(3-Glycidyloxypropyl)triethoxysilane supplier

Name
(3-Glycidyloxypropyl)triethoxysilane
EINECS 220-011-6
CAS No. 2602-34-8
Article Data24
CAS DataBase
Density 1.012 g/cm³
Solubility 3.3g/L at 20℃
Melting Point < -50 ºC
Formula C₁₂H₂₆O₅Si
Boiling Point 303.6 ºC at 760 mmHg
Molecular Weight 278.421
Flash Point 110.9 ºC
Transport Information
Appearance colorless clear liquid
Safety 26
Risk Codes 36/37/38-20
Molecular Structure
Hazard Symbols Xi,Xn
Synonyms Silane,[3-(2,3-epoxypropoxy)propyl]triethoxy- (6CI,7CI,8CI);3-(2,3-Epoxypropoxy)propyltriethoxysilane;3-(Triethoxysilyl)propyl glycidyl ether;3-Glycydoxylpropyltriethoxysilane;Dynasylan GLYEO;GF 82;GOPTS;Glycidyl 3-(triethoxysilyl)propyl ether;KBE 403;NB1115;NV 1115;Silan GF 82;Silquest A 1871;Triethoxy(3-glycidoxypropyl)silane;WD 60;Z 6041;[3-(Glycidyoxy)propyl]triethoxysilane;g-Glycidoxypropyltriethoxysilane;3-Glycidoxypropyltriethoxy silane;
PSA 49.45000
LogP 1.84030

Synthetic route

: 106-92-3
Allyl glycidyl ether

: 998-30-1
Triethoxysilane

: 2602-34-8
(3-glycidyloxypropyl)triethoxysilane

Conditions

Conditions	Yield
[siloxideRh(cod)](SBA-15) at 100℃;	96%
With silica supported poly-3-(2-aminoethylamino)propylsiloxane platinum complex at 110℃; for 2h;	94.8%
With (TFAPDI)Co(2-ethylhexanoate)2 at 0 - 20℃; for 1.08333h; Temperature; Inert atmosphere; Sealed tube;	94%

: 106-92-3
Allyl glycidyl ether

: 998-30-1
Triethoxysilane

A: triethoxy(2-glycidoxy-1-methylethyl)silane

B: 1607-23-4
glycidyl 1-propenyl ether

C: 78-10-4
tetraethoxy orthosilicate

D: 2602-34-8
(3-glycidyloxypropyl)triethoxysilane

Conditions

Conditions	Yield
Speier's catalyst at 70 - 90℃; for 1.5h; Further byproducts.;	A n/a B n/a C n/a D 78.9%

...Expand

: 106-92-3
Allyl glycidyl ether

: 27491-84-5
triethyl hydrogen silicate

A: C12H24O5Si

B: 3126-95-2
3-Propoxy-1,2-epoxypropan

C: 2602-34-8
(3-glycidyloxypropyl)triethoxysilane

Conditions

Conditions	Yield
[rhodium(I)(1,5-cyclooctadien)(trimethylsiloxide)(P(cyclohexyl)3)] at 25℃; for 0.25h; Product distribution; Further Variations:; Reagents; Temperatures;

...Expand

: 106-92-3
Allyl glycidyl ether

: 998-30-1
Triethoxysilane

A: 2602-34-8
(3-glycidyloxypropyl)triethoxysilane

B: C12H24O5Si

Conditions

Conditions	Yield
With (MeAPDI)Co(OAc)2 at 20℃; for 1h; Reagent/catalyst; Inert atmosphere; Sealed tube; Overall yield = 87 %; Overall yield = 217 mg;

...Expand

: 106-92-3
Allyl glycidyl ether

: 998-30-1
Triethoxysilane

A: 1607-23-4
glycidyl 1-propenyl ether

B: 2602-34-8
(3-glycidyloxypropyl)triethoxysilane

Conditions

Conditions	Yield
With cobalt(II) 2-ethylhexanoate at 20℃; for 1.5h; Reagent/catalyst; Temperature; Inert atmosphere; Sealed tube; Overall yield = 326 mg;

