5,10-Dimethyldihydrophenazine supplier

Name
5,10-Dimethyldihydrophenazine
EINECS
CAS No. 15546-75-5
Article Data13
CAS DataBase
Density 1.117 g/cm³
Solubility
Melting Point 150-152 °C (dec.)(lit.)
Formula C₁₄H₁₄N₂
Boiling Point 339.426 °C at 760 mmHg
Molecular Weight 210.279
Flash Point 149.748 °C
Transport Information UN 2811 6.1/PG 3
Appearance Yellowish crystal
Safety 26-28-36/37/39-45
Risk Codes 23/24/25-36/37/38
Molecular Structure
Hazard Symbols T
Synonyms 5,10-Dihydro-5,10-dimethylphenazine;5,10-Dimethyl-5,10-dihydrophenazine;N,N'-Dimethylphenazine;NSC 149969;
PSA 9.86000
LogP 3.23220

Synthetic route

: 5,10-dimethyl-2,3,5,10-tetrahydro-phenazine

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

Conditions

Conditions	Yield
Lufteinwirkung;

: 2836-03-5
N,N-dimethyl-1,2-phenylenediamine

: 765-87-7
cyclohexane-1,2-dione

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

Conditions

Conditions	Yield
With sodium acetate; acetic acid

: 92-82-0
Phenazin

: 74-88-4
methyl iodide

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

Conditions

Conditions	Yield
With potassium

: 613-32-1
5,10-dihydrophenazine

: 74-88-4
methyl iodide

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

Conditions

Conditions	Yield
With n-butyllithium In 1,2-dimethoxyethane; hexane for 0.833333h; Ambient temperature;	2.1 g
Stage #1: 5,10-dihydrophenazine With sodium In tetrahydrofuran; toluene at 20℃; Inert atmosphere; Stage #2: methyl iodide In tetrahydrofuran; toluene Inert atmosphere;

5-methyl-phenazinium-methyl sulfate: 5-methyl-phenazinium-methyl sulfate

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

Conditions

Conditions	Yield
With methyl magnesium iodide; diethyl ether

: 74-88-4
methyl iodide

dilithium-compound of 5,10-dihydro-phenazine: dilithium-compound of 5,10-dihydro-phenazine

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

Conditions

Conditions	Yield
With 1,2-dimethoxyethane

: 74-88-4
methyl iodide

disodium-compound of 5,10-dihydro-phenazine: disodium-compound of 5,10-dihydro-phenazine

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

Conditions

Conditions	Yield
With 1,2-dimethoxyethane

: 74-88-4
methyl iodide

lithium-compound of 5-methyl-5,10-dihydro-phenazine: lithium-compound of 5-methyl-5,10-dihydro-phenazine

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

5-methyl-phenazinium-methyl sulfate: 5-methyl-phenazinium-methyl sulfate

A: 20057-16-3
fully reduced 5-methylphenazinium

B: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

Conditions

Conditions	Yield
With methyl magnesium iodide; diethyl ether anschliessend Behandeln mit H2O;

: 765-87-7
cyclohexane-1,2-dione

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: aqueous HCl 2: Lufteinwirkung View Scheme

: 3213-79-4
N,N'-dimethyl-1,2-phenylenediamine

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: aqueous HCl 2: Lufteinwirkung View Scheme

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

: 189114-61-2
silver(I) triflimide

: N,N'-dimethyl-5,10-dihydrophenazine-5-ium-5-yl bis(trifluoromethanesulfonyl)imide

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 1h;	93%

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

: C14H13Br2N2P

Conditions

Conditions	Yield
With phosphorus tribromide In pyridine at 20℃; for 12h;	78%

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

A: 63508-56-5
10-methyl-2(10H)-phenathiazineone

B: 92-82-0
Phenazin

Conditions

Conditions	Yield
With hydrogen bromide; dimethyl sulfoxide at 100 - 110℃; for 2h; oxidative demethylation;	A 12% B 77%

