | A 91% B n/a |
(1S,1'S)-N-(1'-phenylethyl)-1-<2''-(methylamino)phenyl>ethylamine
A
(S)-1-phenyl-ethylamine
B
N-methyl ortho-ethylaniline
Conditions | Yield |
---|---|
With hydrogen; ammonium formate; palladium on activated charcoal In methanol Heating; | A 62% B 90% |
S(+)-2-phenyl-propanoic acid amide
(S)-1-phenyl-ethylamine
Conditions | Yield |
---|---|
With bis-[(trifluoroacetoxy)iodo]benzene In water; acetonitrile Ambient temperature; | 85% |
((R)-1-Phenyl-ethyl)-((1S,2R,6R,7S)-1,10,10-trimethyl-3-oxa-tricyclo[5.2.1.02,6]dec-4-yl)-amine
(S)-1-phenyl-ethylamine
Conditions | Yield |
---|---|
With citric acid In diethyl ether for 2.5h; | 83% |
ethanone-1-phenyl-O-(phenylmethyl)oxime
(S)-1-phenyl-ethylamine
Conditions | Yield |
---|---|
With borane; (2S)-(-)-2-amino-3-methyl-1,1-diphenylbutan-1-ol-borane In tetrahydrofuran for 24h; Ambient temperature; | 80% |
(1R)-1-phenyl-2-({[(1S)-1-phenylethyl]amino}oxy)ethanol
A
(S)-1-phenyl-ethylamine
B
(R)-1-phenyl-1,2-ethanediol
Conditions | Yield |
---|---|
With hexacarbonyl molybdenum In water; acetonitrile at 85℃; for 1h; | A 80% B n/a |
(E)-1-phenyl-N-(1-phenylethylidene)methanamine
(S)-1-phenyl-ethylamine
Conditions | Yield |
---|---|
With (1R,2S)-norephedrine; diborane Inert atmosphere; | 80% |
(αS,1'S)-N-(1-Phenylethyl)-2-fluoro-α-methylphenylmethylamine
A
(S)-1-phenyl-ethylamine
B
(S)-1-(2-fluorophenyl)ethylamine
Conditions | Yield |
---|---|
With ammonium formate; palladium on activated charcoal In methanol for 0.5h; Heating; Yields of byproduct given; | A n/a B 79% |
(S)-N-hydroxy-α-methyl-benzenemethanamine ethanedioate
(S)-1-phenyl-ethylamine
Conditions | Yield |
---|---|
With hydrogenchloride; acetic acid; zinc In water at 80℃; for 6h; | 78% |
(S)-3-methyl-2-((S)-1-phenylethylamino)butan-1-ol
(S)-1-phenyl-ethylamine
Conditions | Yield |
---|---|
Stage #1: (S)-3-methyl-2-((S)-1-phenylethylamino)butan-1-ol With periodic acid; methylamine In methanol; water at 20℃; for 3h; Stage #2: With hydrogenchloride In methanol for 0.5h; Further stages.; | 76% |
(S)-1-phenyl-ethylamine
Conditions | Yield |
---|---|
With sulfuric acid In ethyl acetate | 74.4% |
carbon disulfide
(S)-1-phenyl-ethylamine
N,N'-bis<(S)-(1-phenylethyl)>thiourea
Conditions | Yield |
---|---|
In ethanol Inert atmosphere; Reflux; | 100% |
at 47℃; | 97% |
In ethanol for 20h; Heating; | 79% |
glyoxylic acid ethyl ester
(S)-1-phenyl-ethylamine
ethyl <(S)-1-phenylethyl>iminoethanoate
Conditions | Yield |
---|---|
In toluene for 0.333333h; Heating; | 100% |
In toluene at 110℃; under 760.051 Torr; | 100% |
(S)-1-phenyl-ethylamine
formic acid ethyl ester
(S)-N-formyl-1-phenylethylamine
Conditions | Yield |
---|---|
In toluene for 15h; Heating; | 100% |
