1-bromohexadecane supplier

Name
1-bromohexadecane
EINECS 204-008-7
CAS No. 112-82-3
Article Data36
CAS DataBase
Density 0.999 g/cm³
Solubility insoluble in water
Melting Point 16-18 °C(lit.)
Formula C₁₆H₃₃Br
Boiling Point 335.5 °C at 760 mmHg
Molecular Weight 305.342
Flash Point 139.8 °C
Transport Information
Appearance colourless to yellow liquid or solid
Safety 26-36
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms 1-Hexadecyl bromide;Cetyl bromide;Hexadecyl bromide;NSC 4193;Palmitylbromide;n-Hexadecyl bromide;
PSA 0.00000
LogP 6.86260

Synthetic route

: 36653-82-4
1-Hexadecanol

: 112-82-3
hexadecanyl bromide

Conditions

Conditions	Yield
With ethyl 2,2-dibromoacetoacetate; triphenylphosphine In dichloromethane at 20℃; for 0.25h;	99%
With hydrogen bromide at 100℃;	91%
With hydrogen bromide; cetyltrimethylammonim bromide for 2h; Irradiation;	88%

: 4860-03-1
1-Chlorohexadecan

: 112-82-3
hexadecanyl bromide

Conditions

Conditions	Yield
With sodium bromide; 1,2-dibromomethane In N,N-dimethyl-formamide at 100℃; for 6h; different amounts of NaBr; further temperatures;	99%

: 3-<(hexadecyloxy)sulfonyl>-N,N,N-trimethylpropanaminium fluorofulfate

: 112-82-3
hexadecanyl bromide

Conditions

Conditions	Yield
With sodium bromide In water; benzene at 25℃; for 48h;	95%

: 52756-05-5
N-hexadecyl-N'-tosylhydrazine

A: 63758-87-2
1,2-dibromohexadecane

B: 1950-69-2
toluene-p-sulfonyl bromide

C: 112-82-3
hexadecanyl bromide

Conditions

Conditions	Yield
With bromine In chloroform for 2.5h; Ambient temperature;	A 9 % Chromat. B 93% C 55 % Chromat.

...Expand

: 4-Dimethylamino-butane-1-sulfonic acid hexadecyl ester; hydrobromide

: 112-82-3
hexadecanyl bromide

Conditions

Conditions	Yield
In toluene at 110℃; for 8h;	92%

: hexadecyl <2>betylate fluorosulfate

: 112-82-3
hexadecanyl bromide

Conditions

Conditions	Yield
With potassium bromide In water at 25℃; for 5h;	90%
With potassium bromide In water

: hexadecyl 2-(2-hydroxyethylthio)ethanesulfonate

: 112-82-3
hexadecanyl bromide

Conditions

Conditions	Yield
With potassium bromide In N,N-dimethyl-formamide at 85℃; for 4h;	90%

: 66143-65-5
3-Dimethylamino-propane-1-sulfonic acid hexadecyl ester; hydrobromide

: 112-82-3
hexadecanyl bromide

Conditions

Conditions	Yield
In toluene at 110℃; for 2h;	70%

: 146404-40-2
1-tosyl-1-hexadecylhydrazine

A: 1950-69-2
toluene-p-sulfonyl bromide

B: 112-82-3
hexadecanyl bromide

Conditions

Conditions	Yield
With N-Bromosuccinimide In tetrahydrofuran for 16h; Ambient temperature; Irradiation;	A n/a B 68%

: 7307-53-1
hexadecyl methyl ether

: 112-82-3
hexadecanyl bromide

Conditions

Conditions	Yield
With hydrogen bromide; cetyltributylphosphonium bromide

: 58587-19-2
1-(2-tetrahydropyranyloxy)hexadecane

: 112-82-3
hexadecanyl bromide

Conditions

Conditions	Yield
With triphenylphosphine dibromide 1:1 addition complex In dichloromethane Ambient temperature;

: 83486-05-9
C22H38Br2Te

A: 32294-60-3
diphenyl ditelluride

B: 112-82-3
hexadecanyl bromide

Conditions

Conditions	Yield
With sodium bromide In N,N-dimethyl-formamide at 70℃; Yield given;

