1,10-Phenanthroline monohydrochloride supplier

Name
o-Phenanthroline monohydrochloride monohydrate
EINECS 223-325-1
CAS No. 3829-86-5
Density 1.385 g/cm3 (-100.15 C)
Solubility soluble in water
Melting Point 224-225 °C(lit.)
Formula C₁₂H₈N₂^.HCl
Boiling Point 365.1 °C at 760 mmHg
Molecular Weight 216.67
Flash Point 164.8 °C
Transport Information UN 2811 6.1/PG 3
Appearance white to light yellow or slightly purple powder
Safety 45-60-61
Risk Codes 25-50/53
Molecular Structure
Hazard Symbols T, N
Synonyms 1,10-Phenanthroline,monohydrochloride (8CI,9CI);1,10-Diazaphenanthrene hydrochloride;1,10-Phenanthroline hydrochloride;NSC 4265;
PSA 25.78000
LogP 3.58500

Synthetic route

: 3829-86-5
1,10-phenanthroline hydrochloride

: copper dichloride

: (1,5,9,13-tetraaza-3,4,7,8,11,12,15,16-tetrabenzocyclohexadeca-1,3,5,7,9,11,13,16-octaene)copper(I) nitrate

Conditions

Conditions	Yield
In water from aq. soln. of CuCl2 and soln. of phenanthroline hydrochloride in 2:1, 1:1 molar ratio at pH 6.5 maintained by an alkali soln.; solvent evapd. in a water bath; ppt. washed (H2O); dried (air); elem. anal.;	96%

: 3829-86-5
1,10-phenanthroline hydrochloride

: copper dichloride

: [Cu(II)(1,10-phenantroline)2(H2O)]Cl2 complex

Conditions

Conditions	Yield
In water from aq. soln. of CuCl2 and soln. of phenanthroline hydrochloride in 1:2, 1:3 molar ratio at pH 6.5 maintained by an alkali soln.; solvent evapd. in a water bath; ppt. washed (H2O); dried (air); elem. anal.;	90%

: 3829-86-5
1,10-phenanthroline hydrochloride

: 90076-65-6
bis(trifluoromethane)sulfonimide lithium

: 1309962-26-2
C2HF6NO4S2*C12H8N2

Conditions

Conditions	Yield
With water at 20℃; for 2h;	90%

: copper(II) choride dihydrate

: 3829-86-5
1,10-phenanthroline hydrochloride

: 555-06-6
sodium p-aminobenzoate

: [Cu(phen)2Cl]Cl*2p‑aminobenzoic acid*4H2O

Conditions

Conditions	Yield
In methanol for 1h;	88%

...Expand

: 7722-64-7
potassium permanganate

: ammonium chloride

: 7732-18-5
water

: 3829-86-5
1,10-phenanthroline hydrochloride

: 12775-96-1, 15158-11-9, 15721-63-8, 16941-75-6, 17493-86-6, 19498-52-3, 20499-83-6, 20499-84-7, 20499-85-8, 20499-86-9, 20573-10-8, 20573-11-9, 21595-51-7, 21595-52-8, 22206-52-6, 26445-28-3, 28959-95-7, 37362-93-9, 39417-05-5, 54603-16-6, 54603-23-5, 54603-32-6, 54603-40-6, 54603-48-4, 54603-81-5, 54603-89-3, 56316-56-4, 95985-91-4, 122297-32-9, 7440-50-8
copper

: [Cu(1,10-phenanthroline)2Cl]2[MnCl3(1,10-phenanthroline)]Cl*2water

Conditions

Conditions	Yield
In methanol byproducts: Mn(2+); stirring 1:1:2:2 mixt. of copper, permanganate salt, phenanthroline deriv., NH4Cl in methanol at 50-60°C in air for 2 h; addn. of isopropanol, isolation of crystals, elem. anal.;	87%

