1-Thio-β-D-glucose sodium salt supplier

Name
1-THIO-BETA-D-GLUCOSE SODIUM SALT
EINECS 234-200-6
CAS No. 10593-29-0
Article Data3
CAS DataBase
Density
Solubility Soluble in water
Melting Point 173 °C
Formula C₆H₁₂NaO₅S
Boiling Point 432.6 °C at 760 mmHg
Molecular Weight 218.206
Flash Point 215.5 °C
Transport Information
Appearance White to off-white solid
Safety 6-24/25
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms Glucopyranose,1-thio-, monosodium salt, b-D- (8CI);b-D-Glucopyranose,1-thio-, monosodium salt (9CI);1-Thio-b-D-glucopyranose sodium salt;Thioglucose sodium salt;
PSA 90.15000
LogP -2.66680

Synthetic route

: 19879-84-6
tetraacetyl thioglucose

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

Conditions

Conditions	Yield
With sodium methylate In methanol for 0.25h; Ambient temperature;

: 6806-56-0, 13639-50-4, 51898-27-2, 62860-10-0, 63783-77-7, 92217-67-9, 92217-68-0, 130796-15-5
O2,O3,O4,O6,S-Pentaacetyl-1-thio-β-D-glucopyranose

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

Conditions

Conditions	Yield
With sodium methylate In methanol at 0 - 20℃;

: 50-99-7
D-glucose

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1.1: 2-chloro-1,3-dimethylimidazolinium chloride; triethylamine / water-d2; acetonitrile / 0.05 h / 0 °C 1.2: 1.5 h / 0 °C 2.1: sodiumsulfide nonahydrate / water-d2 / 1 h / 20 °C View Scheme

: C6H11O8S2(1-)*Na(1+)

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

Conditions

Conditions	Yield
With sodiumsulfide nonahydrate In water-d2 at 20℃; for 1h; Solvent;

: 542-69-8
1-iodo-butane

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

: 85618-17-3
n-butyl 1-thio-β-D-glucopyranoside

Conditions

Conditions	Yield
In methanol at 20℃; for 1h;	100%

: 16258-05-2
D,L-2-amino-5-hexenoic acid

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

: 1195070-24-6
2-amino-6-(1-thio-β-D-glucopyranosyl)hexanoic acid

Conditions

Conditions	Yield
With 2,2’-azobis[2-(2-imidazolin-2-yl)propane]dihydrochloride at 20℃; pH=4; aq. acetate buffer; regioselective reaction;	98%

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

: bis(2-phenylpyridyl)[5-pentafluorophenyldipyrrianto]iridium(III)

: bis(2-phenylpyridyl){5-[2,3,5,6-tetrafluoro-4-(1'-thio-β-D-glucosyl)phenyl]dipyrrinato}iridium(III)

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 20℃; for 0.333333h;	98%

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

: 2,6,7-trimethyl-3-chloronaphthazarin

: 5,8-dihydroxy-3-(β-D-glucopyranosyl-1-thio)-2,6,7-trimethylnaphthalene-1,4-dione

Conditions

Conditions	Yield
In methanol; acetone at 20℃; for 5h;	96%

: 1454932-56-9
C14H13ClO4

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

: 5,8-dihydroxy-3-(β-D-glucopyranosyl-1-thio)-6,7-dimethyl-2-ethylnaphthalene-1,4-dione

Conditions

Conditions	Yield
In methanol; acetone at 20℃; for 5h;	96%

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

: 16817-38-2
(4S)-2,2-dioxo-1,2,3-oxathiazolidinone-4-carboxylic acid

: (R)-2-Sulfoamino-3-((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-ylsulfanyl)-propionic acid

Conditions

Conditions	Yield
With sodium hydrogencarbonate In water at 20℃; for 4h;	95%
With sodium hydrogencarbonate at 20℃; for 4h;

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

: 2,3-dichloro-5,8-dihydroxy-6,7-dimethylnaphthalene-1,4-dione

: 2,3-di(β-D-glucopyranosyl-1-thio)-5,8-dihydroxy-6,7-dimethylnaphthalene-1,4-dione