: 36653-82-4
1-Hexadecanol

bromophosphorus: bromophosphorus

: 112-82-3
hexadecanyl bromide

stearic acid cetyl ester: stearic acid cetyl ester

: 112-82-3
hexadecanyl bromide

Conditions

Conditions	Yield
With hydrogen bromide at 150℃;

: 1190-63-2
hexadecyl stearate

: 10035-10-6, 12258-64-9
hydrogen bromide

: 112-82-3
hexadecanyl bromide

Conditions

Conditions	Yield
at 160℃;

: 20779-14-0
methanesulfonic acid hexadecyl ester

: 112-82-3
hexadecanyl bromide

Conditions

Conditions	Yield
With sodium bromide

: 143-27-1
hexadecylamine

: 112-82-3
hexadecanyl bromide

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 2: 1.) base, 2.) O-(2,4-dinitrophenyl)hydroxylamine 3: 68 percent / NBS / tetrahydrofuran / 16 h / Ambient temperature; Irradiation View Scheme

: 18049-99-5
N-hexadecyl-p-toluenesulfonamide

: 112-82-3
hexadecanyl bromide

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 1.) base, 2.) O-(2,4-dinitrophenyl)hydroxylamine 2: 68 percent / NBS / tetrahydrofuran / 16 h / Ambient temperature; Irradiation View Scheme

: 36653-82-4
1-Hexadecanol

A: 112-82-3
hexadecanyl bromide

B sodium-compound of (+-)-2-oxo-tetrahydro-furan-3-carboxylic acid ethyl ester: sodium-compound of (+-)-2-oxo-tetrahydro-furan-3-carboxylic acid ethyl ester

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: 87 percent / Et3N / CH2Cl2 / 0 - 4 °C 2: 91 percent / CH2Cl2 / 1 h / 0 °C 3: 95 percent / NaBr / benzene; H2O / 48 h / 25 °C View Scheme
Multi-step reaction with 3 steps 1: 87 percent / Et3N / CH2Cl2 / 0 - 4 °C 2: HBr / CH2Cl2 3: 70 percent / toluene / 2 h / 110 °C View Scheme

: 83634-89-3
hexadecyl 3-(dimethylamino)propanesulfonate

A: 112-82-3
hexadecanyl bromide

B sodium-compound of (+-)-2-oxo-tetrahydro-furan-3-carboxylic acid ethyl ester: sodium-compound of (+-)-2-oxo-tetrahydro-furan-3-carboxylic acid ethyl ester

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 91 percent / CH2Cl2 / 1 h / 0 °C 2: 95 percent / NaBr / benzene; H2O / 48 h / 25 °C View Scheme
Multi-step reaction with 2 steps 1: HBr / CH2Cl2 2: 70 percent / toluene / 2 h / 110 °C View Scheme

: 83634-99-5
4-Dimethylamino-butane-1-sulfonic acid hexadecyl ester

A: 112-82-3
hexadecanyl bromide

B sodium-compound of (+-)-2-oxo-tetrahydro-furan-3-carboxylic acid ethyl ester: sodium-compound of (+-)-2-oxo-tetrahydro-furan-3-carboxylic acid ethyl ester

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: HBr / CH2Cl2 2: 92 percent / toluene / 8 h / 110 °C View Scheme

: 81609-29-2
1-phenyltellurohexadecane

A: 112-82-3
hexadecanyl bromide

B sodium-compound of (+-)-2-oxo-tetrahydro-furan-3-carboxylic acid ethyl ester: sodium-compound of (+-)-2-oxo-tetrahydro-furan-3-carboxylic acid ethyl ester

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: bromine / CCl4 / 0.17 h / Ambient temperature 2: sodium bromide / dimethylformamide / 70 °C View Scheme

: 57-09-0
cetyltrimethylammonim bromide

A: 112-82-3
hexadecanyl bromide

B: 75-50-3
trimethylamine

Conditions

Conditions	Yield
Heating;

: 66143-69-9
hexadecyl ethenesulfonate

: 112-82-3
hexadecanyl bromide

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: triethylamine / dichloromethane; isopropyl alcohol / 20 °C / Inert atmosphere 2: potassium bromide / N,N-dimethyl-formamide / 4 h / 85 °C View Scheme

: 36653-82-4
1-Hexadecanol

A: 629-80-1
n-hexadecylaldehyde

B: 112-82-3
hexadecanyl bromide

Conditions

Conditions	Yield
Stage #1: 1-Hexadecanol With N,N-dimethylthiourea In dichloromethane at 20℃; Stage #2: With N-Bromosuccinimide In dichloromethane at 20℃; for 3h;	A n/a B 91 %Chromat.