...Expand

: 106-92-3
Allyl glycidyl ether

: 998-30-1
Triethoxysilane

A: 1607-23-4
glycidyl 1-propenyl ether

B: 2602-34-8
(3-glycidyloxypropyl)triethoxysilane

C: C12H24O5Si

Conditions

Conditions	Yield
With (PyBox)Co(2-ethylhexanoate)2 at 20℃; for 1h; Reagent/catalyst; Inert atmosphere; Sealed tube; Overall yield = 68 %; Overall yield = 168 mg;

...Expand

: 2602-34-8
(3-glycidyloxypropyl)triethoxysilane

: 60-24-2
2-hydroxyethanethiol

: C14H32O6SSi

Conditions

Conditions	Yield
With potassium carbonate at 20℃; for 3h;	100%

: 2602-34-8
(3-glycidyloxypropyl)triethoxysilane

: 97-39-2
1,3-Di(2-tolyl)guanidine

: 1,3-bis(2-methylphenyl)-1,2,3-tris(2-hydroxy-3-(3-(triethoxysilyl)propoxy)propyl)guanidine

Conditions

Conditions	Yield
at 85℃; for 2h;	98.4%

: 2602-34-8
(3-glycidyloxypropyl)triethoxysilane

: 27231-36-3
2-mercapto-5-methylbenzimidazole

: 1-((1-(2-hydroxy-3-(3-(triethoxysilyl)propoxy)propyl)-6-methyl-1H-benzimidazol-2-yl)thio)-3-(3-(triethoxysilyl)propoxy)propan-2-ol

Conditions

Conditions	Yield
at 80 - 120℃; for 4h; Inert atmosphere;	98.4%

: 2602-34-8
(3-glycidyloxypropyl)triethoxysilane

: 2489-77-2
1,1,3-trimethylthiourea

: N,N,N'-trimethyl-N'-(2-hydroxy-3-(3-(triethoxysilyl)propyloxy)propyl)thiourea

Conditions

Conditions	Yield
at 85℃; for 2h;	98.2%

: 2602-34-8
(3-glycidyloxypropyl)triethoxysilane

: 101-01-9
N,N',N''-triphenylguanidine

: 1,2,3-triphenyl-1,3-bis(2-hydroxy-3-(3-(triethoxysilyl)propoxy)propyl)guanidine

Conditions

Conditions	Yield
In toluene at 85 - 90℃; for 1h;	98.1%

: 2602-34-8
(3-glycidyloxypropyl)triethoxysilane

: 109-46-6
1,3-dibutylthiourea

: N,N'-di-n-butyl-N,N'-bis({2-hydroxy-3-[3-(triethoxysilyl)propyloxy]propyl})thiourea

Conditions

Conditions	Yield
at 85 - 90℃; for 2.5h;	97.2%

: 2602-34-8
(3-glycidyloxypropyl)triethoxysilane

: 124-38-9
carbon dioxide

: C13H26O7Si

Conditions

Conditions	Yield
With tetrabutylammomium bromide In neat (no solvent) at 100℃; under 3750.38 Torr; for 2h;	96%
With (2-hydroxyphenyl)diphenyl(propyl)phosphonium iodide In neat (no solvent) at 90℃; under 7500.75 Torr; for 4h; Temperature; Autoclave;	93%

: 295-37-4
1,4,8,11-Tetraazacyclotetradecane

: 2602-34-8
(3-glycidyloxypropyl)triethoxysilane

: 1-(1,4,8,11-tetraazacyclotetradecan-1-yl)-3-(3-(triethoxysilyl)-propoxy)propan-2-ol

Conditions

Conditions	Yield
In toluene for 24h; Reflux; Inert atmosphere;	93%
In toluene for 24h; Inert atmosphere; Reflux;

