1-Diazo-2-naphthol-4-sulfonic acid supplier

Name
1-Diazo-2-naphthol-4-sulfonic acid
EINECS 212-958-9
CAS No. 887-76-3
Density 1.5366 (rough estimate)
Solubility water: 15.8 g/L (20 °C)
Melting Point 160 °C (dec.)(lit.)
Formula C₁₀H₆N₂O₄ S
Boiling Point 160oC
Molecular Weight 250.235
Flash Point 微溶于水，溶于碱。
Transport Information UN 2925 4.1/PG 2
Appearance brown adhering powder or paste
Safety 16-26-36/37/39-45-48
Risk Codes 5-11-34
Molecular Structure
Hazard Symbols F,C
Synonyms 4-Sulfo-2,1-naphthoquinone diazide;
PSA 120.37000
LogP 2.25176

Synthetic route

: 116-63-2
1-amino-2-naphthol-4-sulfonic acid

: 887-76-3
2-hydroxy-4-sulfo-naphthalene-1-diazonium-betaine

Conditions

Conditions	Yield
With copper(I) sulfate; water; copper(II) sulfate; sodium nitrite
With water; sodium chloride; sodium nitrite
With zinc nitrite das Zinksalz entsteht;

: 2-acetoxy-4-sulfo-naphthalene-1-diazonium-betaine

: 887-76-3
2-hydroxy-4-sulfo-naphthalene-1-diazonium-betaine

Conditions

Conditions	Yield
With water

salt of/the/ 1-amino-naphthol-(2)-sulfonic acid-(4): salt of/the/ 1-amino-naphthol-(2)-sulfonic acid-(4)

: 887-76-3
2-hydroxy-4-sulfo-naphthalene-1-diazonium-betaine

Conditions

Conditions	Yield
With zinc nitrite; sodium nitrite das Zinksalz entsteht;
With zinc nitrite das Zinksalz entsteht;
With mercury(II) nitrite das Quecksilbersalz entsteht;

: 116-63-2
1-amino-2-naphthol-4-sulfonic acid

: 7758-99-8
copper(II) sulfate

sodium nitrite: sodium nitrite

: 887-76-3
2-hydroxy-4-sulfo-naphthalene-1-diazonium-betaine

...Expand

: 116-63-2
1-amino-2-naphthol-4-sulfonic acid

zinc sulfate: zinc sulfate

sodium nitrite: sodium nitrite

: 887-76-3
2-hydroxy-4-sulfo-naphthalene-1-diazonium-betaine

...Expand

: 64-17-5
ethanol

: 887-76-3
2-hydroxy-4-sulfo-naphthalene-1-diazonium-betaine

: 6357-85-3
2-naphthol-4-sulfonic acid

: 887-76-3
2-hydroxy-4-sulfo-naphthalene-1-diazonium-betaine

: 887-77-4
1-hydroxy-4-sulfo-naphthalene-2-diazonium-betaine

: 3-hydroxy-4-(3-sulfo-inden-1-ylazo)-naphthalene-1-sulfonic acid

Conditions

Conditions	Yield
With hydrogenchloride; sodium hydroxide Irradiation.Ansaeuern mit wss.Salzsaeure;

: 887-76-3
2-hydroxy-4-sulfo-naphthalene-1-diazonium-betaine

: 3-hydroxy-4-(3-sulfo-inden-1-ylazo)-naphthalene-1-sulfonic acid

Conditions

Conditions	Yield
With hydrogenchloride; sodium hydroxide Irradiation.Ansaeuern mit wss.Salzsaeure;

: 887-76-3
2-hydroxy-4-sulfo-naphthalene-1-diazonium-betaine

: 6-chloro-2-hydroxy-4-sulfo-naphthalene-1-diazonium-betaine

Conditions

Conditions	Yield
With sulfuric acid under 5320 - 6080 Torr; bei der Chlorieren;
With chlorosulfonic acid under 5320 - 6080 Torr; bei der Chlorieren;
With chlorine at 70℃;
With chlorosulfonic acid under 5320 - 6080 Torr; bei der Chlorieren;
With sulfuric acid under 5320 - 6080 Torr; bei der Chlorieren;

: 887-76-3
2-hydroxy-4-sulfo-naphthalene-1-diazonium-betaine

: 6-bromo-2-hydroxy-4-sulfo-naphthalene-1-diazonium-betaine

Conditions

Conditions	Yield
With chlorosulfonic acid; bromine at 60 - 65℃;
With sulfuric acid; bromine; iodine at 70 - 75℃;

: 887-76-3
2-hydroxy-4-sulfo-naphthalene-1-diazonium-betaine

: 586387-97-5
2-hydroxy-6-nitro-4-sulfo-naphthalene-1-diazonium-betaine

Conditions

Conditions	Yield
With sulfuric acid; nitric acid at 0 - 5℃;

: 887-76-3
2-hydroxy-4-sulfo-naphthalene-1-diazonium-betaine

: 1-sulfo-indene-3-carboxylic acid ; sodium-salt

Conditions

Conditions	Yield
With hydrogenchloride Irradiation.mit Sonnenlicht;

: 887-76-3
2-hydroxy-4-sulfo-naphthalene-1-diazonium-betaine

: 135-19-3
β-naphthol

: 2538-79-6
Calcon

Conditions

Conditions	Yield
in alkal. Loesung;

