2-Bromo-3-hexyl-5-iodothiophene supplier

Name
2-Bromo-5-iodo-3-hexylthiophene
EINECS
CAS No. 160096-76-4
Article Data17
CAS DataBase
Density 1.727
Solubility
Melting Point
Formula C₁₀H₁₄BrIS
Boiling Point 121°C/0.6mmHg(lit.)
Molecular Weight 373.096
Flash Point
Transport Information
Appearance
Safety
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms 2-Bromo-3-hexyl-5-iodo-thiophene;
PSA 28.24000
LogP 5.23800

Synthetic route

: 69249-61-2
3-hexyl-2-bromothiophene

: 160096-76-4
2-bromo-5-iodo-3-hexylthiophene

Conditions

Conditions	Yield
With [bis(acetoxy)iodo]benzene; iodine In dichloromethane at 20℃; for 4h;	97%
With N-iodo-succinimide In chloroform; acetic acid at 20℃; for 16h; Darkness;	89%
With N-iodo-succinimide; toluene-4-sulfonic acid In ethanol at 22 - 50℃; for 0.416667h;	89%

: 116971-11-0
2,5-dibromo-3-hexylthiophene

: 160096-76-4
2-bromo-5-iodo-3-hexylthiophene

Conditions

Conditions	Yield
Stage #1: 2,5-dibromo-3-hexylthiophene With tetrabutylammonium tetrafluoroborate; zinc dibromide; (2,2'-bipyridine)nickel(II) dibromide In N,N-dimethyl-formamide at -10.16℃; Electrolysis; Stage #2: With iodine In N,N-dimethyl-formamide Further stages.;

: 1693-86-3
3-hexylthiophene

: 160096-76-4
2-bromo-5-iodo-3-hexylthiophene

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1.1: 95 percent / tetrabutylammonium bromide; methanol; Br2 / CH2Cl2 / 20 °C 2.1: ZnBr2; tetrabutylammonium tetrafluoroborate / NiBr2 2,2'-bipyridine / dimethylformamide / -10.16 °C / Electrolysis 2.2: I2 / dimethylformamide View Scheme
Multi-step reaction with 2 steps 1: 95 percent / N-bromosuccinimide / tetrahydrofuran / 1 h / 0 °C 2: 97 percent / I2; iodobenzene diacetate / CH2Cl2 / 4 h / 20 °C View Scheme
Multi-step reaction with 2 steps 1: N-Bromosuccinimide / tetrahydrofuran 2: iodine; [bis(acetoxy)iodo]benzene / tetrahydrofuran View Scheme

: 3761-92-0
n-hexylmagnesium bromide

: 160096-76-4
2-bromo-5-iodo-3-hexylthiophene

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1.1: diethyl ether 2.1: 95 percent / tetrabutylammonium bromide; methanol; Br2 / CH2Cl2 / 20 °C 3.1: ZnBr2; tetrabutylammonium tetrafluoroborate / NiBr2 2,2'-bipyridine / dimethylformamide / -10.16 °C / Electrolysis 3.2: I2 / dimethylformamide View Scheme

: 111-25-1
1-bromo-hexane

: 160096-76-4
2-bromo-5-iodo-3-hexylthiophene

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1.1: magnesium / diethyl ether / 3.25 h / 20 °C / Inert atmosphere; Cooling with ice 1.2: 24 h / Inert atmosphere 2.1: N-Bromosuccinimide / tetrahydrofuran / 1 h / 0 °C 3.1: [bis(acetoxy)iodo]benzene; iodine / dichloromethane / 0 - 20 °C View Scheme
Multi-step reaction with 3 steps 1.1: magnesium / diethyl ether / 1 h / Reflux; Inert atmosphere 1.2: Reflux; Inert atmosphere 2.1: N-Bromosuccinimide / dichloromethane / Darkness; Inert atmosphere 3.1: iodine; [bis(acetoxy)iodo]benzene / tetrahydrofuran / 8 h / 20 °C / Inert atmosphere; Darkness View Scheme

: 1408285-51-7
4,4,5,5-tetramethyl-2-(5-(trimethylstannyl)thiophen-2-yl)-1,3,2-dioxaborolane

: 160096-76-4
2-bromo-5-iodo-3-hexylthiophene

: 1452670-63-1
2-(3'-n-hexyl-5'-bromo[2,2'-bithiophen]-5-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0) In N,N-dimethyl-formamide at 100℃; for 0.333333h; Solvent; Reagent/catalyst; Concentration; Temperature; Time; Stille Cross Coupling; Microwave irradiation;	95%