Conditions

Conditions	Yield
In methanol; acetone at 20℃; for 18h;	95%

: 36528-53-7
2,3-dichloro-5,8-dimethoxynaphthalene-1,4-dione

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

: 2,3-di(β-D-glucopyranosyl-1-thio)-5,8-dimethoxynaphthalene-1,4-dione

Conditions

Conditions	Yield
In methanol; acetone at 20℃; for 1.5h;	94%

: 117-80-6
2,3-Dichloro-1,4-naphthoquinone

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

: 2,3-di(β-D-glucopyranosyl-1-thio)naphthalene-1,4-dione

Conditions

Conditions	Yield
In methanol; acetone at 20℃; for 1.5h;	93%

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

: 74-88-4
methyl iodide

: 30760-09-9
methyl 1-deoxy-1-thio-β-D-glucopyranoside

Conditions

Conditions	Yield
In methanol	91%

: 8-(4-fluoro-3-nitrophenyl)-4,4-difluoro-4-bora-3a,4a-diaza-s-indacene

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

: 8-[3-nitro-4-(1'-thio-β-D-glucosyl)phenyl]-4,4-difluoro-4-bora-3a,4a-diaza-s-indacene

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 20℃; for 0.25h;	91%
In N,N-dimethyl-formamide at 20℃; for 0.25h;	91%

: C25H38N4O6

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

: C49H86N4O26S4

Conditions

Conditions	Yield
With hydrogenchloride; 2,2-dimethoxy-2-phenylacetophenone In water at 20℃; UV-irradiation;	90%

: C25H42N4O6

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

: C37H66N4O16S2

Conditions

Conditions	Yield
With hydrogenchloride; 2,2-dimethoxy-2-phenylacetophenone In water at 20℃; UV-irradiation;	90%

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

: [5-(4-fluoro-3-nitrophenyl)dipyrrinato]bis(2-phenylpyridyl)iridium(III)

: C43H36IrN5O7S

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 20℃; for 0.333333h;	90%

: 2,3,6,7-tetrachloro-5,8-dimethoxynaphthalene-1,4-dione

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

: 6,7-dichloro-2,3-di(β-D-glucopyranosyl-1-thio)-5,8-dimethoxynaphthalene-1,4-dione

Conditions

Conditions	Yield
In methanol; acetone at 20℃; for 1.5h;	89%

: 8-(2,3,4,5,6-pentafluorophenyl)-4,4-difluoro-4-bora-3a,4a-diaza-s-indacene

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

: 8-[2,3,5,6-tetrafluoro-4-(1'-thio-β-D-glucosyl)phenyl]-4,4-difluoro-4-bora-3a,4a-diaza-s-indacene

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 20℃;	88%
In N,N-dimethyl-formamide at 20℃; for 0.25h;	88%

: 3383-21-9
3,5-di-tert-butyl-o-benzoquinone

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

: (2S,3R,4S,5S,6R)-2-(4,6-Di-tert-butyl-2,3-dihydroxy-phenylsulfanyl)-6-hydroxymethyl-tetrahydro-pyran-3,4,5-triol

Conditions

Conditions	Yield
In water; acetic acid for 4h;	87%

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

: 27826-82-0
ditetradecyl maleate

: 101009-69-2
ditetradecyl (R,S)-2-(β-D-glucopyranosylthio)succinate

Conditions

Conditions	Yield
With acetic acid In isopropyl alcohol at 55℃; for 1h; pH=8;	85%

: C44H34F10N4O4

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

: 5,15-bis-(3-methoxy-1,1-dimethyl-3-oxopropyl)-10,20-bis-[4-(1’-thio-β-D-glucosyl)-2,3,5,6-tetrafluorophenyl]-calix[4]phyrin(1.1.1.1)

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 20℃; for 1h; Inert atmosphere; Darkness;	85%

: 2-chloro-5,8-dihydroxy-3-methoxy-6,7-dimethylnaphthalene-1,4-dione

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

A: 2,3-di(β-D-glucopyranosyl-1-thio)-5,8-dihydroxy-6,7-dimethylnaphthalene-1,4-dione

B: (2R,3S,4S,4aR,12aS)-2-hydroxymethyl-3,4,7,10-tetrahydroxy-8,9-dimethyl-3,4,4a,12a-tetrahydro-2Hnaphtho[2,3-b]pyrano[2,3-e][1,4]-oxathiine-6,11-dione

C: 2-(β-D-glucopyranosyl-1-thio)-5,8-dihydroxy-3-methoxy-6,7-dimethylnaphthalene-1,4-dione

Conditions

Conditions	Yield
In methanol; acetone at 20℃; for 1.5h;	A 5% B 5.5% C 84%

...Expand

: C79H102BF2N15O13S2

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

: C85H114BF2N15O18S3

Conditions

Conditions	Yield
With triethylamine In dimethyl sulfoxide at 20℃; for 0.5h; Darkness;	83%

C43H30F10N4O4: C43H30F10N4O4

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

: 5-(3-methoxy-1,1-dimethyl-3-oxopropyl)-15-(5-[4,4-dimethyldihydrofuran-2(3H)-one]-yl)-10,20-bis-[4-(1’-thio-β-D-glucosyl)-2,3,5,6-tetrafluorophenyl]-calix[4]phyrin(1.1.1.1)

