1-Bromotetradecane supplier

Name
1-Bromotetradecane
EINECS 203-999-3
CAS No. 112-71-0
Article Data18
CAS DataBase
Density 0.93 g/cm³
Solubility insoluble in water
Melting Point 5-6 °C(lit.)
Formula C₁₄H₂₉Br
Boiling Point 307.5 °C at 760 mmHg
Molecular Weight 277.288
Flash Point 127.3 °C
Transport Information
Appearance pale yellow liquid
Safety 26-36-24/25
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms 1-Tetradecyl bromide;Myristyl bromide;NSC 83468;Tetradecyl bromide;n-Tetradecyl bromide;n-Tetradecyl-1-bromide;
PSA 0.00000
LogP 6.08240

Synthetic route

: 1120-36-1
1-tetradecene

: 112-71-0
1-Bromotetradecane

Conditions

Conditions	Yield
With hydrogen bromide In 1,4-dioxane; hexane at 20℃; for 1h;	98%
With 2,2,4-trimethylpentane; tetradecafluorohexane; bromine at 20℃; for 2h; Irradiation;	94%

: 52756-06-6
N-tetradecyl-N'-tosylhydrazine

A: 112-71-0
1-Bromotetradecane

B: 6064-45-5
1,2-dibromotetradecane

C: 1950-69-2
toluene-p-sulfonyl bromide

Conditions

Conditions	Yield
With bromine In chloroform for 2.5h; Ambient temperature;	A 52 % Chromat. B 11 % Chromat. C 93%

...Expand

: 1120-36-1
1-tetradecene

A: 112-71-0
1-Bromotetradecane

B: 74036-95-6
2-bromotetradecane

Conditions

Conditions	Yield
With acetic acid In 1,4-dioxane; 1,2-dichloro-ethane	A 10% B 90%

: 112-72-1
1-Tetradecanol

: 112-71-0
1-Bromotetradecane

Conditions

Conditions	Yield
With sulfuric acid; hydrogen bromide
With chloroform; phosphorus tribromide at 0℃; zuletzt bei 50grad;
With phosphorus; bromine bei Siedetemperatur;

: 67-56-1
methanol

: 629-73-2
1-Hexadecene

: 112-71-0
1-Bromotetradecane

Conditions

Conditions	Yield
With FeBr3*6H2O; oxygen; ozone 1.) 0 deg C; 2.) methanol, reflux, 15 min; Yield given. Multistep reaction;

: 83486-04-8
C20H34Br2Te

A: 112-71-0
1-Bromotetradecane

B: 32294-60-3
diphenyl ditelluride

Conditions

Conditions	Yield
With sodium bromide In N,N-dimethyl-formamide at 70℃; Yield given;

: 77774-34-6
tetradecyl tert-butyldimethylsilyl ether

: 1034-39-5
dibromotriphenylphosphorane

: 112-71-0
1-Bromotetradecane

Conditions

Conditions	Yield
In dichloromethane for 0.166667h; Ambient temperature;

: 77953-88-9
1-Tetradecyl phenyl telluride

A: 112-71-0
1-Bromotetradecane

B sodium-compound of (+-)-2-oxo-tetrahydro-furan-3-carboxylic acid ethyl ester: sodium-compound of (+-)-2-oxo-tetrahydro-furan-3-carboxylic acid ethyl ester

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: bromine / CCl4 / Ambient temperature 2: sodium bromide / dimethylformamide / 70 °C View Scheme

: 112-71-0
1-Bromotetradecane

: 603-35-0
triphenylphosphine

: 25791-20-2
(n-tetradecyl)triphenylphosphonium bromide

Conditions

Conditions	Yield
In toluene Reflux;	100%
at 140℃; for 7h;	92%
In benzene for 48h; Substitution; Heating;	92%

: 112-71-0
1-Bromotetradecane

: 86-51-1
2,3-dimethyoxybenzaldehyde

: 33597-07-8
(+/-)-1-hydroxy-1-(2.3-dimethoxy-phenyl)-pentadecane

Conditions

Conditions	Yield
Stage #1: 1-Bromotetradecane With iodine; magnesium In diethyl ether Stage #2: 2,3-dimethyoxybenzaldehyde In diethyl ether for 4h; Reflux;	100%
With lithium In tetrahydrofuran at 0℃;	63%