With Novozyme 435 CALB In tetrahydrofuran at 20℃; Green chemistry; Enzymatic reaction; | 95% |
formaldehyd
(S)-1-phenyl-ethylamine
(S,S,S)-1,3,5-tris(α-methylbenzyl)-1,3,5-hexahydrotriazine
Conditions | Yield |
---|---|
In dichloromethane for 0.5h; Ambient temperature; | 100% |
In water at 0℃; for 0.5h; | 100% |
In methanol at 25℃; for 1h; | 96% |
Phenylselenyl chloride
(S)-1-phenyl-ethylamine
N-<(S)-1-Phenylethyl>benzeneselenamide
Conditions | Yield |
---|---|
With triethylamine In tetrahydrofuran at 0℃; for 2h; | 100% |
(S)-1-phenyl-ethylamine
6-chloro-3,4-dihydro-1H-naphthalen-2-one
(6-Chloro-3,4-dihydro-naphthalen-2-yl)-((S)-1-phenyl-ethyl)-amine
Conditions | Yield |
---|---|
In toluene at 110℃; | 100% |
(S)-1-phenyl-ethylamine
3-Ethyl-1-isopropyl-piperidine-2,4-dione
3-Ethyl-1-isopropyl-4-((R)-1-phenyl-ethylamino)-5,6-dihydro-1H-pyridin-2-one
Conditions | Yield |
---|---|
In toluene for 24h; Heating; | 100% |
(S)-1-phenyl-ethylamine
benzaldehyde
(S)-N-benzylidene(1-phenylethylamine)
Conditions | Yield |
---|---|
In toluene for 1h; Ambient temperature; | 100% |
In toluene for 2h; Reflux; Molecular sieve; Dean-Stark; | 98% |
With molecular sieve; potassium carbonate | 94% |
(S)-1-phenyl-ethylamine
chloroacetyl chloride
2-chloro-N-((1S)-1-phenylethyl)acetamide
Conditions | Yield |
---|---|
In dichloromethane | 100% |
With potassium carbonate In dichloromethane Heating; | 97% |
Stage #1: (S)-1-phenyl-ethylamine With potassium carbonate In tetrahydrofuran at 20℃; Stage #2: chloroacetyl chloride In tetrahydrofuran at 20℃; for 4h; Friedel-Crafts Alkylation; | 96% |
Conditions | Yield |
---|---|
With 4 A molecular sieve In dichloromethane at 20℃; for 70h; | 100% |
Conditions | Yield |
---|---|
With platinum(IV) oxide; hydrogen In methanol for 11h; | 100% |
Stage #1: (S)-1-phenyl-ethylamine; acetone With sodium tris(acetoxy)borohydride; acetic acid In 1,2-dichloro-ethane at 25℃; Stage #2: With sodium hydrogencarbonate In 1,2-dichloro-ethane | 80% |
Stage #1: (S)-1-phenyl-ethylamine; acetone Stage #2: With sodium tetrahydroborate In methanol at 20℃; for 2h; | 65% |
(S)-1-phenyl-ethylamine
4-Chlorobutanoyl chloride
(S)-N-(1-phenylethyl)-4-chlorobutyrylamide
Conditions | Yield |
---|---|
With triethylamine In tetrahydrofuran at 0℃; for 0.5h; | 100% |
With triethylamine In dichloromethane |
(S)-1-phenyl-ethylamine
butyl glyoxalate
n-butyl N-((1S)-phenylethyl)-α-iminoacetate
Conditions | Yield |
---|---|
With magnesium sulfate In diethyl ether for 10h; Ambient temperature; | 100% |
(S)-1-phenyl-ethylamine
cyclohexanecarbaldehyde
N-(2-cyclohexylethylidene)-(S)-α-methylbenzylamine
Conditions | Yield |
---|---|
With magnesium sulfate In toluene | 100% |
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