• Name

  1-Tetradecanol

• EINECS 204-000-3
• CAS No. 112-72-1
• Article Data102
• CAS DataBase
• Density 0.833 g/cm³
• Solubility insoluble in water
• Melting Point 35-39 °C(lit.)
• Formula C₁₄H₃₀O
• Boiling Point 263.2 °C at 760 mmHg
• Molecular Weight 214.392
• Flash Point 125.9 °C
• Transport Information
• Appearance white low melting solid or flakes
• Safety 24/25
• Risk Codes 38
• Molecular Structure
• Hazard Symbols Xi
• Synonyms Tetradecyl alcohol;n-Tetradecan-1-ol;n-Tetradecanol;n-Tetradecyl alcohol;Tetradecanol;Tetradecanol(7CI);1-Hydroxytetradecane;1-Tetradecyl alcohol;Adol 18;Alfol 14;Conol1495;Hinol 14SS;Kalcohl 40;Kalcohl 4098;Kalcol 4098;Lanette 14;Lanette K;Lanette Wax KS;Lorol C 14;Loxanol V;Myristic alcohol;Myristyl alcohol;NSC8549;Nacol 14-95;
• PSA 20.23000
• LogP 4.67980

Synthetic route

124-10-7

methyl myristoate

112-72-1

1-Tetradecanol

Conditions

Conditions	Yield
With C32H36ClNO2P2Ru; potassium tert-butylate; hydrogen In neat (no solvent) at 120℃; under 38002.6 Torr; for 20h; Autoclave; Green chemistry;	99%
With [RuCl2(2-(diphenylphosphino)-N-((6-((diphenylphosphino)methyl)pyridin-2-yl)methyl)ethan-1-amine)]; potassium tert-butylate; hydrogen In tetrahydrofuran at 80℃; under 38002.6 Torr; for 5h; Catalytic behavior; Autoclave;	97%
Stage #1: methyl myristoate With phenylsilane; fac-[Mn-(xantphos)(CO)3Br] at 120℃; for 12h; Inert atmosphere; Stage #2: With water; sodium hydroxide In methanol at 20℃; Inert atmosphere;	96%

Tetradecyloxymethyl-benzene

112-72-1

1-Tetradecanol

Conditions

Conditions	Yield
With 18-crown-6 ether; tert-butylamine; tert-butyl alcohol; potassium In tetrahydrofuran at 20℃; for 2h;	98%

144708-82-7

1-Methoxymethoxy-tetradecane

112-72-1

1-Tetradecanol

Conditions

Conditions	Yield
With methanol; DOWEX-50W-X2 for 30h; Heating;	96%

108-88-3

toluene

Tetradecyloxymethyl-benzene

A

112-72-1

1-Tetradecanol

B

620-47-3

1-methyl-3-(phenylmethyl)-benzene

C

620-83-7

1-methyl-4-(phenylmethyl)benzene

D

713-36-0

2-benzyltoluene

Conditions

Conditions	Yield
With boron trifluoride diethyl etherate at 120℃; for 2h;	A 96% B n/a C n/a D n/a

...Expand

77774-34-6

tetradecyl tert-butyldimethylsilyl ether

112-72-1

1-Tetradecanol

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In methanol; dichloromethane at 20 - 25℃; for 0.333333h; Flow reactor;	96%

544-63-8

n-tetradecanoic acid

112-72-1

1-Tetradecanol

Conditions

Conditions	Yield
With zirconium(IV) borohydride In tetrahydrofuran at 25℃; for 1h; Reduction;	95%
With sodium tetrahydroborate; benzene-1,2-diol; trifluoroacetic acid In tetrahydrofuran at 25℃; for 4h;	91%
With hydrogen In neat (no solvent) at 160℃; under 37503.8 Torr; for 24h;	88%

124-06-1

Ethyl myristate

112-72-1

1-Tetradecanol

Conditions

Conditions	Yield
With C30H34Cl2N2P2Ru; potassium methanolate; hydrogen In tetrahydrofuran at 100℃; under 38002.6 - 76005.1 Torr; for 15h; Glovebox; Autoclave;	94%
With kieselguhr; copper at 350℃; under 73550.8 - 147102 Torr; Hydrogenation;
With lithium aluminium tetrahydride

146404-39-9

C21H38N2O2S

112-72-1

1-Tetradecanol

Conditions

Conditions	Yield
With potassium hydroxide; ethanol; oxygen Heating;	91%

14980-92-8

ethyl 2-bromomyristate

112-72-1

1-Tetradecanol

Conditions

Conditions	Yield
With sodium tetrahydroborate at 65℃; for 24h;	90%

4,4,5,5-tetramethyl-2-(tetradecyloxy)-1,3,2-dioxaborolane

112-72-1

1-Tetradecanol

Conditions

Conditions	Yield
With water; silica gel In methanol at 60℃; Inert atmosphere;	89%