: 603-35-0
triphenylphosphine

: 112-82-3
hexadecanyl bromide

: 14866-43-4
(1-hexadecyl)triphenylphosphonium bromide

Conditions

Conditions	Yield
In toluene Reflux;	100%
In toluene at 90℃; for 48h;	79%
In acetonitrile for 36h; Heating;	68%

: 111-51-3
N,N,N',N'-tetramethyl-1,4-butanediamine

: 112-82-3
hexadecanyl bromide

: 29908-17-6
butane-1,4-diyl bis(N,N-dimethyl-N-hexadecylammonium) dibromide

Conditions

Conditions	Yield
In acetonitrile for 25h; Heating;	100%

: 112-82-3
hexadecanyl bromide

: 66143-67-7
cetyl azide

Conditions

Conditions	Yield
With sodium azide In N,N-dimethyl-formamide at 20℃; for 12h;	100%
With sodium azide; Aliquat 336 In formamide at 100℃; Rate constant; Product distribution; further solvent;	97%
With sodium azide; Aliquat 336 In formamide at 100℃;	97%

: 62-53-3
aniline

: 112-82-3
hexadecanyl bromide

: 77772-74-8
N,N-dihexadecylphenylamine

Conditions

Conditions	Yield
With sodium hydroxide In toluene	100%
With potassium carbonate; potassium iodide In butan-1-ol at 110℃; for 72h;	85%
With potassium carbonate; potassium iodide In N,N-dimethyl acetamide at 160℃; for 16h;	76%

: 2150-44-9
1-carbomethoxy-3,5-dihydroxybenzene

: 112-82-3
hexadecanyl bromide

: 370564-68-4
methyl 3,5-bis(hexadecyloxy)benzoate

Conditions

Conditions	Yield
With potassium carbonate In acetonitrile at 100℃;	100%
With potassium carbonate In acetonitrile at 100℃;	99%
With potassium carbonate In acetonitrile Heating;	99%
With potassium carbonate In acetonitrile at 110℃;	98%
With potassium carbonate Inert atmosphere;

: 616-47-7
1-methyl-1H-imidazole

: 112-82-3
hexadecanyl bromide

: 1-hexadecyl-3-methyl-3H-imidazol-1-ium; bromide

Conditions

Conditions	Yield
at 100℃; for 21h;	100%
In toluene for 6h; Reflux;	99%
In toluene for 6h; Reflux;	99%

: 111-42-2
2,2'-iminobis[ethanol]

: 112-82-3
hexadecanyl bromide

: 18924-67-9
2,2'-(hexadecylazanediyl)diethanol

Conditions

Conditions	Yield
With potassium hydrogencarbonate; potassium iodide In acetonitrile for 3h; Reflux;	100%
With potassium carbonate; potassium iodide In acetonitrile for 12h; Inert atmosphere; Reflux;	96.1%
With potassium carbonate; potassium iodide In acetonitrile
With N-ethyl-N,N-diisopropylamine In methanol for 96h; Reflux;

: 1030366-99-4
2,6-bis(1H-benzo[d]imidazol-1-yl)pyridine

: 112-82-3
hexadecanyl bromide

: 2Br(1-)*C51H79N5(2+)

Conditions

Conditions	Yield
at 160℃; for 30h; Inert atmosphere; Neat (no solvent); Sealed tube;	100%
at 160℃; for 30h;

: 90844-14-7
dimethyl-5-hydroxyisophthalic acid

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

: 112-82-3
hexadecanyl bromide

: 258883-88-4
dimethyl 5-(hexadecyloxy)isophthalate

Conditions

Conditions	Yield
With potassium iodide; potassium carbonate In diethyl ether	100%
With potassium carbonate In diethyl ether	100%

...Expand

: 56-54-2, 130-95-0, 572-59-8, 572-60-1, 42151-59-7, 47342-58-5, 72402-50-7, 72402-51-8, 72402-52-9, 72402-53-0, 101143-86-6, 101143-87-7, 101143-88-8, 146925-10-2
(6-methoxyquinolin-4-yl)((1S,4S,5R)-5-vinylquinuclidin-2-yl)methanol