: 2602-34-8
(3-glycidyloxypropyl)triethoxysilane

: 17455-13-9
18-crown-6 ether

: 120-80-9
benzene-1,2-diol

: potassium[18-crown-6]bis(catecholato)(3-glycidyloxypropyl)silicate

Conditions

Conditions	Yield
With potassium methanolate In methanol at 20℃; for 3h; Inert atmosphere;	92%

...Expand

: 2602-34-8
(3-glycidyloxypropyl)triethoxysilane

: C6H11F4O2Si(1-)*H3N*H(1+)

Conditions

Conditions	Yield
With ammonium hydrogen difluoride In water at 20℃;	91%

: 2602-34-8
(3-glycidyloxypropyl)triethoxysilane

: C60H110O35Si10

Conditions

Conditions	Yield
With tetramethyl ammoniumhydroxide In water; isopropyl alcohol at 40℃; for 4h; Solvent; Reagent/catalyst; Temperature;	90%

: 2602-34-8
(3-glycidyloxypropyl)triethoxysilane

: 294-90-6
1,4,7,10-tetraazacyclododecan

: 1-(1,4,7,10-tetraazacyclododecan-1-yl)-3-(3-(triethoxysilyl)-propoxy)propan-2-ol

Conditions

Conditions	Yield
In toluene for 24h; Reflux; Inert atmosphere;	79%

: 109-01-3
1-methyl-piperazine

: 2602-34-8
(3-glycidyloxypropyl)triethoxysilane

A: 1222257-47-7
2,2-diethoxy-8-(4-methylpiperazinyl)methyl-1,6-dioxa-2-silacyclooctane

B: 1222257-50-2
C30H64N4O8Si2

C: 1222257-49-9
C32H70N4O9Si2

Conditions

Conditions	Yield
With sodium ethanolate In ethanol; toluene at 116 - 145℃;	A 78% B n/a C n/a

...Expand

(3-Glycidyloxypropyl)triethoxysilane Specification

The gamma-Glycidoxypropyltriethoxysilane, with the CAS registry number 2602-34-8, is also known as 3-(2,3-Epoxypropyloxy)propyltriethoxysilane. It belongs to the product categories of Epoxy; Epoxy Silanes. Its EINECS registry number is 220-011-6. This chemical's molecular formula is C₁₂H₂₆O₅Si and molecular weight is 278.42. What's more, both its IUPAC name and systematic name are the same which is called Triethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane. It is used as coupling agent.

Physical properties about gamma-Glycidoxypropyltriethoxysilane are: (1)ACD/LogP: 1.87; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 1.87; (4)ACD/LogD (pH 7.4): 1.87; (5)ACD/BCF (pH 5.5): 15.49; (6)ACD/BCF (pH 7.4): 15.49; (7)ACD/KOC (pH 5.5): 247.48; (8)ACD/KOC (pH 7.4): 247.48; (9)#H bond acceptors: 5; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 12; (12)Polar Surface Area: 49.45 Å²; (13)Index of Refraction: 1.442; (14)Molar Refractivity: 72.91 cm³; (15)Molar Volume: 275 cm³; (16)Surface Tension: 30.2 dyne/cm; (17) Density: 1.012 g/cm³; (18)Flash Point: 110.9 °C; (19)Enthalpy of Vaporization: 52.22 kJ/mol; (20)Boiling Point: 303.6 °C at 760 mmHg; (21)Vapour Pressure: 0.00166 mmHg at 25 °C.

When you are dealing with this chemical, you should be very careful. This chemical is inflammation to the skin, eyes and respiratory system or other mucous membranes. What's more, it's harmful by inhalation. In case of contacting with eyes, you should rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1) SMILES: O(CCC[Si](OCC)(OCC)OCC)CC1OC1
(2) InChI: InChI=1S/C12H26O5Si/c1-4-15-18(16-5-2,17-6-3)9-7-8-13-10-12-11-14-12/h12H,4-11H2,1-3H3
(3) InChIKey: JXUKBNICSRJFAP-UHFFFAOYSA-N

Product Name

(3-Glycidyloxypropyl)triethoxysilane

Synthetic route

(3-Glycidyloxypropyl)triethoxysilane Specification

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