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

: C14H12Br4N2P2

Conditions

Conditions	Yield
With phosphorus tribromide In pyridine at 115℃; for 36h;	75%

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

: 31102-98-4
2-formyl-5,10-dimethyl-5,10-dihydrophenazine

Conditions

Conditions	Yield
With trichlorophosphate In 1,4-dioxane Ambient temperature;	66%
With trichlorophosphate In 1,4-dioxane Mechanism;	63%
With trichlorophosphate In 1,4-dioxane	63%
With trichlorophosphate In 1,4-dioxane Mechanism;
With sodium acetate; trichlorophosphate In 1,4-dioxane at 20℃;

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

: 670-54-2
ethenetetracarbonitrile

: 83720-88-1
2,2'-(2,3,5,10-tetrahydro-5,10-dimethylphenazine-2,3-ylidene)bis(propanedinitrile)

Conditions

Conditions	Yield
In acetone various solvents, reaction in aerobic and anaerobic conditions, effect of reaction conditions on the nature of the reaction products;	22%
In acetone	22%

: 92-82-0
Phenazin

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

: 1518-16-7
7,7',8,8'-tetracyanoquinodimethane

: 74515-57-4
3C14H14N2*2C12H8N2*5C12H4N4

Conditions

Conditions	Yield
In acetone cooling within few hours;

...Expand

: 99-65-0
meta-dinitrobenzene

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

: 125106-16-3
5,10-Dimethyl-5,10-dihydro-phenazine; compound with 1,3-dinitro-benzene

Conditions

Conditions	Yield
In acetonitrile

: 100-25-4
para-dinitrobenzene

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

: 125106-15-2
5,10-Dimethyl-5,10-dihydro-phenazine; compound with 1,4-dinitro-benzene

Conditions

Conditions	Yield
In acetonitrile

: 99-35-4
1,3,5-trinitrobenzene

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

: 125106-14-1
5,10-Dimethyl-5,10-dihydro-phenazine; compound with 1,3,5-trinitro-benzene

Conditions

Conditions	Yield
In acetonitrile

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

: 1518-16-7
7,7',8,8'-tetracyanoquinodimethane

: 2531-30-8
2-(4-Dicyanomethylene-cyclohexa-2,5-dienylidene)-malononitrile; compound with 5,10-dimethyl-5,10-dihydro-phenazine

Conditions

Conditions	Yield
In acetonitrile
With Phenazin In acetone for 24h; slow cooling;

: 129-79-3
2,4,7-trinitrofluorene-9-one

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

: 125106-13-0
2,4,7-Trinitro-fluoren-9-one; compound with 5,10-dimethyl-5,10-dihydro-phenazine

Conditions

Conditions	Yield
In acetonitrile

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

: 670-54-2
ethenetetracarbonitrile

: 83720-87-0
5,10-Dimethyl-5,10-dihydro-phenazine; compound with 2,3-dicyano-but-2-enedinitrile

Conditions

Conditions	Yield
In acetonitrile

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

: 670-54-2
ethenetetracarbonitrile

: 83720-87-0
5,10-Dimethyl-5,10-dihydro-phenazine; compound with 2,3-dicyano-but-2-enedinitrile

Conditions

Conditions	Yield
In toluene; acetonitrile for 3h;

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

: 712-74-3
1,2,4,5-tetracyanobenzene

: 102964-35-2
5,10-Dimethyl-5,10-dihydro-phenazine; compound with benzene-1,2,4,5-tetracarbonitrile

Conditions

Conditions	Yield
In acetonitrile

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

: 1172-02-7
9-dicyanomethylene-2,4,7-trinitrofluorene

: 125106-12-9
2-(2,4,7-Trinitro-fluoren-9-ylidene)-malononitrile; compound with 5,10-dimethyl-5,10-dihydro-phenazine

Conditions

Conditions	Yield
In acetonitrile

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

: 118-75-2
chloranil

: 125106-11-8
5,10-Dimethyl-5,10-dihydro-phenazine; compound with 2,3,5,6-tetrachloro-[1,4]benzoquinone