: 112-71-0
1-Bromotetradecane

: 3,6-dihydroxy-9H-fluoren-9-one

: 1216990-63-4
C41H64O3

Conditions

Conditions	Yield
With sodium carbonate In N,N-dimethyl-formamide Reflux;	100%

: 112-71-0
1-Bromotetradecane

: 33329-35-0
N,N-bis[3-(dimethylamino)propyl]-N',N'-dimethylpropane-1,3-diamine

: C57H123N4(3+)*3Br(1-)

Conditions

Conditions	Yield
In acetonitrile for 24h; Reflux;	100%
In acetonitrile for 40h; Reflux;

: 576-26-1
2.6-dimethylphenol

: 112-71-0
1-Bromotetradecane

: 1335029-37-2
2-(tetradecyloxy)-1,3-dimethylbenzene

Conditions

Conditions	Yield
With potassium carbonate In acetonitrile for 48h; Williamson synthesis; Inert atmosphere; Reflux;	99.3%
Stage #1: 2.6-dimethylphenol With sodium hydroxide In ethanol at 25℃; for 2h; Stage #2: 1-Bromotetradecane In ethanol; N,N-dimethyl-formamide at 60℃; for 6h;	79%

: 112-71-0
1-Bromotetradecane

: 609-08-5
Diethyl methylmalonate

: 114289-75-7
methyl-tetradecyl-malonic acid diethyl ester

Conditions

Conditions	Yield
	99%
(i) Na, (ii) /BRN= 1742640/; Multistep reaction;
With sodium ethanolate 1.) ethanol, reflux, 15 min, 2.) ethanol, reflux, overnight; Multistep reaction;

: 280-57-9
1,4-diaza-bicyclo[2.2.2]octane

: 112-71-0
1-Bromotetradecane

: 1-tetradecyl-1-azonia-4-azabicyclo[2.2.2]octane bromide

Conditions

Conditions	Yield
In ethyl acetate at 20℃; for 24h;	99%
In acetone at 20 - 50℃; for 1.5h;	72%
In acetonitrile for 0.5h; Ambient temperature;
In acetone at 20℃; for 48h;
In ethyl acetate at 20℃; for 24h;

: 112-71-0
1-Bromotetradecane

: 3316-09-4
1,2-dihydroxy-4-nitrobenzene

: 156450-07-6
1,2-di(tetradecyloxy)-4-nitrobenzene

Conditions

Conditions	Yield
With potassium carbonate In N,N-dimethyl-formamide; acetone	99%

: 112-71-0
1-Bromotetradecane

: 19218-94-1
1-iodotetradecane

Conditions

Conditions	Yield
With sodium iodide In acetone for 27h; Heating;	99%
With sodium iodide In acetone for 48h; Reflux; Inert atmosphere;	94%

: 112-71-0
1-Bromotetradecane

: 1219732-61-2
4-dodecyloxy-4'-hydroxybenzil

: 1219732-50-9
4-dodecyloxy-4'-(tetradecyloxy)benzyl

Conditions

Conditions	Yield
With potassium carbonate In N,N-dimethyl-formamide at 90℃;	99%

: 112-71-0
1-Bromotetradecane

: 136630-39-2
2,7-dibromo-9H-carbazole

: 1362213-92-0
2,7-dibromo-9-tetradecylcarbazole

Conditions

Conditions	Yield
Stage #1: 2,7-dibromo-9H-carbazole With sodium hydride In N,N-dimethyl-formamide; mineral oil for 0.5h; Inert atmosphere; Stage #2: 1-Bromotetradecane In N,N-dimethyl-formamide; mineral oil at 20℃; for 2h; Inert atmosphere;	99%

: 110-18-9
N,N,N,N,-tetramethylethylenediamine

: 112-71-0
1-Bromotetradecane

: 1335230-85-7
C20H45N2(1+)*Br(1-)

Conditions

Conditions	Yield
In acetone at 20℃; for 3h; Reflux;	99%
In acetone for 3h; Reflux;	99%
In acetonitrile at 40℃; for 72h;
In acetonitrile at 45℃; for 2h;

