Conditions | Yield |
---|---|
With oxone; methanesulfonic acid; tetra-(n-butyl)ammonium iodide at 60℃; for 8h; Reagent/catalyst; Temperature; Large scale; | 87% |
N,N'-diphenacyl-terephthalamide
1,4-bis(5-phenyl-2-oxazolyl)benzene
Conditions | Yield |
---|---|
With trichlorophosphate | |
With sulfuric acid |
1,1'-diphenyl-2,2'-(N,N'-dioxy-N,N'-p-phenylenebismethylene-diamino)-bis-ethanone
1,4-bis(5-phenyl-2-oxazolyl)benzene
Conditions | Yield |
---|---|
With sulfuric acid; acetic anhydride for 0.0333333h; |
zinc(II) chloride tetrahydrate
1,4-bis(5-phenyl-2-oxazolyl)benzene
[ZnCl2(H2O)(1,4-bis(5-phenyloxazol-2-yl)benzene)]*1,4-bis(5-phenyloxazol-2-yl)benzene
Conditions | Yield |
---|---|
In acetonitrile High Pressure; mixt. of bisoxazol and Zn salt (0.1:0.48 molar ratio) in CH3CN heated at100°C in teflon-lined steel reactor for 72 h; cooled, crystd. within 24 h; elem. anal.; | 68% |
zinc(II) chloride tetrahydrate
1,4-bis(5-phenyl-2-oxazolyl)benzene
[ZnCl2(1,4-bis(5-phenyloxazol-2-yl)benzene)]n
Conditions | Yield |
---|---|
In acetonitrile High Pressure; mixt. of bisoxazol and Zn salt (0.1:0.48 molar ratio) in CH3CN heated at110°C in teflon-lined steel reactor for 72 h; cooled, crystd. within 24 h; elem. anal.; | 65% |
zinc(II) chloride tetrahydrate
1,4-bis(5-phenyl-2-oxazolyl)benzene
acetonitrile
Conditions | Yield |
---|---|
In acetonitrile High Pressure; mixt. of bisoxazol and Zn salt (0.1:0.48 molar ratio) in CH3CN heated at150°C in teflon-lined steel reactor for 72 h; cooled, crystd. within 24 h; elem. anal.; | 65% |
1,4-bis(5-phenyl-2-oxazolyl)benzene
1,4-bis<5-(p-Bromophenyl)-4-bromo-2-oxazolyl>benzene
Conditions | Yield |
---|---|
With bromine for 7h; Heating; | 38% |
Conditions | Yield |
---|---|
at 180 - 190℃; |
1,4-bis(5-phenyl-2-oxazolyl)benzene
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide for 12h; |
The CAS register number of 1,4-Bis(5-phenyloxazol-2-yl)benzene is 1806-34-4. It also can be called as 1,4-Bis(5-phenyl-2-oxazolyl)benzene and the systematic name about this chemical is 2,2'-benzene-1,4-diylbis(5-phenyl-1,3-oxazole). The molecular formula about this chemical is C24H16N2O2 and the molecular weight is 364.4. It belongs to the following product categorie which include Scintillators.
Physical properties about 1,4-Bis(5-phenyloxazol-2-yl)benzene are: (1)ACD/LogP: 6.45; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): 6.45; (4)ACD/LogD (pH 7.4): 6.45; (5)ACD/BCF (pH 5.5): 46659.19; (6)ACD/BCF (pH 7.4): 46659.19; (7)ACD/KOC (pH 5.5): 76490.56; (8)ACD/KOC (pH 7.4): 76490.56; (9)#H bond acceptors: 4; (10)#Freely Rotating Bonds: 4; (11)Polar Surface Area: 52.06 Å2; (12)Index of Refraction: 1.613; (13)Molar Refractivity: 105.4 cm3; (14)Molar Volume: 302.6 cm3; (15)Polarizability: 41.78x10-24cm3; (16)Surface Tension: 48.1 dyne/cm; (17)Density: 1.204 g/cm3; (18)Flash Point: 307 °C; (19)Enthalpy of Vaporization: 84.18 kJ/mol; (20)Boiling Point: 585.1 °C at 760 mmHg; (21)Vapour Pressure: 4.62E-13 mmHg at 25 °C.
Uses of 1,4-Bis(5-phenyloxazol-2-yl)benzene: it can be used to produce 1,4-bis[5-(p-Bromophenyl)-4-bromo-2-oxazolyl]benzene. This reaction will need reagent Br2. This reaction needs heating. The reaction time is 7 hour(s). The yield is about 38%.
When you are using this chemical, please be cautious about it as the following:
This chemical is irritating to eyes, respiratory system and skin. It is harmful by inhalation, in contact with skin and if swallowed. If you want to use this chemical, wear suitable protective clothing. When you are using it, do not breathe dust and avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
You can still convert the following datas into molecular structure:
(1)SMILES: n1cc(oc1c4ccc(c2ncc(o2)c3ccccc3)cc4)c5ccccc5
(2)InChI: InChI=1/C24H16N2O2/c1-3-7-17(8-4-1)21-15-25-23(27-21)19-11-13-20(14-12-19)24-26-16-22(28-24)18-9-5-2-6-10-18/h1-16H
(3)InChIKey: MASVCBBIUQRUKL-UHFFFAOYAO
(4)Std. InChI: InChI=1S/C24H16N2O2/c1-3-7-17(8-4-1)21-15-25-23(27-21)19-11-13-20(14-12-19)24-26-16-22(28-24)18-9-5-2-6-10-18/h1-16H
(5)Std. InChIKey: MASVCBBIUQRUKL-UHFFFAOYSA-N
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