: 850881-09-3
3-hexylthiophene-2-boronic acid pinacol ester

: 160096-76-4
2-bromo-5-iodo-3-hexylthiophene

: 154717-21-2
5’-bromo-3,4’-dihexyl-2,2’-bithiophene

Conditions

Conditions	Yield
With sodium hydrogencarbonate; tetrakis(triphenylphosphine) palladium(0) In 1,2-dimethoxyethane for 24h; Heating;	90%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In Dimethyl ether; water for 24h; Reflux;	90%

: 160096-76-4
2-bromo-5-iodo-3-hexylthiophene

: pyridin-2-ylzinc(II) bromide

: 1189375-66-3
2-(4-bromo-3-hexylthien-2-yl)pyridine

Conditions

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 20℃; for 24h; Inert atmosphere;	89%
With tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 20℃; for 24h; Inert atmosphere;	89%

: 871-84-1
1,7-Octadiyne

: 160096-76-4
2-bromo-5-iodo-3-hexylthiophene

: 1,8-bis(5-bromo-4-hexylthiophen-2-yl)octa-1,7-diyne

Conditions

Conditions	Yield
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); triethylamine In N,N-dimethyl-formamide at 55℃; for 21h; Sonogashira Cross-Coupling; Inert atmosphere; Schlenk technique;	84%
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); triethylamine In 1,2-dimethoxyethane at 55℃; for 22h;	73%

: 160096-76-4
2-bromo-5-iodo-3-hexylthiophene

poly(3-hexylthiophene), Mn 17000, Mw/Mn 1.28 by GPC; monomer(s): 2-bromo-3-hexyl-5-iodothiophene: poly(3-hexylthiophene), Mn 17000, Mw/Mn 1.28 by GPC; monomer(s): 2-bromo-3-hexyl-5-iodothiophene

Conditions

Conditions	Yield
Stage #1: 2-bromo-5-iodo-3-hexylthiophene With isopropylmagnesium chloride In tetrahydrofuran at 0℃; for 0.5h; Stage #2: With Cl2Ni(1,3-bis(diphenylphosphino)propane)2 In tetrahydrofuran at 20℃; for 24h;	78%

: C18H19B2F2N3O2

: 160096-76-4
2-bromo-5-iodo-3-hexylthiophene

: C22H21BBrF2N3S

Conditions

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran at 80℃; for 18h; Suzuki Coupling; Inert atmosphere;	77%

: 1-hexyl-2-(tributylstannyl)-1H-pyrrole

: 160096-76-4
2-bromo-5-iodo-3-hexylthiophene

: 2-(5-bromo-4-hexylthiophen-2-yl)-1-hexyl-1H-pyrrole

Conditions

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0) In N,N-dimethyl-formamide at 70℃; for 32h; Stille Cross Coupling; Inert atmosphere;	76%

: 160096-76-4
2-bromo-5-iodo-3-hexylthiophene

head-to-tail Br-poly(3-hexylthiophene), Mn 9300, Mw/Mn 1.10; monomer(s): 2-bromo-3-hexyl-5-iodothiophene: head-to-tail Br-poly(3-hexylthiophene), Mn 9300, Mw/Mn 1.10; monomer(s): 2-bromo-3-hexyl-5-iodothiophene

Conditions

Conditions	Yield
Stage #1: 2-bromo-5-iodo-3-hexylthiophene With isopropylmagnesium chloride In tetrahydrofuran at 0℃; for 1h; Stage #2: With 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) In tetrahydrofuran at 20℃; for 6h;	72%

: C37H30B2F2N4O3S

: 160096-76-4
2-bromo-5-iodo-3-hexylthiophene

: C41H32BBrF2N4OS2

Conditions

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran at 80℃; for 18h; Suzuki Coupling; Inert atmosphere;	71%

: 308795-91-7
3-methyl-pyridin-2-ylzinc bromide

: 160096-76-4
2-bromo-5-iodo-3-hexylthiophene

: 1227833-65-9
C16H20BrNS

Conditions

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 20℃; for 24h; Inert atmosphere;	41%