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 20℃; for 1h; Inert atmosphere; Darkness;	83%

: 13965-31-6
dichloro(2,2'-bipyridine)platinum(II)

: 7732-18-5
water

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

: [Pt(H4tg-κS)2(2,2'-bipyridyl)] dihydrate

Conditions

Conditions	Yield
at 60℃; for 1h;	81%

...Expand

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

: 1-[(triisopropylsilyl)ethynyl]-1,2-benziodoxol-3(1H)-one

: (2R,3S,4S,5R,6S)-2-(hydroxymethyl)-6-(((trimethylsilyl)ethynyl)thio)tetrahydro-2H-pyran-3,4,5-triol

Conditions

Conditions	Yield
Stage #1: sodium 1-thio-β-D-glucopyranoside With N,N,N',N'-tetramethylguanidine In tetrahydrofuran at 24℃; for 0.0833333h; Stage #2: 1-[(triisopropylsilyl)ethynyl]-1,2-benziodoxol-3(1H)-one In tetrahydrofuran at 24℃; for 0.0833333h;	81%

: C27H42N4O6

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

: C47H82N4O26S4

Conditions

Conditions	Yield
With hydrogenchloride; 2,2-dimethoxy-2-phenylacetophenone In water at 20℃; UV-irradiation;	81%

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

: 30754-23-5
heptakis(6-deoxy-6-iodo)cyclomaltoheptaose

: heptakis(6-S-β-D-glucopyranosyl-6-thio)cyclomaltoheptaose

Conditions

Conditions	Yield
With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone at 70℃; for 7h;	80%

: 51783-57-4
3-chloro-2,5,8-trimethoxynaphthalene-1,4-dione

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

: 3-(β-D-glucopyranosyl-1-thio)-2,5,8-trimethoxynaphthalene-1,4-dione

Conditions

Conditions	Yield
In methanol; acetone at 20℃; for 0.6h;	80%

: 15012-66-5
2-chloro-5,8-dihydroxy-3-methoxynaphthalene-1,4-dione

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

: 2-(β-D-glucopyranosyl-1-thio)-5,8-dihydroxy-3-methoxynaphthalene-1,4-dione

Conditions

Conditions	Yield
In methanol; acetone at 20℃; for 1.5h;	80%

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

: meso-hexakis(pentafluorophenyl)[26]hexaphyrin

: meso-5,10,15,20,25,30-hexakis-[4-(1’-thio-β-D-glucosyl)-2,3,5,6-tetrafluorophenyl]-[28]hexaphyrin

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 20℃; Inert atmosphere; Darkness;	78%

: 10593-29-0
sodium 1-thio-β-D-glucopyranoside

: 81847-18-9
1,6,19,24-Tetraoxa-2,5,20,23-tetraoxocyclohexatriconta-3,21-diene

: (R,S)-3,21(22)-bis(β-D-glucopyranosylthio)-1,6,19,24-tetraoxacyclohexatriacontan-2,5,20,23-tetrone

Conditions

Conditions	Yield
With acetic acid In isopropyl alcohol at 50℃; for 3h; pH=8;	77%

1-Thio-β-D-glucose sodium salt Chemical Properties

IUPAC Name: Sodium (2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxane-2-thiolate
Systematic of 1-Thio-β-D-glucose sodium salt (CAS NO.10593-29-0): EINECS 234-200-6 ; Sodium glucopyranosyl sulphide
CAS NO: 10593-29-0
Molecular Formula of 1-Thio-β-D-glucose sodium salt (CAS NO.10593-29-0): C₆H₁₁NaO₅S
Molecular Weight: 218.2033
Molecular Structure:

Melting Point: 173 °C
H bond acceptors: 5
H bond donors: 4
Freely Rotating Bonds: 6
Polar Surface Area: 84.95 Å²
Flash Point of 1-Thio-β-D-glucose sodium salt (CAS NO.10593-29-0): 215.5 °C
Enthalpy of Vaporization: 79.48 kJ/mol
Boiling Point: 432.6 °C at 760 mmHg
Vapour Pressure: 2.66E-09 mmHg at 25°C

1-Thio-β-D-glucose sodium salt Safety Profile

Safety Statements: 6
S6: Keep under ... (there follows the name of an inert gas).
WGK Germany: 3

Product Name

1-THIO-BETA-D-GLUCOSE SODIUM SALT

Synthetic route

1-Thio-β-D-glucose sodium salt Chemical Properties

1-Thio-β-D-glucose sodium salt Safety Profile

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