Product Name

  • Name

    10,10-Oxybisphenoxarsine

  • EINECS 200-377-3
  • CAS No. 58-36-6
  • Density 1.40-1.42
  • Solubility Insoluble in water and slightly denser than water
  • Melting Point 180-184 °C
  • Formula C24H16As2O3
  • Boiling Point 531.3 °C at 760 mmHg
  • Molecular Weight 502.232
  • Flash Point 214.1 °C
  • Transport Information UN 1557 6.1/PG 2
  • Appearance clear light yellow liquid with a mild odor
  • Safety
  • Risk Codes
  • Molecular Structure Molecular Structure of 58-36-6 (10,10-Oxybisphenoxarsine)
  • Hazard Symbols
  • Synonyms Phenoxarsine,10,10'-oxydi- (6CI,7CI,8CI);10,10'-Bis(phenoxarsinyl) oxide;10,10'-Oxidiphenoxarsine;10,10'-Oxybisphenoxarsine;Bis(10-phenoxarsyl) oxide;Bis(phenoxarsin-10-yl) ether;10H-Phenoxarsine, 10,10'-oxybis-;SA 546;Vinadine;Vinyzene(pesticide);Vinyzene BP 5;Vinyzene BP 5-2DIDP;Vinyzene BP505;Vinyzene SB 1PR;
  • PSA 27.69000
  • LogP 2.82620

Synthetic route

10-<2-chloro-1-(chloromethyl)ethoxy>phenoxarsine

10-<2-chloro-1-(chloromethyl)ethoxy>phenoxarsine

A

1,3-Dichloro-2-propanol
96-23-1

1,3-Dichloro-2-propanol

B

10,10,oxybisphenoxarsine
58-36-6

10,10,oxybisphenoxarsine

Conditions
ConditionsYield
With water In acetoneA 83.8%
B 93.9%
10-sec-butyl-10H-phenoxarsine
55369-40-9

10-sec-butyl-10H-phenoxarsine

10,10,oxybisphenoxarsine
58-36-6

10,10,oxybisphenoxarsine

Conditions
ConditionsYield
With oxygen
diphenylether
101-84-8

diphenylether

10,10,oxybisphenoxarsine
58-36-6

10,10,oxybisphenoxarsine

Conditions
ConditionsYield
(i) AsCl3, (ii) O2; Multistep reaction;
10-allylphenoxarsine
39548-42-0

10-allylphenoxarsine

10,10,oxybisphenoxarsine
58-36-6

10,10,oxybisphenoxarsine

Conditions
ConditionsYield
With oxygen
10-tert-butylphenoxarsine
39548-35-1

10-tert-butylphenoxarsine

10,10,oxybisphenoxarsine
58-36-6

10,10,oxybisphenoxarsine

Conditions
ConditionsYield
With ethanol
phenoxarsine chloride

phenoxarsine chloride

10,10,oxybisphenoxarsine
58-36-6

10,10,oxybisphenoxarsine

Conditions
ConditionsYield
With ethanol; ammonia
10-chloro-10H-phenoxarsine
2865-70-5

10-chloro-10H-phenoxarsine

10,10,oxybisphenoxarsine
58-36-6

10,10,oxybisphenoxarsine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: toluene; diethyl ether
2: O2
View Scheme
Multi-step reaction with 2 steps
1: benzene; diethyl ether
2: O2
View Scheme
Multi-step reaction with 2 steps
1: toluene; diethyl ether
2: aq. EtOH
View Scheme
Elaidic Acid
112-79-8

Elaidic Acid

10,10,oxybisphenoxarsine
58-36-6

10,10,oxybisphenoxarsine

(E)-Octadec-9-enoic acid phenoxarsin-10-yl ester

(E)-Octadec-9-enoic acid phenoxarsin-10-yl ester

Conditions
ConditionsYield
In toluene Heating;80.8%
10,10,oxybisphenoxarsine
58-36-6

10,10,oxybisphenoxarsine

acrylic acid
79-10-7

acrylic acid

Acrylic acid phenoxarsin-10-yl ester

Acrylic acid phenoxarsin-10-yl ester

Conditions
ConditionsYield
In toluene Heating;71.5%
succinic acid anhydride
108-30-5

succinic acid anhydride

10,10,oxybisphenoxarsine
58-36-6

10,10,oxybisphenoxarsine

Succinic acid diphenoxarsin-10-yl ester

Succinic acid diphenoxarsin-10-yl ester

Conditions
ConditionsYield
In toluene for 5h; Heating;66%
2-butenoic acid
3724-65-0