: 160096-76-4
2-bromo-5-iodo-3-hexylthiophene

: 154717-21-2
5’-bromo-3,4’-dihexyl-2,2’-bithiophene

: 850881-10-6
2-bromo-5-(5-(3-hexylthiophen-2-yl)-3-hexylthiophen-2-yl)-3-hexylthiophene

Conditions

Conditions	Yield
Stage #1: 5’-bromo-3,4’-dihexyl-2,2’-bithiophene With n-butyllithium In tetrahydrofuran; hexane at -80℃; for 1h; Stage #2: With zinc(II) chloride In tetrahydrofuran; hexane at -80 - 20℃; Stage #3: 2-bromo-5-iodo-3-hexylthiophene; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran; hexane at 20℃; for 24h; Negishi cross-coupling;	38%
Stage #1: 5’-bromo-3,4’-dihexyl-2,2’-bithiophene With n-butyllithium In tetrahydrofuran at -80℃; for 1h; Stage #2: 2-bromo-5-iodo-3-hexylthiophene With zinc(II) chloride In tetrahydrofuran at 20℃; for 24h;	38%

: 160096-76-4
2-bromo-5-iodo-3-hexylthiophene

: 291273-95-5
5-bromo-4,4'-dihexyl-2,2'-bithiophene

Conditions

Conditions	Yield
Stage #1: 2-bromo-5-iodo-3-hexylthiophene With isopropylmagnesium chloride In tetrahydrofuran at 0℃; for 1h; Stage #2: With 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) In tetrahydrofuran at 20℃; for 1h;

: 160096-76-4
2-bromo-5-iodo-3-hexylthiophene

(PPh3)2Ni(Ph)Br: (PPh3)2Ni(Ph)Br

A polymer, polymerization at 0 deg C, end groups H, monomer(s): bromobenzene; 2-bromo-3-hexyl-5-iodothiophene: polymer, polymerization at 0 deg C, end groups H, monomer(s): bromobenzene; 2-bromo-3-hexyl-5-iodothiophene

B polymer, polymerization at 0 deg C, end groups Ph and Br, monomer(s): bromobenzene; 2-bromo-3-hexyl-5-iodothiophene: polymer, polymerization at 0 deg C, end groups Ph and Br, monomer(s): bromobenzene; 2-bromo-3-hexyl-5-iodothiophene

C polymer, polymerization at 0 deg C, end groups Ph and H, monomer(s): bromobenzene; 2-bromo-3-hexyl-5-iodothiophene: polymer, polymerization at 0 deg C, end groups Ph and H, monomer(s): bromobenzene; 2-bromo-3-hexyl-5-iodothiophene

Conditions

Conditions	Yield
Stage #1: 2-bromo-5-iodo-3-hexylthiophene With isopropylmagnesium chloride In tetrahydrofuran at 0℃; for 1h; Stage #2: (PPh3)2Ni(Ph)Br In tetrahydrofuran; toluene at 0℃; for 6h; Further stages. Title compound not separated from byproducts.;	A 2 % Spectr. B 20 % Spectr. C 78 % Spectr.

...Expand

: 160096-76-4
2-bromo-5-iodo-3-hexylthiophene

(PPh3)2Ni(Ph)Br: (PPh3)2Ni(Ph)Br

A polymer, polymerization at RT, end groups Ph and Br, monomer(s): bromobenzene; 2-bromo-3-hexyl-5-iodothiophene: polymer, polymerization at RT, end groups Ph and Br, monomer(s): bromobenzene; 2-bromo-3-hexyl-5-iodothiophene

B polymer, polymerization at RT, end groups Ph and H, monomer(s): bromobenzene; 2-bromo-3-hexyl-5-iodothiophene: polymer, polymerization at RT, end groups Ph and H, monomer(s): bromobenzene; 2-bromo-3-hexyl-5-iodothiophene

C polymer, polymerization at RT, end groups H, monomer(s): 2-bromo-3-hexyl-5-iodothiophene: polymer, polymerization at RT, end groups H, monomer(s): 2-bromo-3-hexyl-5-iodothiophene

Conditions

Conditions	Yield
Stage #1: 2-bromo-5-iodo-3-hexylthiophene With tert-butylmagnesium chloride In tetrahydrofuran Stage #2: (PPh3)2Ni(Ph)Br In tetrahydrofuran; toluene at 20℃; for 4h; Further stages. Title compound not separated from byproducts.;	A 13 % Spectr. B 67 % Spectr. C 20 % Spectr.

