Conditions | Yield |
---|---|
With aluminium trichloride at 23℃; for 4h; Friedel-Crafts acylation; | 96% |
With aluminum (III) chloride for 8h; Friedel-Crafts Acylation; Inert atmosphere; |
tris(4-fluorophenyl)bismuthane
terephthaloyl chloride
1,4-bis-(4-fluorobenzoyl)-benzene
Conditions | Yield |
---|---|
With tributyl-amine In 1-methyl-pyrrolidin-2-one at 80℃; for 5h; Schlenk technique; Inert atmosphere; | 77% |
With triethylamine; tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane at 80℃; for 3h; | 73% |
carbon monoxide
para-diiodobenzene
1,4-bis-(4-fluorobenzoyl)-benzene
Conditions | Yield |
---|---|
With mesoporous material MCM-41-immobilized palladium(II)-schiff base complex In tetrahydrofuran at 68℃; under 1900.13 Torr; for 3.5h; Inert atmosphere; Schlenk technique; | 72% |
(S)-[1,1']-binaphthalenyl-2,2'-diol
1,4-bis-(4-fluorobenzoyl)-benzene
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 150℃; for 9h; | 86% |
1,4-bis-(4-fluorobenzoyl)-benzene
Conditions | Yield |
---|---|
With sulfuric acid; nitric acid In (2S)-N-methyl-1-phenylpropan-2-amine hydrate | 83.7% |
sodium acetylide
1,4-bis-(4-fluorobenzoyl)-benzene
1,4-di[1-hydroxy-1-(p-fluorophenyl)-prop-2-ynyl]benzene
Conditions | Yield |
---|---|
With acetylene In tetrahydrofuran; dimethyl sulfoxide at 23℃; | 61% |
BPA
1,4-bis-(4-fluorobenzoyl)-benzene
Conditions | Yield |
---|---|
With potassium carbonate Polymerization; |
4,4'-Dihydroxybiphenyl
9,9'-bis(4-hydroxyphenyl)-10-anthrone
1,4-bis-(4-fluorobenzoyl)-benzene
Conditions | Yield |
---|---|
With potassium carbonate Polymerization; |
4,4'-Dihydroxybiphenyl
9,9'-bis(4-hydroxyphenyl)-10-anthrone
1,4-bis-(4-fluorobenzoyl)-benzene
Conditions | Yield |
---|---|
With potassium carbonate Polymerization; |
4,4'-Dihydroxybiphenyl
9,9-bis(4-hydroxyphenyl)fluorene
1,4-bis-(4-fluorobenzoyl)-benzene
Conditions | Yield |
---|---|
With potassium carbonate Polymerization; |
9,9'-bis(4-hydroxyphenyl)-10-anthrone
1,4-bis-(4-fluorobenzoyl)-benzene
Conditions | Yield |
---|---|
With potassium carbonate Polymerization; |
9,9-bis(4-hydroxyphenyl)fluorene
1,4-bis-(4-fluorobenzoyl)-benzene
Conditions | Yield |
---|---|
With potassium carbonate Polymerization; |
4,4'-Dihydroxybiphenyl
chloro-p-hydroquinone
1,4-bis-(4-fluorobenzoyl)-benzene
1,4-bis-(4-fluorobenzoyl)-benzene
1,4-di-(3-p-fluorophenyl-[3H]-naphtho[2,1-b]pyran-3-yl)-benzene
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 61 percent / acetylene / tetrahydrofuran; dimethylsulfoxide / 23 °C 2: 84 percent / PPTS; trimethyl orthoformate / CH2Cl2 / 5 h / Heating View Scheme |
1,4-bis-(4-fluorobenzoyl)-benzene
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 61 percent / acetylene / tetrahydrofuran; dimethylsulfoxide / 23 °C 2: 84 percent / PPTS; trimethyl orthoformate / CH2Cl2 / 5 h / Heating 3: hexane; CH2Cl2 / 0.01 h / 20 °C View Scheme |
1,4-bis-(4-fluorobenzoyl)-benzene
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 61 percent / acetylene / tetrahydrofuran; dimethylsulfoxide / 23 °C 2: 84 percent / PPTS; trimethyl orthoformate / CH2Cl2 / 5 h / Heating 3: hexane; CH2Cl2 / 0 h / -30 °C / UV-irradiation View Scheme |
1,4-bis-(4-fluorobenzoyl)-benzene
1,4-di-(8-bromo-3-p-fluorophenyl-[3H]-naphtho[2,1-b]pyran-3-yl)-benzene
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 61 percent / acetylene / tetrahydrofuran; dimethylsulfoxide / 23 °C 2: 78.4 percent / PPTS; trimethyl orthoformate / CH2Cl2 / 5.5 h / Heating View Scheme |
1,4-bis-(4-fluorobenzoyl)-benzene
1,4-di-(2-p-fluorophenyl-6-phenyl-5-ethoxycarbonyl-[2H]-naphtho[2,1-b]pyran-2-yl)-benzene
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 61 percent / acetylene / tetrahydrofuran; dimethylsulfoxide / 23 °C 2: 65 percent / PPTS; trimethyl orthoformate / CH2Cl2 / 24 h / Heating View Scheme |
9H-carbazole
1,4-bis-(4-fluorobenzoyl)-benzene
Conditions | Yield |
---|---|
With potassium tert-butylate In N,N-dimethyl-formamide at 120℃; for 24h; Inert atmosphere; |
This chemical is called 1,4-Bis(4-fluorobenzoyl)benzene, and its systematic name is benzene-1,4-diylbis[(2-fluorophenyl)methanone]. With the molecular formula of C20H12F2O2, its molecular weight is 322.30. The CAS registry number of this chemical is 68418-51-9
Other characteristics of the chemical can be summarised as followings: (1)ACD/LogP: 3.83; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 3.83; (4)ACD/LogD (pH 7.4): 3.83; (5)ACD/BCF (pH 5.5): 479.63; (6)ACD/BCF (pH 7.4): 479.63; (7)ACD/KOC (pH 5.5): 2888; (8)ACD/KOC (pH 7.4): 2888; (9)#H bond acceptors: 2; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 4; (12)Polar Surface Area: 34.14 Å2; (13)Index of Refraction: 1.59; (14)Molar Refractivity: 85.82 cm3; (15)Molar Volume: 254 cm3; (16)Polarizability: 34.02×10-24cm3; (17)Surface Tension: 45.7 dyne/cm; (18)Density: 1.268 g/cm3; (19)Flash Point: 180.2 °C; (20)Enthalpy of Vaporization: 74.46 kJ/mol; (21)Boiling Point: 480.1 °C at 760 mmHg; (22)Vapour Pressure: 2.22E-09 mmHg at 25°C.
You can still convert the following datas into molecular structure:
1.SMILES: O=C(c1ccccc1F)c2ccc(cc2)C(=O)c3ccccc3F
2.InChI: InChI=1/C20H12F2O2/c21-17-7-3-1-5-15(17)19(23)13-9-11-14(12-10-13)20(24)16-6-2-4-8-18(16)22/h1-12H
3.InChIKey: WZIAJVRIELTJDH-UHFFFAOYAC
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