629-63-0

myristonitrile

A

2016-42-4

tetradecylamine

B

112-72-1

1-Tetradecanol

Conditions

Conditions	Yield
With samarium diiodide; water; triethylamine; diisopropylamine In tetrahydrofuran at 20℃; for 2h; Inert atmosphere;	A 86% B 13%

555-45-3

tritetradecanoylglycerol

112-72-1

1-Tetradecanol

Conditions

Conditions	Yield
With 5 wt% Re/TiO2; hydrogen In neat (no solvent) at 230℃; under 37503.8 Torr; for 24h; Autoclave;	86%

110-27-0

Tetradecanoic acid 1-methylethyl ester

112-72-1

1-Tetradecanol

Conditions

Conditions	Yield
Stage #1: Tetradecanoic acid 1-methylethyl ester With triethyl borane; sodium methylate In tetrahydrofuran; diethyl ether at 20℃; for 6h; Inert atmosphere; Stage #2: With sodium hydroxide In tetrahydrofuran; methanol; diethyl ether at 20℃; for 2h; Reagent/catalyst; Solvent; Time;	84%
With diphenylsilane; tris(triphenylphosphine)rhodium(I) chloride In tetrahydrofuran at 50℃; for 24h;	90 % Spectr.

112-71-0

1-Bromotetradecane

A

112-72-1

1-Tetradecanol

B

1-Tridecyloxymethoxy-tetradecane

Conditions

Conditions	Yield
With potassium superoxide; tetraethylammonium bromide In N,N-dimethyl-formamide at 5 - 10℃; for 3h;	A 2% B 80%

123-75-1

pyrrolidine

629-63-0

myristonitrile

A

74673-29-3

1-tetradecylpyrrolidine

B

2016-42-4

tetradecylamine

C

112-72-1

1-Tetradecanol

Conditions

Conditions	Yield
With samarium diiodide; water; triethylamine In tetrahydrofuran at 20℃; for 0.0833333h; Inert atmosphere;	A 24% B 71% C 4.4%

...Expand

130340-56-6

2-(3-carboxypropyl)-5-(12-hydroxydodecyl)thiophene

A

112-70-9

tridecan-1-ol

B

112-72-1

1-Tetradecanol

C

36653-82-4

1-Hexadecanol

D

62643-46-3

20-hydroxyeicosanoic acid

Conditions

Conditions	Yield
With Raney nickel W-2 In ethanol for 2h; Heating; Further byproducts given;	A 3.5% B 6% C 12.6% D 65%

...Expand

130340-56-6

2-(3-carboxypropyl)-5-(12-hydroxydodecyl)thiophene

A

112-70-9

tridecan-1-ol

B

112-72-1

1-Tetradecanol

C

117197-09-8

tridecyl hexanoate

D

62643-46-3

20-hydroxyeicosanoic acid

Conditions

Conditions	Yield
With Raney nickel W-2 In ethanol for 2h; Heating; Further byproducts given;	A 3.5% B 6% C 0.5% D 65%

...Expand

130340-56-6

2-(3-carboxypropyl)-5-(12-hydroxydodecyl)thiophene

A

112-70-9

tridecan-1-ol

B

112-72-1

1-Tetradecanol

C

71801-23-5

tetradecyl hexanoate

D

62643-46-3

20-hydroxyeicosanoic acid

Conditions

Conditions	Yield
With Raney nickel W-2 In ethanol for 2h; Heating; Further byproducts given;	A 3.5% B 6% C 0.6% D 65%

...Expand

130340-56-6

2-(3-carboxypropyl)-5-(12-hydroxydodecyl)thiophene

A

112-70-9

tridecan-1-ol

B

112-72-1

1-Tetradecanol

C

62643-46-3

20-hydroxyeicosanoic acid

D

130340-57-7

n-hexanoic acid 1-hexadecyl

Conditions

Conditions	Yield
With Raney nickel W-2 In ethanol for 2h; Heating; Further byproducts given;	A 3.5% B 6% C 65% D 0.1%

...Expand

130340-56-6

2-(3-carboxypropyl)-5-(12-hydroxydodecyl)thiophene

A

112-70-9

tridecan-1-ol

B

112-72-1

1-Tetradecanol

C

62643-46-3

20-hydroxyeicosanoic acid

D

14331-11-4

hexadecyl hexanoate

Conditions

Conditions	Yield
With Raney nickel W-2 In ethanol for 2h; Heating; Further byproducts given;	A 3.5% B 6% C 65% D 0.25%

...Expand

130340-56-6

2-(3-carboxypropyl)-5-(12-hydroxydodecyl)thiophene

A

112-70-9

tridecan-1-ol

B

112-72-1

1-Tetradecanol

C

62643-46-3

20-hydroxyeicosanoic acid

D

29710-33-6

tetradecyl heptanoate

Conditions

Conditions	Yield
With Raney nickel W-2 In ethanol for 2h; Heating; Further byproducts given;	A 3.5% B 6% C 65% D 0.4%