...Expand

: 160096-76-4
2-bromo-5-iodo-3-hexylthiophene

(PPh3)2Ni(o-Tol)Br: (PPh3)2Ni(o-Tol)Br

A polymer, polymerization at 0 deg C, polymerization time 10 min, end groups Ph and Br, monomer(s): o-bromotoluene; 2-bromo-3-hexyl-5-iodothiophene: polymer, polymerization at 0 deg C, polymerization time 10 min, end groups Ph and Br, monomer(s): o-bromotoluene; 2-bromo-3-hexyl-5-iodothiophene

B polymer, polymerization at 0 deg C, polymerization time 10 min, end groups Ph and H, monomer(s): o-bromotoluene; 2-bromo-3-hexyl-5-iodothiophene: polymer, polymerization at 0 deg C, polymerization time 10 min, end groups Ph and H, monomer(s): o-bromotoluene; 2-bromo-3-hexyl-5-iodothiophene

Conditions

Conditions	Yield
Stage #1: 2-bromo-5-iodo-3-hexylthiophene With isopropylmagnesium chloride In tetrahydrofuran at 0℃; for 1h; Stage #2: (PPh3)2Ni(o-Tol)Br In tetrahydrofuran; toluene at 0℃; for 0.166667h; Further stages. Title compound not separated from byproducts.;

...Expand

: 160096-76-4
2-bromo-5-iodo-3-hexylthiophene

(PPh3)2Ni(o-Tol)Br: (PPh3)2Ni(o-Tol)Br

A polymer, polymerization at 0 deg C, polymerization time 155 min, end groups Ph and Br, monomer(s): o-bromotoluene; 2-bromo-3-hexyl-5-iodothiophene: polymer, polymerization at 0 deg C, polymerization time 155 min, end groups Ph and Br, monomer(s): o-bromotoluene; 2-bromo-3-hexyl-5-iodothiophene

B polymer, polymerization at 0 deg C, polymerization time 155 min, end groups Ph and H, monomer(s): o-bromotoluene; 2-bromo-3-hexyl-5-iodothiophene: polymer, polymerization at 0 deg C, polymerization time 155 min, end groups Ph and H, monomer(s): o-bromotoluene; 2-bromo-3-hexyl-5-iodothiophene

Conditions

Conditions	Yield
Stage #1: 2-bromo-5-iodo-3-hexylthiophene With isopropylmagnesium chloride In tetrahydrofuran at 0℃; for 1h; Stage #2: (PPh3)2Ni(o-Tol)Br In tetrahydrofuran; toluene at 0℃; for 2.58333h; Further stages. Title compound not separated from byproducts.;

...Expand

: 160096-76-4
2-bromo-5-iodo-3-hexylthiophene

(PPh3)2Ni(o-Tol)Br: (PPh3)2Ni(o-Tol)Br

polymer, Mn = 3600, Mw/Mn = 1.78, monomer(s): o-bromotoluene; 2-bromo-3-hexyl-5-iodothiophene: polymer, Mn = 3600, Mw/Mn = 1.78, monomer(s): o-bromotoluene; 2-bromo-3-hexyl-5-iodothiophene

Conditions

Conditions	Yield
Stage #1: 2-bromo-5-iodo-3-hexylthiophene With isopropylmagnesium chloride In tetrahydrofuran at 0℃; for 1h; Stage #2: (PPh3)2Ni(o-Tol)Br In tetrahydrofuran; toluene at 0℃; for 1.58333h; Further stages.;

: 160096-76-4
2-bromo-5-iodo-3-hexylthiophene

(PPh3)2Ni(o-Tol)Br: (PPh3)2Ni(o-Tol)Br

polymer, Mn = 4300, Mw/Mn = 1.91, monomer(s): o-bromotoluene; 2-bromo-3-hexyl-5-iodothiophene: polymer, Mn = 4300, Mw/Mn = 1.91, monomer(s): o-bromotoluene; 2-bromo-3-hexyl-5-iodothiophene

Conditions

Conditions	Yield
Stage #1: 2-bromo-5-iodo-3-hexylthiophene With isopropylmagnesium chloride In tetrahydrofuran at 0℃; for 1h; Stage #2: (PPh3)2Ni(o-Tol)Br In tetrahydrofuran; toluene at 0℃; for 2.08333h; Further stages.;

: 160096-76-4
2-bromo-5-iodo-3-hexylthiophene

: 850881-12-8
5-(4,3'-dihexyl-2,2'-bithienyl-5-yl)-4,4,5,5-tetramethyl-[1,3,2]-dioxaborolane