...Expand

: 7722-64-7
potassium permanganate

: ammonium chloride

: 3829-86-5
1,10-phenanthroline hydrochloride

: 12775-96-1, 15158-11-9, 15721-63-8, 16941-75-6, 17493-86-6, 19498-52-3, 20499-83-6, 20499-84-7, 20499-85-8, 20499-86-9, 20573-10-8, 20573-11-9, 21595-51-7, 21595-52-8, 22206-52-6, 26445-28-3, 28959-95-7, 37362-93-9, 39417-05-5, 54603-16-6, 54603-23-5, 54603-32-6, 54603-40-6, 54603-48-4, 54603-81-5, 54603-89-3, 56316-56-4, 95985-91-4, 122297-32-9, 7440-50-8
copper

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

: [Cu(1,10-phenanthroline)2Cl]2[MnCl4]*DMF

Conditions

Conditions	Yield
In methanol; N,N-dimethyl-formamide byproducts: Mn(2+); stirring 1:1:2:2 mixt. of copper, permanganate salt, phenanthroline deriv., NH4Cl in methanol and DMF at 50-60°C in air for 2 h; addn. of isopropanol, isolation of crystals, elem. anal.;	82%

...Expand

: HP(C2H5)2C6H5(1+)*Cr(NCS)4(P(C2H5)2C6H5)2(1-) = {HP(C2H5)2C6H5}{Cr(NCS)4(P(C2H5)2C6H5)2}

: 3829-86-5
1,10-phenanthroline hydrochloride

: C12H9N2(1+)*Cr(NCS)4(P(C2H5)2C6H5)2(1-) = {C12H9N2}{Cr(NCS)4(P(C2H5)2C6H5)2}

Conditions

Conditions	Yield
In methanol; water; butan-1-ol dissolving of amine hydrochloride in water, addn. of the phosphine-complex in methanol-butanol; filtn. after 10-15 min, washing (methanol), drying at room temp. in air, elem. anal.;	72%

: nitridotechnetic(VI) acid

: 3829-86-5
1,10-phenanthroline hydrochloride

: 131810-72-5
nitridoperoxo 1,10-phenanthroline technetium(VII)

Conditions

Conditions	Yield
elem. anal.;	70%

: {HP(C2H5)2C6H4CH3}(1+)*Cr(NCS)4(P(C2H5)2C6H4CH3)2(1-) = {HP(C2H5)2C6H4CH3}{Cr(NCS)4(P(C2H5)2C6H4CH3)2}

: 3829-86-5
1,10-phenanthroline hydrochloride

: C12H9N2(1+)*Cr(NCS)4(P(C2H5)2C6H4CH3)2(1-) = {C12H9N2}{Cr(NCS)4(P(C2H5)2C6H4CH3)2}

Conditions

Conditions	Yield
In water dissolving of amine hydrochloride in water, addn. of Cr complex; addn. of methanol-butanol, filtn. after 10-15 min, washing (methanol), drying at room temp. in air, elem. anal.;	65%

: mer-diaqua(oxydiacetato)oxovanadium(IV)

: 3829-86-5
1,10-phenanthroline hydrochloride

: o-phenanthroline(oxydiacetato)oxovanadium(IV) monohydrate

Conditions

Conditions	Yield
In water under anaerobic conditions; water soln. of ligand (1 equiv.) added slowly to aq. soln. of V complex; left to stand for 4 d; crystals collected; elem. anal.;	53%

: 3829-86-5
1,10-phenanthroline hydrochloride

A: 66127-01-3
3-bromophenanthroline

B: 100125-12-0
3,8-dibromo-1,10-phenathroline

Conditions

Conditions	Yield
With bromine In nitrobenzene at 130 - 140℃; for 3h;	A 33% B 17%
With water; bromine In nitrobenzene
With bromine In bromobenzene at 135℃; for 36h;

: 3829-86-5
1,10-phenanthroline hydrochloride

: 66127-01-3
3-bromophenanthroline

Conditions

Conditions	Yield
With bromine In nitrobenzene	26%
With bromine	26%

: 3829-86-5
1,10-phenanthroline hydrochloride

: 879879-66-0
3-anisyl-1,10-phenanthroline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 26 percent / Br2 / nitrobenzene View Scheme

: 3829-86-5
1,10-phenanthroline hydrochloride

: 3-anisyl-2-mesityl-1,10-phenanthroline

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: 26 percent / Br2 / nitrobenzene 2: 20 percent / diethyl ether View Scheme