: 112-82-3
hexadecanyl bromide

: C36H57N2O2(1+)

Conditions

Conditions	Yield
In acetonitrile for 24h; Heating;	100%

: 112-82-3
hexadecanyl bromide

: 130-95-0
Quinine

: C36H57N2O2(1+)*Br(1-)

Conditions

Conditions	Yield
In acetonitrile for 26h; Reflux;	100%

: 43071-19-8
2-[(Dimethylamino)methyl]pyridine

: 112-82-3
hexadecanyl bromide

: C24H45N2(1+)*Br(1-)

Conditions

Conditions	Yield
In acetonitrile Reflux;	100%

: 13677-79-7
gallaldehyde

: 112-82-3
hexadecanyl bromide

: 138433-02-0
3,4,5-tris(hexadecyloxy)benzaldehyde

Conditions

Conditions	Yield
With potassium carbonate; potassium iodide In N,N-dimethyl-formamide at 70℃; for 14h;	99.1%

: 110-86-1
pyridine

: 112-82-3
hexadecanyl bromide

: 140-72-7
cetylpyridinium bromide

Conditions

Conditions	Yield
In ethanol for 40h; Reflux;	99%
In toluene at 20 - 110℃; for 25h; Inert atmosphere;	92%
In acetonitrile for 24h; Reflux;	75%

: 280-57-9
1,4-diaza-bicyclo[2.2.2]octane

: 112-82-3
hexadecanyl bromide

: 62634-16-6
TA 279

Conditions

Conditions	Yield
In acetonitrile at 70℃;	99%
In ethyl acetate at 20℃; for 24h;	99%
In acetonitrile for 3h; Heating;	95%

: 122-80-5
N-acetyl-p-phenylenediamine

: 112-82-3
hexadecanyl bromide

: 85074-37-9
N-(4-dihexadecylaminophenyl)acetamide

Conditions

Conditions	Yield
With sodium carbonate In 2-methoxy-ethanol	99%
With sodium hydrogencarbonate In N,N-dimethyl-formamide at 120℃; for 14h;	82%

: 22323-82-6
(S)-(+)-(2,2-dimethyl-[1,3]dioxolan-4-yl)methanol

: 112-82-3
hexadecanyl bromide

: 57959-37-2
3-O-hexadecyl-1,2-O-isopropylidene-sn-glycerol

Conditions

Conditions	Yield
With tetrabutylammomium bromide at 80℃; for 20h;	99%
With sodium hydride In N,N-dimethyl-formamide at 20℃; for 24h; Yield given;
In (2S)-N-methyl-1-phenylpropan-2-amine hydrate; hexane; toluene

: 56552-80-8
(R)-3-benzyloxy-1,2-propanediol

: 112-82-3
hexadecanyl bromide

: 13071-57-3
(R)-((2,3-bis(hexadecyloxy)propoxy)methyl)benzene

Conditions

Conditions	Yield
With sodium hydride In N,N-dimethyl-formamide at 20℃; for 0.5h;	99%
With tetra-(n-butyl)ammonium iodide; sodium hydride In N,N-dimethyl-formamide at 20℃; for 36h; Etherification;	68%
Stage #1: (R)-3-benzyloxy-1,2-propanediol With sodium hydride In N,N-dimethyl-formamide for 0.25h; Stage #2: hexadecanyl bromide In N,N-dimethyl-formamide at 20℃; for 3h;	43%
With sodium hydride 1.) DMF, 5 deg C, 2 h, 2.) DMF, RT, overnight; Yield given. Multistep reaction;

: 86-73-7
9H-fluorene

: 112-82-3
hexadecanyl bromide

: 123864-05-1
9,9-dihexadecyl-9H-fluorene

Conditions

Conditions	Yield
With potassium tert-butylate In tetrahydrofuran at 40℃; for 40h; Inert atmosphere;	99%

: 112-82-3
hexadecanyl bromide

: 54-11-5
nicotin

: C26H47N2(1+)

Conditions

Conditions	Yield
In acetonitrile Heating;	99%

: 112-82-3
hexadecanyl bromide

: 54-11-5
nicotin

: C26H47N2(1+)*Br(1-)

Conditions

Conditions	Yield
In acetonitrile for 24h; Reflux;	99%

: 107-43-7
betaine

: 112-82-3
hexadecanyl bromide

: (2-hexadecyloxy-2-oxoethyl)trimethylammonium bromide

Conditions

Conditions	Yield
In acetonitrile at 80℃; for 72h;	99%
In acetonitrile at 80℃; Green chemistry;	91%