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1.1: 90 percent / aq. NaHCO3 / [Pd(PPh3)4] / 1,2-dimethoxy-ethane / 24 h / Heating 2.1: n-BuLi / tetrahydrofuran; hexane / 1 h / -80 °C 2.2: tri(isopropyl)borate / tetrahydrofuran; hexane / -78 - 20 °C 2.3: tetrahydrofuran; hexane / 20 °C View Scheme
Multi-step reaction with 2 steps 1.1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / water; Dimethyl ether / 24 h / Reflux 2.1: n-butyllithium / tetrahydrofuran / 0.5 h 2.2: 24 h / 20 °C View Scheme

: 160096-76-4
2-bromo-5-iodo-3-hexylthiophene

: 850881-10-6
2-bromo-5-(5-(3-hexylthiophen-2-yl)-3-hexylthiophen-2-yl)-3-hexylthiophene

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1.1: 90 percent / aq. NaHCO3 / [Pd(PPh3)4] / 1,2-dimethoxy-ethane / 24 h / Heating 2.1: n-BuLi / tetrahydrofuran; hexane / 1 h / -80 °C 2.2: ZnCl2 / tetrahydrofuran; hexane / -80 - 20 °C 2.3: 38 percent / [Pd(PPh3)4] / tetrahydrofuran; hexane / 24 h / 20 °C View Scheme
Multi-step reaction with 2 steps 1.1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / water; Dimethyl ether / 24 h / Reflux 2.1: n-butyllithium / tetrahydrofuran / 1 h / -80 °C 2.2: 24 h / 20 °C View Scheme

: 160096-76-4
2-bromo-5-iodo-3-hexylthiophene

: 850881-13-9
5-([N-(2,6-diisopropylphenyl)]-9-perylenyl-3,4-dicarboximide)-4,3'-dihexyl-2,2'-bithiophene

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1.1: 90 percent / aq. NaHCO3 / [Pd(PPh3)4] / 1,2-dimethoxy-ethane / 24 h / Heating 2.1: n-BuLi / tetrahydrofuran; hexane / 1 h / -80 °C 2.2: tri(isopropyl)borate / tetrahydrofuran; hexane / -78 - 20 °C 2.3: tetrahydrofuran; hexane / 20 °C 3.1: 90 percent / aq. tripotassium phosphate / [Pd(PPh3)4] / 1,2-dimethoxy-ethane / 3 h / 80 °C View Scheme
Multi-step reaction with 2 steps 1.1: 90 percent / aq. NaHCO3 / [Pd(PPh3)4] / 1,2-dimethoxy-ethane / 24 h / Heating 2.1: n-BuLi / tetrahydrofuran; hexane / 1 h / -80 °C 2.2: ZnCl2 / tetrahydrofuran; hexane / -80 - 20 °C 2.3: 76 percent / [Pd(PPh3)4] / tetrahydrofuran; hexane / 24 h / 65 °C View Scheme

: 160096-76-4
2-bromo-5-iodo-3-hexylthiophene

: 5-([N-(2,6-diisopropylphenyl)]-9-perylenyl-3,4-dicarboximide)-4,3',3''-trihexyl-2,2';5',2''-terthiophene

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1.1: 90 percent / aq. NaHCO3 / [Pd(PPh3)4] / 1,2-dimethoxy-ethane / 24 h / Heating 2.1: n-BuLi / tetrahydrofuran; hexane / 1 h / -80 °C 2.2: ZnCl2 / tetrahydrofuran; hexane / -80 - 20 °C 2.3: 38 percent / [Pd(PPh3)4] / tetrahydrofuran; hexane / 24 h / 20 °C 3.1: n-BuLi / tetrahydrofuran; hexane / 1 h / -80 °C 3.2: ZnCl2 / tetrahydrofuran; hexane / -80 - 20 °C 3.3: 35 percent / [Pd(PPh3)4] / tetrahydrofuran; hexane / 24 h / 65 °C View Scheme
Multi-step reaction with 2 steps 1.1: n-BuLi / tetrahydrofuran; hexane / 1 h / -80 °C 1.2: ZnCl2 / tetrahydrofuran; hexane / -80 - 20 °C 1.3: 38 percent / [Pd(PPh3)4] / tetrahydrofuran; hexane / 24 h / 20 °C 2.1: n-BuLi / tetrahydrofuran; hexane / 1 h / -80 °C 2.2: ZnCl2 / tetrahydrofuran; hexane / -80 - 20 °C 2.3: 35 percent / [Pd(PPh3)4] / tetrahydrofuran; hexane / 24 h / 65 °C View Scheme