: 3829-86-5
1,10-phenanthroline hydrochloride

: 862694-14-2
2-mesityl-8-anisyl-1,10-phenanthroline

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: 26 percent / Br2 / nitrobenzene 2: 26 percent / diethyl ether View Scheme

: 6268-10-6
4-chloro-9,10-dihydro-9,10-dioxo-1-anthracenecarboxylic acid

: 3829-86-5
1,10-phenanthroline hydrochloride

: 82-44-0
1-chloroanthracene-9,10-dione

Conditions

Conditions	Yield
With 1-methyl-pyrrolidin-2-one In sulfuric acid; water

: 13476-99-8
tris(acetylacetonato)vanadium(III)

: 7732-18-5
water

: 3829-86-5
1,10-phenanthroline hydrochloride

: 767607-07-8
[(V(o-phenanthroline)2Cl)2O](2+)

Conditions

Conditions	Yield
In methanol reflux in MeOH;

...Expand

: molybdenum (IV) sulfide

: 3829-86-5
1,10-phenanthroline hydrochloride

: (1,10-phenanthroline)0.295MoS2

Conditions

Conditions	Yield
In water prepn. from aq. dispersion of MoS2 and aq. soln. of 1,10-phenanthroline hydrochloride according to A. S. Golub et al., Solid State Ionics, 1996,vol. 91, p. 307; elem. anal.;

: molybdenum (IV) sulfide

: 3829-86-5
1,10-phenanthroline hydrochloride

: (1,10-phenanthroline)0.095MoS2

Conditions

Conditions	Yield
In water prepn. from aq. dispersion of MoS2 and aq. soln. of 1,10-phenanthroline hydrochloride according to A. S. Golub et al., Solid State Ionics, 1996,vol. 91, p. 307; elem. anal.;

: 3829-86-5
1,10-phenanthroline hydrochloride

: copper(II) perchlorate

: 15891-89-1
[Cu(phen)](2+)

Conditions

Conditions	Yield
In water mixing the aq. soln. of the ligand with the metal perchlorate soln. in at least 500-fold excess; not sepd., detected in soln. by UV/VIS;

: zinc(II) perchlorate

: 3829-86-5
1,10-phenanthroline hydrochloride

: 16561-55-0
[Zn-1,10-phenanthroline](2+)

Conditions

Conditions	Yield
In water mixing the aq. soln. of the ligand with the metal perchlorate soln. in at least 500-fold excess; not sepd., detected in soln. by UV/VIS;

: 3829-86-5
1,10-phenanthroline hydrochloride

: Mn(2+)*2C12H8N2*Cr2O7(2-)=Mn(C12H8N2)2Cr2O7

Conditions

Conditions	Yield
With dichromate anion In water heating to about 80°C;
With Mn(2+) salt; Cr2O7(2-) In water heating to about 80°C;

: Mo(4+)*C2O4H(1-)*3OH(1-)*H2O={Mo(C2O4H)(OH)3(H2O)}

: 3829-86-5
1,10-phenanthroline hydrochloride

: C12H9N2(1+)*Mo(4+)*C2O4(2-)*2OH(1-)*Cl(1-)*H2O=C12H9N2{Mo(C2O4)(OH)2Cl(H2O)}

Conditions

Conditions	Yield
In water stirred; ppt. is washed (water, ethanol), dried under vac., elem. anal.;

: 3829-86-5
1,10-phenanthroline hydrochloride

: nickel(II) perchlorate

: 24968-26-1
[Ni(1,10-phenanthroline)](2+)

Conditions

Conditions	Yield
In water mixing the aq. soln. of the ligand with the metal perchlorate soln. in at least 500-fold excess; not sepd., detected in soln. by UV/VIS;

: 15170-51-1
nitrosyltrichlororhenium

: 3829-86-5
1,10-phenanthroline hydrochloride

: bis(1,10-phenanthrolinium) nitrosyldichlorotrithiocyanatorhenate

Conditions

Conditions	Yield
With KSCN In water the Re-complex is dissolved in a soln. of KSCN; mixt. refluxed for 15 min; phenanthrolinium hydrochloride added dropwise and with stirring; ppt. changes to oily drops at water-bath temp., mother liquor is separated, oil is repeatedly washed and dried under vac., elem. anal.;