: 112-71-0
1-Bromotetradecane

: 54-11-5
nicotin

: C24H43N2(1+)

Conditions

Conditions	Yield
In acetonitrile Heating;	99%

: 112-71-0
1-Bromotetradecane

: 54-11-5
nicotin

: C24H43N2(1+)*Br(1-)

Conditions

Conditions	Yield
In acetonitrile for 24h; Reflux;	99%

: 112-71-0
1-Bromotetradecane

: 17345-77-6
1-bromo-3,4-dihydroxybenzene

: 881209-76-3
4-bromo-1,2-bis(tetradecyloxy)benzene

Conditions

Conditions	Yield
With potassium carbonate In acetonitrile for 48h; Reflux;	99%

: 112-71-0
1-Bromotetradecane

: 541-15-1
L-carnitine

: (4-tetradecyloxy-2-hydroxy-4-oxobutyl)trimethylammonium bromide

Conditions

Conditions	Yield
In acetonitrile at 80℃; for 24h;	99%

: 112-71-0
1-Bromotetradecane

: 40501-41-5
methyl 4'-hydroxy-4-biphenylcarboxylate

: 1439362-31-8
4'-tetradecyloxy-biphenyl-4-carboxylic acid methyl ester

Conditions

Conditions	Yield
Stage #1: methyl 4'-hydroxy-4-biphenylcarboxylate With potassium carbonate; caesium carbonate In acetone for 0.0833333h; Inert atmosphere; Stage #2: 1-Bromotetradecane In acetone for 72h; Inert atmosphere; Reflux;	98.9%

: 112-71-0
1-Bromotetradecane

: 708-06-5
2-hydroxynaphthalene-1-carbaldehyde

: 2-tetradecoxy-1-naphthaldehyde

Conditions

Conditions	Yield
With potassium carbonate In N,N-dimethyl-formamide for 12h; Williamson Ether Synthesis; Reflux;	98.41%

: 112-71-0
1-Bromotetradecane

: 108-98-5
thiophenol

: 94763-48-1
phenyl tetradecanyl sulfide

Conditions

Conditions	Yield
With n-butyllithium In tetrahydrofuran; hexane for 0.333333h; Ambient temperature;	98%
With sodium hydroxide In ethanol; N,N-dimethyl-formamide at 20℃;	97%
With tetra-(n-butyl)ammonium iodide; triethylamine In tetrahydrofuran for 6h;	90%

: 96-27-5
rac-3-sulfanylpropane-1,2-diol

: 112-71-0
1-Bromotetradecane

: 79768-75-5
rac-1-S-tetradecyl-1-thioglycerol

Conditions

Conditions	Yield
With potassium hydroxide In hexane for 48h; Ambient temperature;	98%
With potassium carbonate In water; acetone for 24h; Ambient temperature;

: 112-71-0
1-Bromotetradecane

: 86-74-8
9H-carbazole

: 20863-25-6
9-tetradecylcarbazole

Conditions

Conditions	Yield
With sodium hydride In tetrahydrofuran; N,N-dimethyl-formamide; mineral oil at 20℃; Inert atmosphere; Heating;	98%
With sodium hydride In tetrahydrofuran; N,N-dimethyl-formamide at 20℃; for 1h;	97%

: 107-03-9
1-thiopropane

: 112-71-0
1-Bromotetradecane

: propyl tetradecyl sulfide

Conditions

Conditions	Yield
With n-butyllithium In tetrahydrofuran; hexane for 0.333333h; Ambient temperature;	98%

: 112-71-0
1-Bromotetradecane

: 2917-26-2
16-mercaptohexadecanoate

: 1-Tetradecylsulfanyl-hexadecane

Conditions

Conditions	Yield
With n-butyllithium In tetrahydrofuran; hexane for 0.333333h; Ambient temperature;	98%

: 112-71-0
1-Bromotetradecane

: 38145-93-6
1,2:3,4-di-O-isopropylidene-D-mannitol

: 203244-51-3
1,2:3,4-di-O-isopropylidene-5,6-di-O-tetradecyl-D-mannitol

Conditions

Conditions	Yield
With potassium hydroxide In toluene for 3h; Heating;	98%
With sodium hydroxide; tetrabutylammomium bromide In water at 80℃; for 8h;	56%