Yield

Multi-step reaction with 3 steps
1.1: 90 percent / aq. NaHCO3 / [Pd(PPh3)4] / 1,2-dimethoxy-ethane / 24 h / Heating
2.1: n-BuLi / tetrahydrofuran; hexane / 1 h / -80 °C
2.2: ZnCl2 / tetrahydrofuran; hexane / -80 - 20 °C
2.3: 38 percent / [Pd(PPh3)4] / tetrahydrofuran; hexane / 24 h / 20 °C
3.1: n-BuLi / tetrahydrofuran; hexane / 1 h / -80 °C
3.2: ZnCl2 / tetrahydrofuran; hexane / -80 - 20 °C
3.3: 35 percent / [Pd(PPh3)4] / tetrahydrofuran; hexane / 24 h / 65 °C
View Scheme

Multi-step reaction with 2 steps
1.1: n-BuLi / tetrahydrofuran; hexane / 1 h / -80 °C
1.2: ZnCl2 / tetrahydrofuran; hexane / -80 - 20 °C
1.3: 38 percent / [Pd(PPh3)4] / tetrahydrofuran; hexane / 24 h / 20 °C
2.1: n-BuLi / tetrahydrofuran; hexane / 1 h / -80 °C
2.2: ZnCl2 / tetrahydrofuran; hexane / -80 - 20 °C
2.3: 35 percent / [Pd(PPh3)4] / tetrahydrofuran; hexane / 24 h / 65 °C
View Scheme

: 160096-76-4
2-bromo-5-iodo-3-hexylthiophene

: 671775-27-2
(5-bromo-4-hexylthiophen-2-yl)magnesium chloride

Conditions

Conditions	Yield
With isopropylmagnesium chloride In tetrahydrofuran at 0℃; for 1h;
With isopropylmagnesium chloride In tetrahydrofuran at 20℃; for 1h;
With isopropylmagnesium chloride
Stage #1: 2-bromo-5-iodo-3-hexylthiophene With TurboGrignard In tetrahydrofuran at 40℃; for 0.25h; Inert atmosphere; Stage #2: In tetrahydrofuran at 20℃; for 0.75h; Inert atmosphere;

2-Bromo-3-hexyl-5-iodothiophene Chemical Properties

Molecular Structure of 2-Bromo-3-hexyl-5-iodothiophene (CAS No.160096-76-4):

Molecular Formula: C₁₀H₁₄BrIS
Molecular Weight: 373.0916
CAS No: 160096-76-4
H bond acceptors: 0
H bond donors: 0
Freely Rotating Bonds: 5
Polar Surface Area: 28.24 Å²
Index of Refraction: 1.594
Molar Refractivity: 73.315 cm³
Molar Volume: 216.015 cm³
Surface Tension: 42.725 dyne/cm
Density: 1.727 g/cm³
Flash Point: 157.131 °C
Enthalpy of Vaporization: 55.638 kJ/mol
Boiling Point: 336.205 °C at 760 mmHg
Vapour Pressure: 0 mmHg at 25°C
InChI: InChI=1/C₁₀H₁₄BrIS/c1-2-3-4-5-6-8-7-9(12)13-10(8)11/h7H,2-6H2,1H3
InChIKey: SDMKEQYHISDGKT-UHFFFAOYAP
Std. InChI: InChI=1S/C₁₀H₁₄BrIS/c1-2-3-4-5-6-8-7-9(12)13-10(8)11/h7H,2-6H2,1H3
Std. InChIKey: SDMKEQYHISDGKT-UHFFFAOYSA-N
Systematic Name: 2-Bromo-3-hexyl-5-iodothiophene

2-Bromo-3-hexyl-5-iodothiophene Specification

2-Bromo-3-hexyl-5-iodothiophene (CAS No.160096-76-4), its synonym is 2-Bromo-5-iodo-3-hexylthiophene .

Product Name

2-Bromo-5-iodo-3-hexylthiophene

Synthetic route

2-Bromo-3-hexyl-5-iodothiophene Chemical Properties

2-Bromo-3-hexyl-5-iodothiophene Specification

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