...Expand

124-25-4

myristylaldehyde

112-72-1

1-Tetradecanol

Conditions

Conditions	Yield
With Au0998Ag0002; hydrogen; triethylamine at 90℃; under 6080.41 Torr; for 24h; chemoselective reaction;	63%
With acetic acid; zinc
With ethanol; sodium

4286-55-9

1-bromo-6-hexanol

trioctylaluminum

trioctylaluminum

112-72-1

1-Tetradecanol

Conditions

Conditions	Yield
With potassium fluoride; benzylnixantphos; iron(II) acetate In tetrahydrofuran at 0 - 40℃; for 44h; Negishi Coupling; Inert atmosphere;	60%

629-63-0

myristonitrile

112-72-1

1-Tetradecanol

Conditions

Conditions	Yield
With samarium diiodide; water; triethylamine In tetrahydrofuran at 20℃; for 2h; Inert atmosphere;	55%

2009-83-8

6-chloro-1-hexanol

1070-00-4

trioctylaluminum

112-72-1

1-Tetradecanol

Conditions

Conditions	Yield
With potassium fluoride; benzylnixantphos; iron(II) acetate In tetrahydrofuran at 0 - 40℃; for 44h; Negishi Coupling; Inert atmosphere;	38%

41320-43-8

S-methyl O-tetradecyl dithiocarbonate

A

629-59-4

tetradecane

B

112-72-1

1-Tetradecanol

Conditions

Conditions	Yield
With triethyl borane; tri-n-butyl-tin hydride In hexane; benzene at 20℃; for 0.333333h;	A 18% B 30%

10374-74-0

tetradec-7-ene

A

629-59-4

tetradecane

B

112-72-1

1-Tetradecanol

Conditions

Conditions	Yield
With tert.-butylhydroperoxide; zirconocene dichloride; sodium bis(2-methoxyethoxy)aluminium dihydride 1.) THF, 72 h, 40 deg C, 2.) ClCH2CH2Cl, 1 h, room temp.; Yield given. Multistep reaction;	A 10% B n/a

1120-36-1

1-tetradecene

112-72-1

1-Tetradecanol

Conditions

Conditions	Yield
With 3,6,9-trioxaundecane; diborane und anschliessend mit wss.Wasserstoffperoxid und wss.Natronlauge;

62936-14-5

(E)-5-tetradecenol

112-72-1

1-Tetradecanol

Conditions

Conditions	Yield
Hydrogenation;

110-36-1

n-butyl myristate

112-72-1

1-Tetradecanol

Conditions

Conditions	Yield
With sodium; butan-1-ol

1-TETRADECANOL Chemical Properties

Product Name: 1-Tetradecanol
Synonyms: Dytol R-52;dytolr-52;Dehydag wax 14;Emery 3334;Epal 14 ;Alfol 14;alfol14;Cachalot M-43 NF;
The Molecular formula of 1-TETRADECANOL(112-72-1): C₁₄H₃₀O
The Molecular Weight of 1-TETRADECANOL(112-72-1): 214.39
Molecular Structure : 
EINECS: 204-000-3
Melting point: 35-39 °C(lit.)
Boiling point: 289 °C(lit.)
Flash point: >230 °F
density: 0.823 g/mL at 25 °C(lit.)
vapor density: 7.4 (vs air)
storage temp.:-20°C
Water Solubility: insoluble

1-TETRADECANOL Uses

1-TETRADECANOL Toxicity Data With Reference

1-TETRADECANOL Consensus Reports

1-TETRADECANOL Safety Profile

Questionable carcinogen with experimental tumorigenic data. A human skin irritant. Combustible when exposed to heat or flame; can react with oxidizing materials. To fight fire, use CO₂, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALCOHOL, DENATURED; ALCOHOLS, C6-12; ALCOHOLS, C9-11; ALCOHOLS, C12-13, ETHOXYLATED; ALCOHOLS, C12-15, ETHOXYLATED; ALCOHOLS, C12-16, ETHOXYLATED; ALCOHOLS, C14-15, ETHOXYLATED; ALCOHOLS, C16-18, ETHOXYLATED; ALCOHOLS, C8-10, ETHOXYLATED PROPOXYLATED; ALCOHOLS, C12-15, ETHOXYLATED PROPOXYLATED; ALCOHOLS, N.O.S. and TETRADECANOL, mixed isomers.
The Hazard Codes of 1-TETRADECANOL(112-72-1):  Xi
The Risk Statements information of 1-TETRADECANOL(112-72-1):
38:  Irritating to the skin 
The Safety Statements information of 1-TETRADECANOL(112-72-1):
24/25:  Avoid contact with skin and eyes