: 89-55-4
5-bromosalicyclic acid

: 112-82-3
hexadecanyl bromide

: 28294-58-8
5-hexadecylsalicylic acid

Conditions

Conditions	Yield
Stage #1: hexadecanyl bromide With lithium In diethyl ether at -10℃; for 2h; Inert atmosphere; Stage #2: With copper(l) iodide In diethyl ether at 0℃; for 1h; Inert atmosphere; Stage #3: 5-bromosalicyclic acid In diethyl ether at 60℃; for 4h; Inert atmosphere;	98.1%

: 1066-26-8
sodium acetylide

: 112-82-3
hexadecanyl bromide

: 629-89-0
1-octadecyne

Conditions

Conditions	Yield
In 5,5-dimethyl-1,3-cyclohexadiene; N,N-dimethyl-formamide at 0 - 20℃; Inert atmosphere;	98%
With ammonia at 25℃; unter Druck;
With ammonia; N,N-dimethyl-formamide nach Entfernung des Ammoniaks bei 65-70grad;

: 108-89-4
picoline

: 112-82-3
hexadecanyl bromide

: 2315-40-4
1-hexadecyl-4-methylpyridinium bromide

Conditions

Conditions	Yield
In acetonitrile for 48h; Menshutkin Reaction; Reflux;	98%
at 110℃; for 4h;	72%
at 110℃; for 6h;	60%

: 96-27-5
rac-3-sulfanylpropane-1,2-diol

: 112-82-3
hexadecanyl bromide

: 21562-32-3
(+/-)-1-S-hexadecylthioglycerol

Conditions

Conditions	Yield
With potassium hydroxide In methanol for 48h; Ambient temperature;	98%
With potassium hydroxide In ethanol for 24h; Ambient temperature;	95%
With potassium hydroxide In ethanol	95%

: 19488-09-6
sodium 4-methoxyphenylthiolate

: 112-82-3
hexadecanyl bromide

: 94404-46-3
1-hexadecyl 4-methoxyphenylsulfide

Conditions

Conditions	Yield
In methanol Ambient temperature;	98%

: 127-08-2
potassium acetate

: 112-82-3
hexadecanyl bromide

: 629-70-9
hexadecyl acetate

Conditions

Conditions	Yield
With Aliquat 336 In neat (no solvent) at 85℃; for 3h;	98%
With aluminum oxide at 234℃; for 0.0208333h; Irradiation;	95%
Aliquat 336 for 20h; Ambient temperature;	93%
With aluminum oxide 1.) water, 2.) 85 deg C, 20 h;	88%

1-bromohexadecane Chemical Properties

Synonyms: N-HEXADECYL BROMIDE;HEXADECYL BROMIDE;CETYL BROMIDE;1-BROMOHEXADECANE;1-HEXADECYL BROMIDE;1-Bromhexadecan;1-bromo-hexadecan;HEXADECANE,1-bromo-
MF: C₁₆H₃₃Br
MW: 305.34
EINECS: 204-008-7
MP: 16-18 °C
BP: 190 °C11 mm Hg
Density : 0.999 g/mL at 25 °C
Vapor Density : 10.6 (vs air)
Vapor Pressure : <1 mm Hg ( 20 °C)
Refractive Index : n20/D 1.4609(lit.)
FP: >230 °C
Water Solubility : INSOLUBLE
BRN : 773989
STructural Formula:

1-bromohexadecane Toxicity Data With Reference

Hazard Codes ：

Xi
Risk Statements ：
R36/37/38: Irritating to eyes, respiratory system and skin

1-bromohexadecane Safety Profile

Safety Statements :
S26: In case of contact with eyes, rinse immediately with plenty of WATER and seek medical advice
S36: Wear suitable protective clothing

1-bromohexadecane Specification

Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials.
Incompatibilities with Other Materials Strong oxidizing agents, strong bases.
Hazardous Decomposition Products Carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization Will not occur.

Product Name

1-bromohexadecane

Synthetic route

1-bromohexadecane Chemical Properties

1-bromohexadecane Toxicity Data With Reference

1-bromohexadecane Safety Profile

1-bromohexadecane Specification

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