: 1072-63-5
1-vinylimidazole

: 112-71-0
1-Bromotetradecane

: 888500-15-0
1-vinyl-3-tetradecyl-3H-imidazol-1-ium bromide

Conditions

Conditions	Yield
for 5h; Inert atmosphere; Reflux;	98%
In ethyl acetate for 24h; Reflux; Inert atmosphere;	95%
In methanol at 60℃; for 15h;
In acetonitrile Reflux;

: 112-71-0
1-Bromotetradecane

: 98-92-0
nicotinamide

: 5442-84-2
3-carbamoyl-1-tetradecylpyridinium bromide

Conditions

Conditions	Yield
In acetonitrile for 48h; Reflux;	98%

: 25018-67-1
1,2;4,5-di-O-isopropylidene-β-D-(-)-fructopyranose

: 112-71-0
1-Bromotetradecane

: 171081-78-0
3-O-Tetradecyl-1,2:4,5-di-O-isopropylidene-β-D-fructopyranose

Conditions

Conditions	Yield
With sodium hydroxide In dimethyl sulfoxide for 3h; Ambient temperature;	97%

: 616-47-7
1-methyl-1H-imidazole

: 112-71-0
1-Bromotetradecane

: 1‐tetradecyl‐3‐methylimidazolium bromide

Conditions

Conditions	Yield
In toluene at 80℃; for 24h;	97%
In acetonitrile for 6h; Heating;
at 90℃; for 48h;

: 112-71-0
1-Bromotetradecane

: 35214-35-8
9-imidazolylfluorene

: 1332836-47-1
1-(fluoren-9-yl)-3-tetradecylimidazol-3-ium bromide

Conditions

Conditions	Yield
In acetonitrile at 90℃; for 72h; Inert atmosphere;	97%

1-Bromotetradecane Specification

The IUPAC name of Tetradecane, 1-bromo- is 1-bromotetradecane. With the CAS registry number 112-71-0, it is also named as Myristyl bromide; 1-Tetradecyl bromide. The product's categories are alkyl bromides; monofunctional & alpha,omega-bifunctional alkanes; monofunctional alkanes. It is pale yellow liquid which is stable and incompatible with strong bases, strong oxidizing agents. In addition, this chemical can be obtained from tetradecyl alchohol by bromination.

The other characteristics of this product can be summarized as: (1)ACD/LogP: 4.34; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 4.34; (4)ACD/LogD (pH 7.4): 4.34; (5)ACD/BCF (pH 5.5): 1162.76; (6)ACD/BCF (pH 7.4): 1162.76; (7)ACD/KOC (pH 7.4): 5443.48; (8)#H bond acceptors: 0; (9)#H bond donors: 0; (10)#Freely Rotating Bonds: 5; (11)Index of Refraction: 1.449; (12)Molar Refractivity: 42.21 cm³; (13)Molar Volume: 157.2 cm³; (14)Surface Tension: 28.3 dyne/cm; (15)Enthalpy of Vaporization: 39.79 kJ/mol; (16)Vapour Pressure: 1.32 mmHg at 25°C; (17)Rotatable Bond Count: 12; (18)Exact Mass: 276.145264; (19)MonoIsotopic Mass: 276.145264; (20)Heavy Atom Count: 15.

Uses: Used in organic synthesis. For example: It can react with piperazine to get 1,4-ditetradecyl-piperazine. This reaction needs reagent K2CO3 and solvent acetonitrile at temperature of 100 - 110 °C. The reaction time is 1.5 hours. The yield is 84 %.

When you are using this chemical, please be cautious about it as the following:
It is irritating to eyes, respiratory system and skin, so people should avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. If you want to contact this product, you must wear suitable protective clothing.

People can use the following data to convert to the molecule structure.
1. SMILES: BrCCCCCCC;
2. InChI: InChI=1/C7H15Br/c1-2-3-4-5-6-7-8/h2-7H2,1H3.

Product Name

1-Bromotetradecane

Synthetic route

1-Bromotetradecane Specification

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