: 887-76-3
2-hydroxy-4-sulfo-naphthalene-1-diazonium-betaine

NaOH/KOH: NaOH/KOH

sodium sulfide: sodium sulfide

: 6357-85-3
2-naphthol-4-sulfonic acid

...Expand

: 7790-94-5
chlorosulfonic acid

: 887-76-3
2-hydroxy-4-sulfo-naphthalene-1-diazonium-betaine

2-hydroxy-4.x-bis-chlorosulfonyl-naphthalenediazonium-(1)-betaine: 2-hydroxy-4.x-bis-chlorosulfonyl-naphthalenediazonium-(1)-betaine

: 887-76-3
2-hydroxy-4-sulfo-naphthalene-1-diazonium-betaine

aqueous sodium sulfite: aqueous sodium sulfite

2-hydroxy-naphthalene-disulfonic acid-(1.4): 2-hydroxy-naphthalene-disulfonic acid-(1.4)

Conditions

Conditions	Yield
Erhitzen des Reaktionsgemisches mit Kupfer(II)-sulfat und Kupfer; das Natrium-Salz reagiert;

: 887-76-3
2-hydroxy-4-sulfo-naphthalene-1-diazonium-betaine

HNO3+H2SO4: HNO3+H2SO4

: 586387-97-5
2-hydroxy-6-nitro-4-sulfo-naphthalene-1-diazonium-betaine

: 7647-01-0
hydrogenchloride

: 887-76-3
2-hydroxy-4-sulfo-naphthalene-1-diazonium-betaine

3-sulfo-indene-carboxylic acid-(1): 3-sulfo-indene-carboxylic acid-(1)

Conditions

Conditions	Yield
Sonnenlicht oder UV-Licht.Irradiation;

: 7790-94-5
chlorosulfonic acid

: 887-76-3
2-hydroxy-4-sulfo-naphthalene-1-diazonium-betaine

: 7782-50-5
chlorine

x-chloro-2-oxy-naphthalene-sulfonic acid-(4)-diazonium hydroxide-(1): x-chloro-2-oxy-naphthalene-sulfonic acid-(4)-diazonium hydroxide-(1)

...Expand

: 887-76-3
2-hydroxy-4-sulfo-naphthalene-1-diazonium-betaine

: 7664-93-9
sulfuric acid

: 7782-50-5
chlorine

x-chloro-2-oxy-naphthalene-sulfonic acid-(4)-diazonium hydroxide-(1): x-chloro-2-oxy-naphthalene-sulfonic acid-(4)-diazonium hydroxide-(1)

...Expand

1-Diazo-2-naphthol-4-sulfonic acid Specification

The 1-Diazo-2-naphthol-4-sulfonic acid, with the cas registry number 887-76-3, has the systematic name and IUPAC name(which is the same) of 4-diazonio-3-hydroxynaphthalene-1-sulfonate. This is a kind of yellow needle-like crystal, and is slightly soluble in water and soluble in alkali. Its product categories are including azo/diazo compounds; nitrogen compounds; organic building blocks.

The characteristics of this chemical are as follows: (1)#H bond acceptors: 6 ; (2)#H bond donors: 2 ; (3)#Freely Rotating Bonds: 3 ; (4)Polar Surface Area: 100.13; (5)Tautomer Count: 3; (6)Exact Mass: 250.004827; (7)MonoIsotopic Mass: 250.004827; (8)Topological Polar Surface Area: 114; (9)Heavy Atom Count: 17; (10)Formal Charge: 0; (11)Complexity: 422.

The production method is as below: Firstly, dissolve the 1-amino-2-naphthol-4-sulfonic acid with caustic soda and then make the suspension with acid; Secondly, diazotize the sodium nitrite and add little copper-bath; Thirdly, diazo oxide will separate out from solution with the form of free acid or sodium salt; Lastly, go through the process of filtering, acid with vitriol to get the products.

As to its usage, it is widely applied in many ways. It could be used as the intermediate of acidic dye and mordant dyes; It could be used in synthysis of mordant dyes, azo dyes and so on.

While dealing with this chemical, you should be very cautious. This is a kind of corrosive chemicalc which may destroy living tissue on contact. Then it is highly flammable, for it may catch fire in contact with air, only needing brief contact with an ignition source, with a very low flash point or evolve highly flammable gases in contact with water. Besides, it could cause burns. Therefore, you should take the following instructions. Wear suitable protective clothing, gloves and eye/face protection, and if in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice, and if in case of accident or if you feel unwell seek medical advice immediately (show the label where possible). Then, keep away from sources of ignition - No smoking, and then keep wet with ... (appropriate material to be specified by the manufacturer).

Additionally, the following datas could be converted into the molecular structure:
(1)SMILES:[O-]S(=O)(=O)c2c1ccccc1c([N+]#N)c(O)c2
(2)InChI:InChI=1/C10H6N2O4S/c11-12-10-7-4-2-1-3-6(7)9(5-8(10)13)17(14,15)16/h1-5H,(H-,13,14,15,16)
(3)InChIKey:QHIBNGIZPPHJAT-UHFFFAOYAY

Product Name

1-Diazo-2-naphthol-4-sulfonic acid

Synthetic route

1-Diazo-2-naphthol-4-sulfonic acid Specification

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