2-butenoic acid

10,10,oxybisphenoxarsine
58-36-6

10,10,oxybisphenoxarsine

(E)-But-2-enoic acid phenoxarsin-10-yl ester

(E)-But-2-enoic acid phenoxarsin-10-yl ester

Conditions
ConditionsYield
In toluene Heating;62.8%
succinic acid
110-15-6

succinic acid

10,10,oxybisphenoxarsine
58-36-6

10,10,oxybisphenoxarsine

succinic acid mono(10-phenoxyarsinyl) ester

succinic acid mono(10-phenoxyarsinyl) ester

Conditions
ConditionsYield
In toluene for 5h; Heating;61.2%
succinic acid
110-15-6

succinic acid

10,10,oxybisphenoxarsine
58-36-6

10,10,oxybisphenoxarsine

Succinic acid diphenoxarsin-10-yl ester

Succinic acid diphenoxarsin-10-yl ester

Conditions
ConditionsYield
In toluene for 8h; Heating;59%
10,10,oxybisphenoxarsine
58-36-6

10,10,oxybisphenoxarsine

10-oxo-10H-10λ5-phenoxarsin-10-ol
4846-20-2

10-oxo-10H-10λ5-phenoxarsin-10-ol

Conditions
ConditionsYield
With ethanol; iodine
ethanol
64-17-5

ethanol

phosphoric acid
86119-84-8, 7664-38-2

phosphoric acid

10,10,oxybisphenoxarsine
58-36-6

10,10,oxybisphenoxarsine

bis-phenoxarsinyl-(10)

bis-phenoxarsinyl-(10)

...Expand
hydrogen bromide
10035-10-6, 12258-64-9

hydrogen bromide

10,10,oxybisphenoxarsine
58-36-6

10,10,oxybisphenoxarsine

phenoxarsine bromide

phenoxarsine bromide

10,10,oxybisphenoxarsine
58-36-6

10,10,oxybisphenoxarsine

10,10'bis(phenoxarsine) selenide

10,10'bis(phenoxarsine) selenide

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: conc. HI / benzene / 2 h
2: H2Se, pyridine / ethanol / 2 h
View Scheme

10,10-Oxybisphenoxarsine Consensus Reports

EPA Extremely Hazardous Substances List. Arsenic and its compounds are on the Community Right-To-Know List.

10,10-Oxybisphenoxarsine Standards and Recommendations

OSHA PEL: TWA 0.5 mg(As)/m3

10,10-Oxybisphenoxarsine Specification

The 10,10-Oxybisphenoxarsine, with the CAS registry number 58-36-6, is also known as Bis(phenoxarsin-10-yl) ether. It belongs to the product categories of Industrial/Fine Chemicals. Its EINECS number is 200-377-3. This chemical's molecular formula is C24H16As2O3 and molecular weight is 502.23. What's more, its systematic name is 10,10'-oxybis(10H-phenoxarsinine). Its classification code is Skin / Eye Irritant. It is a new kind of industrial mould inhibitor. It is mouldproof and antibacterial, and is one of the most effective antimicrobial in industrial fields. It can be used as an antimicrobial add to the PVC products, plastic products, PVC flooring, metope paint and so on.

Physical properties of 10,10-Oxybisphenoxarsine are: (1)#H bond acceptors: 3; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 2; (4)Polar Surface Area: 27.69 Å2; (5)Flash Point: 214.1 °C; (6)Enthalpy of Vaporization: 77.65 kJ/mol; (7)Boiling Point: 531.3 °C at 760 mmHg; (8)Vapour Pressure: 7.77E-11 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)SMILES: O5c1c(cccc1)[As](O[As]2c4ccccc4Oc3c2cccc3)c6ccccc56
(2)Std. InChI: InChI=1S/C24H16As2O3/c1-5-13-21-17(9-1)25(18-10-2-6-14-22(18)27-21)29-26-19-11-3-7-15-23(19)28-24-16-8-4-12-20(24)26/h1-16H
(3)Std. InChIKey: VCRZAKVGPJFABU-UHFFFAOYSA-N

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
bird - wild LD50 oral 24mg/kg (24mg/kg)   Toxicology and Applied Pharmacology. Vol. 21, Pg. 315, 1972.
guinea pig LCLo inhalation 141mg/m3/2H (141mg/m3)   Toxicology. Vol. 10, Pg. 341, 1978.
guinea pig LD50 oral 24mg/kg (24mg/kg) BEHAVIORAL: MUSCLE WEAKNESS

LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION

SKIN AND APPENDAGES (SKIN): HAIR: OTHER		 Toxicology. Vol. 10, Pg. 341, 1978.
mouse LDLo oral 42mg/kg (42mg/kg)   Archives of Environmental Contamination and Toxicology. Vol. 14, Pg. 111, 1985.
rat LD50 oral 40mg/kg (40mg/kg) BEHAVIORAL: MUSCLE WEAKNESS

LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION

SKIN AND APPENDAGES (SKIN): HAIR: OTHER		 Toxicology. Vol. 10, Pg. 341, 1978.

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