Conditions

Conditions	Yield
In acetonitrile

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

: 99794-32-8
benzo<1,2-c:4,5-c'>bis<1,2,5>thiadiazole-4,8-diylidenebis(malononitrile)

: 104792-52-1
2-(8-Dicyanomethylene-8H-benzo[1,2-c;4,5-c']bis[1,2,5]thiadiazol-4-ylidene)-malononitrile; compound with 5,10-dimethyl-5,10-dihydro-phenazine

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

: 83720-87-0
5,10-Dimethyl-5,10-dihydro-phenazine; compound with 2,3-dicyano-but-2-enedinitrile

: 83720-86-9
C19H15N5O

Conditions

Conditions	Yield
With oxygen In ethanol

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

: 84-58-2
2,3-dicyano-5,6-dichloro-p-benzoquinone

: 125106-10-7
5,10-Dimethyl-5,10-dihydro-phenazine; compound with 4,5-dichloro-3,6-dioxo-cyclohexa-1,4-diene-1,2-dicarbonitrile

Conditions

Conditions	Yield
In acetonitrile

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

: 109-77-3
malononitrile

: 83720-90-5
2-(10-(methylphenazine)-2-ylidene)propanedinitrile

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

: 106-51-4
p-benzoquinone

: 125106-17-4
5,10-Dimethyl-5,10-dihydro-phenazine; compound with [1,4]benzoquinone

Conditions

Conditions	Yield
In acetonitrile

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

: C14H14N2(1+)*BF4(1-)

Conditions

Conditions	Yield
With nitrosonium tetrafluoroborate; trifluoroacetic acid In acetonitrile

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

: C14H14N2(1+)*Cl2O2P(1-)

Conditions

Conditions	Yield
With N,N-dimethyl-formamide; trichlorophosphate In benzene

: 15546-75-5
5,10-dihydro-5,10-dimethylphenazine

: 5,10-dihydro-5,10-dimethylphenazine radical cation

Conditions

Conditions	Yield
With 1,1,2,2-tetraisopropylhydrazine radical cation; tetrabutylammonium perchlorate In acetonitrile at 25℃; Rate constant; single electron transfer, other reagents;

5,10-Dimethyldihydrophenazine Chemical Properties

Molecular Structure of 5,10-Dimethyldihydrophenazine (CAS NO.15546-75-5):

IUPAC Name: 5,10-dimethylphenazine
Empirical Formula: C₁₄H₁₄N₂
Molecular Weight: 210.2744
H bond acceptors: 2
H bond donors: 0
Freely Rotating Bonds: 0
Polar Surface Area: 6.48 Å²
Index of Refraction: 1.615
Molar Refractivity: 65.73 cm³
Molar Volume: 188.1 cm³
Surface Tension: 41.3 dyne/cm
Density: 1.117 g/cm³
Flash Point: 149.7 °C
Enthalpy of Vaporization: 58.29 kJ/mol
Boiling Point: 339.4 °C at 760 mmHg
Vapour Pressure: 9.2E-05 mmHg at 25°C
Melting point: 150-152 °C (dec.)(lit.)
Product Categories: Heterocyclic Building Blocks; N-Containing;Others

5,10-Dimethyldihydrophenazine Safety Profile

Hazard Codes: Toxic T
Risk Statements: 23/24/25-36/37/38
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-28-36/37/39-45
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S28:After contact with skin, wash immediately with plenty of soap-suds.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR: UN 2811 6.1/PG 3
WGK Germany: 3
HazardClass: 6.1(b)
PackingGroup: III

5,10-Dimethyldihydrophenazine Specification

5,10-Dimethyldihydrophenazine , with CAS number of 15546-75-5, can be called phenazine, 5,10-dihydro-5,10-dimethyl- ; 5,10-Dihydro-5,10-dimethylphenazine ; 5,10-dihydro-5,10-dimethylphenazine 98% .

Product Name

5,10-Dimethyldihydrophenazine

Synthetic route

5,10-Dimethyldihydrophenazine Chemical Properties

5,10-Dimethyldihydrophenazine Safety Profile

5,10-Dimethyldihydrophenazine Specification

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