: 20427-59-2
copper hydroxide

: 3829-86-5
1,10-phenanthroline hydrochloride

: 147-85-3
L-proline

: Cu(L-prolinate)(1,10-phenanthroline)Cl*3H2O

Conditions

Conditions	Yield
In ethanol; water L-proline in H2O added to freshly prepared Cu(OH)2, C12H8N2*HCl in ethanol added with gentle warming; residue removed, soln. concd. under reduced pressure, crystd., elem. anal.;

...Expand

: 3829-86-5
1,10-phenanthroline hydrochloride

: copper dichloride

: (1,10-phenanthroline)2CuCl2

Conditions

Conditions	Yield
In water at pH 6; not isolated; monitored by UV;

: 87331-61-1
aquo nitrosyldihydroxo oxalato rhenic acid

: 3829-86-5
1,10-phenanthroline hydrochloride

: 87331-75-7
1,10-phenanthroline nitrosylchloro oxalato rhenium

Conditions

Conditions	Yield
In water refluxing a soln. of the rhenium complex acid and 1,10-phenanthroline hydrochloride for 3 h; filtn., washing with water and ethanol, drying in vacuo, elem. anal.;

: manganese(II) perchlorate

: 3829-86-5
1,10-phenanthroline hydrochloride

: 19709-60-5
(1,10-phenanthroline)manganese(II)

Conditions

Conditions	Yield
In water mixing the aq. soln. of the ligand with the metal perchlorate soln. in at least 500-fold excess; not sepd., detected in soln. by UV/VIS;

1,10-Phenanthroline monohydrochloride Chemical Properties

The Molecular Structure of 1,10-Phenanthroline, hydrochloride (1:1) (CAS NO.3829-86-5):

Empirical Formula: C₁₂H₉ClN₂
Molecular Weight: 216.6663
IUPAC: 1,10-phenanthroline hydrochloride
Nominal Mass: 216 Da
Average Mass: 216.6663 Da
Monoisotopic Mass: 216.045426 Da
Flash Point: 164.8 °C
Enthalpy of Vaporization: 58.73 kJ/mol
Boiling Point: 365.1 °C at 760 mmHg
Melting Point: 224-225 °C(lit.)
Solubility H2O: 0.1 g/mL, clear
Water Solubility: soluble
BRN: 4007967
Appearance: white to light yellow or slightly purple powder
Vapour Pressure: 3.38E-05 mmHg at 25°C
InChI
InChI=1/C12H8N2.ClH/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;/h1-8H;1H
Smiles
c12c3ncccc3ccc2cccn1.Cl
Product Categories: Aromatic Hydrocarbons (substituted) & Derivatives;Heterocyclic Compounds;Analytical Chemistry;Chelating Reagents;Phenanthrolines

1,10-Phenanthroline monohydrochloride Safety Profile

Hazard Codes: Toxic T Dangerous N
Risk Statements: 25-50/53
R25 :Toxic if swallowed
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety Statements: 45-60-61
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S60:This material and its container must be disposed of as hazardous waste
S61:Avoid release to the environment. Refer to special instructions / safety data sheets
RIDADR UN: 2811 6.1/PG 3
WGK Germany: 3
F 8:Photosensitive
HazardClass: 6.1
PackingGroup :III

1,10-Phenanthroline monohydrochloride Specification

1,10-Phenanthroline, hydrochloride (1:1) (CAS NO.3829-86-5) is also called as 1,10-Diazaphenanthrene hydrochloride ; 1,10-Phenanthroline hydrochloride ; EINECS 223-325-1 ; NSC 4265 ; Phenanthroline hydrochloride ; 1,10-Phenanthroline monohydrochloride monohydrate ; 1,10-Phenanthroline, monohydrochloride .

Product Name

o-Phenanthroline monohydrochloride monohydrate

Synthetic route

1,10-Phenanthroline monohydrochloride Chemical Properties

1,10-Phenanthroline monohydrochloride Safety Profile

1,10-Phenanthroline monohydrochloride Specification

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